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By R. A. Payant, J. A. Finch

Under certain conditions of air and moisture, sulphide materials can spontaneously heat, or selfheat. The reaction mechanisms of self-heating are not well understood. Most previous work has involved pyrrhotite because it is the most reactive sulphide. The current work investigates the self-heating behavior of sulphide mixtures composed of sulphides other than pyrrhotite. The four studied sulphides were pyrite, chalcopyrite, sphalerite and galena. The rest-potential was measured for each. Binary mixtures formed as a 1 : 1 weight ratio were pyrite-galena, chalcopyrite-galena, pyrite-chalcopyrite and chalcopyrite-pyrite. The four sulphides and the binary mixtures were subjected to standard self-heating tests. The four individual sulphides did not self-heat. However, mixtures of pyrite-galena and chalcopyrite-galena with rest-potential difference (?E) >0.3 volts did self-heat while the mixtures of pyrite-chalcopyrite and chalcopyritesphalerite with rest-potential differences (?E) = 0.1 volts did not self-heat. The results demonstrate that when certain non self-heating sulphides are combined they can self-heat. A possible explanation based on galvanic interaction and formation of hydrogen sulphide as an intermediate product is discussed.

Jan 1, 2009

By Seher Ata

"Virtual reality, a three-dimensional computer generated environment, has become recognized delivery system for many forms of education. This article describes the application of virtual reality to mineral processing education. An interactive mineral processing visualisation module has been developed at University of New South Wales (UNSW), Australia. The module provides students with an overview of a base metal concentrator, details about each stage of the process, as well as revealing how the mined ore progresses from stage to stage. The module also involves developing a number of instructional based plant layouts and flowsheets in the virtual environment that are intended to assist the user in understanding the essential components of the base metal concentrator.INTRODUCTIONVirtual Reality (VR) is the creation of an artificial environment that is experienced through sights and sounds provided by a computer (Squelch, 2001). The simulated environment is achieved through a host of technologies such as three-dimensional graphics, audio feedback and special peripheral devices to produce interactive environments.VR has been used in diverse fields including medicine (Riener & Harders, 2012), entertainment (Hsu, 2011), military (Manojlovich, Prasithsangaree, Hughes, Chen, & Lewis, 2003), manufacturing (Zimmermann, 2008; Jiang, 2011), and chemical processing (Schofield, Lester, & Wilson 2005; Squires, Andersen, Reklaitis, Jayakumar, & Carmichael, 2014). VR is also becoming recognized delivery system for many forms of education, including engineering education (Bell & Fogler, 1996; Bell & Scott, 1998; Shin, 2002). For example, virtual laboratories have been designed and developed to teach students fundemental features of the heterogeneous catalytic mechanisms and absorption columns (Bell & Fogler, 1995), the multi-phase and multi-component blast furnace iron making process (Babich & Senk, 2009) and to guide students to identify various safety measures while working in real laboratory (Bell & Fogler, 1996)."

Jan 1, 2016

By M. Kucharski

The model of the Outokumpu direct-to-copper process deals with a steady-state process the parameters of which do not depend on time. To give a prediction for the process outcome, "a modified black box" method, which ignores most of the chemical reactions in the furnace, was used. This method takes input and output parameters into consideration. The presented model describes the Outokumpu direct-to blister process in the form of the set of linear equations which give mass and enthalpy balances as well as the distribution of elements between blister copper and slag. However, only major substances where quantities in the feed charge exceed a certain level (for example 0.5 kg/ lMg of smelted concentrate) are taken into consideration. Minor elements are distributed among slag and metal phases in a different way. Some of the equations are derived from distribution coefficients. The value of distribution coefficients can be calculated from plant production data.

Jan 1, 2007

By M. Ruel

In today's highly competitive worldwide market, it is becoming extremely important for managers to make sure that all resources are used where needed the most. That way, all resources are generating added value, process control equipments are maintained in an optimal state for best performance, and final product is produced at least cost. Performance monitoring is the only way to ensure that everyone is working on top priorities toward the same goal. How can we add value to these warehouses of data? The data is there and the information is hidden; it is just waiting to be extracted. A process performance monitoring system is able to determine if a loop, a system, a unit, or a plant meets the expected performances. The system prioritizes the areas that need attention. It also provides historical reports of the plant status by areas, by loops, and by identified problems. This information is provided to different categories of users in an appropriate format for each one. The system also includes diagnostics and tools to detect and analyze problems.

Jan 1, 2007

By P. A. Riveros

The literature on the arsenic disposal practices of the metallurgical industry and the long term stability of the disposed arsenic compounds were reviewed from a Canadian perspective. The review was complemented with visits to selected operating metallurgical sites to obtain information on their specific arsenic disposal practices and the behaviour of their impounded residues. The arsenic disposal procedure currently favoured by the industry involves the formation of an insoluble ferric arsenate compound which is allowed to sediment at the bottom of tailings or residue ponds. It has been shown recently that this poorly formed crystalline compound is similar to ?arsenical ferrihydrite? which is ferrihydrite containing strongly adsorbed arsenate anions. Despite concerns about its long term stability on thermodynamic grounds, arsenical ferrihydrite appears to be stable for many years in the proper environment which includes a slightly acidic pH and oxidizing conditions. A high Fe/As ratio and the presence of heavy metals appear to increase the stability of arsenical ferrihydrite. High temperature operations, such as those encountered in the autoclave treatment of refractory gold ores, are conducive to the formation of scorodite, FeAsO42H2O, and/or a series of ferric arseno-hydroxy-sulphate compounds depending on the solution composition. Scorodite has several advantages over arsenical ferrihydrite as a disposal compound including a lower iron demand, a higher density and a greater thermodynamic stability. New procedures have been developed to generate scorodite at ambient pressure. These procedures would offer significant reductions in capital cost because of the elimination of the need for autoclaves. Lime precipitation which was widely used in the past is being abandoned as a result of strong evidence showing that calcium arsenate compounds decompose slowly in contact with atmospheric CO2 to form calcium carbonate and soluble arsenic acid. In all cases, the long term stability of the disposed arsenic compounds depends on a number of factors including disposal site characteristics, particle crystallinity and size distribution, the presence of complexing agents and the effect of bacterial activity.

May 1, 2002

The effect of superficial gas rate distribution (Jg profile) on down-the-bank metallurgical response was tested in the rougher-scavenger bank (eight 10-m3 tank cells, 4 roughers and 4 scavengers) at Highland Valley Copper Mine's Cu/Mo separation circuit. Three Jg profiles were tested: (a) as found (i.e., typical practice), (b) increasing decreasing (i.e., increasing from cell 1 to 4 and decreasing from cell 5 to 8), and (c) decreasing-increasing (i.e., decreasing from cell 1 to 4 and increasing from cell 5 to 8). The Jg profile approach proved to be of considerable value. Profile (b) gave the best metallurgical results, i.e., the highest down-the-bank grade/recovery (increase in grade at constant recovery was approx. 3-4% compared to the as found case) and the most efficient Cu/Mo separation (cumulative Cu recovery was reduced by almost half - approx. from 20% to 12%, at 99% Mo recovery). The success of the evaluation prompted the implementation of profile (b). Detailed gas dispersion characterization tests (Jg and Db (bubble size)) showed significant discrepancies between the Jg measured directly (using the McGill University sensor) and the Jg calculated from field instrument readings (volumetric gas flowmeter) and machine dimensions (cell cross-sectional area). Tests were designed to reveal the source of disagreement. It was observed that a significant number of bubbles were not able to float (i.e., they were entrained with the tailings), the evidence appearing to be a significant number of very small bubbles (approx. 200-300 µm) which did not have sufficient buoyancy to rise. Consequently, rather than relying on the field instrument, the evaluation depended on the McGill University Jg sensor, which collects bubbles in a tube near the pulp-froth interface, thus providing significance to the data as the measurements were obtained from bubbles that almost certainly floated.

Jan 1, 2007

By C. Greimel

Modern roadheaders provide a safe and cost-effective, yet very flexible way of mechanical tunnel and roadway excavation. In the last years, SANDVIK Mining and Construction has developed a NEW ROADHEADER GENERATION, which incorporates new features, allowing significant improvements of underground excavation. Partial face cutting machines such as roadheaders excavate the desired profile by means of a cutter unit mounted on a swiveling boom. This flexible method for mechanical excavation makes the roadheader suitable for a large range of profile varieties and most rock characteristics. Over 1,250 roadheaders have been delivered since the 1960s from the Zeltweg plant of Sandvik Mining and Construction, with the current products ranging from the light-duty, 130kW MR220 machine, widely used in the tunneling and coal industry to the heaviest 300kW tunneling and hardrock mining roadheaders. Roadheaders are generally used in coal mine development, salt/potash mining as well as construction and hard rock mining. This paper describes the technology behind the succesful introduction of hard rock cutting with roadheaders, and aims to offer best practise operation experiences from various hard rock cutting sites.

Oct 1, 2010

By A. G. Doll

The Bond low energy impact (crushing) work index test is specified to be performed on rock specimens between 50 mm and 75 mm in effective diameter. NQ-diameter drill core, frequently used in mineral exploration programs does not meet that specification, it being 45 mm diameter or less. This paper reports the effect of performing the impact test on contiguous sections of HQ diameter and NQ diameter core, exploring the hypothesis that the contiguous intervals give equivalent results in spite of the core diameter difference.

Jan 1, 2012

By M. Dupuis

In the present study, the heat balance of the Hirakud smelter aluminium reduction cell has been accurately assessed using only a surface thermocouple and a pyrometer, As it is well known that using a single linear or quadratic relationship to estimate the heat flux from the measured surface temperature does not provide the accuracy required to close the cell heat balance, this approach was not used in this study, Instead, the fundamental natural convection and radiation heat flux equations were used systematically for each measurement point, Practically, this means that the ambient air temperature and at least one ambient radiative temperature must also be known in addition to the surface temperature for each measurement point. Sometimes, the radiative heat flux could not be accurately estimated using a single ambient radiative temperature, In those cases, a more accurate estimation based on two ambient radiative temperatures and corresponding view factors has been used instead, It turns out that although at least three temperature measurements are required to estimate a single heat flux, it takes a lot less time to make those temperature measurements using a pyrometer than directly measuring the heat flux using an expensive heat flux meter, Furthermore, no loss in accuracy was detected when using this approach as the cell heat balance could be closed within 5%, the level of accuracy typical of cell heat balance assessment using heat flux meter.

Jan 1, 2004

By Matthew S. Hall

Gold/iron oxide catalysts have been prepared and their catalytic performance evaluated for low temperature CO oxidation. The method and temperature used to dry the sample has a significant effect on their catalytic activity. Analysis by TEM revealed the catalysts contained Au particles, although catalysts with high and low activity did not always differ in their microstructure as evidenced by TEM. Catalysts were characterised using XPS and the difference between the Au(4d) and C(1s) binding energies measured; in general the greater the difference, the higher the catalytic activity of the material.

Oct 1, 2003

By G. M. Behrend

"AbstractMeasurement and control systems in minerals processing plants are usually well thought out and designed. The criteria and design parameters have been interpreted correctly.However, these systems often fail to perform satisfactorily or break down altogether as a result of in-plant conditions which are unpredictable and over which the instrument systems designer has no direct control. The foresight necessary to anticipate the problems and allow for them in the systems design can only be generated by experience.This paper lists the most common of these problems and offers practical methods for their solution. It then follows with an analysis of instrument installation practices and comments on special points that need watching.Finally, instrument maintenance is discussed with a view to achieving good maintenance at the best possible economy.Good MeasurementGeneralTHE MINES and mineral processing plants of the nineteen seventies, after decades of sensible caution, have now committed themselves to extensive automatic control. X-ray analyzers are freely specified. Sample acquisition systems are efficient and automated, computers are reliable and relatively cheap, and computer control systems in conjunction with the new analyzers are operating in a good many plants and are proving to be profitable.The sight of shift foremen and floor operators assembled in front of a TV-tube and taking a computer data display as gospel truth is quite common now, and yet was quite unthinkable only ten years ago."

Jan 1, 1977

By W. J. Bennett

"I AM very happy to have this opportunity of speaking to the Montreal Branch of the Canadian Institute of Mining and Metallurgy.I have selected as the subject of my remarks transportation in that area which is at present our only source of uranium -Northwest Canada. Considering the widespread interest in atomic energy, the end-product of uranium, it may be wondered why I have not chosen to speak of a more spectacular aspect of the development. I hope it will be evident from what I have to say that transportation plays a very dominant role in our effort to maintain a continuing supply from Eldorado's producing property at Port Radium on Great Bear lake and from its coming producer at Beaver lodge Lake in Northwest Saskatchewan. Moreover, transportation has such a bearing on the entire mineral development of the Northwest that it cannot help but be of concern to an organization of this kind. Finally, the transportation problem, of which I shall try to tell you something, is quite unique and the story of its solution or partial solution is, I believe, an interesting one.Transportation experience on this continent indicates that the cheapest method of moving freight is still by water -with •rail, highway, and air transportation following, and in that order •of economic significance. Excluding rail transportation, since the area has as yet no railway lines, this order also applies in the Northwest. I shall direct my remarks to the two kinds of transportation which serve our uranium producers -water and air."

Jan 1, 1952

By A. Boehm

"For recycling LD slag into the steel making process, the phosphorous containing calcium silcate phases have to be removed from iron oxide phases. One possible technical solution could be magnetic separation in a wide range of susceptibilities from ferromagnetic to paramagnetic. To check the feasibility of magnetic separation the distribution of the magnetic susceptibility in size classes as well as the liberation of the phosphorous containing phase were evaluated by a new method combining two dimensional physical property analysis with QEMSCAN analysis. The particle size classes of energy controlled comminution products were subdivided into fractions of defined magnetic susceptibility using a hand magnet of well known field properties (pick up method). On the one hand the susceptibility classes were wet assayed on the other hand analyzed by QEMSCAN followed by data evaluation using iDiscover 5.3.1(FEI), which was adapted to the data structure of two physical properties (size and magnetic mass susceptibility). The results allow the comparison of mass based (3D) cumulative distribution of grades from the wet assays with the area based (2D) distribution from QEMSCAN analysis, in order to control a systematic (size dependent) stereological error for this special type of material. As the physical separation property forms a crucial parameter the results from the liberation analysis by QEMSCAN can be interpreted more profound with respect to an expectable separation result. Once the various mineral compositions of the particles are assigned to the physical properties the Henry Reinhardt chart serves to predict the best possible separation result and thus the feasibility of a separation technique.INTRODUCTIONThe two Austrian steel plants operated by voestalpine AG produce about 650,000 t (voestalpine 2014) of LD slag in the course of steel production from pig iron according to the basic oxygen process blowing oxygen in the converter by an oxygen lance. The process is also known as the Linz Donawitz (LD) steelmaking process. By the addition of lime (CaO), carbon, phosphorus, silica, manganese and sulfur, which are present in the molten pig iron, shall be oxidized and bound in the slag either as oxide or silicate phases, or leave the slag in the gaseous phase (CO). The average chemical composition of the investigated LD slag is given in table 1."

Jan 1, 2016

By P. Harvey

"Following initial discovery in 1991, BHP Billiton Diamonds Inc. opened Canada’s first diamond mine, the EKATI Diamond Mine (EKATI) in the Northwest Territories on October 14, 1998. Four short years later, on November 29, 2002, saw the opening of North America’s first underground diamond mine, the Koala North mine. Nestled between the original Panda open pit and the new Koala pit, which is in the early stages of production, Koala North represents the only underground kimberlite mining venture in Arctic conditions outside the new underground mines being developed by ALROSA in the Yakutsk region of eastern Russia. Extensive underground kimberlite mining has been practiced in the Republic of South Africa for much of the 20th century and continues today.Underground mining represents a key component of the long-term business plan for EKATI. As various open pits reach their economic limit, continued recovery of high-value ore at depth is dependent upon the ability to productively mine the kimberlite pipes by underground methods. As a function of its location, size, and value, the Koala North pipe is ideally positioned to host the first underground mine at EKATI. Koala North is designed and approved as a learning mine, from which to gain valuable experience in preparation for the potential mining of other larger, higher value pipes by underground methods in the development, the Koala North mine is well into its production ramp-up phase and currently producing at around 1,200 t/day from the first two production levels."

Jan 1, 2005

By C. R. Julian

THE large pyrites ore-bodies, the underground mining of which is to be described, are situated at Rio Tinto in the Province of Huelva in Southern Spain. The situation of the different ore-bodies with relation to one another is shown in Figure 1. It will be seen on the plan that the strike of the ore-bodies is approximately east and west. The geology of the district has been very fully described by Dr. D. Williams (1), so that for the purposes of this paper it will be sufficient to give briefly the salient features o each of the two larger ore-bodies which are being mined by underground methods at the present time. (a) San Dionisio.-This ore-body is the largest single deposit in Rio Tinto, having on its upper levels a length of 3,500 ft. On the upper levels the average width is approximately 200ft. but in places on the lower levels there is a width of 900ft. of un broken pyrites. Diamond-drill holes, without running out of ore, show the ore-body to persist to a depth of at least 1,600 ft. The ore-body in the upper part lies between slate and porphyry walls, but in depth is enclosed in porphyry walls. (b) South Lode.-Faulting is considered to be responsible for the break in the solid ore between South Lode and San Dionisio. On the upper levels, the South Lode ore-body has an unbroken length of 4,000 ft. The massive pyrites has a maximum width of 300ft. and an average of about 100 ft. Ore has been proved to a depth of 1,000 ft., at which depth the ore-body is much reduced both in length and breadth. This ore-body, to the depth at which it has been proved, lies entirely between slate and porphyry walls. The South Lode and the San Dionisio ore-bodies are mined both by open-cast and by underground methods. There is evidence that these mines have been exploited intermittently during the last 3,000 years; but, as is to be expected, no records are available of the tonnage mined prior to the time of purchase by the present company.

Jan 1, 1940

By Robert B. Parsons

"First down and four to go. In the game Of football, this is not a bad position to be in. However, in this game of political football, it means that there is still a long way to go. The government in Ottawa has concluded an important agreement with one producing province, and now has at least four more provinces to deal with-B. c., Saskatchewan, Nova Scotia and Newfoundland.On September 1, 1981, the federal and Alberta governments took a significant step forward in formulating an oil and gas policy for Alberta and the rest of Canada on signing a comprehensive five-year agreement that covers taxes, prices, incentives and other fiscal matters related to the production and marketing of oil and gas.This month, Tax Notes examines the main features of the agreement, and offers some eye-opening observations of what the new accord could mean for the future of the Canadian petroleum sector in particular and Canadian business in general."

Jan 1, 1981

By M. J. Sapko, R. W. Watson, E. S. Weiss

The relative incerdivity of several blasting agents was evaluated in the Bureau's Bruceton Experimental Mine (BEM) . The minimum charge weights resulting in the ignition of predispersed oil shale dust clouds were measured for each of the explosives. A 400 g unstennned charge of ANFO (ammonium nitrate-fuel oil) was sufficient to initiate an oil shale dust explosion, whereas a 1000 g unstenuned charge of an emulsion blend did not ignite the dust even with the addition of 4% methane gas. Several stenuning materials were evaluated in the BEM for their effectiveness in preventing the ignition of near stoichiometric methane-air mixtures. Water stenuning was superior to all other inhibitors tested against methane. Explosibility testing of fine sulfide ore dust in a 20 L chamber and in the BEM show that the dust is capable of propagating an explosion given nominal concentrations of 700 to 800 g/m3. Results are encouraging and irrlicate that there is merit in pursuing explosive composition as a means of reducing ignition probability of oil shale and sulfide dust clouds generated during nonnal blasting operations. The proper selection of explosives and stenuning materials should significantly reduce the probability of secondacy dust explosions in oil shale and sulfide ore mining.

May 11, 1988

By A. A. Brant

ONE of the reasons advanced for the decline in prospecting and discovery is that, as regards surficial examination, the law of diminishing returns is becoming applicable. Fewer surficially unprospected fields remain; therefore, fewer discoveries by such means result. Much in the nature of mineral resources remains to be unearthed, but even now, and more so in the future, will discovery depend on painstaking petrographic and structural mapping, aided, where necessary, by judicious applications of all the complementary scientific knowledge and devices (e.g., thin section microscopy, geophysics, and drilling) that experience proves effective in localizing a mineral deposit even beneath drift, lake, or muskeg. It is to be expected, then, that the rate of discovery will decrease, that the cost per discovery will greatly increase, and that the work of discovery will become more and more the careful, methodical assembling of field data, conscientiously interpreted on the basis of scientific knowledge by trained, experienced operatives. In view of these trends, the status of applied geophysics to Canadian mining exploration and development work might well be reviewed. The niche which geophysics may occupy relative to geological surveying and drilling has been clarified by the last twenty years' experience. The cloud of somewhat justifiable scepticism that followed the 'geophysical promotion' period of the late 1920's has lifted. Mining, exploration, and finance companies, in open-minded fashion, are seeking sound advice as to what are the scope and limitations of the geophysical methods at present practised. The purpose of this paper and the following one is, therefore, as far as lies within the author's power, to review briefly the geophysical methods at present in practice in Canada, and, at greater length, to joint out impartially and critically their scope, merits, shortcomings, an possible future development. The treatment will be non-technical, the hope being that an accurate statement of the present status of geophysics in Canada may do much to result in a sounder, saner growth of what, in the future, shall undoubted} y prove an increasingly useful tool in exploration and development work. ?

Jan 1, 1942

By R. R. Potter

"New Brunswick became a separate province in 1784, shortly after the influx of a large number of Loyalists from the United States. Many of these people settled along the Saint John River, including the area of excellent farmland near the present town of Woodstock. There were indications that some of these early settlers recognized iron formations in the vicinity of Woodstock about 1820, however the nature of the deposits was not known until 1836 when Dr. C. T. Jackson, a geologist commissioned by the State of Maine, investigated the mineral potential of the area. Jackson(1) described the ""ore"" as compact red hematite yielding 44 per cent pure metallic iron, and suggested that sizable tonnages may be present. It was about this time that an extensive limonite deposit was found in north-central Maine, near Mt. Katahdin. Other iron depostis were found in the Nictaux area of Nova Scotia, and a few years later at Londonderry* (Fig. 1). In 1837, Richard Ketchum of Jacksonville, on whose land iron ores had been found, petitioned the provincial government to incorporate a company. After much study, the York and Carleton Mining Company Bill was passed on March 15, 184 7. Several other petitions were passed permitting the company to construct roads, obtain woodland, etc. (2) . The first blast furnace was erected in 1848 on the west bank of the Saint John River near the mouth of Lanes Creek."

Jan 1, 1999

By L. Magne, A. Pinto, M. Maldonado, J. A. Finch

Estimation of gas holdup from electrical conductivity measurements has been used in lab and industrial installations. The approach is based on the application of Maxwell's model, which relates the concentration of a dispersed phase in a continuous medium to measurements of the electrical conductivity of the dispersed phase, continuous medium and the resulting mixture (dispersion). When applied to inferring the collection zone gas holdup in a three phase system and to facilitate real-time on-line measurement, the slurry is assumed to behave as the continuous medium and gas bubbles as a nonconducting dispersed phase. This article derives an equation for estimating gas holdup in a three phase system, eliminating the assumption that the slurry behaves as a continuous medium but rather as a dispersion of non-conducting solid particles in water. In this formulation only water behaves as the continuous medium in the sense of Maxwell, and gas holdup in a three phase system is then calculated from the application of the Maxwell model twice: (1) to determine solid content in a two-phase system, and (2) to determine solid plus gas holdup in a three phase system. To validate the new equation and quantify the errors incurred by assuming slurry is the continuous phase a laboratory flotation cell was instrumented to continuously measure the conductivity of two and three phase dispersions with known solids contents. As the amount of gas in a lab flotation machine is difficult to measure directly or by another indirect technique such as using pressure signals, 2.5 mm dielectric plastic spheres having a density of ca. 1.3 g/cm3 were used instead of air bubbles for validation. Experimental results demonstrated that the continuous medium assumption underestimates gas holdup and that the resulting bias error increases linearly with the solid content and decreases with the magnitude of gas holdup.

Jan 1, 2016