XPS Study on the Reaction Mechanism of Chlorite with New Anionic Collector A6

"In this article, with the help of the X-ray photoelectron Spectroscopy (XPS), a modern test method, all the characteristics of the chlorite,and adsorption collector A6 on the surface of chlorite have been studied. There exist abundant carboxylic C-O and C=O structures in the Carbon XPS atlas with strong adhesive ability after the reaction between new collector A6 and chlorite, which indicates that the ring structure and ether-base functional groups can strengthen the reaction between collector A6 molecule and chlorite surface. The results of XPS analysis indicate that the photoelectron spectroscopy peaks of Mg2p and Al2p moved towards low energy after collector A6 absorbed on chlorite surface, which indicates that chemical bonding through electron cloud transfer happened between collector A6 and Mg, Al ions of chlorite surface. The chemical reaction promoted the adsorption of A6 on chlorite surface and eventually improved the ability of A6 to float and collect chlorite.INTRODUCTIONThere are a large amount of iron-bearing silicate minerals such as chlorite in different types of gangue minerals in iron ore from different areas besides quartz (Yingyong et al, 2012; Qiang et al, 2009). There always exist Mg2+, Al3+ Fe3+ and other metallic ions due the isomorphic replacement among the irons of this kind of minerals. The dissolution often occurs on the surface of minerals with abundant metallic ions during grinding process, and some ions are exposed on the surface, such as Mg2+, Fe3+, Al3+, Si4+, which can increase the surface electrical behaviour of iron-bearing silicate minerals (Wanzhong & Chuanyao, 2002; Yuping et al., 2007), making it easy for the surface to react preferentially with the depressants such as causticizing starch which making it impossible for the surface to reach with conventional anionic fatty acid collector (Mowla et al, 2008). Thus, the beneficiation efficiency is dramatically decreased and the improvement of concentrate grade becomes very difficult. The conventional aliphatic acid collector has some defects such as poor selectivity, poor low temperature resistance, sensitive to water hardness, etc. Thus, the addition of synergist (Liu, & Yu, 2015) or other compound reagents (Zhou et al, 2015) can promote the adsorption of reagents to mineral surface, and improve the collecting capacity and selectivity of aliphatic acid collector to minerals. The addition of polar group to nonpolar group in aliphatic acid can improve the water solubility, dispensability and hard water resistance (Tian et al, 2013). The nitrogen atoms in amid ate aliphatic acid collector can adsorb on mineral surface by itself and supply coordinate electron which can form chelating keys to improve the collecting capacity of collector. There exist coordinate electron in oxygen atoms of ether acid collector, which, along with the oxygen on carboxyl compose chelate with metal (Luo et al, 2015). There are also exist some opinions that the ether acid can arrange into similar crown ether structure which can absorb on mineral surface. A new alicyclic unsaturated ether acid compounds collector A6 is adopted in this paper, the structural formula is listed in Figure 1. The A6 has a strong collecting ability to chlorite with strong water solubility and low temperature resistance."