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By V. V. Morozov, Ganbaatar Zorigt, Delgerbat Lodoy, Y. P. Morozov

"At the processing plant Erdenet, a new facility for advanced ore diagnostics in-stream (at the conveyor), based on optical analyser of mineral composition, was tested. Such systems provide highly accurate in-stream measurements of ore properties. The system provided information on the ore mineralogical composition, the particle size distribution and the impregnation of minerals. A special flatbed facility for optical spectrum-based estimation of fine-crushed ore has been developed, being incorporated into the existing system of ore sampling and analysis. Application of the flatbed facility renders possible a high accuracy of determining ore mineralogical composition. High precision of the optical spectrum-based estimation is achieved using special devices, installed in the sampling and the sample analysis flow sheet, applied by the technical control department. Modern systems for optical spectrum-based estimation of ore grade provide a basis for effective automated control of ore benefication processes, based on the principle of advanced ore grade control. Process management task of grinding and flotation was to choose options that take into account the composition and grade of the ore coming. The calculation data array comprises consumption of reagents, ore processing, grind size etc. The systems implemented at the processing plant contributed to increasing copper and molybdenum recovery. INTRODUCTION In-stream ore grade analysis is a new trend in effective control of ore benefication processes. This is realised based on radiometric measurements in the X-ray and visible spectrum regions, in which mineral components of the initial ore (Sbárbaro and Villar, 2010) or the benefication products become apparent (Hyotyniemi and Ylinen, 1998; Haavisto and Hyötyniemi, 2010). An important advantage of such methods is in-stream measuring ore parameters, including mass fractions of individual minerals, which makes it possible to use the information obtained in the processes of automated control."

Jan 1, 2018

By Khoi Nguyen, Keeney. Luke

An outcome of geometallurgical mapping and modeling is the generation of continuous down hole profiles of quantitative geometallurgical attributes at assay scale. These attributes vary from traditional routine data collection methods such as assays and geotechnical logging (e.g. RQD, Fracture Frequency), to new measurements including petrophysical attributes, EQUOtip hardness data and modelled estimates of metallurgical performance indices (e.g. A*b, BMWi). Highly variable continuous geometallurgical data with high spatial resolution can make it difficult to identify spatially continuous domains. An automated method based on the well known time series analysis technique of cumulative summation (CuSum) has been developed which uses statistical analysis to identify domain boundaries in down hole profiles. A bootstrap analysis automatically identifies potential domain boundary locations with associated confidence levels and a series of t-tests determine the significance of defined populations. A hierarchical clustering algorithm is applied to results to enable data sensitivity to be taken into account. The method produces statistically significant populations and is suitable for application on either single or multiple drill hole datasets. Domains defined preserve the inherent variability of the continuous down hole data and provide a method for scaling up variability data (i.e. assay interval scale) to mine scale (i.e. bench scale, block model). A major advantage of the method is its ability to provide suitable input parameters for use in spatial modeling of non-additive and non-linear geometallurgical attributes through conditional simulation techniques.

Jan 1, 2014

By M. S. Eygi

This study covers the investigations based on the electrokinetic and rheological properties to explain the interactions between kaolin minerals and commercially available polyelectrolyte in anionic character. Additional adsorption test were also conducted to support the interaction mechanism. Adsorption tests showed that adsorption densities decrease by increasing the solid content. In-creasing the solids contents from 1% to 30% by weight resulted in the decrease on adsorption from 2.14 mg/g to 1.85 mg/g. Because of its difficulty, the solids ratio at 70% was not studied. However, following to trend of the curve plotted adsorption density-solid ratio, an estimation was made and adsorption density at 70% solid content was extracted from the curve as 1.75~1.80 mg/g. The electrokinetic studies pointed out that the presence of polyelectrolyte increase the zeta potential of kaolin from 40 mV to 60 mV which is reasonable conditions to disperse and stabilize the kaolin slurry and lower the viscosity. When these result of the different tests are combined and considered together, 2 mg/g polyelectrolyte concentration was noted as optimal concentration where adsorption density, viscosity and zeta potential of the slurries give maxima and remain constant after this concentration.

Jan 1, 2014

By Nirmal Weerasekara, Malcolm Powell, Mohsen Yahyaei

"The conditions under which rocks become superficially damaged during the grinding process are not well understood. The main purpose of the work presented here is to understand how superficial breakage occurs under incremental low-energy impacts. To enable this study a series of abrasion tests with multi-size pilot mills have been performed. Outcomes of numerical simulation corresponding to each test were examined to investigate the experimental results. Abrasion tests have been conducted using three grinding mill sizes (i.e. 1.8, 1.2, and 0.8 m). Two types of ore were used to investigate different hardness strengths. To ensure abrasion was the dominant mechanism, in all tests the mill speed was reduced to 40% of critical speed. The relationship between the Fractional mass loss rate and particle size was investigated by randomly collecting seven tracer particles from sizes -73+63, -53+45, and -37.5+31.5 mm. It was evident from the results that the Fractional mass loss rate of angular particles declines as the particle size increases whereas the Fractional mass loss rate decreases from fine to coarse in rounded particles. Results of Discrete Element Method (DEM) simulations indicate that fine particles experience higher levels of collision energy per particle and this value reduces as the particle size increases and mill size reduces. This explains the higher Fractional mass loss rate of smaller particles as well as the increase in the Fractional mass loss rate as the mill size increases. Linked DEM and experimental data indicates that under these test conditions surface damage attrition is the dominant mechanism. This work suggests that DEM simulation can be implemented to predict the abrasion wear of particles in mills."

Jan 1, 2014

By T. Fujita

A high-grade fluorite ore is converted into hydrogen fluoride to produce many kinds of materials containing fluorine. Recently, it is becoming necessary to use low-grade fluorite ore due to the depletion of high grade ore. The low-grade fluorites usually have impurities such as SiO2, P, CaCO3 and arsenic. The most impurities such as SiO2, CaCO3 and P can be removed by using flotation method. However, the removal of arsenic is difficult, and the arsenic contamination decreases the hydrogen fluoride production percentage. The novel technologies for processing low-grade fluorite ore are urgently needed, in order to lower the arsenic concentration to less than 100 mg/kg. In this study, the removal of arsenic from low-grade fluorite ore has been investigated by means of an autogenous grinding using tower mill in sulfuric acid aqueous solution and 0.3 mm zirconia balls in water. The nano grinding in water can prevent the dissolution of 0.3 mm size zirconia balls as grinding media by sulfuric acid solution. Experimental results showed that the arsenic concentration was reduced from 260 mg/kg to 90 mg/kg and CaF2 recovery reached 90% by this process.

Sep 1, 2012

By A. A. Novoselov, U. Kelm

"Large volumes of mine tailings accumulated in surroundings of porphyry copper deposits represent a growing threat to environment. They contain significant concentrations of toxic metal and metalloids which can contaminate river runoff, ground waters or can be transported by wind. Both extreme pH of fluids in tailings impoundments and high surface areas of processed mineral grains provide their increased reactivity. As a result, during only a few decades, As, Cu, and Mo can be mobilized, redistributed through the tailing column and accumulated through post-deposition leaching, evaporation and contamination with natural fluids. Those processes are reflected in the forming of secondary minerals. Gypsum, Fe oxides/hydroxides, efflorescent salts and clay minerals are typical alteration products in tailings. Here we present the results of reactive transport simulations implemented on the base of PHREEQC and SUTRA codes. The one-dimension model emulates the mass balance between rainfall, evaporation and subsurface runoff, the kinetically- and thermodynamically-driven dissolution of tailing minerals, advective and diffusive transport of tailing fluids, and precipitation of secondary phases. A typical tailing column is composed of four unequal layers with predominance of (i) evaporation, (ii) secondary mineralization above, (iii) below water table, and (iv) near the bottom of dump. Those horizons are characterized by contrasting pH, chemical composition and bulk mineralization of pore fluids, distinct accessibility of atmospheric oxygen and, as a consequence, distinct intensity of sulfide oxidation. The modeling and its verification on Chilean tailings impoundments reveal the complexity and high rates of secondary mineralization. The accumulation of toxic alteration products is controlled by fluid transport through the tailing column induced by both rainfall/evaporation and exchange with subsurface runoff. The geochemical modeling is a powerful approach which allows comparing the processes in tailing deposits produced by distinct flotation regimes and providing the long-term predictions of their environmental impact as well as identifying sectors of tailings for possible re-processing."

Jan 1, 2018

By Yuqing Feng, Ping Fang, Dezhou Wei, Zichuan Guan, Shuling Gao, Baoyu Cui

"Air core, as an inevitable phenomenon of rotational flow field inside hydrocyclone, has a major impact on hydrocyclone’s separation characteristics. The air core formation process, its structural features and its influencing factors were investigated systematically in this paper. Numerical study on the air core of a f50 mm hydrocyclone was carried out using a commercial computational fluid dynamics (CFD) modelling software package ANSYS/Fluent with the selection of Reynolds Stress Model (RSM) for the turbulence model and Volume of Fluid (VOF) for capturing the air-liquid interface. Physical experiments were conducted under the same geometry and operation conditions and the particle image velocimetry (PIV) technology was used to measure the liquid flow. The CFD results are compared with the experimental measurement with good agreement demonstrated. The air core was formed generally at around 0.7 s, air outsides of the air core was eliminated completely after 1.7 s. The centreline axial velocities and the water blocking hydrocyclone simulations showed that air of the air core entered the hydrocyclone from the underflow area and exhausted from the overflow area, but there was also some air flowing into the air core from the overflow area. The largest swing of the air core occurred on the top of the underflow pipe, and a protuberance similar to the shape of Adam’s apple appeared when the air entered the vortex finder. CFD simulation results also showed that the air core diameter was decided by axial position and parameters of hydrocyclone. The structural parameters have more effects on the air core diameter than the operational parameters."

Jan 1, 2014

By Takaaki Wajima

The slag was attempted to be converted into the adsorbent for phosphate removal from aqueous solution using the alkali fusion method. The slag was mixed with NaOH powder (NaOH / Slag = 1.6), and then the mixture was heated at 600 ? for 6 h to prepare the precursor. The precursor was stirred at room temperature in distilled water to synthesize the adsorbent, and the removal ability of the obtained adsorbent for phosphate from aqueous solution was investigated. The products, including hydrocalumite and calcite, were synthesized, and the removal efficiencies of the adsorbent for F- and PO43- showed higher than those of raw BF slag, especially removal of PO43- are excellent (99 %), while the removal of Cl- , SO42-, NO3- and Br- was minor. The adsorbent could remove PO43- selectively in the co-existing solution of Cl-, NO3-, F-, SO42- and Br-.The equilibrium adsorption capacity of the adsorbent for PO43- was extrapolated using Langmuir and Freundlich models, and experimental data are found to fit Langmuir than Freundlich. The calculated maximum adsorption capacity of the adsorbent for PO43- is higher than other adsorbent reported previously. The high affinity of the adsorbent for PO43- in aqueous solution was caused by the formation of hydroxyapatite [Ca5(PO4)3(OH)] and brushite [CaHPO4?2H2O]. The prepared adsorbent is expected to be anew inorganic adsorbent for the removal of phosphate ion from wastewater. Keywords: Blast furnace slag, Alkali fusion, Phosphate removal, High selectivity

Sep 1, 2012

By A. Üçyildiz

Magnesium borates of varying compositions and properties are synthesized using different reagents and methods for the possible potential uses as termoluminescent material, anti-wear and anti-friction additive, fire retardant, catalyst for the conversion of hydrocarbons, whisker material and ferroelastic material. In the current work, the conditions for synthesizing MgB4O7 compound by high-temperature solid-state reactions were investigated using boric acid and magnesium oxide as the starting materials. The MgO:B2O3 mole ratios applied in the experiments were 1:1, 1:2, 1:3 and the thermal behaviours of each mixture were studied between 25~1200°C by TG/DTA analyses under static air atmosphere to find out the probable formation temperature of MgB4O7 phase. Considering TG/DTA results, freshly prepared boric acid and magnesium oxide solid mixtures were heated at predeter-mined temperatures and the phases were identified by XRD analyses. Accordingly, MgO:B2O3 mole ratio of 1:2, heating temperature of 950°C and a reaction time of 2 hours were selected as the optimum conditions for the formation of maximum amounts of MgB4O7. After obtaining solids prepared at the pre-determined optimum conditions, their chemical composition, IR spectrum, TG/DTA pattern, B.E.T. surface area value, particle size distribution and SEM images were deter-mined to point out the possible use areas. Experimental results showed that it was not possible to obtain pure product at the optimum conditions due to formation of minor amounts of t-Mg2B2O5 and the presence of some unreacted B2O3. The product synthesized has the potential for use as a corrosion inhibitor on some metal surfaces.

Jan 1, 2014

By A. Güney

Currently, recycling technologies use relatively homogeneous plastics because hand-sorting waste feed is too expensive. Many promising technologies for separating mixed thermoplastics are being investigated, but they are still uneconomical and unreliable. Burning plastics for recycling is not used because of poisonous gases released when their burning. PET and PVC cannot be separated using conventional gravity separation techniques because their specific gravities overlap; PET density changes from 1.33 g/cc to 1.37 g/cc and PVC density is between 1.32 g/cc and 1.37 g/cc. For this reason, plastic recycling needs new techniques. Among these techniques froth flotation, also used in mineral processing, can be useful for its cost and simplicity. In this method, a plastic is selected from mixture, tried to regain its natural property, hydrophobicity. In this study the experiments were applied by using plasticizer reagents to make the selected plastics hydrophobic and us-ing NaOH to render the other hydrophilic. Post-consumed PET and PVC are evaluated by concerning the effects of selected parameters (particle size, concentration of plasticizer reagent, amount of NaOH, conditioning time and the effect of conditioning temperature). At the end of the experiments, optimum parameters for selective flotation of PET from PVC was found as particle size of -4.76 + 3.36 mm, NaOH amount of 30 kg/t, conditioning temperature of 75°C, conditioning time of 30 minutes, reagent amount of 300 mg/L. Consequently, PET was re-covered with 99.7% purity and 57% efficiency.

Jan 1, 2014

By Stuart Simpson

The biggest environmental challenge in mining is the management of mine tailings. Deep----sea tailings placement (DTSP) is practiced where the environmental impacts are predicted to be less than the impacts of tailings storage facilities on land. However, DSTP is often highly controversial owing to the challenges in assessing the impacts in deep water environments and potential long----term impacts beyond the proposed tailings footprint. It is well recognized that total contaminant concentrations are often poor predictors of the risk posed by contaminants in sediments. Metals within tailings are mostly present in highly mineralised forms that are typically much less bioavailable to organisms when compared to other common anthropogenic metals. Thus while metal concentrations in tailings can often appear alarmingly high, when compared to sediment quality guidelines (SQGs) used for assessing common urban and industrial impacts, the bioavailability is typically low. Although now well----embedded within risk----based sediment quality assessment frameworks, contaminant bioavailability is still often overlooked in the management of contaminated sediments. In this presentation, we assess and demonstrate the low bioavailability and chronic ecotoxicology of mineral----rich tailings to two benthic invertebrates, recognized for their sensitivity to metals: impairment of reproduction of the amphipod, Melita plumulosa, and the harpacticoid copepod, Nitocra spinipes. We demonstrate that the metal exposure from mine tailings is low when total concentrations are considered, and that the dose to the organism and toxic response observed is highly dependent on contaminant bioavailability. We discuss a range of approaches for the effective incorporation of metal bioavailability when applying SQGs or setting site-specific management limits for mine tailings in marine environments. While proposed DSTP operations require a high level of environmental scrutiny and monitoring during operation and post-closure, environmentally sustainable operations may be achieved when the bioavailable forms of metals within tailings remain below suitable management limits.

Jan 1, 2014

By A. Otsuki

This paper describes the evaluation method of dispersion and coagulation of silica nano-particles by means of interactive force apparatus. The apparatus measures the size of fine particles in aqueous solution or organic solvent of high concentration and/or low optical transparency. Other conventional apparatus for size measurements (such as, apparatus utilizing dynamic light scattering) are difficult to measure the size of particles in such conditions accurately, due to multi-scattering of light in the sample solution or solvent. The apparatus measures the interactive force between two surfaces, i.e. the gold-coated glass hemisphere and the brass flat plate, (which is fixed at the bottom of the sample cell). The apparatus has three parts, i.e. main part (which consists of electric balance, hemisphere and flat plate), control part (i.e. personal computer, piezo-stage controller and voltage supplier), and detecting part (i.e. multi-meter and oscilloscope). During the measurement, electric field is applied between the hemisphere and flat plate, and thus dielectric particles are arranged toward the direction of electric field in the area between two plates. When the two plates are close to each other, two different forces (i.e. repulsive force and attractive force) will alternately act on particles due to the structure change of the particles. The repulsive force occurs when the structure of particles is stretched by compressive force; whereas the attractive force occurs when the aggregate structure is broken. The cycle of the repulsive and attractive forces is a primary size of particle or size of aggregate, which depends on the degree of agglomeration. The measured size of particles, which is varied depending on their degree of dispersion and coagulation, determined the characteristics of the silica particles. In this research work, the effect of size and concentration of particles in aqueous solution on the degree of dispersion and coagulation of the silica particles were investigated. Spherical silica particles were selected for this investigation due to their variety of size. This apparatus can be used to evaluate the degree of dispersion and coagulation of other nano-particles in various solvents in many process industries.

Jan 1, 2014

By Xiaoping Xu, Tiansong Dong, Guosheng Wang

"Jianfengpo tin ore is located in Jiangxi Province, China. The cassiterite is fine and dispersed. It is hard to separate marmatite from a variety of sulfide minerals. Because the iron-containing sulfide minerals including pyrrhotite, pyrite and chalcopyrite are detrimental to the improvement of the grade of zinc concentrate. Besides, the presence of the iron oxides and ferro-carbonate minerals results in the difficult beneficiation of tin. Therefore, Jianfengpo tin ore is a kind of refractory cassiterite polymetallic sulfide ore. According to the properties of Jianfengpo tin ore, the technology process of "Sulphide ore preflotation-Bulk flotation of sulphur and zinc-Separation of sulphur and zinc -Magnetic separation-Gravity concentration" was developed to recover the valuable materials including marmatite, pyrite, magnetite, cassiterite and indium comprehensively. For the feed ore containing 0.87% Sn and 0.70% Zn, a zinc concentrate of 44.56% Zn with a recovery of 69.10%, a high-grade tin concentrate of 54.38% Sn with a recovery of 53.03% and a low-grade tin concentrate of 6.54% Sn with a recovery of 1.25% can be achieved in the batch flotation tests. In the industrial tests, for the feeding which contains 0.55% Sn and 0.65% Zn, the tin concentrate of 49.10% Sn with a recovery of 48.52% as well as the zinc concentrate of 45.11% Zn with a recovery of 60.10% can be produced. Thus some pyrite and magnetite concentrate are recovered as well. So Zinc, tin, sulphur and iron ores are recovered effectively by the technology."

Jan 1, 2014

By Douglas W. Fuerstenau

Some historical sketches of the early development of froth flotation are presented. Flotation technology involves several aspects: chemical control of mineral hydrophobicity, selectivity in flotation, flotation kinetics, flotation machines, and process optimization and control. However, only some aspects of the regulation of mineral flotability by the addition of chemical collectors in some selected cases are discussed. The early contributions to flotation science by Langmuir, Gaudin, Wark, and Taggart are briefly outlined. With a firmer understanding of surface chemistry, electrochemistry, and the electrical double layer, progress has been made in understanding the fundamentals of flotation chemistry, although sound theoretical underpinnings still are needed in these very complex systems. Flotation chemistry is related very directly to the type of mineral being floated since the systems depend strongly on the chemical and physical characteristics of the minerals. Full discussion of chemical reagent phenomena would be in terms of the behavior of naturally flotable minerals, sulfides, oxides, silicates and alumino-silicates, and salt-type minerals. At this time, citing a few cases involving salt-type minerals and oxides, the dependence of their flotation surface chemistry will be discussed in terms of the role of adsorption, surface reaction, and the hydrophobic effect.

Sep 1, 2012

By M. M. Yahyaei

The Sarcheshmeh new concentration plant uses a 32 ft×16 ft constant speed (10.5 RPM) SAG mill with two 5500 hp motors which could rotate in two directions. The mill liners are chrome-molybdenum steel casting type with a Brinnell hardness between 325 and 375 with the lifter face angle of 14° and lifter height of 152 mm. The shell liner consists of 120 (two 60 rows) pieces with a High-High configuration in a rail design. A specially designed liner wear profile measuring device enabled fast and accurate measurements inside the mill during the mill shut-down periods. The measurements indicated that the liner wear profile along the liner length is non-uniform and the highest wear occurs between 1.25m and 2.75m of the mill length. The average weight of liners at the time of removal was 47% of the original weight indicating a significant metal loss. The modification of liner shape was undertaken with the aim of having a uniform profile at the liner removal time. The proposed liner unlike the pervious type did not have a uniform shape with a lifter height of 187mm at the section where the wear rate was high. It was believed that this new profile could arrive at a uniform profile at the liner change out time. A study was also directed to the possible change of charge motion due to the liner profile modification. The dynamic behaviour of charge was investigated through the analysis of forces acting on a single ball using mill characteristics such as mill diameter, rotational speed, lifter height and release angle. The simulation of charge motion with this method and Milltraj TM software indicated that the impact position of charge will change only one degree due to the maximum increase of 35 mm in the lifter height. This assured that the installation of the modified liner would not have any adverse effect on the mill because of ball impacting the mill shell. It was predicated that the amount of scrap metal will reduce to 30% from the current value of 47% beside 1500 h increase in the liner life time.

Jan 1, 2014

Cenospheres is a sandlike hollow sphere component of the fly ash that is collected in coal-burning electric power generating plants. Metal coated particles have been widely used in industries. Magnetron sputtering method which was used to coat copper film on the surface of the cenospheres is a widely used coating technique in large surface metal coating. A newly designed equipment is used to make the fine particle coating can be carried out because the fine particle is hard to disperse and it must make the particle keep moving to let every direction of the particle be coated. The copper film coated is compact, smooth, even and without uncoated spots under the optical microscopy and SEM. The film has good affinity to the cenosphere surface. The film does not separate with cenoshpere surface even when the cenosphere is crushed. The XRD, SEM, XPS, SPM was used to study the copper film characteristic. It is shown that using this newly designed magnetic sputtering equipment can coat high quality copper nanofilm on the cenoshpere surface.

Jan 1, 2014

By V. G. Prikhodko, G. I. Sukhinin, I. V. Yarygin, A. V. Fedoseev, S. A. Novopashin

"The first experiments on the vacuum drying of spherical clay sample are presented and the theoretical model of the process is considered. The model is based on the solution of the heat and the moisture transfer equations with the effective thermal conductivity and water diffusion coefficients for wet porous clay-like medium. The time and radial dependence of the temperature and the moisture were calculated for different initial conditions. The results obtained for the time dependence of the moisture content are in good agreement with the experimental results obtained in the initial period, when all the moisture in the sample did not freeze to form an ice crust. INTRODUCTION Capillary-porous materials very often occur in nature and in industry. A porous medium is a solid matrix with voids, or pores, which are continuously connected. These pores are usually filled with fluids or moisture, water vapor and air that can pass through the medium because the voids are interconnected. The void fraction in the solid matrix is referred to as the porosity. Porosity or void fraction is a measure of the void (i.e. ""empty"") spaces in a material, and is a fraction of the volume of voids over the total volume. The moisture content in porous media determines the properties of the porous body, its mechanical and thermo-physical properties, such as density, plasticity, viscoelasticity, swelling, cracking, and so on. Complex processes of heat and mass transfer occur in porous bodies when they are heated or cooled, during drying or freezing (Luikov,1966). The course of these processes depends essentially on the physical-chemical composition of the solid matrix of the porous body, on its fractal dimension, porosity and morphology. The clay and clay minerals are the most important porous materials in the history of the mankind (Mukherjee, 2013). Clay is a very fine grained, unconsolidated rock matter, which is plastic when wet, but becomes hard and stony when heated. It has its origin in natural processes, mostly complex weathering, transported and deposited by sedimentation within geological periods. Clay is composed of silica {SiO2), Alumina (Al2O3) and water (H2O) plus appreciable concentrations of oxides of iron, alkali and alkaline earth, and contains groups of crystalline substances such as quartz, feldspar, and mica. Building materials, bricks, and tiles, pottery, porcelain and faience are made from clay. Clay is used in the food and medical industry, and, not least, in the mining industry as a carrier containing aluminum, silicon and other valuable elements, as well as metals (copper, gold) as constituents, contained in the pores in the form of micro- and nano-particles or grains."

Jan 1, 2018

By B. McFadzean, K. Moller

"The mechanism whereby thiol collectors adsorb onto a mineral surface has been widely studied. Most of these studies examine the mineral surface at equilibrium state and, often, well above monolayer coverage. However, the formation of species at the mineral surface is a complex process that is both kinetically and thermodynamically controlled. In a typical industrial application, the dosage of collector will be around monolayer level. This study uses isothermal titration microcalorimetry to measure the heat evolved during the reaction of sodium ethyl xanthate (SEX) and sodium isobutyl dithiocarbamate (SIBDTC) and their mixtures with galena and chalcopyrite. The sensitivity of the instrument allows heats of reaction of sub-monolayer quantities of thiol collector to be measured.The study found that both the magnitude and kinetics of the reaction between a collector and a mineral surface was dependent on the type of mineral and the type of collector. Proposals are made for the reactions based on literature and the evidence from this investigation. It was found that when collectors were reacted with mixtures of galena and chalcopyrite, that the magnitude of the reaction was lower compared to that measured for the pure minerals alone. This may be due to galvanic interactions between the minerals, resulting in a passivating effect on one or both of the minerals."

Jan 1, 2014

By Graeme Heyes, Warren J. Bruckard, Michael A. Somerville

"Over the past few years CSIRO Minerals has been conducting research aimed at developing a continuous copper converting process to replace the traditional two-stage batch process that is currently used to produce blister copper. Sirosmelt type reactors and calcium-ferrite (lime-based) slags have been used rather than the conventional iron silicate slags. The research work has now been extended to focus on the development of a single-stage continuous copper making process (so-called direct copper converting) in which copper concentrates are converted to low-sulfur blister copper in a single step, that is the smelting and converting steps occur in one continuous stage.One feature of the direct copper converting process is that copper losses to the slag phase can be high, meaning the slag produced needs to be treated to recover the copper value. The feasibility of the whole copper making process will most likely depend on the efficiency and cost effectiveness of the copper recovery stage. Flotation has been identified as the most economical option to recover the copper from direct copper converting slags where it has been estimated that a copper recovery from the slag of above 90% is required to make the overall single stage copper making process economically feasible.A limited series of laboratory batch flotation tests was conducted on a suite of calcium-ferrite-based slags made in laboratory smelting trials. Copper sulfide concentrates from MIM were used as feed-stocks. The objectives of this work were to develop a robust flotation process to maximise the copper recovery and iron rejection from slags made in the process, and to establish operating conditions for future continuous flotation pilot plant trials.The slags treated included a reduced low copper slag, an oxidised high copper slag composite, and a very reduced low copper self-pulverising slag. The copper content of the slags varied from 2.9% to 14% Cu and the CaO/Fe ratio varied between 0.30 and 0.54. In general, the higher the copper content the more oxidised the slag. The copper was present as metallic copper, oxide copper and copper-calcium ferrite phases with the phase mix related to smelting conditions. The slags were crushed, ground, wet-screened at 355 or 210 µm to remove coarse metallic particles of copper, and floated at natural pH (about pH 11) using reagents and conditions appropriate for the selective recovery of the copper phases. Reagent additions were typically 200 g/t KEX and 500 g/t Na2S.9H2O and the grind size was generally a P80 of about 40 µm."

Jan 1, 2003

By E. V. Manlapig, M. C. Harris

"The complexity of the flotation process has made the identification of an appropriate model structure for the predictive simulation of flotation circuits far from obvious. Work performed under the auspices of the AMIRA P9 flotation program has indicated that the metallurgical performance achieved from a flotation cell arises from the interaction of two essentially independent property classes, namely the cell operating conditions and the properties of the cell feed stream. These observations have led to the development of a model structure that associates a constant set of flotation parameters to the streams of the circuit, which are transformed into a flotation response depending on the operating conditions within the flotation cell.A variety of alternative model structures exist within the literature which do not make this distinction between cell and stream flotation properties, and many of these models are in widespread use for flotation optimisation and design studies, both in industry and academia.In this paper, circuit survey and laboratory batch flotation data collected from an industrial flotation circuit are analysed. The data demonstrate that streams in an industrial flotation circuit exhibit varying particle floatability – concentrate streams typically float faster than tailing streams (Figure 1(a)). This floatability, however, is generally conserved around the various units within the flotation process (i.e. the effective floatability of the combined feed and product streams of a unit is equivalent (Figure 1(b)))."

Jan 1, 2003