The Mechanism of Xanthate Adsorption on Pyrite

The flotation of pyrite in ethyl xanthate solutions is presented along with electrokinetic results. The results have been analysed in view of recently published thermodynamic calculations as well as other published data on the pyrite-xanthate system including adsorption and voltarnmetry studies. The flotation response of pyrite in xanthate solutions is characterised by two maxima, one at pH 4 and the other at pH 8-9. The acidic maxima is also associated with a reversal in the electrophoretic mobility of pyrite, probably due to the formation of ferric xanthate on the pyrite surface through chemisorption of xanthate ions while the basic maxima is not associated with major changes in the mobility and flotation at this pH can probably be attributed the adsorption of dixanthogen. It is concluded that there is not sufficient experimental evidence to conclusively attribute the lack of flotation response in solutions at near neutral pH to any particular phenomena, either kinetic or thermodynamic.