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By J. A. Gutierrez-Rodriguez, R. J. Purcell, F. F. ApIan

"Based on contact-angle measurements and the work of adhesion equation, the hydrophobicity of a wide variety of coals was found to decrease with decreasing rank, fixed carbon and total carbon content and with increasing oxygen and hydroxyl content. The estimated hydrophobicity, based on the water-sessile-drop contact angle, is '\.. 20% for lignite, increases with increasing rank up to a maximum of 'V70% for low (LV) and medium (MV) volatile bituminous coals and then decreases somewhat for anthracite. Using the captive-bubble technique, the calculated hydrophobicity ranges from '\.. 0% (below HV A bituminous rank) to a maximum of 55% for L V-MV coal. The former estimation is believed to be the more accurate. While the water-sessile-drop contact angle as measured on a polished-coal surface is usually larger than that shown by the captive-bubble method, the two values were found to converge at""' 95% relative humidity. It is proposed that the surface of coal consists of three kinds of sites: strongly hydrophobic, weakly hydrophobic and hydrophilic. The sessile-drop technique measures the total hydrophobic sites whereas the captive-bubble method measures only the more strongly hydrophobic sites. A water film covers the weakly hydrophobic sites preventing their detection by the captive-bubble technique.INTRODUCTIONCoal is a mixture of the degradation products of plants and of mineral matter. The appearance and properties of a specific coal is determined by the nature of the original vegetation and the extent of the physical and chemical changes which have occurred after deposition. The coalification process may be considered to have started with peat formation followed by a transition to lignite due to burial under sediments and metamorphic processes. Further metamorphic transformation to bituminous coals and, finally, under intense metamorphic action, to anthracite causes the carbon content and rank of the coal to increase. With such a wide variation in their genesis and composition, equally wide variations in the degree of hydrophobicity of different coals may be expected. It is the purpose of this paper to provide a means of estimating the hydrophobicity of a given coal sample based on rank parameters."

Jan 1, 1989

By J. H. Rose

This paper describing the milling practice at the Magma Copper Co., Superior, Ariz., is one of a series being prepared by the Bureau of Mines on milling methods and costs in the various mining districts throughout the United States. ACKNOWLEDGMENT The authors wish to acknowledge their indebtedness to William Koerner, general manager of the Magma Copper Co., for permission to prepare this article; to J. S. Garrott, former mill superintendent, for the historical facts; and to Walter Cooksley, general foreman, for his assistance in obtaining the data.

Jan 1, 1930

By R. Ward Stahl

The underground junction or intersection is analogous to the doorway or window in a building in that the continuous wall or support for the overhead structure has been weakened by making the opening. Some type of bridge or support seems necessary to prevent roof sag and possibly eventual failure at this point, although frequently it appears that little is done until a fatal accident induces action. The intersection generally represents less than 15 percent of the exposed roof area. As a result of recent multiple fatalities, some of which occurred at or near intersections, the Bureau of Mines was asked to examine the junction-support problem more thoroughly and to report its findings. A national survey of the junction-support systems in use has been made by correspondence, and the local area has been canvassed rather thoroughly to determine just what and how much is being done.

Jan 1, 1962

The investigation summarized in this report addressed two primary issues: the determination and use of correction factors, and the development of guidelines for velocity measurement site selection. Other ancillary issues which were addressed include a comparison of measurement methods and devices, aircourse cross-sectional area measurement, and characteristics of mine airways. An exhaustive literature search and analysis was performed; extensive in-mine experiments were conducted; a quantitative analysis of the data was used to develop correction factor tables and site selection guidelines. The reported results of other researchers who have examined the correction factors and site selection criteria, were analyzed in light of the results of this study. The measurement devices included in the experimental phase were: vane anemometer, vortex shedding anemometer, a prototype thermoanemometer, smoke tube, and, oil of wintergreen. The measurement methods include single-point centerline, timed¬-point traverse, continuous traverse for the anemometers, and various distances and cloud positions for the smoke tube and oil of wintergreen devices.

Jan 1, 1983

By K. L. Paciorek

The aim of the present study was to determine the thermal oxidative behavior of materials used in coal mines, with emphasis on the type and relative concentration of the products, in particular the toxic species formed. To supplement this work and to gain understanding as to the type of products possibly formed and also to assess the limitations and advantages of the various analytical methods used a literature survey of the past investigations performed on the compositions of direct interest to the subject program was conducted. The compositions thus covered were cellulose, polyvinyl chloride, neoprene, urethanes, polyamides, polyesters, polyethylene, epoxy, phenoxy, urea-formaldehyde and melamine formaldehyde resins. The results of this review are compiled in the Appendix. The experimental work consisted of thermal oxidative degradation of 36 materials and 4 composites using a stagnation burner apparatus developed in these laboratories which affords a dynamic system approximating somewhat the conditions encountered in underground coal mines. This technique as employed during this program gave only the relative product concentration at specific periods of the decomposition process, The advantage of this approach is that in this manner screening of materials can be accomplished in conjunction with some assessment of the decomposition rate as influenced by temperature and material composition. Limited static tests were performed using a sealed tube method. The materials studied were grouped according to their compositions. The following were the main groups: (a) polyvinyl chloride-containing materials, (b) neoprene compositions, (c) rigid foams (urethanes, isocyanates), (d) miscellaneous materials (including jute, fiberglass, polyethylene and some articles of unknown composition), (e) coal and fluids (phosphate esters, organic esters, oil-water emulsions), and finally (J) composites. The latter comprised a mixture of a phosphate ester fluid with (a) coal, (b) a representative polyvinyl chloride sample, and (c) a neoprene type composition.

Jan 1, 1972

By Wilbur I. Duvall

In a review of so 40 papers on damage to residential structures resulting from blasting, only 3 were found that present data on the observed amplitude and frequency of the vibration levels produced by blasting together with an observed degree of damage to a residential structure. The data from these three reports have been analyzed statistically to determine if one of the quantities, displacement, velocity, or acceleration, is more reliable than the others for estimating the degree of damage to a residential structure. From this analysis the conclusion is drawn that a given degree of damage to a structure is most closely related to the magnitude of the particle velocity of the wave motion passing thru the earth at the structure location. On the average, only minor damage it observed for peak particle velocities of 5.4 inches per second, and major damage is observed for peak particle velocities of 7.6 inches per second. When the spread of the data is taken into consideration, the following statement can be made: Wave motions that have a peak particle velocity in excess of 2 inches per second have a fair probability of producing some damage to structures, whereas wave motions that have a peak velocity less than 2 inches per second have a very low probability of causing any damage. Therefore, the recommendation is made that vibration levels in the vicinity of residential structures should be maintained below a peat particle velocity of 2 inches per second. The above criterion for safe blasting is considered to hold over a wide variety of soil and rock conditions because the original data were obtained for a wide range of soil and rock conditions and on various types of residential structures. INTRODUCTION Ever since explosives were discovered and developed for mining purposes, there has existed the problem of what effects the air and ground vibrations resulting from blasting have on structures of various types. This problem is

Jan 1, 1962

By R. V. Higgins, A. J. Leighton

A computer program has been devised to calculate the reservoir performance of water floods of complicated well - spacing patterns . The method and program have been tested by calculating the waterflood performance of fivespot patterns using oils of different viscosities and the performance calculations agreed closely with laboratory results . The program on a high - speed digital computer will process the performance prediction in about 1 minute , which is very rapid for a prediction using so much fluid mechanics and nonlinear geometry . The program has been presented in such a way that one may use it as given and save the time required to write and " debug " one of his own . gram processes a complex reservoir analysis , many of the complicated steps are explained in detail , both for the fluid mechanics and the directions for the computer . The subtle features that originally delayed the application of the program to unusual combinations of permeability and viscosity relationships are incorporated and explained

Jan 1, 1963

By Richard A. Allwes

This U.S. Bureau of Mines report presents the results of structural analyses and full-scale physical tests conducted on a steel-set arch and tri-set. The purpose of the analyses and tests was to evaluate the suitability of these structures for use in roof-fall prone areas. The arch canopy test and design procedures previously developed by the Bureau were utilized in this evaluation. Theoretical resistance functions were established for the steel-set arch and tri-set and were representative of the experimental behavior of the structures. The resistance functions were used to determine the energy absorption capacity of the structures and to predict their dynamic response to impact loading. The dynamic tests demonstrated that the arch canopy design procedure is appropriate for tri-sets and yields conservative designs for both steel-set arches and tri-sets. As a result of this work, it is recommended that these two structures may be considered for use in roof-fall prone areas and for rehabilitation work, provided the arch canopy design procedure is utilized for each application and the principles underlying the design procedure are understood.

Jan 1, 2010

By Grace N. Broderick

U.S. supply and demand data for coal, by States and regions, were tabulated for the years 1960 and 1965. Estimates are provided of State-by-State quantitative data for the coal industry that can be integrated into State and regional energy balances by source, form, and consumer sectors, and used for estimates of interstate and interregional energy flows. The tables give an estimated total supply of coal available for consumption, and also report the distribution of the supply among the major consuming sectors (household and, commercial, industrial, transportation, and electricity generation). To enable comparison of coal data with those for other energy forms, tonnages were converted to British thermal units (Btu). Future energy analysis studies could be facilitated by changes in the categorization of information collected on the coal industry. The data shown are based primarily on Bureau of Mines source material.

Jan 1, 1969

By A. F. Baker

Tests were conducted in commercial foundries to determine the suitability of calcined anthracite as a cupola fuel. The calcined anthracite performed satisfactorily at two of the three foundries where iron-melting tests were conducted. Performance at the third installation was unsatisfactory because metal temperatures deviated widely and, in general, were lower than is desirable for the type of castings being made.

Jan 1, 1963

These proceedings consist of an overview of the in situ mining research currently being carried out by the Bureau of Mines. The following papers emphasize two general aspects of the in situ mining method: the environment and productivity. Both areas are extremely important, particularly because in situ leach mining is a relatively new mining method from a commercial point of view. Topics covered include the restoration of ground water, the selection of lixiviants, in situ mining of commodities other than uranium, in situ mining costs, the application of resistance measurements to in situ mining, an acid leach mining case history, and the use of branched boreholes for in situ mining. A bibliography of Bureau of Mines publications on in situ mining is appended.

Jan 1, 1981

8053. Andreev, B. A. Zakashanakii, M. S., Samsonov, N. N., and Fotiadi, E. E. A Textbook of Gravitational -Surveying, (in Russian). Gosgeolizdat, Moscow-Leningrad, 1941, 432 pp. This textbook was written at the suggestion of-the faculty of geophysical exploration of the Leningrad Mining Institute. It contains two parts: (1) Theory and technique, and (2) Applications to geology and exploration. The features bringing; the text up-to-date include: (a) Description of the principal modern gravimeters; particular attention to the method of simultaneous oscillation of 4 pendulums; (b) discussion of the aperiodic oscillation of torsion balances; outline of the construction of variometers Z -20 and Z-40; (c) material for aid in interpretation, such as reference-charts, formulas with their derivation, atlas of theoretical curves, and examples of interpretative calculations; (d) considerations in the planning of surveys and the densities of various rocks; and (e) detailed analysis of significant examples. The text is provided with a bibliography, V. S.

Jan 1, 1946

By S. P. Kinney, P. H. Royster, T. L. Joseph

"The study described in this paper, on the reactions in an iron blast furnace, is part of the investigation being conducted by the Bureau of Mines on combustion of coke and the reduction of iron oxides in the blast furnace. Previous study of the combustion zone of the iron blast furnace, by means of a series of as samples taken through the tuyeres across the hearths of 13 blast furnaces, showed that the combustion of the coke in the blast-furnace hearth is complete at a distance of 32 to 40 inches from the nose of the tuyere, measured horizontally toward the center of the furnace. The results of this previous work are sum¬marized in the curves shown in figure 1, where it will be noted that practically all of the oxygen disappears at a distance of approximately 30 inches from the nose of the tuyere.In order to determine the height at which oxygen is found in a vertical direction above the tuyeres - it had been suggested that the combustion zone turned upward near the tuyere and to obtain comparisons with the samples taken at the Bureau of Mines experimental6 (5-ton) blast-furnace at Minneapolis, the Bureau extended the gas sampling on a commercial furnace to a number of planes between the tuyere level and the stock line. The sampling was conducted on a 300-ton furnace, making foundry iron, operated by the Central Iron and Coal Co., at Holt, Ala. The furnace was smelting Southern red and brown ores and nodules from pyrite sinter. Figure 3 is a vertical section of the furnace showing the six planes sampled."

Apr 1, 1926

By Clyde E. Williams

[As a results of work conducted during the past three years, the Northwest Experiment Station of the Bureau of Mines, in cooperation with the University of Washington at Seattle, Washington, has developed a process for the production of sponge iron. Commercial operation of this process in a 3 to 4-ton scale has been so satisfactory that its use on a large scale (20 to 100 tons per day) can be safely considered. Description of Process. The process consists in passing a mixture of iron ore and coal through a rotating kiln heated at one end to a temperature sufficient to convert iron oxide to metallic iron, discharging, cooling, and separating the sponge iron from the residual coke and silicious material on a magnetic separator. Both the coal and the ore should be crushed to peso as 6-meth scream, tans producing particles finer then 1/12 of an inch. Seventy-five parts of coal or other carbonaceous material arc charged with every 100 parts of ore), This large amount of coal is required in order to supply sufficient carbon to maintain a strongly reducing atmosphere in the charge, but may be reduced to about 65 parts per 100 parts of ore by recovering and using tae carbon that remains in the discharge product. Large-scale operation and refinements in furnace design should lower this ratio to perhaps 56 or 60 parts of coal to 100 parts of ore.]

Jan 1, 1924

By R. L. Mazza

This final report on methods of reducing and controlling methane in coal mine gob areas indicates that vertical degas holes are beneficial to the mines of northern West Virginia working the Pittsburgh Coal. The USBM funded project involved the drilling and testing of eight vertical holes (four over longwall panels and four over room and pillar panels) based on a review of 13 previously in existence. Areas of observation included gas production history, flow entry profile, underground methane reductions, strata separations, and casing loads (accompanying subsidence). Observations led to the drilling of successful holes drilled short of the mine. Eleven gas production response to applied vacuum tests were conducted at nine degas holes under the contract. Significant production responses were recorded over longwall gobs.

Jan 1, 1977

By W. J. Fene, G. W. Grove

An important activity of the Safety Division of the Bureau of Mines , in its efforts to reduce accidents , is the safety inspection of mines . Inspections are made at the request of the operators and are not connected with the inspections by the various State departments of mines . The operating management is furnished with a confidential report of the results of the Bureau's inspections , with recommendations for elimination of the hazards found . These mine - safety inspections include a study of mining practices , conditions , and equipment and in some cases the sampling and analysis of mine air and coal dust . The Bureau of Mines has no regulatory powers , therefore the recommendations made in these reports are merely suggestions , and operators are not required to adopt them . Mine inspections are a check on safety standards , methods , and practices and are essential to any accident -prevention program . A foreman or superintendent may be sincere in his efforts to operate a mine safely and believe that he has done everything possible to attain this end . However , experience has shown that because of his familiarity with the mine and the consequent " nearness " of its various features many unsafe conditions may be , and in most cases are , overlooked ; an inspector , particularly an outsider who is trained to look for hazards , can point out the unsafe conditions overlooked by the foreman or superintendent . Some companies employ safety engineers who make regular inspections of their mines , report substandard conditions and hazards found , and make recommendations for correcting them . Unless these recommendations are carried out the inspections have little value . In making recommendations , due consideration should be given to the feasibility of carrying them out ; the management may and very often does consider a recommendation impracticable because of the

Mar 1, 1935

This report summarizes a study conducted by The Service Bureau Corporation for the Bureau of Mines. Evaluations reflected herein are the result of an independent investigation by The Service Bureau Corporation of methane considerations during coal mining. The study is oriented toward a systematic analysis of methane control problems during coal mining. Throughout this study an attempt has been made to ensure considerations consistent with the recently enacted Federal Coal Mine Health and Safety Act of 1969. References to reports by The Bureau of Mines and others are made for the purposes of establishing identification between the evaluations contained in this report and on-going research efforts.

Jan 1, 1970

By Irvin Pritts

This report describes the design, fabrication, and testing of a prototype instrument which demonstrates the feasibility of determining respirable coal dust concentrations by light reflectance photometry. Coal dust is collected on a filter and the quantity collected is continuously monitored by reflectance-photometry. Light emission and detection is accomplished by reflective object sensors, which have both light source and detector in one chip. The use of a pulsed light source insures low drift characteristics of the measuring circuitry. The collection of the respirable coal dust on filters facilitates accurate calibration and also allows measurement verification, if desired, by well-accepted, gravimetric methods.

Jan 1, 1981

By E. F. Ferrell

Electrowon molybdenum powders and a commercial hydrogen-reduced powder, all with different minor impurities, were investigated by the Bureau of Mines with respect to inherent properties, to fabrication techniques, and to proper-ties of the fabricated sheet. Compared with the commercial hydrogen-reduced powder, the electrowon powders had a larger particle size, a greater flow rate, a higher apparent density, and a lower oxygen content. Sheet materials prepared from the two types of powders showed similar mechanical properties, under the same conditions of heat treatments, except for low-temperature ductility. Yield strengths varied with carbon content, heat treatment, and test temperature.

Jan 1, 1970

By C. H. Manney

This report deals with the feasibility of the use of vocoders as an integral part of a mine electromagnetic voice communication system. Limitations imposed by the nature of the transmission path, background noise and equipment are examined. Some properties of vocoders and apparent advantages of the use of vocoders in a mine communication are discussed. The conclusion is reached that the man-made noise level will ultimately determine the workability of such a system.

Jan 1, 1972