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By S. Mathur

Oxide particles are commonly used as fillers in plastics, paper, rubber etc. (particulate composites). The successful fabrication of such composites is dependent upon the adhesive strength of the filler particles to the matrix. The compatibility of the matrix and the filler particles is generally enhanced by adsorption of surface modifiers such as surfactants and polymers at the particle-matrix interface. In order to develop a scientific basis for selection of appropriate modifiers it is necessary to understand their adsorption mechanism(s). Specifically, adsorption of polymeric additives is attributed to a combination of chemical and electrostatic interactions, hydrogen bonding and van der Waals forces. Hydrogen bonding has been suggested to be the primary adsorption mechanism for non-ionic polymers. However, a literature survey of Poly(ethylene oxide)(PEO)-oxide system suggested PEO, a non-ionic polymer, to be substrate specific. A systematic study was undertaken to investigate the adsorption mechanism(s) of a PEO on oxide particles. It was determined that strong Bronsted acid sites on the surface interact with the ether oxygen, a Lewis base, of PEO to induce adsorption. In this work characterization of PEO binding sites on oxides is reported and the mechanism(s) of PEO adsorption discussed.

Jan 1, 1997

By M. Mathiba

High CO2 fluxes associated with reclaimed coal mine spoils pose an environmental hazard where such sites are used for building. CO2 concentrations in excess of 25% have been reported in homes constructed on or down gradient of such spoils. The objective of this study was to investigate the effect of a mitigation trench used at one mine site on CO2 fluxes across the trench using chamber?based trace gas measurement. LI8100 automated CO2 flux system was used to measure CO2 fluxes from 32 sample points located across a deep mitigation trench on June 8 and 9. The maximum recorded fluxes were 7.29 and 8.18 µmol/m2/s, with averages of 4.15 and 5.50 µmol/m2/s, up and down-dip respectively. These preliminary results show CO2 flux is higher up-hill than down-hill at 95% significant level. This work shows that flux measurement can be used to investigate CO2 migration on reclaimed mine land. Further work is necessary to allow geostatistical modeling of the spatial variability of CO2 fluxes over reclaimed coal mine spoils. Knowledge gained would assist mining practitioners and regulators in reclamation planning for envisaged post-mining land uses.

Jan 1, 2010

In early 1970, General Mills Chemicals, Inc. announced the availability of en improved liquid ion exchange reagent, LIX® 64N, for the recovery of copper from various solutions, such as dump leach liquors. LIX 64N has been shown to be a considerable advance over LIX 64, and is presently in use in three commercial plants. Results have been very gratifying. For example, one of the plants was designed for operational production of 40,000 pounds copper per day, and in fact reached this output within the third week following startup of the plant. In addition to the operating plants, another is scheduled to come on stream this month with L D( 64N being used to extract and recover both copper and nickel. The chemical properties and operating characteristics of this reagent have been fully described in a previous paper. 1 LIX 64N is quite an effective and selective extractint for copper, even with copper contents as high as 15 g/l, but the reagent is somewhat limited in pH range, and loses some of its extraction efficiency as the pH drops below 0.8. Liquors derived from vat leaching, electrolytic tankhouae bleed streams, or some of the new leach schemes derived to solubilize copper from sulfide concentrates are examples of the liquors that present major problems when treated via liquid ion exchange. LIX 64N could extract some of the copper from such streams, but recovery was limited to about 75 percent. Also, in some parts of the world there are streams which are relatively low in copper (-5 g/l) but which are very high in acid (25-50 g/1 H2SO4). Again, LIX 64N can attain only about 75 percent recovery from such streams. For effective treatment, these streams require a reagent which will maintain the excellent selectivity of LIX 64N, and will

Jan 1, 1971

By James J. Fallon

The industrial minerals industry is defined loosely and a specific list is presented. Criteria by which to judge prospects and examples are provided. General trends of the industry are observed.

Jan 1, 1984

By H. Huang, R. N. Gow

"The reactivity of an enargite mineral electrode was investigated spectroelectrochemically under conditions typically found in alkaline sulfide leach solutions, with pH 11-13 and Na2S additions of 50 and 250 gL-1. A bulk enargite electrode was cycled between 0 and -1,000 mV for each set of solution conditions. Raman spectroscopy was used to determine and compare surface formations against species in mass-balanced EH-pH diagrams generated using STABCAL. Previously, it was determined that arsenic could be selectively leached under alkaline conditions at an average solution potential of -300mV, across the pH range 11-13. Operating under such conditions allowed for the selective leaching of arsenic with elemental sulfur formation. From several of the voltammograms obtained during this current testing, the formation of elemental sulfur appeared at increasingly reducing conditions with increasing sulfide concentration. At high concentrations, copper started to dissolve, possibly as a bisulfide complex, reducing the selectivity of the leach, unlike previous studies. However, the presence of the higher sulfide concentration is also anticipated to prevent passivation by consuming any surface formation of elemental sulfur. This study provides insight into the operating parameters of alkaline sulfide leaching in regards to the selectivity of arsenic leaching, as well as guidance for control of reagents and solution potential and, of course, the need for water treatment afterwards.IntroductionEnvironmental limitations on the pyrometallurgical processing of arsenic-bearing concentrates have forced operations to consider other solutions. Attempts to hydrometallurgically process enargite (Cu3AsS4) fall into two categories: the co-dissolution of arsenic and copper under acidic conditions, and the selective leaching of arsenic under basic conditions. The authors believe that the selective leaching of arsenic is more amenable because it produces a solid copper phase, preferably chalcocite (Cu2S) or covellite (CuS) that could then be processed using conventional methods already in place in the copper and gold industries. Potential leaching methods include alkaline sulfide leaching (Achimovicovica et al., 1999; Anderson and Twidwell, 2008a,b; Tongamp et al., 2009 and 2010), hypochlorite leaching (Vinals et al., 2003; Curreli et al., 2005; Mihaljovic et al., 2007), ammoniacal leaching (Gajam and Raghavan, 1983), and acid leaching (Gow et al., 2014b) with or without fine grinding to mechanically activate the enargite surface and increase normally slow leach reaction kinetics (Achimovicova et al., 1999; Balaz et al., 2000; Balaz and Achimovicova, 2006). In this study, the reactivity of enargite under alkaline sulfide leach conditions was examined."

Jan 1, 2015

By Ari Jokilaakso, Junjie Shi, Zhuo Chen, Pekka Taskinen, Xiang Gao

The amount of copper flash smelting slag has increased during the recent years along with an increasing slag-to-metal ratio. During slag tapping, some copper sulfide is mechanically entrained. As a result, it is necessary to recover copper matte from the slag by suitable methods. At present, the most common way is slow, controlled cooling in a transfer ladle. However, research on the detailed effects of slow cooling and the function of slag modification is rare. This paper described experiments that were performed at different cooling rates (0.5, 1.5, 3, and 7 °C/min), with and without additive. A detailed characterization of the copper-rich phase and its particle size was subsequentlymade using SEM-EDSmicrographs and image analysis software.With a decrease in cooling rate, the particle size of the copper-rich matte phase became larger. The addition of gypsum and carbon as a slag modifier affected the size of the copper-rich phase slightly, and its chemical composition was modified compared with the experiments without additive.

Jul 31, 2020

By T. M. Dyhr, T. E. Wilson

Although environmental management costs during mine operation depend on the size, type, climatic and geochemical conditions of operation, general cost categories are identified and mean values, as a percentage of total operating cost, are determined for coal and non-coal surface and underground mines (medium-size) with on-site beneficiation and tailings disposal facilities. Cost trends are charted from 1963 through the present.

Jan 1, 2004

By W. L. Hollinshead

For more effective and cost-saving production in tunnels, the machinery used on construction sites in the future will be equipped with guidance systems combined with working-procedure management systems. This paper describes sensors for these systems and vari¬ous system configurations. A project is described that uses a computerized guidance system on an underground mining machine for guidance and profile control.

Jan 1, 2000

By S. Nickson, M. Grenon

Oriented borehole data provide the means to characterize a rock mass. In this paper, the geomechanical caving potential of a hard rock mine project is investigated. In particular, the influence of random joints to the resulting block size distributions is addressed. The implications of this approach in preliminary investigations on the choice of mining methods are discussed with reference to one site.

Jan 1, 2003

By Franklin B. Woodbury

As part of its goal of helping maintain an adequate supply of minerals to meet national economic and strategic needs, the U.S. Department of the Interior's Bureau of Mines is evaluating alternative technologies to treat oxidized taconites. Since process control is an essential element in the application of these process technologies, research was performed with a prototype monitoring system. A Californium-252 neutron source and a thermal neutron capture- gamma ray spectra analysis method was utilized to measure the amount of iron and the percent solids in the process slurries. The concentrate and tailing streams in a 410-kilogram-per-hour (900- pound-per-hour) pilot plant employing a selective flocculation and cationic flotation process were monitored. The results obtained showed that the thermal neutron capture-gamma ray reaction can be used to provide process control parameters.

Jan 1, 1979

By L. M. Turner

Perlite is a unique mineral that upon heating expands to about twenty times its original volume. Mining is by open pit method. The processing cycle involves crushing, screening and sizing the ore. An on-site quality control facility at the Manville Products No Agua mine exerts a high degree of control over every phase of the operation from blasting to finished product.

Jan 1, 1985

By J. Gawler

In June 2005 the Minerals Council of Australia signed a Memorandum of Understanding (MoU) with the Australian Government which states an intention ?for mining companies and government to work together with Indigenous people to build sustainable, prosperous communities in which individuals can create and take up social, employment and business opportunities in mining regions?. Implementation of the MoU has begun with demonstration sites established across Australia. All sites are using a Regional Partnership Agreement (RPA) model as a framework for enabling local people to find local solutions to local issues in partnership with mining companies, governments and Indigenous communities. Mining and resources companies can provide important input into regional economic development and capacity building by working through local partnerships. Company benefits include gaining a social licence to operate, access to a reliable skilled workforce, better longterm relationships with Indigenous communities and sustainable regional communities. All levels of government, Australian, State and Local, are working collaboratively to address unemployment and other issues in remote Indigenous communities. The Australian Government has adopted RPAs as one mechanism for implementing its whole-of-government approach to Indigenous affairs. This leading edge work is unique to Australia and the model has applications and significant learning for other countries and industries.

Jan 1, 2007

By P. Tsakiris

The increasing social interest for the environmental issues, forces the authorities to enact more rigorous regulations. The mining industry is one of the sectors that concentrate vigorous remonstrance. It is an absolutely justified reaction, as a result of the numerous contaminated and polluted sites that have been inherited by previous operations and they remain unremedied. The lack of a consolidated global legislation, transfers the burden of decisions to the national level. This paper consists of two parts. At the first part, it discusses the critical role of the state to form an effective environmental policy, feasible for the context of the national economy. Afterwards it analyses two of the main points, which must be considered by the regulator for the excavation activity, the abandoned sites and the duration of the mining investment. The aims are to defuse, in the short-term, the public pressure, protecting the economic growth and, at the same time, to form a basic structure for the development of the corporate social responsibility. The second part presents an alternative financial instrument for the Greek regulatory framework, conformed to the characteristics of the Greek Economy, and analyses the expected benefits both for the business and the social welfare.

Jan 1, 2002

By Brent K. Nelson, D. Lee Petersen, Charles R. Nelson

INTRODUCTION The Soudan 2 Cavern was completed in 1986 as a physics research laboratory located 713 m below ground in northern Minnesota. A paper in the 1985 RETC proceedings presented the background and planned usage for the cavern, site investigation and rock conditions, contract documents, and a bid summary. This is a follow-up paper describing construction of the cavern. The Soudan 2 excavation, 71.8 m long by 13.9 m wide by 11.6 m high, was excavated by drill and blast methods and mucked by crawler tractor and mine hoist. The excavation sequence consisted of twin top-heading pilot tunnels followed by removal of the top heading pillar and finally the bench. Various blasting designs were used to achieve adequate breakage and acceptable levels of blast damage control at the cavern perimeter. The geologic conditions exposed in the cavern, and the support needs of the rock encountered, are compared to the conditions interpreted from the site investigation. The influence of specific geologic features on cavern performance will be described. Initial support and final lining consisted of full length grouted rockbolts and reinforced and plain shotcrete. Trials were conducted with steel-fiber reinforced shotcrete and microsilica additives. The performance of the rock and support systems was tracked with single point extensometers, convergence measurements

Jan 1, 1987

By Bela Koman

Abstract - A shiploading terminal near Punta Arenas, the southernmost city of the world (lat. 53°-10'S, long. 70°-54' W) is described. Strong winds, choppy seas, frequent gales, rain, and snow make it difficult to load ships at an offshore berth in this area. Detailed site investigations, including a wind-recording program, supplied sufficient information for the analysis of operating conditions. The weather pattern of the entire region, including the predictability of gales, was utilized in the analysis. The results showed that a bulk loading terminal at this location is feasible, provided that the design takes into consideration the specific problems of the site. The final layout shows a terminal that can be approached from several different directions, depending on the direction of the wind. The mooring system is arranged to allow alter- native ways of attaching and casting off mooring lines and executing docking and departing maneuvers. The berth is supported on piles and contains the minimum of structures, relying on a slewing shiploader to reach the ship in any position, with only limited fore and aft shifting of the vessel for loading the extreme hatches. Results of wind recording, statistical analysis of wind and wave data, operating criteria, and the results of berth availability analysis are included in the paper.

Jan 1, 1987

By P Moser

Within the EU-research project "Blasting Control", jointly operated with partners from France, Italy and Greece, between 1992 and 1995, the Department of Mining Engineering of the Montanuniversity Leoben, Austria took over the task to develop a diagnosis system applicable in underground drifting, in order to identify possible reasons for blast failures or poor blast performance. For that purpose 120 m of 12 m2 test galleries were excavated at two different mine sites. For every blast performed the collar and bottom position of every hole drilled, the charged hole length and the drift and face profile of the round blasted were monitored. These 'geometrical" data were put directly from the measuring devices into SURPAC, the mine planning software chosen for data analysis. Based on the data computed, 3D plots comparing actual and planned data were made visible on the screen or as hard copies. Experience from the introduction of this system into a mining operation showed, that the system developed contributes to an improved understanding of the reasons for blast failures and forms the basis for an improved blast design. The soft- ware package SURPAC was also used to train the miners directly at the mine site in order to improve the quality of their work.

Jan 1, 1996

The development of economical and effective treatment processes for solid and aqueous waste is a critical issue facing the mining industry today. Cyanide, nitrates and acid rock drainage are environmentally sensitive effluents that require treatment or containment for acceptable disposal. In situ biotreatment processes are an emerging technology (Thayer) for cyanide oxidation, denitrification, sulfide mineral alteration and metal re- mineralization. Biological cyanide oxidation is competitive with chemical treatment processes (peroxide, alkaline chlorination) for process solutions, spent ore and tailings detoxification. Microbial denitrification treats mine waste contaminated with nitrates from blasting, processing or nitrification of the host rock. Bio-alteration of sulfide minerals and metal re-mineralization may present the most cost-effective and environmentally acceptable method of dealing with sulfide tailings and leachate solutions. Field test programs for cyanide bio-degradation and denitrification of spent ore and process solutions were designed and run at two mines. Although the treatment bacteria and the application processes are similar, each waste presented site-specific problems for adapting the biotreatment processes. Some of the site problems include climate, ore geochemistxy, field bacteria production, waste microbiology and application engineering. This paper compares treatment design and results for cyanide oxidation and denitrification in heap detox treatments.

Jan 1, 1992

By Cheryl L. Mardock, Michael D. Strickler

The Bureau of Mines is examining mineral deposits bearing strategic elements such as cobalt, for which the United States heavily relies on imports. The Turner-Albright volcanogenic sulfide deposit in southwestern Oregon is marginally economic based on its gold content and associated silver, copper, zinc, and cobalt values. Bureau research on the Turner-Albright deposit was performed (1) to evaluate domestic cobalt recovery as a byproduct of gold production from massive sulfide ores; (2) to develop an analogue of modern sea-floor polymetallic deposits to determine the economic potential of the deep-sea resources; and (3) to compile information on the geochemistry and genesis of the deposit that can aid in future onshore exploration. Cold was introduced as near micrometer-sized disseminations by exhalative hydrothermal fluids near sea-floor vent sites and by late influxes of mineralizing fluids into lower zones of brecciated sulfides and basaltic fragments. Cobalt is a substitutional element in pyrite that occurs in outlying halos around original vent sites. Mineralogic studies conducted with a scanning-electron microscope and an electron microprobe determined that none of the ore minerals are amenable to traditional beneficiation methods such as gravity and flotation. An experimental oxygen pressure-leaching procedure developed by the Bureau has proven successful in treating such complex ores.

Jan 1, 1990

By John R. Keith

Keith, John R. 1968. Relationships of lead and zinc contents of trees and soils, Upper Mississippi Valley District. Preprint, Fall 1968 Meeting, Soc. Mining Engineers of AIME. Lead and zinc contents of elm, maple, and oak trees and of soils in which the trees grew were determined in samples from the Upper Mississippi Valley mining district, and from an area outside but contiguous to the district. The lead and zinc analyses of plant materials served to differentiate the mineralized and non-mineralized areas. Stems contained about two times as much lead and about 2-5 times as much zinc as did leaves taken from the same stems. Lead and zinc analyses of all soil horizons could be used to differentiate between the two areas. Soils at most sample sites in the mineralized district seemed to be more reliable than plants for geochemical prospecting and are a more practical sampling medium. Soil samples from areas with thick loess cover, however, failed to indicate the presence of mineralized bodies whereas tree samples from the same sites contained anomalous amounts of lead and zinc. It is suggested that in areas of thick loess cover plant samples could be used in prospecting for lead and zinc.

Jan 1, 1968

By R. M. Tyson

Sulfides present in the troctolitic and footwall rocks are placed into one of three major zones (hornfels, cloud, and basal) on the basis of their stratigraphic position and mineralogy. Hornfels sulfides, enriched in Fe, represent remobilized sedimentary sulfide. Sulfides from the Cloud Zone are probably magmatic and are enriched in PGE, Cu, Ni, and Ag. The basal sulfides, composing most of the ore, resulted from contamination of the magma by remobilized sedimentary sulfide. The basal sulfides exhibit a differentiation trend in their mineralogy and chemistry. PGE, Cu, and Ag are enriched with increasing differentiation which is attributed to fractionation within an immiscible sulfide liquid.

Jan 1, 1986