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By K. H. March

In the present very highly competitive condition of the bituminous coal business, it is becoming increasingly apparent that coal mines which do not lend themselves to efficient mechanization cannot long survive. It would seem that those mining operations best fitted to survive the struggle for existence are burdened with the considerable capital and maintenance cast of carefully selected mechanical and electrical mining equipment. The ever changing conditions of coal mine operations require equipment which is adaptable to a variety of uses; and investigation of the mechanical and electrical equipment in most mines will show that the operating duty of much of this equipment is considerably different from that duty for which it was originally selected. And it would appear that one of the essential qualifications for a successful mine management is a marked ability to get satisfactory operating results from equipment which has been transferred from some other operation, rebuilt, rearranged, or in some way adapted to the job at hand. As a striking example of such mechanical ingenuity, many of us recall that the first longwall jigging conveyor used in Nova Scotia was built in Sydney Mines from odds and ends in the scrap pile at a total cost of less than $50.

Jan 1, 1930

By P. A. Gonzalez Contreras

Scorodite is considered as a secondary mineral formed from the product of weathering of primary minerals by chemical or biological reactions. In the case of biological scorodite formation, microorganisms mimic and accelerate what in nature takes a very long time, i.e. biocrystallisation. The goal of the biological scorodite formation is to form very stable arsenic crystals suitable for long-term and safe disposal. The biological formation of scorodite is a novel combination of biological oxidation, biocrystallisation, and proper bioreactor design to achieve the biological formation of scorodite crystals in one step. We have explored simultaneous biological arsenic and iron oxidation at 30ºC and at 70ºC leading to arsenic-jarosite phases and scorodite, respectively. As biologically formed scorodite crystals are very stable (TCLP < 1 mg/L As (V)), the risk of arsenic toxicity is minimized when leaching takes place. This process is suitable for arsenic concentrations above 0.5 g/l As achieving up to 20 mg/l As in the effluent. This biological scorodite formation system is a selfsufficient bio-oxidation system and therefore many new applications can be explored such as reprocessing of arsenic trioxide, orpiment or calcium arsenate to scorodite crystals for a stable and safe disposal.

Jan 1, 2014

By J. E. Nelson

This paper will examine the problems inherent in matching grinding mills with electric motors through connecting elements such as clutches. Emphasis will be on the uncertainties of mill torque and power demands and the need to recognize these if dependable, safe designs are to be obtained.

Jan 1, 1972

By Bryn Harris

Answer to the question is given as 42! Asked the wrong question So got the wrong answer How does this apply to the mining industry? And particularly to this session on Water? Water is just one aspect of mining/minerals/metals Should not be looked at in isolation Need to adopt a ?holistic? approach

May 1, 2013

By M. Jorgensen, I. Markland, D. Shuck

"The McLaughlin Mine owned by Homestake Mining Company is located 70 miles northeast of San Francisco in California's coastal range. The mine began operations in February of 1985. The mill currently processes 3,000 short-ton per day of sulfide ore that has an average grade of 0.15 ounces of gold per ton, plus another 3,000 tons per day in a newly completed oxide circuit. Annual production from the mine totals over 200,000 ounces.The sulfide ore extraction process involves three basic steps, grinding, oxidation of sulfide minerals in an autoclave, and cyanide leaching for recovery of gold in a carbon-in-pulp circuit. This process, which incorporates a new technology where oxidation of sulfide minerals is conducted prior to cyanide leaching to facilitate gold recovery, was successful from start-up. However, limitation in the grinding mills initially limited sulfide tonnage throughput.This paper discusses modifications made in the grinding circuit, both mechanical and operational, to resolve it deficiency. The SAG mill, in particular, was unable to achieve design tonnage initially and proved to be most troublesome. Complications occurred due to the hardness and variability of ore being processed, short component life, and a lifter /liner arrangement that had to be tailored to the particular circumstances at McLaughlin. IntroductionHomestake Mining Company's McLaughlin Mill, located in northern California, was designed to process a refractory gold ore at a rate of 3,000 tpd to render the ore amenable to cyanidation. Seven years transpired between discovery of the near-surface ore body in 1978 and the February, 1985 plant start-up. Development of the McLaughlin mill and open pit gold mine hinged on the use of autoclave technology to achieve design recoveries."

Jan 1, 1991

By M. Leroux, S. R. Rao, J. A. Finch

"Poor Pb/Zn selectivity during Pb flotation in laboratory tests on a Mississippi Valley-type Pb/Zn ore was traced to a pH effect. In the pH range 9.5-11 sphalerite floated readily without copper activation. Compared to sphalerite flotation with copper activation this procedure gave equivalent selectivity but reduced flotation rate.Possible mechanisms of this sphalerite flotation without copper activation are discussed. Activation by Fe(OH) 2 is suggested, the Fe++ions being derived from superficial oxidation of pyrite in the ore.INTRODUCTIONGalena and sphalerite commonly occur together. The usual practice is to float galena first followed by the flotation of sphalerite after activation with copper (II) sulphate. If ores contain pyrite it is depressed by maintaining an alkaline pH (9- 10) and using NaCN as depressant.In flotation tests with a Pb/Zn ore from Polaris selective flotation of galena could not be achieved consistently as a considerable amount of sphalerite, even though unactivated, floated. A systematic study was carried out to determine the cause of this problem. This led to the unexpected finding that sphalerite floated in the alkaline pH range 9.5-11.0 without preactivation with Cuso 4 . This paper describes the results of this study and discusses a possible mechanism of the flotation of sphalerite."

Jan 1, 1987

By Esau Arinaitwe

The most extensively used methods and approaches for characterizing and selecting frothers for plant application are based on measurements in clean water in the absence of solids and without consideration of physicochemical factors that are known to influence the properties and behavior of practical flotation froths, and hence metallurgical performance. These factors include aquatic chemistry, collectors, modifiers, particle shape and size, and pH. Understanding interactions between these factors and the role and relevance that they play in characterizing frothers and froth zone properties will greatly aid in the frother selection and evaluation process. Such an understanding will also greatly enhance the ability to create frother solutions that are sufficiently robust to plant variability (such as mineralogical, comminution, operational, physical and chemical). This paper reports results of a “systems approach” study designed to probe ways in which physicochemical factors a) influence frothing and bubble size in 2- and 3-phase systems, and b) confound correlation of fundamental measurements with flotation outcome. The concepts and insights gleaned from fundamental frother studies, together with empirical laboratory flotation tests and a thorough understanding of plant needs and challenges were used to develop and implement customized frother formulation at a Cu-Mo flotation plant. Plant metallurgical data and qualitative assessment of froth zone properties showed that a frother formulation developed using the approach described here provided marked improvements in froth characteristics (mineralization, mobility, stability, persistence). These improvements resulted in better circuit control and significant performance advantages, such as improved coarse particle recovery, without detrimental downstream effects. INTRODUCTION Successful recovery of value minerals of sufficient grade via the flotation process requires selective manipulation of the value minerals to render them hydrophobic using collectors and modifiers. The hydrophobized minerals then attach to air bubbles and the mineral-bubble aggregates are selectively transported through the froth zone into the launder. Frothers play a critical role in froth formation and more importantly in achieving and maintaining desirable froth characteristics (for example, stability, mobility, persistence) that are essential in facilitating the selective transport and recovery of value minerals. Fundamentally, frothers contribute to the transient stability of thin liquid films and so aid in reducing bubble coalescence rates in the pulp and froth zones, thus maintaining the small bubbles required for efficient bubble-particle attachment. Invariably, the action of frothers at the liquid/gas interface in the pulp and froth zones impacts bubble stability, water and solids transport to the froth, which in turn impacts froth mobility, froth carrying capacity, and the concentrate grade. Consequently, selection and evaluation of frothers for flotation plants requires careful consideration of the frother type, though the choice is limited to only two main classes of compounds in terms of fundamental chemistry (short chain alcohols and polyglycols). Even with the selection of what is thought to be the best frother for a given application, practical knowledge of the froth zone and experience in controlling its properties is essential for maximizing metallurgical performance.

Jan 1, 2019

By N. P. Hristov, L. V. Kuzev

"A simulation study of the fill factor of a drum mill was conducted using two types of grinding media: balls and tetraballpebs. Each medium was composed of equal number of grinding bodies having equal weight but different shape. The difference was in the density of the two grinding media.Standard spherical grinding bodies (balls), which were used in practice, and equivalent (by weight) grinding bodies in the shape of spheroidal tetrahedrons (tetraballpebs) were studied. The simulation was conducted in a module of a 1.2 m diameter drum mill, whose length exceeded twice the diameter of the corresponding grinding body. The grinding balls had a few percent (3 to 6) higher fill factor than the grinding tetraballpebs in the same shell.Vertical sections of the grinding medium were taken across the studied shell module along its axis. They showed the location of each grinding body in the fill volume. Defects in the packing of the grinding bodies and the contacts between them and with the inner surface of the shell were also show. Differences in the contact points of the balls and the tetraballpebs were noted. For the tetraballpebs, we observed contacts both between the spherical surfaces and with the edges and vertices of the grinding bodies.The topography of the grinding media is shown visually.INTRODUCTIONThe grinding balls have been studied extensively. It is the traditional grinding medium in ore processing industry. The parameter characterising the grinding medium is its density. It is the mass of the grinding medium per unit of volume. The parameter may have a range of values. It depends on:• The physical properties of the material they are made of;• The shape of the grinding body;• The dimensions of the body;• Size distribution of the grinding bodies in the grinding media.In comminution, the fill factor of the mill shell is the process parameter that is representative of the grinding medium. Some publications have indicated the disadvantages of ball grinding. For example, Wu, Xiang, Glen, and Duan (2008) note in the analysis of the mechanism of grinding that the balls are not the best grinding media and disadvantages include among others:• Easy over-grinding resulting from the point contact between the balls;• Attrition surface is the smallest in the grinding media;• Poor selective exposure of minerals resulting from the accidental and often significantly more powerful impact on the feed;• The grinding efficiency drops as the fineness of grind is increased;In the Handbook of mineral processing, Polkin (1950) noted that the shape of the grinding bodies determines the volume of the void spaces therein and therefore the shape affects the grinding efficiency per unit of volume of the grinding medium."

Jan 1, 2016

By P. Woo, N. Brodusch, R. Gauvin, H. Demers

The scanning electron microscope (SEM) was primary developed for imaging applications. With the introduction of the Si(Li) energy dispersive spectrometer (EDS), simultaneous imaging and x-ray microanalysis became possible. However, long working distance and high current were needed because the position and small solid angle of the EDS detector. The high spatial resolution is generally obtained at short working distance with a SEM. Unfortunately x-ray microanalysis is never performed in the best imaging conditions. The annular silicon drift detector system is inserted below the objective lens which gives a higher solid angle (up to 1.3 sr). In consequence, a lower working distance and probe current can be used. An improved spatial resolution becomes possible during x-ray microanalysis. With this x-ray detector installed on a cold-field emission scanning electron microscope, quantitative x-ray microanalysis with high spatial resolution at low beam energy and low current becomes possible with the possibility of using the various different type of imaging at the same time. Also, since the count rate can be as high as 1,500 kcps, which lowers significantly the detection limit of elements as well as the minimum feature sizes of different phases that can be distinguished.

Jan 1, 2014

By D. R. Murray

"In 2017, Nutrien Allan Potash remediated a portion of the concrete liner in the production shaft. A set of underslung work platforms and collection boxes were used in conjunction with hydraulic splitters, jackleg drills and hand chippers to excavate and remove the broken concrete. New concrete was placed with the original pressure relief design, using a shaft slip form. Shortly after excavating, it was found that the estimated breaking rate and amount of original concrete in-situ was under estimated. Fifteen feet of excavated concrete (2719cu.ft) and ten feet (of replaced concrete was completed on April 28, 2017, and operation of the production shaft was returned to mine operations. During February 2019, Nutrien Allan Potash began remediation of a portion of the concrete liner in the service shaft. The project is different than the 2017 project, as the remediation has occurred during normal running operations and occurred only on night shift. Rather than hydraulic splitters and hand chippers, the new method includes a concrete saw and mechanical excavator from a working platform. The selected method is based on the lessons learned from the 2017 project in the production shaft. The service shaft project was scheduled to be completed in July, 2019. INTRODUCTION Nutrien Allan Potash is located approximated 75 km east of the city of Saskatoon, Saskatchewan, Canada. There are currently two shafts at Nutrien Allan Potash: the Production Shaft and the Service Shaft, transporting people and material from surface to a depth of 3,335 ft. The Production Shaft was completed in 1967, with one section of grey cast iron tubbing installed in the Blairmore formation between the 1605 and 2037 ft Levels. A second set of cast iron tubbing was installed in the Duperow formation between 2203 and 2463 ft Levels in 1999. The remainder of the concrete as of todays standards is designed as a pressure relief liner. The Service Shaft was completed in 1968, with one section of grey cast iron tubbing installed in the Blairmore formation between the 1600 and 2048 ft Levels. A second set of cast iron tubbing was installed in 1981, with 169 ft installed through the Duperow formation. The remainder of the concrete as of todays standards is designed as a pressure relief liner. PRODUCTION SHAFT REMEDIATION During the second quarter of 2015, the Mine Engineering team were notified of an area of concern in the production shaft. The shaft specialists of Golder Associates Ltd (Golder, formerly Alan Auld Canada) were contacted to complete an inspection of the production shaft liner with emphasis on the area of concern. Based on the inspection and documentation review, it was determined that the concrete at the 2804 foot elevation had been broken out for some time and was retained with #8 rebar bolts with resin encapsulation. The broken concrete was encroaching on the clearance to the conveyance."

Jan 1, 2019

By M. Niinae, F. Nakahara, T. Kawamoto, T. Suzuki

"MgO was chosen as an As(V) immobilization agent and a series of immobilization experiments was performed to obtain insights into the behavior of As(V)and MgO during leaching tests. Our experimental and modeling results demonstrated that As(V) immobilization by MgO consists of the following steps: (i) an increase in soil pH, (ii) desorption of As(V) from the soil, and (iii) the re-immobilization of As(V) by MgO/Mg(OH)2particles. Regarding the behavior of MgO, the modeling results showed that when the MgO dosage was 25 mg MgO/4g-drysoilor less, the majority of MgO was used to increase pH, and less than 1% of MgO was used to sorb As(V), which was consistent with the result of leaching tests showing that a high level of As(V) was leached at the MgO dosages. On the other hand, when the MgO dosage was above 25 mg MgO/4g-drysoil, the percentage of MgO used for As(V) sorption increased up to 35%, and correspondingly, the As(V) leaching level decreased to below 0.01 mg/L As at an MgO dosage of 75 mg MgO/4g-drysoil.INTRODUCTIONOne of the major arsenictransport pathways causing groundwater contamination is the migration of arsenicfrom artificially or naturally contaminated surface soils. Therefore, in this study, the immobilization of arsenate (As(V)) in soils was investigated using commercial-grade magnesium oxide (MgO) as a potential cost-effective measurement to prevent the occurrence of groundwater contamination with As(V).With respect to the use of MgO for remediating As(V)-contaminated environmental media, MgO has been used in several studies to remove As(V)from water(Yu et al., 2011; Jia et al., 2013; Tresintsi et al., 2014). Although these studies demonstrated that MgO effectively removes As(V)from water in water-MgO systems, the behavior of As(V)in water-soil-MgO systems has not been evaluated in the literature, and several questions remain to be answered to comprehensively evaluate the use of MgO as an As(V)immobilization agent in soils. For instance, as is well-documented in the literature(Ford, 2002; Lenoble et al., 2002; Zeng et al., 2008), iron oxy-hydroxide (FeOOH) is one of the important adsorbents for As(V)in both natural and engineered systems. Therefore, it is anticipated that the presence of FeOOH in soils significantly influences the behavior of As(V)in water-soil-MgO systems and consequently, the immobilization performance by MgO. Another important question to be answered is the behavior of MgO during the immobilization treatment. In our previous studies (Suzuki et al., 2013a, 2013b), commercial-grade MgO was demonstrated to effectively immobilize lead and fluoride, and the immobilization effectiveness was indicated to last more than 100 years against the exposure to acid rain (pH 4.0). However, these studies focused on the behavior of contaminants. As a result, little is known about the behavior of MgO during the immobilization treatment. The lack of understanding of the behavior of MgO during immobilization treatment is one of the main concerns leading to relatively low public confidence in immobilization treatments."

Jan 1, 2016

By Rodolfo Zanella

Au/TiO2 catalysts were prepared by deposition-precipitation using NaOH (DPN) (~3 wt % Au) and urea (DPU) (~8 wt % Au), and calcined at various temperatures between 100 and 400 °C. They were characterized by UV-Visible, XANES, EXAFS and TEM. Their activity were tested in the reaction of CO oxidation at 5°C. After preparation, the gold species are in the oxidic state III. They begin to transform into metallic gold under air at ~100 °C for DPN and ~150 °C for DPU. At 200 °C, all the gold is metallic for the two preparation methods. The particle size increases from 1.5 to 3.5 nm with the calcination temperature. The catalytic activity for CO oxidation increases with the percentage of metallic gold, and it is maximum at 200°C for both types of samples. The activities (per mole of Au) are the same for the two types of catalysts. At higher temperatures, the catalytic activity drops. The decrease of activity is mainly due to a change of particle shape with the calcination temperature rather than to the increase of the particle size. At a calcination temperature of 200°C, the particles present small facets with rounded parts, and their outer surface contains a large proportion of low coordinated sites (steps and corners) while at high temperature of calcination, they are truncated octahedra with smooth facets.

Oct 1, 2003

By Simon C. Dominy, Patrick R. Stephenson, Alwyn E. Annels

Abstract - The often complex, erratic, and localized nature of gold is a common feature of many vein-style gold deposits. This style of mineralization is often referred to as being nuggety or possessing a high-nugget effect. As a result of these complexities resource estimation is difficult and in general, only Exploration Results can be provided or an Inferred Mineral Resource estimated from surface drilling data alone. Underground development, further drilling, and probably bulk sampling will be required to delineate Indicated and Measured Resources. Tonnages can generally be estimated from diamond drill and development information with a reasonable degree of confidence. Grade is much more difficult to define with confidence because it is commonly highly erratic and discontinuous in nature. The dependency of higher confidence Resource categories on development information may create a Catch 22 situation, with funding for such development often depending on the prior definition of at least Indicated Resources. There are no easy solutions to these challenges posed by high-nugget effect deposits, and it is important when classifying and reporting not to downplay the uncertainties often associated with Mineral Resource and Ore Reserve estimates for such deposits. However, in common with all deposit types, if the principles that underpin the estimation, classification, and reporting procedures are borne in mind and common sense applied, most issues can be satisfactorily resolved. This paper discusses the classification and reporting of Mineral Resources for high-nugget effect gold vein deposits within the framework of the JORC Code (JORC, 1999).

Jan 1, 2001

By Graham Swan

The case is presented for the development of a spray-on liner for ground support, but only in the context of a new mining system, consistent with the technical and business case advantages of liners compared to alternatives. Over the past 10 years much effort has been expended in specifying and testing the mechanical/environmental properties of various liners, without actually fulfilling any mining system requirements. The results have been generally disappointing, with no consistent and sustained application in a dayto- day production environment being achieved, anywhere. Central to this shortcoming has been the failure of mining/liner ma nufacturing companies to realise that screen/mesh or shotcrete cannot simply be replaced with thin, deformable liners: success will depend upon closely defining and evolving a new, liner- functional mining system. The paper begins with a discussion of some fundamental technical capabilities and constraints associated with 3M Canada?s liner material that has been developed in partnership with Falconbridge Limited. Intended applications for this liner include the support of bursting ground associated with deep mining conditions. With safe application and consistent performance in mind, the paper argues for a new mining system that derives in the first place from best quality drilling and blasting practices. Taking this as a given, a system for waterscaling and liner application prior to mucking out is proposed, followed by bolting through the liner while arranging for the bolts to be explicitly connected to the liner. Some logistical and equipment related challenges of such a mining system are then reviewed and discussed in the context of the business case for liners. It is concluded that this approach, if successful, will provide the greatest benefits in the areas of safer mining, due to reduction in worker exposure, and in reduced mining cycle times.

May 1, 2003

By J. F. Shirley

"Very seldom, if ever, is a molybdenite by-product plant operated exactly the way the process design engineer visualizes it. The best thing the design engineer can do is provide a sound, basic circuit with enough room and flexibility in order that the operating staff can make the necessary modi fi cations to optimize the process. The plant, with minor modifications, should be capable of handling more than one process. This is especially true when the client is having the plant designed for a new process.The writer would like to propose the following ten ""rules-of thumb"" for designing by-product molybdenite plants where the molybdenite is floated out of a copper concentrate. The term rules-of-thumb is used, because there are probably valid reasons for not using one or more of them in a particular plant design. In fact it was 1980 before the writer was all owed to start up a plant where all of these rules were honored in the plant design. This was after 19 years of experience in the design of molybdenite by-product processes and plants. The main reasons for not following the rules are available capital, available space, and the client's experiences based on pilot plant and laboratory test results."

Jan 1, 1981

By A. Otsuki

"This paper discusses the primary collector adsorption onto a sulphide mineral in mixed collector systems to understand its adsorption mechanism. UV-vis measurements were performed to identify the primary collector concentration adsorbed on pyrite, and the adsorption kinetics under different conditions were compared to distinguish their difference between single and mixed collector systems. Small amount of secondary collector addition prior to the primary collector addition significantly improved the adsorption kinetics of primary one. The result was explained by the combination of two previously proposed mechanisms (i.e., different adsorption site mechanism and multi-layer product mechanism). This study showed UV-vis measurement as an effective tool to study mixed collector adsorption behaviour.INTRODUCTIONCollectors are surfactants composed of heteropolar molecules with a non-polar and a polar group (Lotter & Bradshaw, 2010). In a froth flotation process, the function of collector is to improve the hydrophobicity of target minerals and selectively float them with the aid of gas bubbles. Because of the chemical or physical attraction between the polar group and the mineral surfaces sites, collector molecules adsorb on the particle surface with the non-polar group assigned towards the bulk solution (i.e., water), thus the mineral particle surface becomes hydrophobic (Wills & Napier-Munn, 2006).Thiol collectors are major collectors widely used in sulphide mineral flotation. Potassium amyl xanthate (PAX), dithiocarbamate (DTC), dithiophosphate (DTP), mecaptobenzothiazole (MBT) are some common thiol collectors. Previous studies reported that some mixed collectors systems enhanced the flotation performance (e.g., Bradshaw, 1997; Bradshaw et al., 1998; Rao & Forssberg, 1997). Thiol collector mixtures are often used in the flotation of sulphide ores, and discussed with the synergistic benefits (Bradshaw et al., 1998) which include lowering the total collector dosage requirements, improving the sulphide recovery and the rate of flotation as well as the improving the froth characteristics. The current paper mainly considered the mixture between two thiol collectors (PAX and DTC, considered as a weaker and selective collector, and stronger and less selective collector, respectively (Bradshaw, 1997)) to further understand their adsorption mechanism that should assist in improving the flotation performance of refractory gold ore."

Jan 1, 2016

By Mousa Mohammadi

Due to operational advantage of dragline in simultaneous excavation and back-filling, the equipment has gained vast importance in open-pit mining. Besides, absence of auxiliary haulage units and a myriad of other benefits are also credited in favor of excavation of muck piles by the draglines. However, the aspects of production, productivity and economics are of utmost significance in dragline operation and planning. In this light, the present paper is an endeavor to analyze availability and utilization of dragline operations. The paper presents a good amount of data for 4-draglines operating in one of the major opencast projects in India. The study reveals the trends of availability and utilization of these draglines during last 11-years. Furthermore, the study also highlights the salient reasons for loss of available hours and for idling of the draglines. Some startling information and facts have been illustrated in form of graphs and pie charts.

Aug 1, 2013

By M. Y. Williams

Introduction During the economic investigation of Pacific Great Eastern Railway subsidy lands, the P.G.E. Survey of Resources made a geological and mineral survey of a large part of the valley of the Peace river as included in the Province of British Columbia. The immediate valley of the Peace river was surveyed from the mountains to the Alberta boundary; the valley of the Pine river was surveyed throughout; and the Dominion block, 70 miles square and lying astride the Peace river, westward from the Alberta boundary, was very carefully surveyed. The writer was in general charge of the field work, and spent half the field season of 1929 and the field season of 1930 in the region . J. B. Bocock, however, did the major part of the work, spending two seasons, 1929 and 1930, in the area. General Conclusions The rock formations within the area discussed are all sedimentary and range in age from pre-Cambrian to recent. As might be expected, the minerals are in the main non-metallic, coal being by far the most important. Favourable conditions exist for natural gas occurrence, and suitable structures for petroleum concentration occur, although the high carbon ratio of the coals sheds considerable doubt upon the actual occurrence of oil in the area. Materials of minor interest are ochre, calcareous tufa, marl, limonite, gravel, and building stone.

Jan 1, 1934

By Fathi Habashi

Extraction by organic solvents is a chemical process in which metal species in the aqueous phase react with an organic reagent to form an organometallic com- plex, thus, the metal species leave the aqueous phase and enter the organic phase from which it can be stripped back in the aqueous phase to obtain a pure and a concentrated solution. The metal in the organic phase is not bound to carbon atoms as in organometallic compounds but to oxygen, nitrogen, sulphur, or hydrogen by a co-ordination (dative) bond (Habashi, 1999).Solvent extraction was used for the first time in hydrometallurgy in connec- tion with the special and urgent materials requirements of nuclear energy during World War II. A plant was constructed in the United States for the preparation of high-purity uranyl nitrate solution. In this plant, the yellow cake (a high-grade sodium or ammonium uranate) was dis- solved in HNO,, and uranium was selec- tively extracted by ether then stripped by water to give a concentrated solution of pure uranyl nitrate. This was gradually followed by developing methods for other high-priced metals such as plutonium, thorium, niobium, tantalum, zirconium, hafnium, boron, beryllium, and molybde num. The second step took place in the 1960s when solvent extraction was applied for the first time to extract a rela- tively cheap metal-copper. At present, solvent extraction technology is wide- spread, well accepted, and highly efficient. Solvent extraction had its origin in the discovery, by Christian Friedrich Bucholz (1770-1818) in 1805, that uranyl

Sep 1, 1999

By Brooke Clements

The Buffalo Head Hills region is located approximately 350 kilometres northwest of the city of Edmonton in northcentral Alberta (Figure 1). The Alberta diamond joint venture consisting of Ashton Mining of Canada Inc., Alberta Energy Company Ltd and Pure Gold Minerals Inc. began exploring for kimberlites in the Buffalo Head Hills region in late 1996. At the time, the Mountain Lake diatreme, located 200 kilometres to the southwest, was the only reported kimberlitic rock in Alberta (Leckie et al., 1997, Figure 1). Exploration efforts since 1996 have successfully identified a new diamondiferous kimberlite province in Canada.

May 1, 2001