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By David Green

"This paper describes Outokumpu's Tank Cell concept using the unit reactor principle and operating experience gained in various applications. Presently the tank cells used range in size from 35 t pilot size to 100 m' (3500 cuft). The paper discusses operating experience and results from commercial installations in copper and zinc rougher and cleaner services.The key feature of the Tank Cell described is the effective control of the froth phase and resulting possibility to operate on an improved grade recovery curve by manipulating the control variables."

Jan 1, 1995

By G. C. Weatherly, D. S. Wilkinson, A. M. Limarga

Competition between stress generation and relaxation mechanisms during the oxidation process has been observed. However, the nature of the intrinsic growth stress in thermally grown scales is not well understood. In this talk, we will propose a conceptual model to calculate the intrinsic growth stress based on the analysis of stress-driven diffusional process of oxygen ions along the oxide grain boundary. The calculated stress, which is considered to originate from the constrained lateral expansion of the oxide, is in agreement with a range of experimental observations.

Jan 1, 2004

By D. Kim

Kennecott operates one of the largest and most modern copper refineries in the world at Magna, Utah, USA. The inputs to the refinery are anodes produced at Kennecott Smelter, which has extremely high contents of lead and bismuth. In order to minimize undesired effects in the electrolytic refining process, unwanted impurities, especially bismuth, must be controlled. This paper describes the process development of practicing state-of-the-art quality control and presents the pilot test results of using the MRT Technology for Bi production.

Jan 1, 2007

By Y. Kocaefe, D. Kocaefe, G. Ergin

Filtration efficiency depends strongly on the wetting of the bed media by aluminum. This project was undertaken to study the wettability of different types of bed media (tabular alumina) using sessile-drop and infiltration techniques. The samples were analyzed using optical microscopy, SEM, and TEM to study the chemical interactions. The results indicate the spinel formation at the interface. This paper presents some of the findings which compares the two methods and gives the results of the analyses on the wetting of alumina by aluminum.

Jan 1, 2004

By R. Pelletier, Herny. E., C. Allaire

Corrosion of refractory linings by molten metals is controlled by interactions between penetration and chemical reaction. Corrosion of aluminosilicates by molten aluminium is no exception. The early stage of corrosion can be described as a particular case of reactive wetting over a porous medium. Although the reactivity between aluminium and silica is great, which should improve wetting and penetration, the presence of air and the formation of a protective oxide layer disfavours initial penetration. This paper presents the results of an exploratory study on the effect of some parameters on the initial stage of aluminium penetration. Penetration kinetics and metal intrusion tests have been performed on alumina and silica powders with pure aluminium and Al¬5%Mg. Capillary models are used as tools of interpretation. Penetration kinetics tests had a poor reproducibility and the kinetics itself can not be explained very well by the capillary-tube-bundle model. On the other hand, a capillary model initially developed for ice intrusion into freezing soils produced predictions in reasonably good agreement with intrusion pressure measurements. The effect of particle size and alloy composition can be predicted using this model. However, the effects of temperature and powder chemistry need additional interpretations to be rationalised. An unusual resistance to penetration of silica powder by molten aluminium have been observed in a series of experiments. This led the authors to the strange conclusion that oxygen should be seen as an excellent non-wetting agent and that there might be ways to use it in industrial applications.

Jan 1, 2004

By R. von Gal

Hazelett Strip-Casting Corporation has been producing the Hazelett® twin-belt casting machines for copper casting since the mid-1960s. The first commercial casters were developed for copper alloy strip and anode plate. In 1968, development work was started to adapt the twin-belt caster for copper bar casting to be rolled in-line into wire rod. Since then, 36 casters have been sold as part of the CONTIROD® system for the production of a substantial portion of the world's copper rod supply. A unique feature of the twin-belt caster is the mold's ability to comply with the size and shape of the cast bar as it shrinks during solidification. Maintaining contact between the mold and the bar provides a high rate of heat transfer as well as other benefits, including the prevention of surface imperfections caused by remelting in the mold. This paper will give an overview of the continuous evolution of the twin-belt caster technology with an emphasis on recent developments in compliant mold technology for copper casting.

Jan 1, 2007

By MKS Vel, S. Mukhopadhyay, R. Mishra

Off late, the criteria of selecting the refractory have acquired a trend line aiming to a cleaner environment and the utmost importance is given to the eco-friendly approach. The stainless steel making furnaces normally use mag-chrome refractories for the obvious reasons of changing slag basicity from acidic to basic. Such refractories generate toxic fumes and compounds with hexavalent chrome, which is unhygienic if inhaled. The present paper describes the development of a chrome free alumina magnesia carbon refractory, it's different test properties, simulative testing and microstructures. The optimum quantity and distribution of carbon in the brick restricts the carbon pick-up by the steel. Bricks with the same composition were manufactured in the commercial scale and used in a stainless steel making furnaces in USA. The performance of same refractory in this furnace was quite encouraging and at present the same quality brick has become a normal practice in this furnace. Since no chromite is used in making this brick, so no toxic compounds are generated environment remains pollution free.

Jan 1, 2004

By N. Schmitt, E. Blond, F. Hild

Working linings of steel ladles progressively damage during the steel manufacturing process due to both severe thermomechanical and chemical stresses. In the framework of the coupling scheme proposed by Blond et al. (1), this study examines the effects of the thermomechanical loading on the onset of microcracking by considering that the complex microstructure of the slag-impregnated brick is fixed during the steelmaking process. The behaviour of the refractory is identified by using thermoelastic-(asymmetric)viscoplastic constitutive equations. Numerical simulations of a simplified geometry of the lining subjected to cyclic thermal loadings at the inner side are shown. Two cases are analysed, namely, i) the material is a homogeneous continuum with a thermoelastic-(asymmetric)viscoplastic behaviour, ii) the material is porous and saturated by liquid slag, and the skeleton has the previous non-linear behaviour. The stress and strain fields are shown, and for the porous medium the interstitial pressure of slag as well. Comparisons between these assumptions are made to assess the role of slag on the degradation of the working lining.

Jan 1, 2004

By R. S. Forgan

The synthesis and study of a systematic series of phenolic oximes have shown that substitution in the 3-position can greatly affect extractive efficacy. Solid state, solution and gas phase analytical techniques, including X-ray crystallography, EPR and IR spectroscopy and collision induced dissociation mass spectrometry have been assessed for their applicability in interpreting the origins of differences in extractant strength. The dominant substituent effect on pH0.5 is the change in ligand pKa, with the more acidic ligands being stronger extractants. The influence of the 3-substituent on the stabilising intracomplex H-bonding of their copper(II) complexes also affects extractant strength. The 3-NO2 substituted ligand shows the lowest pH0.5 value, due to a combination of its low pKa and a stabilising bifurcated H-bond assembly around the copper(II) centre. Appending an aminomethyl group to the 3-position gives a ligand capable of binding a metal and its attendant anion. These metal salt reagents show potential to open up new flowsheets for the processing of high tenor copper feeds.

Jan 1, 2007

By Mary Jean Buchanan

The last twenty years have seen the advent of environmental concerns and sustainable development, and the industry has witnessed the rise of Environmental Management Systems and their registration through several international standardization systems such as EMAS and ISO 14001. Beyond EMS and ISO 14001, which new goal the mining industry should aim at. Life-cycle assessment (LCA), another tool from the Environmental Management System series, is also on the rise and currently the object of an international standard (ISO 14040:1997). Through LCA, it is possible to assess the environmental aspects and potential impacts associated with products and services, taking into account all the activities required for its fabrication, its use, its transportation and its disposal. How could LCA be applied to the mining industry ? Is the international market pressurizing on mining companies to supply an ?environmental ore?? What about the automobile industry and its use of LCA ? Will it influence the ferrous and non-ferrous metal industry, suppliers of raw materials ? This paper presents a review of possible applications of LCA for the mining industry as well as world trends.

May 1, 2001

By J. M. Cooper

The HBMS reverb furnace in Flin Flon was originally designed in the late 1920s. Throughout the decades campaign life has been increased due to operational practices, technological changes and brick quality improvements. In recent decades the campaign life had been extended such that a complete rebuild was scheduled every 3 years. The latest furnace rebuild and start up has been after a campaign life of nearly 6 years. Brick construction methods and techniques along with furnace operational practices allow the present campaign to be double that of the historical campaign length.

Jan 1, 2007

By M. Spreij, M. Hogenboom

Refractory lining performance of aluminium melting and holding furnaces and downtime due to refractory re-linings, are important parameters for increasing the aluminium output of a cast house and decreasing costs. The importance of refractory materials testing is illustrated by examples of improvements made in refractory lining concepts, quality control and introduction of alternative and newly developed materials. These examples also show that the information given by product definitions of refractory suppliers will in many cases be insufficient to judge the risks and benefits of using alternative materials.

Jan 1, 2004

By Benoît Plante

La mine Tio (QIT Fer et Titane Inc.) exploite à ciel ouvert un gisement d?ilménite massive depuis 1950, générant jusqu?à maintenant plus de 70 Mt de roches stériles potentiellement génératrices de drainage neutre contaminé (DNC), dont une partie est submergée dans le lac Petitpas, au nord de la mine. Si généralement l?ennoiement des rejets miniers a un effet bénéfique pour limiter la contamination des eaux, cela reste à prouver pour ce qui est des stériles générateurs de DNC. Des essais en réservoirs ont été réalisés afin d?évaluer la réactivité de trois différents types de stériles submergés, qui ont été choisis en fonction de leur teneur en ilménite. Afin d?évaluer l?impact de la matière organique sur la réactivité des stériles submergés, chaque type de stérile est étudié en immersion simple ainsi que combinée à des sédiments prélevés au lac Allard, à proximité de la mine, d?où l?eau utilisée dans les essais a aussi été prélevée. L?évolution des teneurs en Ca, Mg, Si et Ni durant les 8 premiers mois d?étude démontrent que les stériles immergés sont réactifs, mais l?impact de la matière organique demeure pour l?instant difficile à préciser. Tank tests on Tio mine waste rock The Tio mine (QIT Iron and Titanium Inc.) exploits a massive ilmenite ore as an open pit since 1950, producing over 70Mt of potentially contaminated neutral drainage (CND)-generating waste rocks. While the underwater disposal of mine wastes generally show a beneficial effect on water contamination, this method still needs to be approved for CND-generating waste rocks. Tank tests were realized in order to evaluate the reactivity in underwater conditions of 3 different waste rock types, chosen with regards to their ilmenite content. In order to evaluate the impact of organic matter on the reactivity of underwater waste rock, each waste rock type was studied in simple immersion and in combination with sediments sampled at Allard lake, located near the mine, where the water for the tests was also sampled. The evolution of Ca, Mg, Si and Ni during the 8 first months of testing show that the waste rocks are reactive underwater, but the impact of the organic matter is till hard to define.

Nov 1, 2008

By F. R. Deluca

"ClassificationClassification is a combination of mechanical and hydraulic operation which separates a pulp into two portions according to their respective settling rate. The finished product, the overflow, is removed from the other product, sand, which requires further grinding.Pulp is the uniform suspension of solids in a liquid. Overflow is the fines and therefore the more slowly settling portion of the pulp which is carried over the top of the classifier by the flow of water; sand is the coarser and more rapidly settling portion of the original pulp which is discharged from the classifier by the mechanical action of the rakes or conveyed out by a ""screw"" .Selective classification is classification that has for its object the concentration of the heavy constituents of the original pulp in the sand product so that it may be ground finer than the lighter constituent.Classification is used as follows:I. To make a size separation, for example, a sand-fines separation so that each product may be given a different treatment.2. For closed circuit grinding so that the maximum size of particles entering the circuit is limited, and so that the useful work is increased by enabling the mill to operate mainly on the particles that require the reduction.3. For differential grinding of the heavy mineral constituent and the gangue. In this case, the heavy mineral is concentrated in the sand product and is reduced further, while the lighter gangue material overflows the classifier.The selection of the proper size and type of classifier is determined by the function required, the character of the ore, and the tonnage to be handled, the initial cost and the operating cost."

Jan 1, 1989

By W. Geslin

Backward extrusion process is a metal forming process, which limits the manufacturing?s extra thickness when compared with classical die forging technique. Because of a lack of alloy?s mechanical behavior knowledge, the basic strategy of design is as follow: ?Definition of a small scale blank ?Performing experiment in order to get useful process data ?Improvement finite element simulation conditions ?Development of the full scale blank forming process (design of tools,...) using the finite element simulation A comparison between the result of modeling and the experimental data has been done to validate the finite element simulation.

Aug 1, 2010

"The South African Mineral Resource Committee (SAMREC), a Working Group of the SAMREC/SAMVAL Committee (SSC), under the joint auspices of the Southern African Institute of Mining and Metallurgy (SAIMM) and the Geological Society of South Africa (GSSA) developed the SAMREC Code. The Code sets out minimum standards, recommendations and guidelines for public reporting of exploration results, mineral resources and mineral reserves in South Africa. It is applicable to the reporting of all styles of solid mineralization or economic deposit. However, certain commodities, namely coal and diamonds, have specific additional reporting requirements. The Code does not apply to oil, gas or water."

Jan 1, 2003

By Leibniz University, D. Zapf

"The demand for gas storage operations with high withdrawal rates and operation modes different to a seasonal storage regime requires a more detailed rock mechanical consideration of thermal induced stresses in the vicinity of the caverns. This means that the change of gas temperatures during operation and the consequences of these temperature changes on the stressing of the salt rock mass must be taken into account in the rock mechanical dimensioning. Within the rock mechanical calculations a loading history, i.e. a pressure versus time dependency, has to be defined. As rock salt has a time dependent material behavior stress redistributions in the rock salt mass take place even under constant internal pressure conditions. Therefore not only withdrawal and filling periods but also the duration of phases with nearly constant internal pressure is significant for the resulting state variables. Within the paper the differences and consequences for the rock mechanical recommendations are discussed. As a result it can be concluded that recommendations with respect to minimum operation pressure as well as for maximum withdrawal rates can be answered only in connection with the respective time intervals."

Jan 1, 2015

Polymer electrolyte membrane (PEM) fuel cell has increasingly become the potential choice of zero-emission power source for portable, mobile and stationary co¬generation applications. However, technical barriers need to be overcome before its widespread commercialization; cost reduction and performance improvement including reliability are the two key areas, that can be realized through better cell/stack design and improved understanding of the transport processes occurring inside the individual cells and stacks. In this presentation, we will provide an overview of various cell/stack models that are available in the literature, their strength and weakness, and then present a comprehensive multi-species, multi-phase and multi-dimensional formulation of a single PEM fuel cell, with consistent and systematic formulation for all the regions involved, including the solid bipolar plates, gas flow channels, the electrode backing layers, the catalyst layers and the electrolyte membrane. Such a detailed approach allows us to extract sufficient information to the analysis of a stack of PEM fuel cells. Stack model will be presented that investigates the various stack designs and flow configurations, and the optimal stack design based on the present study will be described. Also some innovative cell/stack designs will be featured.

Jan 1, 2005

By Lyall J. Lichty

THE property of New Calumet Mines, Limited, is on Calumet island, in the Ottawa river, about sixty-six miles northwest of Ottawa. Lead and zinc orebodies were discovered here in 1893. A gravity concentration plant was built in 1912 but was not a success metallurgically, and the plant was later destroyed by fire. A programme of diamond drilling on the property, started in 1937 and continuing to 1942, indicated ore reserves amounting to 1,300,000 tons averaging 2.75 per cent lead, 8.82 per cent zinc, and 0.041 oz. gold and 6.24 oz. silver per ton( l ). These orebodies have been developed underground by cross-cutting and drifting from a three-compartment vertical shaft, sunk to a depth of 745 feet. 'The ore is a contact metamorphic deposit occurring in rocks of the Grenville series, on or near the contact between biotite gneiss and an overlying calcareous amphibolite(2,3). It consists chiefly of iron-bearing sphalerite, galena, pyrrhotite, pyrite, and minor amounts of chalcopyriteand argentite. The gangue minerals closely associated with the ore are calcite, quartz, and various lime-silicate minerals.

Jan 1, 1945

By A. M. Hadian

The use of dolomite refractories in steel making and cement industries has advantages over other basic products particularly in countries where this type of refractories is produced. Due to existence of high-quality dolomite deposits in many regions of Iran, there is a good potential for producing dolomite refractories in the country. This study focuses on the effect of such additives as iron oxide and alumina on hydration resistance and density of Iranian dolomite. It was found that addition of Fe2O3 is more effective than Al2O3 on increasing density as well as resistance to hydration of dolomite.

Jan 1, 2004