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By H. M. Krieg, M. J. Ungerer, C. G. C. E. van Sittert, D. J. van der Westhuizen

"The transition metals tantalum (Ta) and niobium (Nb) are of significant importance, for example in the nuclear energy sector where they are used as cladding materials, as well as in capacitors and specialized materials. For these applications a high-purity metal is needed. The separation of Ta and Nb is always a challenge since they are found together in nature and have similar chemical and physical properties, resulting in costly and laborious separation processes. A technology that has been used successfully for the separation of these metals entails solvent extraction (SX)1. While separation was achieved in a previous SX study using a sulphuric acid (H2SO4) medium with the extractants diiso-octyl phosphinic acid (PA) and di-(2-ethylhexyl) phosphoric acid (D2EHPA), due to the absence of speciation data for Ta and Nb it is not clear how the separation occurred.One method that might be suitable for determining the speciation of a reaction is molecular modelling. Calculations based on the densityfunctional theory (DFT) are now used not only for light elements and small molecules, but also metal complexes, heavy metals, and especially metal separation in SX2. In this study the aqueous phase used during SX was investigated by studying periodic systems of Ta, as a metal and in salt form, when it is in contact with H2O and H2SO4. The results were used to predict the reaction mechanism occurring during SX. Results showed that (i) in a 1:1 acid-water ratio, the deprotonation of H2SO4 was endothermic, (ii) in a 1:5 ratio deprotonation was exothermic forming HSO4 -, and (iii) in a 1:10 ratio double deprotonation occurred to form SO42- exothermically."

Jan 1, 2017

By Peter N. Calder, Alan Bauer

The complexity of modem open pit load-haul-dump systems is described, and the need for realistic working models is pointed out. Both standard and probabilistic simulation procedures are discussed, probabilistic simulation being indicated as the more powerful and practical technique. Acquisition of the necessary pit operating data required for simulator construction and general modelling procedures are described. Finally, results from a typical open pit simulator are used to indicate the scope of the technique.

Jan 1, 2014

By B. M. Kunar

It is well known that job-related hazards and individual factors influence occupational injuries. However, research involving coalminers has been limited. This case-control study assessed the relationships of job-related hazards and individual/life style factors with injuries among underground coal miners. It compared 245 cases with at least one injury during the previous two-year period with 245 matched controls with no injury. The data were gathered via personal interview and analysed using the conditional logistic model. The significant risk factors were materials handling (adjusted OR 5.15), poor environmental/working conditions (2.63), geological/strata control-related hazards (2.35), lack of formal education (3.00), sleep disorders (1.86), alcohol consumption (2.32), disease (2.23), having a large family (5.40), and risk-taking behaviour (9.40). Machine-related hazards, sleep disorders and alcohol consumption primarily affected workers aged less than 45 years; whereas, environment/working condition-related hazards, presence of disease, smoking, risk-taking behaviour and large family size were more likely among workers aged 45 or over. Keywords: Occupational injuries, sleep disorders, job hazards, alcohol, coal miners

Jan 1, 2010

By P. C. Seligmann

The theory of firing of electric detonators is developed insofar as it affects the design of blasting circuits. Practical values for the firing conditions suited to detonators of local manufacture are tabulated. The design principles of blasting circuits are outlined. This information can be used by mine management to ensure that electric blasting will be done efficiently and economically.

Jan 1, 1979

By L. Woollacott, R. P. King

This paper presents data collected from full-scale plants in order to verify the predictions of a new simulator of CIP or CL operations. Good agreement was found between the experimental data and the simulator predictions. The simulator is able to predict the effects of many of the complex operating phenomena in GIP and CL plants that previous simulation techniques could not describe. This is illustrated by predictions of how factors, such as the manner of carbon transfer, concurrent leaching, and gold loading on eluted carbon, can affect the performance of an adsorption plant.

Jan 1, 1990

By V. H. R. Brereton

The gold deposits of the farms Lisbon and Berlyn in the Eastern Transvaal by V. C. H. R. BRERETON* (Visitor) This paper describes the discovery and recovery of gold, over a period dating back to the 1870s. on the farms Lisbon and Berlyn, situated approxim ately 1I km north-east of Pilgrims Rest. where mining ceased in July 1971. 99 years after gold was first discovered in the Pilgrims Rest and Sabie districts. Included in the paper are accounts of the discovery and mining operations of the Lisbon-Berlyn Company from 1884 to 1890. The operations of small companies and syndicates. the superficial winning of gold by diggers, and the encouraging reports of four mining engineers in 1890 are also mentioned.

Jan 11, 1973

By A. V. L. Narasimham

The practice of refractory lining in Fe Cr furnaces is purely based on the behavior of various refractories used in different parts of the Furnace at elevated temperatures. The choice of the pattern of lining is mostly done on traditionally based concepts. Refractory Lining of a furnace is the most crucial enabler for operational excellence for Ferro Alloys production. During the last few years, no major technological change has taken place in ?Refractory Lining Management?, only freeze lining concept is becoming popular. Many ferro chrome furnaces today, have the refractory lining problems especially at tap holes, resulting in shutdowns and production losses. The author with his experiences for the last 37 years in furnaces of all sizes tried to attempt to investigate into the reasons for premature failure of lining.

Jan 1, 2007

By J. C. Zachariades, D. M. Fraser

The leaching of pyrolusite in acidic ferous sulphate solution was studied so that the important factors governing the kinetics of the reaction could be determined. The reaction is very rapid, and was monitored by continuous measurement and logging of the redox potential in solution by use of a microcomputer. The relationship between redox potential and manganese extraction was established empiricaly for each set of conditions by the use of a technique in which a calibration run was conducted in paralel with each leaching run. The study involved a number of batch leaching runs, and demonstrated that, of the variables investigated, only the initial ferous ion concentration and the reaction temperature afect the rate of manganese extraction. The final extraction did not vary. The reaction was modeled from the results by use of the shrinking-core model and Britan's activation-energy model. The later was found to provide a significantly better fit to the data.

Jan 1, 1991

By J. H. Bulloch

The paper gives an assessment of the available data on the linear elastic fracture mechanics involved in stress corrosion cracking and in the behaviour of reactor pressure-vessel materials exposed to a simulated pressurized water-reactor environment. As a result of the different experimental techniques used in the various studies mentioned, only a few detailed conclusions can be drawn. The data from constant-displacement wedge-opening loading (WOL) tests, with the exception of one study, exhibited very limited or no crack extension during exposure periods of up to 14000 hours. The data from constant-load tests indicated evidence of crack extension, but the nature and extent of the crack extension are still unclear. When crack extension did occur, it was exclusively transgranular in nature. Certain differences in the available test data are tentatively explained in terms of the experimental procedures used, and the need for a consistent code of experimental techniques is highlighted.

Jan 1, 1987

1. Book review • World mineral statistics 1974 to 1978. Production: Exports: Imports. London, H.M.S.O., Institute of Geological Sciences, 1980. (Reviewer: R. P. King) This edition is the third in a regular series prepared by the Institute of Geological Sciences. It is a useful compilation of statistics on the production, export, and import of fifty-eight different mineral commodities. Each mineral is listed by country, and a table is provided for the annual production, the annual imports, and the annual exports for each commodity included. However, some commodities are treated in considerably more detail; for example, aluminium and bauxite have tables under the following headings: Production of Bauxite, Production of Alumina, Production of Primary Aluminium, Exports of Bauxite, Alumina and Aluminium, Imports of Bauxite, Alumina and Aluminium. The information presented is the latest official information available from primary sources; the compilers have not relied on data from secondary compilations. This publication will be of considerable assistance to all who are concerned with the trading of mineral commodities and their production.

Jan 1, 1981

By Q. G. Reynolds

The dual-electrode DC arc furnace, an alternative design using an anode and cathode electrode instead of a hearth anode, was studied at small scale using computational modelling methods. Particular attention was paid to the effect of two key design variables, the arc length and the electrode separation, on the furnace behaviour. It was found that reducing the arc length to brush arc conditions was a valid means of overcoming several of the limitations of the dual-electrode design, namely high voltages and arc deflection.

Jan 1, 2012

By D. D. Howat, J. van der Colf

This paper is the first in a series of three dealing with this subject and also with the rate of oxygen removal from the slags in the presence of solid carbon and with the physicochemical properties of the reduced slags. For selected members of the system, the melting temperatures and primary crystallization products were determined. as were the viscosity and the electrical resistivity of the corresponding melts. All the experiments were conducted in a neutral atmosphere. Where determined, the primary phase was found to be either perovskite or magnesium aluminium titanate. The composition variable exerting the most pronounced influence on viscosity or resistivity was found to be the basicity expressed as the mass ratio (CaO + MgO)jSiO,. The ratio CaOjMgO became important only at Iow basi<:ity values. Although generally there is a direct proportionality between log (viscosity) and log (resistivity), slags h&apos;lving either a very high silica content or a very high titania content have anomalously Iow electrical resistance.

Jan 1, 1979

By A. Kijko, C. W. Funk

Methods for the analysis of seismic hazards in mines are reviewed as illustrations of the techniques that are being used in some South African mines. The classical parameters that describe a hazard are the seismic activity rate, ?, the Gutenberg-Richter value, b, and, occasionally, the maximum regional magnitude, mmax The activity rate is calculated readily owing to the inherent simplicity of its definition. The evaluation method presented for the Gutenberg-Richter b value takes into account the presence of mmax Three statistical procedures are described for the assessment of mmax which the maximum observed magnitude, Xmax a crucial role. Often, the configuration of mine seismic networks is changed, or the networks are improved, which inevitably gives rise to changes in the completeness of the seismic catalogues. The routine analysis of seismic hazards must account for these time dependent changes. A method for the evaluation of hazards is reviewed that accommodates varying levels of quality in the catalogues. Finally, the concept of the volume of ground motion (VGM) is presented. This is a technique that allows for most aspects of seismic hazards in mines. The advantage of the VGM is that a hazard can be described by one physically significant value: the volume of rock (cumulated over a time period) in which the ground motion exceeds some critical particle velocity. Data from the gold mining region in South Africa known as the Far West Rand is used in a demonstration of the discussed methods of hazard analysis.

Jan 1, 1994

By M. Kilfoil

Many minerals processing operations result in crushed rock being mixed with a liquid. Sometimes, the rock particles have to be dried before the next process begins and there may be a considerable distance between the equipment carrying out these processes. Bateman Engineered Technologies (BET) developed, patented and commercialized a method of simultaneous pneumatic conveying and drying. A joint project to assist with optimizing the process is under-way. Part of it is a numerical simulation of the process. The simulation is done using a dedicated program written in MATLAB, (commercial software which is widely used in engineering). It accounts for heat and mass transfer as well as particle transport. The main part of the program consists of a loop containing a series of equations which are evaluated sequentially. During any particular iteration, the properties are changed one at a time. Since the properties are changing relatively slowly, this method gives good results. The outputs of the simulation are consistent with the operational experience of BET’s engineers. The output is very comprehensive and all numerical. Since the program is currently being used for research purposes, flexibility is very important. Thus the output is converted into a spreadsheet file. Variations in the output quantities are displayed graphically using MS Excel. Some simulation could have been done using computational fluid dynamics (CFD) software. The advantages and disadvantages (technical, financial and skills requirements) of the two approaches for this particular type of simulation are compared briefly. Keywords: Pneumatic conveying, Heat and mass transfer, Computer model

Jan 1, 2003

By A. J. Vietti

"Drought conditions and the possible lack of sufficient raw water supply are a constant reminder to the Southern African diamond miner of the need to minimize raw (new) water input while maintaining or expanding mine throughput.Since water input volume is directly related to water output (loss) volume, mainly to the tailings, it is obviously beneficial to dewater the tailings as much as possible. However, this may not always be as easily achieved as first thought. Owing to the unique mineralogy of each kimberlite deposit and the unique chemical profile of each raw water source, dewatering of the slurry is not a standard process that can be applied equally across the entire diamond industry.This paper presents a first-step strategy that kimberlite diamond mine operators should consider and apply to meet and exceed their watersaving targets. Introduction A common metric for measuring water use efficiency in a metallurgical plant is the amount of raw water used per ton of head feed treated (m3/t). The metric includes all water recycled from the dewatering process and from the tailings storage facility (TSF), and the only inputs are tons of ROM ore and cubic metres of raw water make-up to replace water lost to evaporation, seepage, and lock-up at the TSF (Figure 1).The volume of new raw water available to the process is not unlimited and a maximum monthly allowance is typically set during the mine permitting process. Consequently, if the volume of water lost exceeds the volume of new water available or alternatively, in times of drought where the allowable volume is unavailable, the plant has no other option but to reduce throughput.However, if the plant operator is able reduce the volume of water lost to the TSF, the plant will have additional capacity to either increase tonnage throughput or sustain nameplate capacity during periods of severe drought. The obvious conclusion, therefore, is to reduce the volume of water lost to the tailings by improving the efficiency of the dewatering process (typically gravity thickening) simply by increasing the density of the tailings being discharged. In practice, however, the unique mineralogy of each kimberlite deposit and the chemical profile of the raw water source used imply that at some mine sites, solid/liquid separation (or settling) of tailings slurries at the dewatering process is more easily achieved than at others. In these cases, simple practical steps such as firstly improving the flocculant reagent make-up and dosing control, and secondly focusing on thickener discharge control, are the only requirements for enhancing water recovery at the dewatering circuit. At other mine sites however, solid/liquid separation of the tailings may not be achieved at all, in which case efforts to increase water recovery by improving reagent dosage and thickener control would be fruitless unless the colloidal properties of the thickener feed slurry are modified."

Feb 1, 2019

By P. Saari

The Talvivaara deposits are located in Eastern Finland, within the Kainuu Schist Belt. These polymetallic sulphide deposits are of relatively low grade, but bioheapleaching enables economically profitable nickel extraction from the ore. Zinc, cobalt, and copper are also produced. Talvivaara?s production process begins with large-scale open-pit mining and four crushing stages, followed by stacking of the ore in bioleaching heaps. The ore is first leached for 13?14 months on the primary leach pad, after which the leached ore is reclaimed, conveyed, and re-stacked on the secondary heap pad. After secondary leaching, the barren ore will remain on the secondary heaps permanently. In the metals recovery process, the metals are precipitated from the pregnant leaching solution. Construction of the process was begun in spring of 2007 and first metal sulphides were produced at the plant in October 2008. The development of the bioheapleaching process was begun in a 17 000t on-site pilot heap operated during 2005?2008 and has continued in the industrial heap. At industrial scale, the development measures have focused on improving the permeability and aeration of the heap. Challenges with crushing and aerations systems at the beginning of industrial-scale leaching delayed the increase in metal recovery, but after the first two operational years the leaching results have improved significantly and the process is performing as targeted.

Jan 1, 2012

By J H. Sullivan

Contents Background information Locality of Kumba?s Iron Ore Mines Sishen?s Product Specifications Geological Description of boreholes Sample Preperation Block delineations Production Geology Process Laboratory information Turnover times reached Inter Laboratory Comparisons Quality control activities in lab Purpose of laboratory Results attained Standard samples Monitoring of processes with QA/QC standards Mean paired difference of duplicates Duplicate samples Conclusion

Jan 1, 2005

While some of the practical details of ilmenite smelting are not well documented, there is a substantial body of literature on the principles of ilmenite smelting, and the behaviour of solidified titania slag. This information is summarized, focusing on the basic reactions, departure from equilibrium, the behaviour of impurities, and reactions of solidified slag. The emphasis is on the South African operations.

Jan 1, 2007

By D. E. Kraushaar

Ruhrkohle in West Germany evaluates and compares the net present values of long-term periods from its coal mines by a computer assisted long-term planning system. Two main parts of this system are computer programs for the prediction of: (a) mineable reserves and their distribution in longwall panels as a function of dependent geological variables; (b) daily outputs and costs of longwall panels as a function of dependent geo- logical, layout and operational variables. This paper describes the investigations, which ended in the above computer programs: ? the collection of information from past workings and their organization in databases; ? the statistical evaluation of the databases, and ? the resulting correlation formulas. The correlation formulas vary the mean dependent variables as a function of independent variables which can be indicated with high reliability for planning projects in the long run. The system thus serves the purpose of facilitating long-term planning and excluding biased individual judgement of local planning staffs.

Jan 1, 1987

By R. F. Taberer

Within the technology field generally known as biological heap leaching or percolation leaching, lies a wealth of technological knowhow that is potentially patentable and therefore can form the subject matter of patent applications. An organization often overlooks the potential for generating intellectual capital during its research by dismissing the possibility that what it is working on may be novel and inventive and therefore patentable. The organization labours under the misconception that there is nothing patentable in its work mainly because the novel aspect is overlooked against the general background state of the art or, if identified, is not recognized as having sufficient inventive merit. In the field of biological heap leaching, patents have issued on inventions that extend across a large range of technology, including microbiological inventions-for example a particular strain of microbe used in a heap leach application, electro-mechanical inventions, for example a column simulator that simulates the heap leach environment, and thermodynamic inventions such as methods of generating and maintaining heat in a heap.

Jan 1, 2012