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By Felix Cheng

Extensions to the Convention Centre in Adelaide, South Australia consisted in part of construction over the existing railway system comprising nine rail lines and passenger platforms. Vibro-pile (Aust) won the design and construct tender with a solution comprising over 500 cast insitu concrete piles. The pile types were 500 to 900mm diameter non-displacement CFA piles and 400mm diameter displacement V-piles. The V-pile is a cast insitu screw pile developed by Vibropile (Aust) Pty Ltd. Both pile types were installed with minimal noise and vibration required for the project, while the displacement V-pile had the advantage over the CFA pile by developing the same pile capacity but with a smaller diameter and with minimal spoil. The latter was important in alleviating spoil removal problems near the railway tracks and disposal of potentially contaminated spoil. The results of dynamic compression load testing and static lateral load testing indicated that the performance of a 400 mm V-pile was equivalent to a 500 mm CFA for this site. The lateral load testing indicated that the surficial soils have a major influence on the load-deflection response, but despite the site containing up to 4 m of filled ground, the piles were found to carry the required lateral loads satisfactorily.

Jan 1, 2002

By P. Miranda, K. Le, G. Maes, R. Peters

"The Mount Milligan Mine, owned by Thompson Creek Metals Company Inc. (TCM), started operations in September of 2013. It is located between the communities of Fort St. James and Mackenzie and is the first major metal mine to open in British Columbia in 15 years. Based on reserves as of January 1, 2014, it has an estimated 22 year mine life with 2.1 billion pounds of copper and 6 million ounces of gold in reserves. Like all commissioning operations, there have been issues achieving design throughput and recovery due to flow sheet design, equipment failures, control philosophy, and reagent scheme. Efforts to improve overall mill performance include equipment modifications, reagent screening and testing, and grind size testing. Applying these changes to the mill and working closely with the mine has resulted in continuous improvement each month as Mount Milligan looks to achieve the nominal design capacity of 60,000 dry metric tonnes per day in the later part of 2015. Considerable focus is being placed into ensuring size reduction equipment is utilized effectively. Additional modifications and tests are being undertaken to steadily improve processes and alleviate restrictions in the mill. This paper will discuss the start-up and present ramp-up history of Mount Milligan, the current mill processes, and the steps taken to achieve expected production numbers.OPERATION BACKGROUNDMount Milligan is an open-pit copper and gold operation wholly owned and operated by Thompson Creek Metals. It is located approximately 155km northwest of Prince George, British Columbia, between the communities of Mackenzie and Fort St. James. The copper-gold porphyry deposit contains a Measured and Indicated Mineral Resource of 706.7 Mt at 0.18% Cu and 0.33 g/t Au, containing 2.84 billion lb. copper and 7.50 million oz. gold. Mine life is currently estimated at 22.1 years (“Feasibility Update – Mt. Milligan,” 2009). The mill is designed to process 60,000 dry metric tonnes per day and produce 400 dry metric tonnes of concentrate per day averaging 25.5% Cu and 40 ppm Au. Concentrate is delivered by truck and trailer to Mackenzie followed by rail to Vancouver for overseas shipping to various customers.Mount Milligan is considered a “zero discharge” operation meaning no process or surface water will be discharged to the environment. As well, stockpiling is very limited and is only permitted for a short period of time. This scenario presents several unique challenges. Scheduling of ore/waste production must be carefully planned as waste rock is used to build the tailings storage facility (TSF). Reagent selection is also important as persistent chemicals will have a tendency to build up in reclaim water which feeds the process water tank."

Jan 1, 2015

By Stavros H. Constantopoulos

Mediterranean regions such as Greece, Turkey, Cyprus, Corsica and New Caledonia have experienced epidemics of malignant mesothelioma as a result of non-occupational, ??domestic?? exposure to tremolite asbestos and fibrous erionite. This exposure to tremolite asbestos and fibrous erionite is typified ??domestic?? due to its prevalence in regions with natural deposits of tremolite asbestos (or fibrous erionite) where the material from tremolite asbestos or fibrous erionite is used for domestic applications such as whitewashing. However, these exposures may be useful in examining the potential consequences of even small amounts of amphibole asbestos fibers in the ambient air. It can also elucidate the effects of fibers that behave like amphibole asbestos. However, this type of exposure is not useful for studying the potential effects of small amounts of asbestos in the ambient air of big cities due to the differing nature of the fiber types and modes of exposure between the regions. © 2008 Published by Elsevier Inc. Keywords: Tremolite asbestos; Erionite; Domestic; Environmental; Exposure

Jan 1, 2007

By Jerry Wallace

This project consisted of blasting for expansion of a major interstate natural gas transmission pipeline pump station. The pump station handled 400-500 million cubic feet (1 l- 14 million cubic meters) of gas per day.

Jan 1, 1996

By P. H. Derbyshire

The use of continuous flight auger piles has increased significantly in the U.K. to such an extent that it is now the most widely used method of constructing small diameter bored piles. This paper describes the improvements in equipment, techniques and particularly monitoring that have led to this growth. A review of the equipment in use describes how purpose built self erecting machines have been generally adopted. Improvements in ancilliary equipment are described. Concrete has almost completely replaced grout and techniques have been developed to extend the length of reinforcement that can be placed. Leading specialist contractors have developed instrumentation to monitor the construction of the pile (in terms of time, depth, torque, concrete pressure and flow) and keep a record for checking. A further significant development of this monitoring by means of sensors at various levels in the auger stem is described. The results obtained from this monitoring are reviewed and future developments discussed.

Jan 1, 1989

By R. Karl Zipf

Multiple seam mining interactions caused by full extraction mining, whether due to undermining or overmining, frequently involve tensile failure of the affected mine roof. The adverse ground control conditions may prevent mining for both safety and economic reasons. Prior researchers have identified the geometric, geologic and mining factors controlling multiple seam mining interactions. This numerical study examines the mechanics of these interactions using a modeling procedure that 1) incorporates the essential constitutive behavior of the rock such as strain-softening of the intact rock and shear and tensile failure along bedding planes and 2) captures the geologic variability of the rock especially the layering of weak and strong rocks and weak bedding planes. Specifically, the numerical study considered the effect of vertical stress, interburden thickness, and the immediate roof quality of the affected seam in both undermining and overmining situations. The models show that for overburden-to-interburden thickness (OB/IB) ratios of less than 5, interactions do not occur, and that for OB/IB more than 50, extreme interaction is a certainty. In between, the possibility of an interaction was found to depend on gob width-to-interburden thickness ratio, site specific geology and horizontal stress to rock strength ratio in addition to the OB/IB ratio. The models also showed that horizontal stress was profoundly altered well above or below a full extraction area and that these changes are likely to influence the success or failure of multiple seam mining. The role of horizontal stress in multiple seam mining interactions has received little attention in prior investigations. Four factors control the mechanics of multiple seam mining interactions: 1. vertical stress concentration 2. horizontal stress concentration 3. stress re-direction 4. bedding plane slip bands A combination of vertical and horizontal stress increase and high stress gradients in the vicinity of full extraction areas re-orients principal stresses into a very unfavorable direction. This seemingly small stress re-orientation has a profound adverse effect on bedded rock.

By M. Beth McClenaghan

This paper summarizes diamond exploration techniques used in glaciated terrain, focusing on indicator mineral and geochemical methods applied to glacial sediments. Understanding the ice flow history, depositional history, and stratigraphy of glacial sediments are essential to successful sampling, interpretation and follow-up of indicator mineral and geochemical anomalies related to kimberlites. Kimberlite indicator minerals survive glacial transport over long distances and the relative abundance of each mineral in till is a function of the primary mineralogy of individual kimberlites. Indicator mineral distributions observed at a regional scale define the net effect of glacial dispersal, often along different ice flow directions. Local-scale distributions define individual dispersal trains. The medium sand (0.25 to 0.5 mm) fraction of heavy mineral concentrates prepared from glacial sediment samples is best suited for indicator mineral surveys. The application of till geochemistry to diamond exploration is increasing because it is significantly cheaper than indicator mineral analysis and it can be performed quickly. The <0.063 mm (silt+clay) and 0.5 to 2.0 mm (coarse sand) fractions provide the best geochemical contrast between background and kimberlite-rich till. Kimberlite pathfinder elements that provide good contrast include Ni, Cr, Ba, Co, Sr, Rb, Nb, Mg, Ta, Ca, Fe, K, Ti and REE, the relative importance of which will depend on kimberlite composition as well as that of the surrounding bedrock.

May 1, 2002

This paper briefly describes the shaft, including sinking, steel sets and their installation, shaft equipment and winders.INTRODUCTIONThe New Broken Hill Consolidated Ltd. Service Shaft is a vertical concrete-lined circular shaft, 20 ft. in diameter with -steel sets spaced at 12-ft. centres. The diameter of 20 ft. was established as the minimum that would enable the shaft both to house the proposed hoisting and service equipment and to satisfy ventilation requirements as a downcast airway. The 12-ft. set spacing was based on South African practice in similar types of shafts.The shaft extends from the surface to 28 ft. below No. 22 Level, a total depth of 3,194 ft. Sinking was commenced in September 1946, and equipping completed in January 1955. Initially the shaft was sunk and concrete-lined to a depth of 52 ft., using a stiff-legged crane and clam-shell grab for mucking. Operations were suspended at this depth to allow the installation of the steel sinking head-frame, winders and ancillary equipment.Sinking and concreting were recommenced after four months and continued to a depth of 1,035 ft. 6 in., where the shaft connected with a pilot opening. The concrete lining was poured as sinking progressed and was piped from the surface to this depth, after which all concrete was lowered in buckets and discharged through a distributor suspended in the shaft. A cycle of stripping to the pilot opening and concreting was continued until the shaft reached No. 22 Level. From this level the remaining 28 ft. was sunk full size. All plats were cut and concreted as sinking progressed.

Jan 1, 1957

By S. Bellec, A. Berton

"Usually, steady state mass balances are used for the design of mineral processing plants. However, this tool does not take into account the impact of process inputs variability nor does it evaluate process transient behaviours between stationary states, such as mill start-up and shutdown. The use of advanced simulations enables the integration of dynamic behaviours in process design decision-making by highlighting situations that are undetectable by using only steady state mass balances. Applying these simulation tools to brown field projects allows the simulator performances to be calibrated and validated on actual plant data before it is used as a prediction tool for the modified plant.Three (3) simulators were implemented at the design stage of a major upgrade project for an ore processing plant in order to assess process behaviours under different production scenarios. These simulators were built to evaluate the impacts on major elements such as mine production, ore stockpile, concentrator production as well as water demand. A validation of individual equipment models was performed whenever sufficient measured data was available. The simulators were then used to study the impact of ore variability (grade, hardness, throughput), to assess day-to-day production special events, and to evaluate the true stockpiles live capacity.The use of a stochastic simulator for equipment sizing allowed a more precise sizing of many pieces of equipment and avoided important expenses in the fresh water pumping system. The dynamic simulator also confirmed that the water in place system would suffice, even in the most demanding production scenario. Finally, the stockpile simulator allowed an important production bottleneck to be quantified and then made possible the assessment of various practical solutions for the stockpiling-reclaiming issues.Post start-up, process data underlines the fact that using advanced simulation tools was useful to mitigate process-related risks associated to the plant expansion, showing generally accurate prediction and adequate equipment sizing, leading to smooth process commissioning. The presented methods are part of what is now routine in Soutex’s participation in both greenfield and brownfield projects."

Jan 1, 2015

By W. A. Calhoun

This report gives results of metallurgical investigations performed by the Bureau of Mines on mineral samples taken during April 1959, from Hawaiian bauxite deposits on the islands of Kauai, Maui, and Hawaii. The bauxite samples were tested at the Bureau&apos;s Rolla Metallurgy Research Center, Rolla, Mo., to determine if alumina could be extracted. The results were encouraging. Extraction of the alumina by the American Bayer type digest of crude ore samples from Kauai, Maui, and Hawaii recovered 78.8, 73.1, and 70.0 percent, of the total alumina, respectively. These recoveries were increased to 82.8, 85.5, and 79.5 percent by modifying the treatment, which consisted essentially of calcination and weak caustic desilication to provide a residue. The residue was then treated with calcium oxide and digested in a strong caustic solution to extract the alumina.

Jan 1, 1962

By Jason Clarke, André R. Laplante

"The gravity-recoverable gold (GRG) ore characterization test was developed 15 years ago and has been applied to hundreds of ore samples. The test accurately determines the size distribution of GRG, at which grind it is recoverable, and the extent of its liberation above 150 µm. This contribution shows how the test can be simplified, what are the likely problems to occur, and what information is then lost. Two simplified versions of the test are presented, of which the simplest, grinding a 20-kg sample to a P80 of 75 µm, is retained as the best one. A database of 18 comparative tests is presented. The choice of the full GRG test vs. the simple test is discussed, as is the deportment of the GRG recovered in the standard test but not in the simplest test.INTRODUCTIONThe GRG test was developed in 1990 to characterize the progressive liberation of gold in representative samples of ores, with the primary objective of generating data for a gold gravity recovery model (Woodcock and Laplante, 1993; Laplante et al., 2000). Characterization includes the size distribution of GRG as well as the grind size at which it becomes recoverable. This is achieved in a 3-stage protocol of liberation and recovery using a laboratory centrifuge unit, a Laboratory Knelson Concentrator 3 inches in diameter (KC MD3). This protocol is shown in Figure 1. The first stage takes place at a F100 of 850 ?m (F80 of ~550 ?m), the second at F80 of 180 ?m, and the third at a P80 of 75 ?m. The rationale for the three cycles is the desire to preserve the original size distribution of the gold grains in the ore and to obtain a recovery grind size curve. The feed is a representative sample of ore that can be extracted from ore samples (e.g. drill core reject) or stream products of the grinding circuit other than circulating loads or product having undergone hydraulic classification (e.g. rod mill discharge or SAG screen undersize). Ideally the samples should weigh between 60 and 100 kg, depending on feed grade and gold top size. It is beyond the scope of this paper to fully discuss measures of representativity in the ore sample, for example Gy’s minimum sample mass model (Gy, 1979). However, further work in this regard may be an opportunity. The large initial weight facilitates representativity and minimizes weight and sulphide recovery to the concentrate (since concentrate weight is relatively constant at ~100 g), which limits the recovery of gold in nonsulphide gangue or gold carriers (i.e. sulphides). Thus, the 100 g concentrate carries principally discrete gold species, such as electrum, and native gold. The concentrate and a 600-g representative sample of gangue of each stage are screened down to 20 ?m and each size class is fire assayed (the concentrates to extinction, the tails up to 30 g per size class). The five coarsest size fractions of stage-1 concentrate are individually upgraded using a hydrosizer and the concentrates examined with an optical microscope to assess the degree of liberation of the gold phase. Scanning electron microscope work has established that the GRG has an excellent degree of liberation below 150 ?m in stage 1 and generally a good degree of liberation in stages 2 and 3 (Guerney et al., 2003); as a result the size distribution of the GRG has been found to approach closely that of gold grains (Nesset et al. 2005)."

Jan 1, 2006

Difficulties were experienced in the identification of carbonate minerals intimately associated with iron oxides in the so called carbonate ore, which occurs at depth in the Iron Duke Orebody.Determination of refractive indices by examination under the microscope using the immersion method, together with inferred chemical composition indicates that dolomite and parankerite are common constituents. Histograms of the manganese and sulphur contents strongly suggest that manganese is associated with the carbonate minerals, and that the highest sulphur assays occur near the base of the carbonate body.From the present work it is concluded that refractive indices indicate only a very approximate composition for carbonates of the parankerite type.The different carbonate minerals occur in irregular zones.INTRODUCTIONThe Iron Duke deposit is situated in the southern portion of the South Middleback Range on Eyre Peninsula, S.A., 30 miles from Whyalla. (Fig. 1).Drilling at Iron Duke revealed a large body of so called carbonate ore, which was tested in detail at cross section 1000 ft. S by three diamond drill holes, DDH.57, 67 and 78. (Fig. 2)Most specimens of carbonate ore described below were obtained from DDH 67 and 78.GENERAL GEOLOGYThe South Middleback Range is composed of two parallel ridges trending north-south. The Iron Duke orebody is situated on the southern portion of the western ridge. (Fig.1) .The rocks of these ranges belong to the Middleback Group which rests on a gneiss complex. Their age is considered to be Middle Precambrian or late Archaean.

Jan 1, 1963

By L. A. Stewart

This paper describes all occurrences of barite in Arizona that were known or reported to the authors. The history, ownership, production, and geologic setting are discussed for most of the deposits. The uses and specifications of product grades are briefly discussed. Seventy-five deposits were examined in 9 of the 14 counties of the State. The descriptions are given under county headings. No occurrences were reported in the four northeastern counties of Coconino, Navajo, Apache, and Greenlee, nor in Santa Cruz in the southern part of the State. From about half of the deposits examined, 55 samples were taken; of these, 45 were for chemical analysis, and 8 larger samples, ranging from 100 to 350 pounds, for beneficiation tests. A 30-ton bulk sample was taken for pilot-plant tests. Bench-scale flotation tests of the eight samples employing several different procedures and reagent combinations yielded marketable-grade barite products with barite recoveries ranging from 60 to 97 percent. Five of the samples contained enough fluorspar to warrant its recovery. Acid-grade concentrates, which accounted for fluorspar recoveries of 45 to 70 percent, were obtained from three of these ores. Batch laboratory tests of a representative portion of the 30-ton bulk sample revealed that acid-grade fluorspar and high-grade barite concentrates could be recovered. Results of the laboratory and continuous pilot-plant tests of this ore will be presented in a separate report.

Jan 1, 1960

By P. Wittke-Gatterman

ABSTRACT: A three dimensional constitutive law for swelling rock is presented. It can be applied to the osmotic swelling of mudstone as well as to the swelling of rocks containing anhydrite. It describes the development of time-dependent strains and stresses due to swelling considering elastic and viskoplastic behaviour. Furthermore an anisotropic swelling behaviour can be considered. This constitutive model was implemented within a numerical computation program according to the finite element method and calibrated on the basis of the results of measurements in the investigation drift of the Freudenstein tunnel which is completely located in the unleached Gypsum Keuper. A parameter combination could be found which results in a good agreement between numerical solutions and results of measurements. Therewith an analysis procedure which enables the design of tunnels in swelling rock is available. ZUSAMMENFASSUNG: Im vorliegenden Beitrag wird ein dreidimensionales Quellgesetz vorgestellt, das nach derzeitigem Kenntnisstand sowohl auf das osmotische Quellen von Tonsteinen als auch auf das Quellen anhydrithaltiger Ton- beziehungsweise Schluffsteine anwendbar ist. Das Stoffgesetz wurde in ein Finite-Elemente-Programm implementiert und anhand von Meßergebnissen des im unausgelaugten Gipskeuper liegenden Untersuchungsstollens des Freudensteintunnels kalibriert. Es ist gelungen, eine Kennwertkombination zu finden, mit der alle Meßergebnisse gut beschrieben werden können. Damit steht ein Bemessungsverfahren für Tunnel in quellfähigem Gebirge zur Verfügung. RÉSUMÉ: Dans l&apos;article présent un loi de gonflement à trois dimensions est présenté, qui peut être appliqué aussi bien au gonflement osmotique de l&apos;argile compactée q&apos;au gonflement de l&apos;argile compactée ou du limon compacté contenant de l&apos;anhydrite. Le loi de comportement était implémenté dans un programme numérique d&apos;éléments finis et calibré avec des résultats de mesures de la galerie de recherche du tunnel de Freudenstein, situé dans le Keuper de gypse non lessivé. On est réussi à trouver une combinaison de paramètres avec laquelle tous les résultats de mesures peuvent être bien décrits. Par ce moyen, une méthode de dimensionnement existe pour des tunnels dans de la roche capable de gonfler.

Jan 1, 2003

By Brandon Fryman, Josh Hoffman, Rhys Baker

A post-detonation debris collection project was led in conjunction with a large ammonium nitrate(AN) railcar detonation conducted by the Department of Homeland Security-Transportation Security Administration, Department of Defense-Combating Terrorism Technical Support Office, Sandia National Laboratories, and the U.S. Army Dugway Proving Grounds. This important work will aid in underpinning algorithms used in a Quantitative Risk Assessment (QRA) tool. The test also provided valuable data about the effects and consequences following an AN detonation. The test took place at the Utah Dugway Proving Grounds on April 27, 2018 and the debris collection was conducted the following two weeks with an average of 20 persons per day and an approximate total of 1,400 manhours. A paper was presented at the 2019 ISEE Conference on the collection efforts, challenges, and lessons learned. A complete data analysis effort was completed on the test data in 2019 that resulted in updates to the QRA Railcar Potential Explosion Site (PES)model and AN engine. The analysis included an assessment of the debris data resulting from the Derailed test. This paper is meant to serve as a summary of the analysis effort and findings and as an update to the previously presented lessons learned from the debris collection and analysis effort.

By Frank J. Arland

Augered-Cast-in-Place piles have been used successfully for many deep foundation applications. The four case studies discussed herein describe ACIP pile projects where problems developed during ACIP pile installation requiring changes to the method or sequence of installation. The case studies illustrate the importance of understanding existing subsurface conditions and project constraints when considering the use of this pile type. Ground loosening and over-excavation of soil during the augering process, a significant concern for fine to medium sands and non-plastic silts below the water table, can significantly impact adjacent structures. This risk needs to be evaluated during the pile selection process and generally can be mitigated, but not eliminated, by requiring the use of piling equipment with high torque and slow auger rotation speed to advance the auger with minimum amount of rotation. In some applications where high lateral stresses in the soil are present such as at the base of retaining structures, the use of ACIP piles may not be appropriate if structure movement is unacceptable. On the other hand, ACIP piles have been successfully used to support deep foundations in preconsolidated varved deposits where the new structure was designed to accommodate recompression settlement.

Jan 1, 2004

By Francis D. Leathers

Four friction pile load test programs, including 23 tension tests and 9 compression tests, have been performed as part of the Central Artery/Tunnel Project in Boston, Massachusetts. The tests, performed on both precast, prestressed concrete (PPC) piles and steel piles, yielded the following adhesion values: [Soil Type Clay Clay Glacial Till Interbedded Sand and Clay Interbedded Sand and Clay Pile Type PPC Steel Steel Steel PPC Adhesion (psf) 610 to 1,200 230 to 900 220 to 550 680 1,280 ] The adhesion appears to be affected by differences in pile material type, with PPC piles having higher adhesion than steel piles. However, part of the apparent difference for the clay may be due to differences in time between driving and testing. The significant range of test data means that the need for site specific testing to determine or verify design values of adhesion should be considered during design. Creep rates at loads near failure ranged from about 0.02 to 0.18 inches per log cycle of time, with most values in the range of about 0.04 to 0.08 inches per log cycle of time.

Jan 1, 1994

At Copper Refineries Pty. Ltd., Townsville, two reverberatory furnaces of 420 tonnes capacity are used to melt 210000 tonnes/year of copper for subsequent anode casting. When the refinery commenced production in1959, these furnaces were of 300 tonnes capacity. The original furnaces featured a silica brick hearth, magnesite and chrome magnesite side &apos;walls, and a sprung silica brick roof, but were unsatisfactory because of thelow refractory life and high costs. With continuous expansion in production and the incentive to increase furnace life and capacity the design of these furnaces has changed greatly since that time.The present furnaces feature all basic brick, a flat suspended basic brick roof, very extensive use of watercooled copper sections, and are of substantially increased (420 tonnes) capacity. Particular attention has been concentrated on high wear areas such as the taphole, side walls, and charging door jambs. Each furnace in its 24 h cycle, is charged, the copper melted, impurities skimmed off, metal &quot;poled&quot; prior to casting, and cast.The service condition during each of these operations is important in considering furnace refractory life.The improvements in operating practices and furnace &apos;construction which enabled the capacity of the furnaces to be increased are discussed. The life between major repairs to side walls has increased from 90 charges to300 charges.The scope for future improvement is considered and areas for development are suggested.

Jan 1, 1977

By K. V. Raj, C. A. Berry, A. T. Weakley, A. L. Miller, P. R. Griffiths, D. A. Parks

Diesel particulate matter (DPM) has been classified as a carcinogen to humans by the International Agency for Research on Cancer. As a result of its potential carcinogenic nature, DPM exposure is regulated by the Mine Safety and Health Administration. Currently, diesel emissions in the workplace are monitored by collecting the aerosol onto filters, which are then sent to a laboratory for thermal-optical analysis using the NIOSH method 5040. This process can take days or even weeks, and workers can potentially be exposed to excessive levels of DPM before the problem is identified. Moreover, the delay involved in getting the loaded filter to the lab inevitably means the loss of some of the more volatile organic carbon. To remedy this delay, researchers from the National Institute for Occupational Safety and Health are seeking to develop a field-portable, real-time method for measuring elemental and organic carbons in DPM aerosols. In the current study, the use of mid-infrared spectrometry was investigated. It is believed that mid-infrared spectroscopy is more suitable for use in a real-time field-portable device than thermo-optical analysis methods. This article presents a method for measuring organic carbon (OC) and elemental carbon (EC) in DPM for a broad range of OC/EC ratios. The method has been successfully applied to laboratory-generated and mine samples.

By A. N. Holden, W. E. Seymour

DURING the last several years, the U-Zr system has been studied at many laboratories as one of the research programs sponsored by the Atomic Energy Commission. The equilibria in part of this system have been difficult to determine, although the phase diagram from 0 to 60 atomic pct Zr has been established with reasonable certainty. Existing diagrams of the system vary appreciably beyond 60 atomic pct Zr, particularly with regard to the existence of an intermediate phase. Most existing diagrams show a transformation or reaction horizontal near 600°C. In 1955, a collection of uranium phase diagrams&apos; was prepared at the Battelle Memorial Institute and the U-Zr diagram in that collection contained a questionable region in the vicinity of 60 to 80 atomic pct Zr. Summer-Smith" has published a phase diagram of the system that shows no intermediate phase. Summer-Smith did his work with powders and found only the uranium and zirconium eutectoid mixture from X-ray patterns of material annealed below 600°C. Mueller3 at Argonne National Laboratory did similar work with filings, and he found that initially there was a pattern of an intermediate phase, but on long-time annealing

Jan 1, 1957