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By A Califice, E Pirard, M Benzaazoua, R Mermillod-Blondin

Image analysis is more and more considered as a powerful tool for quantitative analysis of ores and concentrates. Apart from being very much dependent upon the quality of the imaging principle and the adequacy of the imaging sensor, quantitative image analysis is also the result of a long chain of material, image and pixel sampling strategies. The most reliable way to demonstrate the accuracy and the precision of modal analysis obtained from images is probably to use a blended material with known proportions of pure minerals and confront the results obtained from different analytical tools. This operation has been performed on a series of mineral blends mimicking the tailings of a flotation operation in a plant operating on massive sulfide mineralisation. The intention was to be able to better predict acid mine drainage potential from direct mineralogical observations. Selected sulfide minerals: pyrite (Py), pyrrhotite (Po), chalcopyrite (Cp) and sphalerite (Sp) were mixed as variable amounts within gangue minerals (quartz, calcite, dolomite and siderite). Typical blends contained six to ten per cent (Py); one to three per cent (Po); 0.5 to one per cent (Cp, Sp); 15 to 40 per cent carbonates and 40 to 75 per cent quartz by mass. The 1000 gram blends were carefully sampled and prepared for X-ray diffraction, chemical analysis by ICP-AES and optical microscopy image analysis (OMIA). Results obtained for the different analytical techniques are compared and discussed revealing the limits and strength of each method in the accurate quantification of sulfide and gangue minerals.

Jan 1, 2008

By Stille H

The choice between drill and blast and mechanical boring methods is often not obvious. There are several factors which may have a de- cisive influence on this choice, such as the geometry and length of the tunnel, site con- ditions and borability of the rock. Both the un- confined compression strength and the joint dis- tance have a considerable influence on the net penetration rate. Site conditions, rock quality and water conditions influence the utilization of the tunnel boring machine. The drill and blast method is normally less sensitive to devi- ations from assumed ground conditions.

Jan 1, 1987

By B G. Lottermoser

Phosphate induced stabilisation has been used to create passive iron phosphate coatings on pyrite and pyrrhotite. The formation of solid phosphate coatings on sulfide grains thereby inhibits sulfide oxidation. The aims of the study were to determine whether phosphate induced stabilisation could control sulfide oxidation and metal mobility in partly oxidised, polymineralic, sulfidic mine wastes. Waste materials were obtained from the acid mine drainage generating, abandoned Montalbion silver mine site, far north Queensland, Australia. The waste consists of quartz, kaolinite/illite, sulfide minerals (galena, chalcopyrite, tetrahedrite, sphalerite, pyrite, arsenopyrite), and pre- and post-mining oxidation products (hydrated Fe, Cu, Pb and alkali mineral salts). SEM observations of waste material treated with potassium orthophosphate showed that metal, metal-alkali and alkali phosphate coatings developed on all sulfides (with the exception of tetrahedrite). The abundance of phosphate phases was dependant on the availability of cations in solution for complexation with the phosphate anion. In turn, the release of cations was dependent on sulfide oxidation or the dissolution of efflorescent mineral salts. Experiments aiming to dissolve these phosphate coatings û using a strongly oxidising solution û showed that the phosphate coatings remained stable, preventing acid generation and metal release. The results of this study demonstrate that liquid phosphate stabilisers can suppress sulfide oxidation and immobilise metals in partly oxidised, polymineralic mine wastes.

Jan 1, 2003

 Increasing concern about the impact of alluvial mining discharges on the water quality of some West Coast rivers lead to a joint West Coast Gold Miners Associate, Trade and Industry funded study by Water Technology (NZ) Ltd. The objective of the study was to assess the treatability of West Coast alluvial gold mining discharges and to develop simple treatment systems which could be effectively adapted to a variety of sites in the region.   The approach was to apply standard water treatment techniques to field situations using low cost technology. Initially the various types of alluvial gold mining operations were identified then after preliminary site investigations and laboratory studies were carried out, site pilot plants were set up. The results of the trials particularly those using chemical aids were encouraging and it was found that chemical aid performance was largely dependent on the degree of mixing at and downstream of the chemical addition point. Design alterations to settling pond configurations in conjunction with optimised chemical addition yielded dramatic results in the form of reduced effluent turbidities.   A generalised approach to effluent treatment was developed and some of the specific 'mix and match' requirements were identified for different types of sites. The general conclusion is that improved physical treatment combined with good plant management and operation and (where necessary) chemical treatment, will produce water of acceptable discharge quality.

Jan 1, 1989

Most internationally traded iron ore resources are derived from multiple mine sites, transported to a port facility where they are blended and possibly further processed prior to shipping. Provided the proportion of contributions varies over a number of shipments an estimate can be made of the bias introduced by mine site sampling, analysis and materials handling systems, using zero-intercept multiple linear regression. Further regression applied to the residuals allows the error variances for the source mines to be estimated. Various sampling strategies are used by the industry. All have shipment-loading sampling on which payment or at least provisional payment is based. In most cases sampling prestockpile is used at mine sites to verify estimated production grades. Train grades are estimated from mine stockpile grades and in some cases train grades are verified by port input sampling. The methodology used is presented in this paper. Simulated data have been used and do not reflect the actual performance of any operator. The merits of the various systems and the implementation and potential limitations of our method are discussed more fully in a companion paper (Ziegelaar and Everett, 2010).

Mar 1, 2010

By L C. Thompson

Biomineralisation is the process by which microorganisms mediate and catalyse inorganic reactions so as to form new mineral assemblages. The goal of biomineralisation as a remediation tool is to control microbial processes and their environment so as to sequester and immobilise specific toxic metals within exceptionally strong bonds of neo-formed mineral assemblages. In this way, the bound metals are no longer mobile within a geological time-scale. Applied biomineralisation uses microorganisms, which are isolated from a metal waste environment and are selected for their ability to rapidly catalyse neo-mineral development from dissolved or leachable metals. A typical waste environment will contain microbes that contribute to the mobilisation of metal contaminants as well as microbes that possess the potential for remineralising available metals. Selection and augmenting the correct combination of bacteria and eliminating the competing mineral degrading reactions are the key to applying biomineralisation as an in situ remediation process. Applied biomineralisation harnesses the microbesÆ ability to stabilise toxic soluble metals into non-mobile mineralassemblages. This paper will discuss and demonstrate the biomineralisation process through several case studies including the Summitville mine site in Colorado, the McCoy-Cove mine in Nevada, the Argonaut mine in California, and an historic lead site in Crooksville, Ohio.

Jan 1, 2004

By Khosrowshahi S

The objectives of grade control remain unchanged but new methods are being developed to attain them. Since the early-1990s, an improvement in the power of mine site computers has made the geostatistical tools of conditional simulation more accessible. Optimisation of the grade control process on mine sites now involves two stages: optimisation of the sampling regime and optimisation of the interpretation of ore and waste boundaries. Optimisation of the sampling regime first requires an understanding of the nature of the mineralisation and in particular the impact of particle size on the sampling precision. This relationship, termed the Fundamental Error of sampling, enables an optimum subsampling protocol to be defined for the sample preparation and assaying. However, the actual sample collection method, whether drilling or trenching, must be correctly selected and the sampling grid should be optimised. The relative costs and benefits of various alternative sampling methods and grids can be determined using the method discussed. The use of the grade control data can also be optimised. In the past ore and waste boundaries were often defined using a linear interpolation algorithm that smoothed the data (such as polygonal, sectional, inverse distance squared or even kriging methods). Frequently the relative impact of ore loss and dilution could not be estimated. Conditional simulation to generate equiprobable alternative maps (realisations) can now be adopted to address these issues. A transfer function is then used to evaluate the similarities and differences between the maps. The Ore Block Optimisation (OBO¬) process is a transfer function that produces a three-dimensional model of the optimal ore block outlines. This provides a clear guide for the mining geologist to refine and mine. The nature of the transfer function and the inputs and outputs are discussed. In the past, reconciliation has been the `acid test' for any grade control system. Any ore blocking method based on conditional simulation can make use of the exhaustive data set to ensure that reconciliation between prediction and production will improve significantly. The OBO¬ method provides a guide to the mining geologist to ensure that the best ore blocks are mined. Misclassification between ore and waste is reduced, ore loss and dilution are minimised (and are measurable) and ore is optimally assigned to stockpiles of various cut-off grades. These advantages significantly enhance mine profitability and control of the mined grade.

Jan 1, 1997

By Fuerstenau DW

The flotation of pyrite in ethyl xanthate solutions is presented along with electrokinetic results. The results have been analysed in view of recently published thermodynamic calculations as well as other published data on the pyrite-xanthate system including adsorption and voltarnmetry studies. The flotation response of pyrite in xanthate solutions is characterised by two maxima, one at pH 4 and the other at pH 8-9. The acidic maxima is also associated with a reversal in the electrophoretic mobility of pyrite, probably due to the formation of ferric xanthate on the pyrite surface through chemisorption of xanthate ions while the basic maxima is not associated with major changes in the mobility and flotation at this pH can probably be attributed the adsorption of dixanthogen. It is concluded that there is not sufficient experimental evidence to conclusively attribute the lack of flotation response in solutions at near neutral pH to any particular phenomena, either kinetic or thermodynamic.

Jan 1, 1993

By F Cesnik, P Griffin, S Green

In July 2004 a flotation concentrate regrind circuit was commissioned in the æHigh GradeÆ Ridgeway concentrator at NewcrestÆs Cadia Valley Operations. This was the culmination of two years of project testing, process design and planning which commenced shortly after commissioning the concentrator in March 2002. During the two-year project evolution alternative grinding technologies were evaluated from conventional ball milling through to sand milling. A Detritor mill was eventually selected for the duty and the criteria on which this selection was based will be presented. As the project evolved so too did the equipment sizing with the concentrator quickly exceeding design capacity of 4 Mtpa and currently averaging 5.6 Mtpa, the process design had to accommodate this and future potential throughput increases. This paper will focus on the supporting testwork, circuit surveys and concentrate properties which were used as the design basis for the project. The economic evaluation which led to the project receiving board approval in November 2003 will also be presented. Detailed design and construction management issues will be discussed as will preliminary results and findings up to November 2004.

Jan 1, 2005

How often does one hear that a recent feasibility study was not a success? Alternatively, when scope of the feasibility study was sent out to tender there was a large discrepancy in tendered prices. If the tendered prices were to be compared to the consumer market, for instance the purchase of a car, where the concept is transport in a controlled and safe manner, prices vary by large factors, but then so do the specifications. In the case of a feasibility study, prices should be within a tighter margin as the tenderers are all quoting against the same concept and specification. Why do these discrepancies occur? Price discrepancies will in every likelihood be attributed to two main factors; one, the perceived amount of work and two, the ability of the bidder to carry the risk associated with the feasibility study. It is, therefore, important that the scoping of the feasibility study covers the detailed requirements as clearly as possible stating what level of accuracy is required. The feasibility study is one of the first activities in the life of a project. The study, like the project it is investigating, is subject to the constraints of time, cost and quality. Its primary objectives are to demonstrate the viability of a project within the outlined scope and constraints.

Jan 1, 1998

By Buisman C. J N, Koch R. O

Soil and groundwater beneath the Budelco zinc production plant at Budel-Dorplein (The Netherlands) are contaminated with metals and sulphate. To avoid contamination of nearby drinking water aquifers in the very distant future, a geohydrological containment system (GCS) and a microbial treatment plant for extracted contaminated groundwater have been developed. As a first step in the design of the system groundwater data from over 150 wells and geological profiles were used to model geohydrological conditions beneath the site. Several configurations of water-extraction wells were deduced from the model. Data gathered during additional fieldwork were then used to improve the model. Finally results that were calculated for the various configurations were used to select an optimal groundwater containment system. Currently some 5000 m3/day groundwater are extracted from a combination of 12 shallow and deep wells. Heavy metals and sulphate have to be removed from the extracted water before it can be discharged into the river system or used as process water. Several water treatment methods have been studied and pilot-tested at the site. The preferred and selected process is based on the activity of sulphate reducing bacteria (SRB) and combines sulphate removal and heavy metal removal in one single step. The anaerobic bacteria reduce the sulphate to sulphide resulting in the precipitation of metal sulphides. A pilot plant gave promising results and a commercial-scale plant has been designed. The proposed design has been tested in a demonstration plant which included all main process units. Test results for all process units are presented. The collected information was then used to optimise the design of the commercial-scale plant. Special attention was paid to automation and safety items. Construction of the plant was finished in May 1992. Start-up, commissioning and operational experience are reported. The concentrations of metals and sulphate in the effluent of the SRB water treatment plant are well within the limits set by the authorities for discharge to public waters.

Jan 1, 1993

The CSIRO acid alumina employs the essential steps of digestion, hydrolysis and calcination to produce pure alumina from ores too high in silica or too low in grade for the Bayer process. The two latter stages have been described in some detail previously but the digestion stage requires separate dis-cussion since ores vary widely in composition and reactivity. Kaolinitic clays require. roasting to 8000C to render the alumina soluble in the 11 per cent sulphuric acid used in the process while some ferruginous laterites require roasting to reduce the reactivity of iron minerals. The iron content of pregnant solutions is kept at a low figure by digesting at temperatures where the solubilities of ferric oxide or basic ferric sulphates are small. A.two-stage, counter-current digestion is necessary to extract a high percentage of alumina from the ores and to pro-duce a basic pregnant liquor, with an S03:Al203 ratio of 1. 9 suitable for high temperature hydrolysis. The second stage of digestion, called the modification stage, treats slightly acid liquors with exces's of ore in the temperature range 1200- 1400C. The first stage operates at 1700-190 C to extract further alumina from modification residues, using recycled acid obtained from later steps of the process. Both temperature ranges are critical for economic operation and for proper con-trol of the iron content of solutions. In batch experiments, thirty minutes is regarded as a suitable retention time for digestion and modification; ores which require much longer than this are less suitable for the process. Impurities. such assilica, titanium and vanadium oxides are discarded in the residue along with iron oxide and do not contaminate the final product. Bivalent metallic sulphates such as MgSO4 can build up in the circuit to a very considerable degree without affecting. product purity.Comparison with other processes shows that the C. S. I. R. O. process is superior for control of contamination by iron, which is the major problem in acid processes. The pure intermediate product (3 A1203. 4 S03. 9 H2O) is also more convenient for cal-cination to alumina than the hydrated aluminium sulphate usually recovered in other processes. Detailed cost comparisons must await pilot-plant evaluation of the C. S. I. R. O. process.

Jan 1, 1963

By G D RICHMOND, Campbell J. J

Aberfoyle Limited has developed the Hellyer complex base metal sulphide deposit located in North West Tasmania. As part of exploration and feasibility study, the ore was extensively tested, including trial milling, and was found to be very fine grained and to have poor flotation selectivity. Substantial innovation was required to produce saleable concentrates at acceptable recoveries and costs. Efforts were made to reduce operating costs, to improve metallurgical performance and to improve work organisation. These efforts were pursued both in design and in subsequent plant operation. This work has resulted in a very competitive operation with production costs in the lowest quartile of the industry. Examples of the measures taken are presented and the results are evidenced by improved plant performance since commissioning.

Jan 1, 1992

By P A. Grossman, J H. Rubinstein, M Brazil, D Whittle

Many ore reserves are harvested by a combination of open pit and underground mining methods. In these cases, there is often material that could be mined by either method, and a choice has to be made. The area containing this material is referred to as the transition zone. Deciding where to finish the open pit and start the underground mine is referred to as the transition problem and it has received some attention in the literature since the 1980s.In this paper, we provide a review of existing approaches to the transition problem encompassing: graph theory-based optimisation employing an opportunity cost approach, heuristics and integer programming. We also present a novel opportunity cost approach, that takes into account a crown pillar, and show how the new approach can be best applied through the unconventional application of an existing mine optimisation tool.CITATION:Whittle, D, Brazil, M, Grossman, P A, Rubinstein, J H and Thomas, D A, 2016. Determining the open pit to underground transition – a new method, in Proceedings Seventh International Conference and Exhibition on Mass Mining (MassMin 2016), pp 731–742 (The Australasian Institute of Mining and Metallurgy: Melbourne).

May 9, 2016

By A Havenga, F, J Hough, R Grobbelaar

After the closure of mines they naturally start to fill up with water. As a result, hydraulic gradients develop between adjacent mines and different hydraulic water pressures are exerted onto peripheral areas or compartments within mines. This results in water flow between mines, or onto the surface. This flow is referred to as intermine flow. The geometry of the collieries in the central Witbank Coalfield make intermine flow possible in several areas. Since the Department of Water Affairs and Forestry declared intermine flow as one of its greatest concerns for granting closure to South African mines, much research into this phenomenon has been undertaken. The importance of the quantification lies in the DepartmentÆs goal of sustainable water management, and the possible long-term financial implications these flows could have for individual mines. The challenges of determining intermine flow are numerous, and attention is focused on the identification of areas where these flows can take place. Detailed mining plans on a regional scale are required, and detailed coal-seam floor data are combined to provide targets for possible interaction between these mines. The quantification of these flows is problematic due to the uncertainties regarding geometrical configurations and the variation in site-specific hydraulic characteristics of the coal and overlying lithilogical layers. To this end, use has been made of several analytic solutions and numerical flow modelling. Stage curves (volume versus elevation curves) for the opencast and underground workings have been calculated and first-order estimates for intermine flow or decant from these areas have been determined. The numerical modelling methodology entailed a down-scaling approach, starting with a broad regional model covering the entire area, followed by modelling the interactions between interconnected mines and finally looking in detail at the major areas of interaction. By considering different scenarios within the context of these flows, possible management options for intermine flow can be evaluated in terms of volumes and qualities that might emanate in the post-closure phases. Challenges for the future include obtaining site-specific information on the groundwater hydraulics and acceptable ranges for model parameters, and verifying model results over time.

Jan 1, 2003

The following is an outline of the main metallurgical process developments which have occurred at Port Pirie during more than 100 years of smelting. Emphasis is placed on those process developments which evolved from research and development at Port Pirie, rather than those based upon purchased or established technology and straightforward plant engineering. Most processes involved have undergone major change and improvement through the efforts of Port Pirie staff. A culture of metallurgical research and development evolved strongly during the years when G K Williams made such a great impact, and continued for half a century. This culture involved strong links with external research bodies, particularly universities. A near complete bibliography of these developments is provided, together with a listing of patents. Research and development by The Broken Hill Associated Smelters Pty Ltd commenced in 1918 at South Melbourne, and after transfer to Port Pirie in 1921, continued there until 1989. Three periods of highly successful innovation resulted ù that of G K Williams into the 1930s, the post-war period until about 1962 and the period with developments led by Denby H Ward from about 1970 to 1985.

Jan 1, 2000

By G Brewster

The Eagle on the Hill tunnels form part of an upgrade of Mt Barker Road, 15 km to the southeast of Adelaide. The upgrade significantly improves safety and reduces delays on this major road, which winds steeply through mountainous terrain. The twin tunnels each spanning 15 metres run in parallel for a length of 480 metres. The tunnels are excavated in slightly weathered high strength slates and very high strength quartzites of the Saddleworth Formation on the western margin of the Mount Lofty Ranges. Steeply dipping slate cleavages and the high fracture ratio result in many slope stability problems in the project area. The level of geotechnical investigation undertaken prior to the calling of tenders for the project was extensive. This included the excavation of a pilot tunnel along one of the tunnel alignments, which allowed accurate mapping and rating of the rock, resulting in an increased level of confidence during the tender process. One of the features of the winning alternative tender design was the use of canopy tubes, flexible steel ribs and shotcrete to replace up to 40 metres of deep portal cuts in unstable rock with driven tunnels. Slope stability issues were overcome with the use of rock dowels and shotcrete. The support concept allowed the safe driving of the tunnel portals with as little as two metres of overburden. The design incorporated lining drainage and criteria for fireproofing based on European experience to ensure the ability of the tunnels to remain stable in the case of a severe fire incident. The support design allowed for maximum flexibility with a range of support types able to deal with the varying ground conditions. Design development and support refinement continued throughout the tunnel construction phase with close liaison between the designer and the constructor. Monitoring and review of feedback from the construction site by the Sydney based design team was easily achieved by means of electronic transfer of photographic and survey information, telephone and fax communication and regular site visits. The contractor for this project is Macmahon Concrete Constructions Joint Venture (MCCJV) and the designer is Connell Wagner. Excavation commenced in January 1998 with tunnel breakthrough having been achieved in early-August 1998 and mid-September 1998 respectively. Concrete lining construction is scheduled for completion in April 1999.

Jan 1, 1999

By K Matsui, T Sasaoka, S Kubota, Y Yosh

A large amount of wastes from the preparation plant is produced. The properties of these wastes vary depending on the mineralogical contents of the mother rock in which the coal is embedded. The waste quality depends on the method of mining and cleaning. The waste mainly consists of clays, quartz, carbonaceous materials, mica, pyrites and so on. About 55 per cent of coal-ash is now utilised and the remains are disposed of at the disposal sites, however, the life of the disposal site is limited. Moreover, it is difficult to find new disposal sites. Therefore, it is requested that the percentage of the utilisation of the coal-ash be increased in every field in Japan. So, it is very much available if the injection material for natural/artificial openings can be applied on the cement that is added to flyash. Among the man-made pozzolans, a flyash is probably the most successful component used in grout injection. When flyash is added to Portland cement concrete, the same kinds of oxides as those of the cement are being added. As an injection component, flyash acts, in part, as a fine aggregate and, in part, as a binding component. However, there is not a substantial alteration of the properties of the original component. From these points of view, in order to clarify to what degree the flyash content affects the properties of the injected grout mixture; different combinations of flyash, Portland cement and water were considered by means of several experiments.

Jan 1, 2003

Hamersley Iron Pty. Limited mines and pro cesses iron ore from two orebodies at Tom Price and Paraburdoo, situated in the North West of Western Australia. Conventional open pit mining methods are used at both sites in that material is drilled and blasted in benches, loaded by shovels and hauled to the Primary Crushers or dumped on waste or low grade material stockpiles. The present drilling fleet, consisting of eight high capacity Bucyrus Erie Rotary drills has evolved from an initial fleet of a large number of small percussion rigs. There are significant physical differences between the ore types encountered at both mines which nec- essitate the drilling of smaller diameter blast holes at Paraburdoo than those at Tom Price. The drilling practice at each site is dis- cussed, with examples of performance achieve- ments under varying drilling conditions.

Jan 1, 1978

By K Friese, H P÷llmann

Clinoptilolites, modified with sodium, produced a material which has been tested for the ability to remove Hg (II) from aqueous nitric acid. The amount of adsorption depends on contact time, acid concentration of aqueous solution and initial mercury concentration. The study of the kinetics of mercury uptake revealed that all sorbents exhibit a fast rate of sorption. The highest sorption capacities were observed for sodium forms, and were up to five times higher than for the unmodified zeolite. The maximum sorption capacity toward mercury is determined as 0.093 ¦g/g at an initial concentration of 10.0 ¦g/L for a clinoptilolite from Tsagaantsav deposit (Mongolia). The sorption of Hg (II) has an ion-exchange nature and consists of three stages, ie the adsorption on the surface of microcrystals, the inversion stage and the ion exchange in the interior of the microcrystal. Sorption capacity decreases with the increase of mercury concentration. The presence of other metal ions such as Cd (II), Cu (II), Ni (II) and Zn (II) increases Hg (II) uptake capacity. Finally, sorption for Hg (II) was investigated in batch systems to evaluate the short-term stability of the sorption properties.

Jan 1, 2008