Experimental and modeling studies of the kinetics in the leaching of pyrolusite

The leaching of pyrolusite in acidic ferous sulphate solution was studied so that the important factors governing the kinetics of the reaction could be determined. The reaction is very rapid, and was monitored by continuous measurement and logging of the redox potential in solution by use of a microcomputer. The relationship between redox potential and manganese extraction was established empiricaly for each set of conditions by the use of a technique in which a calibration run was conducted in paralel with each leaching run. The study involved a number of batch leaching runs, and demonstrated that, of the variables investigated, only the initial ferous ion concentration and the reaction temperature afect the rate of manganese extraction. The final extraction did not vary. The reaction was modeled from the results by use of the shrinking-core model and Britan's activation-energy model. The later was found to provide a significantly better fit to the data.