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By Jennifer L. Durocher

The speciation of Uranium in silica-rich depositional layers in the proximity to uranium ore deposits was investigated using micro X-ray fluorescence (VESPERS beamline), X-ray Photoelectron Spectroscopy, Laser-Ablation ICP-MS, Scanning Electron Microscopy, X-ray diffraction and micro-Raman Spectroscopy. The heterogeneous Si-rich laminations contain micrometer-size inclusions of secondary uranyl-minerals. The U concentration in these layers range from several ppm to lower weight percent and the U 4f spectra indicate variable U6+ : U4+ ratios. Correlation between the concentrations of U and other metals (M) suggests the presence of M-U-bearing nanoparticles or species within the amorphous silica matrix.

Aug 1, 2010

By Charles Graham

For hundreds of years the standard vertical mine shaft was rectangular shaped and timber lined. There are many advantages to rectangular shafts but as mines became deeper the circular shaft became more popular. The chief advantages of circular, concrete lined shafts are their ability to resist lateral pressure and they offer less resistance to ventilation air. A number of elliptical shafts have been sunk in an attempt to realize the advantages of both the rectangular and the circular shaft. A concrete lined elliptical shaft provides better space utilization than a circular shaft, would allow for shaft sinking with two double drum hoists, as well as concurrent level development. The design also makes one sided stations possible and provides for a simple headframe design.

Feb 1, 2008

By Carol E. Jones

?Reclaiming the land? in the Athabasca Oil Sands is becoming a household phrase in Canada. Advances in soil salvage and placement, increasing biodiversity of forest ecosystems and improved design of the landforms are beginning to change the trajectory of the ?reclaimed land? towards a boreal forest. The boreal forest is much more than just a forest; in the area of Fort McMurray AB, roughly one half of the boreal forest is composed of organic wetlands, often called muskeg. How important is muskeg to the boreal forest ecosystem and to the local aboriginal people? Should muskeg be reclaimed? Can muskeg be reclaimed? Ten years ago it was broadly accepted that organic wetlands could not be re-established; in fact this was so well accepted that reclamation of organic wetlands had not been attempted. Over the past decade this conclusion has been re-evaluated and research projects have been undertaken to examine the potential to create organic wetlands in a reclaimed oil sands landscape. This paper examines these questions and the research initiatives necessary to reclaim the other half of the Athabasca Oil Sands.

May 1, 2011

By M. Bertrand

Oxalic precipitation is usually applied to process radioactive wastes or to recover actinides from a multicomponent solution. Precipitation reactions being highly sensitive to many operation parameters, the computer simulation appears to be a very effective tool to forecast the evolutions of the system subjected to various operating conditions. This study focuses on the tetravalent uranium oxalate precipitation modelling which combines population balance and hydrodynamics. Both experimental and numerical studies are carried out in order to analyse the reactor design influence on the precipitate characteristics. The simulations taking into account primary nucleation and crystal growth are in agreement with experiments.

Aug 1, 2010

By L. Kraszewski

"IntroductionPortland cement is produced by burning an accurately proportioned mixture (raw feed) of finely ground limestone, silica, alumina, and iron oxide. The kiln discharge (clinker) is a chemically complex mixture of calcium silicates, aluminates and ferrites which when ground and blended with from 2 to 5 percent of calcium sulphate is sold as Portland cement.ManufactureThe most common raw materials are limestone and clay or shale. The raw mix is finely ground and heated to about (2600°F) 1430°C to decompose the calcium carbonate and combine the calcium oxide with silica, alumina and iron to form a partly fused clinker. The clinker is then ground, usually with a small proportion of calcium sulphate (gypsum), which regulates set. Cements with special properties are produced by varying the oxide composition and also by adding small amounts of chemical agents at the clinker-grinding stage or later.Clinker is manufactured by either wet or dry process methods. In the wet process, raw materials are prepared, blended and fed to the kiln as a water slurry (about 30-35% water) . In the dry process, raw materials are prepared, blended and fed to the kiln as a dry powder (about 0.5% water). The processing procedure is as follows:"

Jan 1, 1982

By C. B. Webber

"Sherritt Gordon's experience with rubber mill liners began in 1964 at the Lynn Lake Farley Mine and continued at the Fox Mine in 1960, and the Ruttan Mine in 1973. This paper describes the history of the performance of rubber mill liners at the three mine operations.LYNN LAKE - FARLEY MINEThe Lynn Lake Farley Mine, which ceased production in 1976 due to exhausted ore reserves, was a 3500 T.P.D. copper-nickel operation; consisting of two parallel rod mills followed by three stages of ball mill grinding. A circuit modification in 1964 necessitated one of the tertiary ball mills to be used as a pyrrhotite regrind mill. This 8' x 5' Hardinge conical mill drawing 225 HP was initially installed with steel liners and lifters. After several months of operation a routine inspection revealed severe channeling and washing behind the liners which was threatening to erode the ball mill shell. It was thought that the highly acidic condition in the mill, due to grinding 100 º6 pyrrhotite, was accelerating the wear of the steel liners. At this time it was decided to reline the mill with rubber liners to see if the wear problem could be relieved, and in December 1964 a set of Skega rubber liners were installed."

Jan 1, 1981

By J. Gao

We present results from our investigation of the concept and practice of using surface-charged latex nanoparticles as building blocks for conductive membranes. Nanoparticles were synthesized by free-radical co-polymerization of two hydrophobic monomers, butyl acrylate (BA) and methyl methacrylate (MMA), a crosslinker, N, N'- methylenebisacrylamide (BIS), and a charged monomer, sulfonate styrene sodium salt (NaSS), in water. The resultant nanospheres were characterized with static and dynamic laser light scattering. Thin films were cast from concentrated particle dispersions, followed by incubation at ?110 °C. Conductivity, water uptake and final charge content were measured. The membranes have higher conductivities than both amorphous films cast from sulfonated BA-MMA-Styrene copolymer chains and BA-BIS-MMA-NaSS gel films. TEM images and neutron scattering spectra confirm the particulate structure of the membranes.

Jan 1, 2005

By Pierre Bénard

To achieve penetration on the energy market, hydrogen must overcome obstacles in the areas of storage, safety and infrastructure. One of the most important is the onboard storage of hydrogen for transportation applications, where large performance gaps exist between the current state of the technology and user expectations. In order to develop and demonstrate viable hydrogen storage technologies for cars, a set of gravimetric and volumetric system targets have been proposed by the US Department of Energy, based on achieving a driving range of 500 km for a hydrogen powered vehicle. A factor of 2 to 3 improvement in both hydrogen storage capacity and energy density is needed along with several other performance goals. Another key issue is safety. Although some of the safety issues can be arguably assigned to misperceptions, hydrogen has specific properties that have to be addressed, particularly in confined geometries where the risk of hydrogen detonations becomes an issue.

May 1, 2007

By R. Ramirez

Atlantic Copper Refinery (Huelva, Spain) has operated the ISA permanent cathode technology since 1995. The current production rates are 260,000 t/y cathodes and 730 t/y anode slimes. These slimes undergo an atmospheric leaching in which their copper content is reduced from an average value of 24 % to 16 %. In June 2005 an optimization study of the leaching conditions was carried out aimed at lowering the copper content in the slimes to less than 8%. At the same time, a new mixer (Outukumpu Technology GLS-mixer) was installed in one of the three leaching reactors. As a result of the improvement of the leaching performance and to prevent the return of tellurium to the tankhouse, a cementation plant was commissioned in July 2005 to ensure a Te content below 50 ppm in the Cu-rich leachate. This paper describes the results of the improvement of the leaching conditions and the operation of the new tellurium removal plant.

Jan 1, 2007

By R. Abel

During the last eight years, the Ventanas electrolytic refinery has been improving its results by applying a series of new operational practices, such as the reduction of electrode spacing from 115 mm to 105 mm., raising the current density to 305 A/m2, modification in the operators shifts to about 70% of the workers, reducing the pulling cycles by two hours, and the erection of a new anode preparation machine. These improvements allowed an increase in the refinery capacity from 323,000 to 382,000 metric tons of electrolytic copper per year. In the same period it has obtained certification under the ISO 9001:2000 and ISO 14001:2004 standards. All of these developments have been achieved using conventional technology with copper starting sheets. The continuous improvement that is covered in this paper has allowed Ventanas to optimize its production, costs, and operational results. For the next years, it is planned to follow the same tendency, bringing the productivity of the plant to higher levels.

Jan 1, 2007

By G. Portillo

Electrospark Deposition (ESD) is a pulsed-arc micro-welding process characterized by using high current electrical pulses, of a short duration, to deposit an electrode material on a metallic substrate. The short duration of the electrical pulse allows for a low heat input over the substrate and an extremely rapid solidification of the deposited material. As a result, the ESD is capable of a wide variety of microstructures like micro-segregationfree solid solutions, nanostructured grains, metastable structures, and amorphous phases. The present work shows a microstructural analysis of rapidly solidified Al-Ni alloys coatings by the ESD process. Field Emission Scanning Electron Microscopy (FE-SEM) and X-Ray Diffraction (XRD) were performed to present the microstructural evolution as a function of the welding parameters. The phases and non-equilibrium metastable structures present in the alloys, and their distribution, were found to be a sensitive function of the alloy composition; hence its formation is governed primarily by thermodynamic considerations.

Jan 1, 2011

By John Emery, George Wang

Research and applied utilization activities for the increased use of ferrous and nonferrous slags in construction are presented. The overall use of blast furnace slag is relatively well known for a range of construction applications from aggregates to slag cements. In contrast to blast furnace slag, which is volumetrically stable and straightforward in its construction uses, steel slag contains hydratable oxides that can result in volumetric instability that must be dealt with through appropriate steel slag aging, testing and quality control to ensure its appropriate use. Particular care must be taken to prevent potential steel slag expansive behaviour in confined applications. Quality requirements and guidelines on steel slag expansivity to further the use of steel slags, with demonstrated acceptable performance, are outlined. There is a full range of proven construction uses - from aggregate to cementitious materials - for copper, nickel and phosphorus nonferrous slag. The use of air-cooled nickel slag is presented, based mainly on practical highway construction experience. It has been shown that air-cooled, crushed nickel slag can be an excellent aggregate in granular base, engineered fill and hot-mix asphalt. There is a good potential for increased ground, granulated copper and nickel slags use as supplementary cementitious materials that is being developed, which takes advantage of the 'latent energy' content. The scope of a new technical text in preparation on the technology of slag utilization is reflected throughout to provide a practical context for the engineer.

Jan 1, 2004

By M. J. Baker

Energy and Minerals Australia Ltd are undertaking a study of the recovery of uranium from the Mulga Rock Deposits in Western Australia. Approximately 80-90% of uranium identified to date is present as tabular layer up to 5 m thick within a lignite seam 30 m to 50 m below surface. Other metals are also present. Metallurgical studies at ANSTO Minerals laboratories in Sydney have focused on identifying a suitable uranium leaching process and assessing the possible downstream impacts of the organic material in the ore. The extraction of other metals has also been examined. This paper provides the results of testwork performed at ANSTO to date.

Aug 1, 2010

By Juan Pablo Vielma

In this work we study how to incorporate risk control to the generation of ultimate pits when orebodies are modeled through a finite number of conditional simulations. To control risk we consider a chance constraint on the value of the ultimate pit. We incorporate this measure into the generation of ultimate pits by solving a stochastic programming version of the ultimate pit problem. We compare this stochastic programming problem to previous approaches such as generating the ultimate pit for each simulation and the hybrid pit approach introduced by Whittle and Bozorgebrahimi. We also study the effect of using different number of simulations in the generation and evaluation of ultimate pits.

Oct 1, 2009

By D. C. Van Aken, O. J. Rajtora

A research effort sponsored by the Department of Energy (DOE) and several steel producers, is investigating the benefits of coating steelcasting nozzles with various materials. Coatings were applied to casting simulation nozzles made from industrial tundish nozzles (primarily of magnesia) and industrial submerged entry nozzles (SEN's) (primarily of alumina-graphite) in order to extend casting time prior to nozzle clogging. Nozzles were coated by air plasma spray (APS) using a 9M series APS system from Sulzer-Metco. The ability of these coatings to provide protection from clogging was evaluated using a steel casting simulation. Substrate-coating compatibility was characterized using optical and SEM microscopy.

Jan 1, 2004

By Lee Barbour

Waste-rock piles from metal mining operations are comprised of large surface deposits of unsaturated, coarse-grained soil and rock. The unsaturated condition and heterogeneous, coarsegrained nature of these deposits make them difficult to monitor or characterize. Key parameters that must be evaluated include; volume-mass relationships (e.g. water content, air content, porosity, density, degree of saturation, grain-size), transport properties (e.g. air-permeability, gas diffusion, hydraulic conductivity), geochemistry (e.g. solids, gas, and fluid phases) and soilatmospheric fluxes (water and gas). This paper describes some of the techniques that have been developed to characterize waste rock piles for uranium mines in Northern Saskatchewan. For each technique, the method of measurement is described, and preliminary field data are presented and discussed.

Nov 1, 2002

By Z. D. Hora

has been no commercial production of either perlite or pumice in British Columbia. Several promising occurrences are known to exist but their development has been delayed due to difficult access and / or remote locations. The Empire Valley perlite deposit is located 120 km east of Clinton. The deposit appears to be a flat-lying volcanic flow 50 to 70 m thick that is part of an Eocene rhyolite and dacite volcanic assemblage. The Francois Lake perlite deposit occurs on the north shore of Francois Lake where perlite is part of a rhyolitic volcanic sequence. The exposure of perlite is about 13 m thick and is considered to be Eocene or Oligocene in age. The Uncha Lake perlite deposit is located about 5 km south Industrial Minerals in Canada of Uncha Lake. Perlite appears to be intercalated with porphyritic rhyolite flows that are comparable to those at Francois Lake. Showings are widespread but poorly exposed and thicknesses are unknown. The Mount Meager pumice deposit is located in the Lillooet River valley at the base of Plinth Mountain. Coarse pumice agglomerate forms a large talus slope that is undercut by the river. Unsorted, angular fragments up to 50 cm in diameter are intermixed with up to 30 per cent of sand and silt-sized particles. The exposed zone is about 200 m long and 50 m high; it is being considered as a source of lightweight aggregate.

Jan 1, 1984

By D. P. Fenton

The Phelps Dodge El Paso Rod Mill produces approximately 2.4 million pounds per day of copper rod from a casting and rolling operation. The newly formed rod is treated to remove mill scale and oxides using a sulfuric acid and hydrogen peroxide solution which is bled periodically when the copper concentration reaches 30-35 g/L. The bleed solution is heated to 75° C to destroy the residual peroxide. Copper is then recovered in a 270 cell EMEW electrowinning plant. Clean acid is also regenerated in the EMEW plant and is returned to the rod cleaning circuit. The EMEW plant commissioned in January 2006, has two operators and replaces a copper sulfate plant with fourteen operators. The EMEW plant has a capacity of 1700 kg/day of cathode copper at 2.1 kWh/kg copper deposited. The electrowinning plant operates in closed circuit with the rod mill returning up to 2600 kg/day of sulfuric acid resulting in zero discharge. Use of dimensionally stable anodes (DSA®) ensures that the acid quality is maintained in the closed loop operation. The operating conditions, performance and plant experience of the EMEW copper and acid recovery plant are discussed.

Jan 1, 2007

By W. Zieman

"The low consumption of reagents can probably be attributed to a good clean type of ore. The cyanide level is kept at 0. 8 lb/ ton of solution and the lime at 1. 8 to 1.9 lb per ton of solution (pH 12. 2 to 12 .3). Experience in cutting down the lime level in half produced troubles in the presses, in the refinery and resulted in higher cyanide consumption. Finally the residue increased under these conditions, High lime always seems to prevent the trouble from occurring.A survey at one mine of the taxable work, performed in the mine shops for use in the mine, showed that under the new regulations, this had increased some 30 times what it was before the new rules came into effect on June 14, 1963.A water softener idea is incorporated at Lamaque with the crude addition of 100 lb of lime per shift to a spare agitator to precipitate the bicarbonates as carbonates from the water before it enters the mill. The lime titration of the softened water is about 0,2 to 0.3 lb per ton of solution (pH 11). This water is used mainly on the filters as washes."

Jan 1, 1964

By M. P. Amsden

"Ecstall Mining is a wholly-owned subsidiary of Texas Gulf Sulphur at Timmins, Ontario. The mill tonnage is 10,000 tons per day of two different ores, a copper zinc ore and a silver lead zinc ore, producing about 2400 tons of concentrates per day. These are as a copper concentrate, a high silver zinc concentrate, a low silver zinc concentrate and a silver-lead concentrate. For flotation recovery a very fine grind is required, about 80% minus 325 mesh and the concentrates produced are 40% minus 10 microns.The thickened concentrates are pumped to the filter floor for filtering and drying. The filtering and drying section is separated from the flotation section by a wall and is controlled from a dryer control room by one operator.Two operating panels are located in this control room. One contains stop-start controls for the thickeners, filter motors and vacuum pump motors, and stop-start controls for dryer feed conveyors and dryer product conveyors to concentrate load-out bins, as well as ammeters for conveyor drive motors. Dryer throughput is regulated by Merrick Type L weightometers located on the dryer discharge conveyors and recorded on tons per hour strip charts.The second panel contains the temperature strip charts, furnace drive ammeters, scrubber and exhaust gas controls, burner controls and panel alarms for the four dryers.Filtered concentrates are dried in Nichols-Herreshoff, multiple hearth, dryers consisting of nine hearths (zinc) and seven hearths (copper and lead). There are two dryers for handling zinc concentrates and one each for copper and lead concentrates. The dryers are heated by burning natural gas. Each zinc dryer handles 1,000 t.p.d. and the copper and lead dryers 750 t.p.d. each.Multiple hearth dryers are unusual in the base metal mining industry and the reasons for selecting them in preference to rotary dryers are as follows:1) The concentrates could only be filtered to 15 to 17 percent moisture. These sloppy filter cakes would be extremely difficult to handle in rotary dryers."

Jan 1, 1972