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By M. Bouchard, B. Cadieux et F. Goutier

Five phases of ice movement were r es pons ible f or glacial dispersion in t he study area. I ce fl ow directi on changed prog r es s ively from SE to SSW and then to the S. All observed glacial sed iments are associated with a south-southwest to south movement; t hey are grouped, on the basis of their texture, structure, morphology and composition, into four distinct lithofacies. A lithological study of the coarse-grained fraction (4-128 mm) of these lithofacies shows systematic compositional differences. These are: 1) variations in the proportions of local bed rock fragments; 2) variations in the horizontal displacement of the maximum abundance peak of a given lithology relative to its source area, and 3) variations in the length of dispersion trains associated with each lithofacies. Although dispersal trains can obviously be mapped without differentiating li thofacies, studies based on the consideration of lithofacies should give more reliable results than conventional methods.

Jan 1, 1984

By F. J. Hrach, S. A. Gasiorowski, J. D. Bittner

"Separation Technologies, LLC (ST) has developed a processing system based on triboelectric charging and electrostatic separation that provides the mineral processing industry a means to beneficiate fine materials with an entirely dry technology. In contrast to the other available electrostatic separation processes that are typically limited to particles greater than 75 µm in size, the ST belt separator is ideally suited for separation of very fine (<1 µm) to moderately coarse (500 µm) materials with very high throughputs.. The technology has been also successfully applied to the beneficiation of a variety of minerals including calcium carbonates, talc, and potash. TECHNOLOGY OVERVIEWThe ST separator utilizes electrical charge differences between materials produced by surface contact or triboelectric charging. When two materials are in contact, material with a higher affinity for electrons gains electrons and thus charges negative, while material with lower electron affinity charges positive. This contact exchange of charge is universally observed for all materials, at times causing electrostatic nuisances that are a problem in some industries. Electron affinity is dependent on the chemical composition of the particle surface and will result in substantial differential charging of materials in a mixture of discrete particles of different composition.In the ST separator (Figures 1 and 2), material is fed into the thin gap 0.9 – 1.5 cm (0.35 -0.6 in.) between two parallel planar electrodes. The particles are triboelectrically charged by interparticle contact. For example, in the case of coal combustion fly ash, a mixture of carbon particles and mineral particles, the positively charged carbon and the negatively charged mineral are attracted to opposite electrodes. The particles are then swept up by a continuous moving open-mesh belt and conveyed in opposite directions. The belt moves the particles adjacent to each electrode toward opposite ends of the separator. The electric field need only move the particles a tiny fraction of a centimeter to move a particle from a left-moving to a right-moving stream. The counter current flow of the separating particles and continual triboelectric charging by carbon-mineral collisions provides for a multistage separation and results in excellent purity and recovery in a single-pass unit. The high belt speed also enables very high throughputs, up to 40 tonnes per hour on a single separator. By controlling various process parameters, such as belt speed, feed point, electrode gap and feed rate, the ST process produces low carbon fly ash at carbon contents of 2 % ± 0.5% from feed fly ashes ranging in carbon from 4% to over 30%."

Jan 1, 2012

By A. D. Mufch, G. P. Mitchell

"THE HARDY MINE of Falconbridge Nickel Mines Limited is located in Lot 9, Concession 1, Levack Township, Sudbury District, Ontario, 20 miles northwest of the city of Sudbury, and a mile west of the town of Levack. The ore deposit is one of the many nickel-copper sulphide bodies found on, or near, the lower contact of the well-known Sudbury norite-micropegmatite irruptive, and is one of a family of ore deposits which occur on the northwest rim of the irruptive.The property was acquired by purchase in 1935. In the same year a magnetometer survey along the footwall contact of the norite, which is covered by about 150 feet of glacial sands and clays, first indicated the location of the orebody. Drilling from 1935 to 1942 outlined the extent of the ore. Shaft sinking was commenced in the fall of 1951, and the mine is now approaching full production at a rate of about 300,000 tons per year.There are several major differences between the geology of the Levack area and the Falcon bridge area, which lies at the opposite extremity of the irruptive, 28 miles to the east. The purpose of this paper is to describe the essential features of the geology of the Levack area as seen in the Hardy mine, and to supplement the recent papers on other properties in the Sudbury area by Davidson (1), Lochhead (2), and Yates (3).General GeologyA recent review of the regional geology and an extensive bibliography of the Sudbury area can be found in the two papers by H. C. Cooke (4, 5). Some of the recent related references are: Jas. E. Thomson (6), E. M. Abraham (7), Franc. R. Joubin (8), W. G. Q. Johnstone (9)."

Jan 1, 1949

By M. R. Khalesi, S. Bellec, C. Bazin, D. Hodouin

Batch grinding tests conducted on a gold ore indicated that gold is not randomly distributed within the size fractions of the ground ore. Since gold leaching performances were found to be dependent of the size of the gold carrying particles an integrated gold ore grinding-leaching simulator should incorporate a method to predict the gold size distribution of a ground ore. The paper describes the results obtained from batch grinding tests showing the non random distribution of gold within the size intervals of a ground ore and the initial developments of a grinding model to predict the gold size distribution in a batch grinding product.

Jan 1, 2011

The JKRBT (JK Rotary Breakage Tester) is a newly developed impact breakage testing device for rapid ore breakage characterisation, and has recently been commercialised after a three year comprehensive validation study, involving five major mining companies and six industrialised JKRBT units deployed worldwide. Comparisons of breakage mechanisms and characterisation data between the JKRBT and the Drop Weight Tester (DWT) indicate that, despite the differences in the breakage modes, the JKRBT can provide statistically similar A*b parameters, by using a data reduction procedure which takes into account the difference in the number of contact points, strain rate and potential for secondary breakage. Feedback from the validation sponsors has indicated higher productivity and better repeatability of the JKRBT compared with the DWT. This better precision, combined with the JKRBT?s wider particle size capability and wider specific energy range, provide a more powerful tool, ideally suited to rapid mapping of ore hardness in geometallurgical and comminution applications.

Jan 1, 2012

By H. C. M. Gordon

IN every co al mine the hazard of fire in the underground workings is always present. This is a natural condition, because the mineral wrought and the supports normally used are themselves combustible and because underground fires may originate in many ways. The main causes of such fires are: (1) Open lights igniting gas, wood, or the coal itself. (2) Explosives igniting gas or coal. (3) Spontaneous combustion. (4) Electric sparks or short circuits igniting gas, wood, or coal. (5) Frictional heat igniting wood, coal, or oily material. (6) Explosions of gas or coal dust igniting wood or coal. The relative importance of these causes, and others less frequently met with, varies from district to district and depends to a great extent on the equipment and supplies used, on the training and discipline maintained among the workmen, and on the liability of the coal to heat spontaneously. It follows, therefore, that open lights should not be used and that, wherever there is the least possibility of methane being encountered, only locked safety lamps of an approved type should be allowed underground. It follows, also, that only &apos;permitted&apos; explosives should be used and that the it use should be confined to conditions under which they are ?permitted?. Similarly, electric equipment should be of an approved type and all such stationary equipment should be housed in well-ventilated fireproof rooms. Such rooms, as well as entries to stables and oil houses, should be provided with doors which can be easily and tightly closed and which should be constructed of fireproof material.

Jan 1, 1937

By S. Steinlechner

"Today the common recycling technologies of automotive catalysts are either energy intensive pyrometallurgical processes generating huge amounts of residues or hydrometallurgical ones which have to cope with effluent problems. Next to that, other valuable metals beside PGMs such as rare earths from the wash coat are not recovered.Therefore, the present paper introduces a hydrometallurgical concept developed in cooperation with the company Railly & Hill for the recovery of the PGMs as well as cerium from the wash coat of the catalysts in a closed loop. Next to the process concept, the required parameters for the different steps are discussed, including the chemical reactions, leaching efficiencies and mass flows, which form the basis for an economic estimation of the concept.Contrary to the pyrometallurgical recycling where the monolith is completely melted down to slag which is typically dumped, in this process the remaining monolith forms an utilizable product for the ceramics/refractory industry. As a result of the closed loop of the leaching media an environmentally friendly process was developed from which nearly no new residues or effluents are generated, with a sustainable usage of chemicals."

Jan 1, 2014

By A. W. Lovett

"THE last two years have been years of recession or, perhaps, years of marking time, depending upon whether the observer is a pessimist or an optimist. There has been a slackening in the industrial tempo that has been reflected in many ways in the national economy. As one of the chief barometers of economic health, the consumption and supply of energy reflect this slowing up.These same two years have also seen significant changes in the relation between the sources of energy. In periods of declining demand, it has happened in the past that coal, as the basic or residual source of energy, has shown the effects to a greater extent than the other energies. In these two years, however, in addition to this usual effect, there has been the acceleration in the Joss of market to diesels in the railway consumption category and the continuing decline in domestic consumption. The story of these years is presented in the statistical tables that form the foundation of this paper. Statistics, particularly in the form of tables, are rather dry and are sometimes difficult to follow but the overall developments are illustrated by graphs which present a more striking picture."

Jan 1, 1959

By A. Hussain

PAPER NOT SUBMITTED FOR PUBLICATION

Jan 1, 1987

By Yulin Zhou, WenFeng Li, Wen Chen

"In this article, with the help of the X-ray photoelectron Spectroscopy (XPS), a modern test method, all the characteristics of the chlorite,and adsorption collector A6 on the surface of chlorite have been studied. There exist abundant carboxylic C-O and C=O structures in the Carbon XPS atlas with strong adhesive ability after the reaction between new collector A6 and chlorite, which indicates that the ring structure and ether-base functional groups can strengthen the reaction between collector A6 molecule and chlorite surface. The results of XPS analysis indicate that the photoelectron spectroscopy peaks of Mg2p and Al2p moved towards low energy after collector A6 absorbed on chlorite surface, which indicates that chemical bonding through electron cloud transfer happened between collector A6 and Mg, Al ions of chlorite surface. The chemical reaction promoted the adsorption of A6 on chlorite surface and eventually improved the ability of A6 to float and collect chlorite.INTRODUCTIONThere are a large amount of iron-bearing silicate minerals such as chlorite in different types of gangue minerals in iron ore from different areas besides quartz (Yingyong et al, 2012; Qiang et al, 2009). There always exist Mg2+, Al3+ Fe3+ and other metallic ions due the isomorphic replacement among the irons of this kind of minerals. The dissolution often occurs on the surface of minerals with abundant metallic ions during grinding process, and some ions are exposed on the surface, such as Mg2+, Fe3+, Al3+, Si4+, which can increase the surface electrical behaviour of iron-bearing silicate minerals (Wanzhong & Chuanyao, 2002; Yuping et al., 2007), making it easy for the surface to react preferentially with the depressants such as causticizing starch which making it impossible for the surface to reach with conventional anionic fatty acid collector (Mowla et al, 2008). Thus, the beneficiation efficiency is dramatically decreased and the improvement of concentrate grade becomes very difficult. The conventional aliphatic acid collector has some defects such as poor selectivity, poor low temperature resistance, sensitive to water hardness, etc. Thus, the addition of synergist (Liu, & Yu, 2015) or other compound reagents (Zhou et al, 2015) can promote the adsorption of reagents to mineral surface, and improve the collecting capacity and selectivity of aliphatic acid collector to minerals. The addition of polar group to nonpolar group in aliphatic acid can improve the water solubility, dispensability and hard water resistance (Tian et al, 2013). The nitrogen atoms in amid ate aliphatic acid collector can adsorb on mineral surface by itself and supply coordinate electron which can form chelating keys to improve the collecting capacity of collector. There exist coordinate electron in oxygen atoms of ether acid collector, which, along with the oxygen on carboxyl compose chelate with metal (Luo et al, 2015). There are also exist some opinions that the ether acid can arrange into similar crown ether structure which can absorb on mineral surface. A new alicyclic unsaturated ether acid compounds collector A6 is adopted in this paper, the structural formula is listed in Figure 1. The A6 has a strong collecting ability to chlorite with strong water solubility and low temperature resistance."

Jan 1, 2016

By Clyde Williams

If you would allow me some liberties, I would re-state the title of this talk as Scientific Research, Our Greatest Resource, because that title would represent more clearly a present-day conception of the metals and minerals situation. It is a subject worthy of careful consideration. Canada and the United States are so similar and interdependent in their national economies that, in the following discussion, examples of conditions in the United States may? be interpreted to apply to Canada as well. Moreover, it is a striking fact that the per capita value of mineral production in Canada and the United States in 1940 was almost the same. Therefore, in the consideration of this subject, I have made no attempt to differentiate between the two countries. The consumption of the world&apos;s mineral resources in the last few decades, and particularly during World War II, has been so enormous as to require some form of magic to ensure the continued progress of civilization in the face of a diminishing supply of these resources which are so critically essential. As Dr. C. K. Leith pointed out in 1941, industrial expansion has been so great that, during the first forty years of this century, the world used more of its mineral recourses than in all preceding history. And this did not include the all-out consumption during the succeeding five years of war.

Jan 1, 1947

By A. V. Tarasov

There are still a number of copper smelters in the world using the roasting and smelting process flow diagram for treating sulphide raw materials. The technical, economic and environmental performance indicators of such operations are inferior to the respective indicators of advanced processes. First of all with respect to copper and sulphur recovery: 95% and 75% as compared with 98% and over 90%, respectively. Based on the studies of the single-stage smelting process to produce white metal and blister copper conducted during recent years an analysis of the feasibility of roastingsmelting technology improvement was carried out in the Gintsvetmet Institute to substantially increase the copper and sulphur recoveries. On the basis of this analysis, it was proposed to modernize the technology and equipment within the framework of the existing process flow-sheet. The proposed modernization implies an increase in the roasting temperature; higher desulphurization degree in the process of roasting; a number of modifications in the roaster design depending on the particular conditions of a given operation; addition of lime flux to the feed charge to roasting; and transition to combined calcium-silicate smelting slags. The metallurgical and energy computations made have indicated that the proposed modifications of the technology will improve the copper and sulphur recovery up to 98% and 90%, respectively. The required capital investments have been estimated using as an example a particular copper smelter, the payback period determined taking into consideration additional output, fuel saving and a reduction in fines for sulphur emissions. For comparison, the capital cost of a smelter modernization is given for change-over to basically new autogenous Ausmelt, Outokumpu and V anyukov smelting technologies.

Jan 1, 2007

By L. Rao, P. Carabin

"Advances in thermal plasma torches have resulted in this technology becoming a commercially viable solution for chemical and metallurgical processes. The main advantages of plasma are its ability to control process chemistry and to build small footprint reactors due to its high energy density and reactivity of the free radicals that are produced. This paper focuses on thermal plasmas produced by DC torches and their applications for waste treatment, production of high purity metals, and nanomaterials. Both transferred and non-transferred torches have been used as either a source of heat or as a reagent in various industrial processes. INTRODUCTIONPlasma technology has become an ideal solution for many industrial chemical, metallurgical and mechanical processes (Venkataramani, 2002). Thermal plasma powered systems are typical used for their unique characteristics such as high energy densities, high temperatures, small installation sizes, rapid startup and shutdown features, controlled process chemistry and use of electrical energy as a heating source resulting in decoupling the heat source from the oxygen flow rate (Heberlein et al., 2007). Depending on the nature of the main plasma forming gas used, thermal plasma systems offer a high temperature heating source coupled with a highly reactive plasma plume rich in free radicals and ions which promote otherwise hard to drive chemical reactions, as well as high heat transfer rates.Industrial plasmas can be broadly classified as thermal plasmas and non thermal plasmas. Thermal plasmas are atmospheric pressure plasmas characterized by local thermodynamic equilibrium (Boulos et al., 1994). Thermal plasmas are typically established between any two current conducting electrodes separated by an insulator. A plasma forming gas is blown between the two conducting electrodes resulting in a high temperature plasma plume. A plasma torch generates and maintains an electrically conducting gas column between the two electrodes; a cathode (negative electrode) and an anode (positive electrode) (Camacho, 1988). If both electrodes are housed in a single housing, resulting in an arc enclosed inside the plasma torch, then such plasma generating torches are termed as non-transferred (NT) plasma torches, whereas, if the second electrode is external to the torch, creating an arc transferred between the cathode and the working piece, then such plasma torches are termed as transferred (T) plasma torches. Depending on the source of the electricity which can be either direct current (DC), alternating current (AC) at main network frequency or at radio frequency (RF), the plasma torches are classified as DC, AC or RF plasma torches (Venkataramani, 2002)."

Jan 1, 2012

By S. Steinlechner, S. Wegscheider

"In the past, the metallurgical industry was most of the time dedicated on their main commodity, recovering base metals like zinc, copper or lead but leaving other valuable side elements in the generated residues. As a result, these accompanying minor elements, like gold, silver, indium or also PGMs can be found in the dumps of the corresponding industry. Because of political unrest, strikes, economic reasons or decreasing primary resources leading to a high supply risk, also those mentioned minor elements moved into the focus of the recycling industry. Therefore, beside the base metals, first of all the recovery of those minor metals would be of high interest contributing to the economic viability of recycling processes, although they occur in much smaller quantities in materials. In this context, residues from zinc industry, like leaching residues or precipitation residues show high potential to carry silver as well as indium next to lead and zinc. Therefore, the paper summarizes carried out thermochemical calculations investigating a possible recovery of silver as well as indium by volatilization and the influence of zinc and lead on this process. Based on these theoretical investigations with HSC, trials in lab scale were done verifying the obtained results.INTRODUCTIONHuge amounts of iron precipitate, mainly jarosite get landfilled every year although there is a high content of valuable metals in this residue beside iron. Nevertheless, jarosite has to be dumped due to the presence of contaminating heavy metals. The accumulation of these residues takes up massive land on the one hand but also causes a series of environmental problems in ecosystems on the other. Moreover, some toxic ingredients such as arsenic and cadmium can be dissolved in rain water and are therefore harmful to the health of the aquatic systems. (Erdem & Özverdi, 2011; ÖzverdI & Erdem, 2010) Approximately 0.5 t of dry jarosite accumulate in the production of 1 t of zinc by the hydrometallurgical zinc-winning route (Svens, 2010). Jarosite is a precipitation residue formed during the iron removal. In general, the iron already exists in the zinc ore which is why zinc ferrite builds up during the roasting step of the zinc ore. Zinc ferrite is only soluble in strongly acidic solutions and during the hot acid leaching step it gets dissolved while zinc and iron enter the solution. It is necessary to get rid of the iron because otherwise it would deposit on the cathode first due to its precious character which would be harmful in the zinc-winning electrolysis. Nevertheless successful investigations were done by adding chlorine to the jarosite to recover silver. These findings leads to another residue which occurs in huge amounts – electric arc furnace dust (abbreviated with EAFD) from the iron and steel industry. In 2013 the annual electric steel production reached about 451 million tons. Around 15-20 kg of EAFD is produced per ton of steel in an electric arc furnace (EAF), creating approximately up to 9 million tons of dust per year. (Grabda, Oleszek, Shibata, & Nakamura, 2014; World Steel Association) Next to elements like zinc, lead and iron, chlorine and fluorine are present in this dust. While galvanized steel plates in the scrap act as a source for zinc, casting powders, flame retardants and synthetic coatings are responsible for the chlorine and fluorine contents in the dust."

Jan 1, 2016

By V. K. Karra

A mathematical model for the performance of a vibrating screen is developed in terms of an oversize partition curve. This is a normalized curve for any assemblage of particles presented for screening when their size is normalized with respect to the 50 per cent passing size (d50 ) under the prevailing screening conditions. Based on the throughfall aperture (hT) of the wire mesh on the deck, the effects of oversize (% >hT), half-size under (% <0.5 hT), deck location and feed rate were evaluated using the existing screen sizing information. All these variables and also the near-mesh (1.25 hTx 0.75 hT) content (%) of the feed affect the d50. Performance data from different decks of a double-deck screen with various feed rates, size distributions and screen apertures were used to evaluate the near-mesh factor. Effects of wet screening and material bulk density are also incorporated in the model. This generalized model is useful for the simulation of a multiple-deck screen. It furnishes the sieve analysis information of all the deck output streams and therefore has a potential use in the over-all circuit evaluation when used in conjunction with relevant crushing and grinding performance models. An example illustrating the prediction capabilities of the model is given.

Jan 1, 1979

By L. Vinnett, I. Panire, J. Yianatos, F. Ruiz

"The effect of operating variables on the flotation performance at steady-state has been extensively used for modelling and simulation of separation processes. However, the dynamic characterization of key variables such as gas dispersion (Sauter mean diameter of bubbles, D32, and bubble surface area flux, SB) and froth discharge rate is rather scarce. In this paper, an experimental design allowed identifying the dynamic response of the flotation process in a laboratory scale flotation cell, using a two-phase system, airwater. The installation included automatic control for the superficial gas rate, JG, and the pulp level. Gas dispersion was evaluated in terms of the Sauter mean diameter of a bubble population and the bubble surface area flux, SB = 6·JG/D32. The D32 was measured using the McGill Bubble Size Analyzer (MBSA) along with a semiautomated algorithm. In addition, the froth discharge velocity was measured in real-time using a Visiofroth system. The control variables were the superficial gas rate and the frother concentration (Teefroth). The dynamic characterization of the flotation process is useful to design algorithms that allow the direct or indirect control of metallurgical variables such as flotation rate, concentrate grade and mineral recovery.INTRODUCTIONGas dispersion indicates the way the gas entering a flotation machine is dispersed throughout the volume of the equipment (Schwarz & Alexander, 2006). The gas dispersion is typically characterized in terms of the bubble size (dB), gas holdup (eG), superficial gas rate (JG), and bubble surface area flux (SB =6·JG/dB) (Finch et al., 2000). All these variables have significant impact on the metallurgical performance of flotation machines. For example, Perez-Garibay et al. (2014) investigated the effect of the particle size, bubble size distribution, superficial gas rate and collector dosage on the flotation performance, for the separation of a sphalerite mineral. The authors observed that recovery increased with the superficial gas rate ranging from JG = 0.04 to JG = 0.08 cm/s and also a maximum recovery was obtained for bubble size close to 300 µm. Gorain et al. (1998) reported a strong correlation between the flotation rate constant and the bubble surface area flux in a zinc cleaner circuit. Both variables were directly proportional at three froth depths in the range of hF =7 - 45 cm. Dobby & Finch (1986) incorporated the effect of the superficial gas rate and the bubble size on the flotation efficiency by means of a kinetic model for the rate constants. Yianatos & Contreras (2010) developed a model to estimate the carrying capacity in large flotation cells by including the bubble surface area flux."

Jan 1, 2016

By Robert B. Parsons

"Canadian investment abroad has been the focus of considerable attention in recent years. Canadian mining companies have been heavy investors in Latin America and are taking a hard look at Central Asia and the Pacific Rim. This international flow of capital is not one-way however. Foreign mining companies continue to make substantial investments in Canada&apos;s mining industry. This month. Tax Notes addresses some of the main Canadian income tax implications of foreign investment in Canada.Foreign Investment in CanadaThere are two basic forms of foreign investment in a Canadian company: share capital and debt. The following comments deal with each of these investments separately. It is appreciated that the relevant tax legislation is, as always, quite complex, and that the notes that follow are intended only to serve as a guide. This article should not be relied on as a substitute for professional advice."

Jan 1, 1994

By P. -A. Bosse, J. Robitaille, P. Blatter

The LaRonde ore is a Cu-Zn-Pb ore with gold (3-4 g/t) and silver (60-100 g/t). The precious metals are recovered with copper concentrate, zinc concentrate and cyanidation of zinc tails via Merrill Crowe precipitation. Subsequent to a recent mill expansion, excessive gold was reporting to zinc concentrate with a concurrent decrease in gold to copper concentrate. Owing to the higher return obtained from the metal, the mill endeavors to recover additional gold and silver to the copper concentrate and minimize the placement of precious metals to the zinc concentrate. A gold deportment study showed that the gold occurs mainly as küstelite, with a moderate amount of electrum and a minor amount of native gold. It also showed that various sulfur-based Au-and/or Ag-bearing coatings on liberated küstelite and electrum were the major mineralogical factors that caused gold and silver to report to zinc concentrate. By frequency, such coatings were observed on 70-80% of total liberated gold particles reporting to the zinc concentrate. Based on the gold deportment and the chemistry of the coatings, the collector chemistry was reviewed and a new collector was added into the circuit which resulted in a significant increase in gold and silver recovery to the copper concentrate. The information obtained from the mineralogy confirmed and guided other process optimization. In this paper, the authors will describe the process mineralogy of the LaRonde ores, and in particular, the mineralogical evidence diagnosing the problem. Reference will also be made to the rationale behind how the problem was solved, the results achieved, and future steps in optimization.

Jan 1, 2005

By D. V. Dorling, J. T. Bowker, J. A. Gianetto

Over the last few years, interest in the development and construction of large diameter, high pressure pipelines from the Mackenzie Delta in northern Canada and Alaska&apos;s North Slope has steadily increased as a result of the projected decline in recoverable natural gas from existing reserves in western Canada. The success of such enormous pipeline projects, which will require utilization of a strain-based design approach, is largely based on successful application of high strength line pipe steels, such as X80 and X100. To fully realize the economic benefits of high strength steels, welding processes and procedures must be developed to ensure that the requirements for high strength and good low temperature toughness are confidently obtainable in field girth welds used in the construction of such pipelines. This study aims to provide a better understanding of the factors that control weld metal strength and toughness for a series of mechanized X100 girth welds produced using a range of narrow-gap gas-metal arc welding procedures. The attainment of high yield strength (> 810 MPa) is considered to be an important target to ensure overmatching strength relative to the longitudinal property distribution of X100 line pipe steel. Some factors that have been considered in this evaluation include influences of gas-metal arc welding process variants (single and multi-wire) and changes in welding procedure specifications, including joint preparation. Key components of this work relate to the reliable measurement of weld metal strength variation through-thickness and as a function of position around the circumference of a given girth weld.

Jan 1, 2005

By M. Tanaka, H. Narita, K. Morisaku

"The selective separation of palladium (Pd), platinum (Pt), and rhodium (Rh) from a hydrochloric acid solution by solvent extraction was investigated using amide-type extractants, i.e., N,N,N’,N’-tetra-n-octyl-thiodiglycolamide (TDGA) and N-n-hexyl-bis(N-methyl-N-n-octyl-ethylamide) amine (BisAA). The separation experiments employed two separation schemes: (1) extraction of Pd with TDGA and that of Rh and Pt with BisAA; and (2) extraction of Rh, Pd, and Pt with BisAA. Separation scheme 1 achieved the highly selective separation of each metal. For separation scheme 2, Rh can be recovered prior to Pd and Pt, despite having a lower selectivity for Pd/Pt than separation scheme 1. INTRODUCTIONThe recent increase in the use of platinum group metals (PGMs) in industry (especially auto catalysts containing palladium (Pd), platinum (Pt), and rhodium (Rh)) has lead to their increasing waste; therefore, improvements in the recovery techniques for PGM have received significant attention. In metal refineries, PGMs are mainly separated and purified by solvent extraction (Cox, 2004). The extraction process used in INCO’s Acton precious metal refinery is one of the most famous commercial processes and is utilized worldwide. In this process, silver is first removed as a residue (AgCl), and then gold, Pd and Pt are extracted from hydrochloric acid (HCl) solutions using dibutylcarbitol (DBC), dialkylsulfide (DAS), and tri-n-butylphosphate (TBP), respectively. Finally, Rh remains in the raffinate (Barns & Edwards, 1982).The development of a successful solvent extraction process depends on the choice of the appropriate extractants. We have studied the extraction of PGM using N,N-disubstituted amide compounds (Narita, Tanaka, Morisaku, & Abe, 2004; Narita, Tanaka, Morisaku, & Tamura, 2006; Narita, Tanaka, & Morisaku, 2008a, 2008b). They are relatively stable against acids, and their metal extractability can be improved by changing the side chain length and/or introducing additional donor atoms like sulfur and nitrogen. We have recently found that thiodiglycolamide and an amide-containing tertiary amine have good extractabilities for Pd and Rh, respectively."

Jan 1, 2012