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By Philip G. Burkhalter

Total yield and backscattered electron coefficients were measured in this Bureau of Mines study in an microanalyzer as a function of atomic number and of primary crier: ;y in the 15- to 35-kilovolt range. The electron coefficients were obtained indirectly from measurements of the specimen electron current and the primary beam current collected in a Faraday cage and were measured with a precision better than 0.5 percent. Secondary electron emission was suppressed with opposing potential applied to a screen grid surrounding the specimen. The values of the backscattered electron coefficients agreed with published values within 5 percent.

Jan 1, 1965

By A. S. Peck

This report presents the results of a cooperative study between the Bureau of Mines and the University of Utah to define the mechanism involved in the adsorption of oleic acid and sodium oleate on fluorite, calcite, and barite, using an infrared spectrophotometer for identifying and measuring the adsorbed reagents and reaction products. Fluorite, calcite, and barite react with oleic acid and sodium oleate in a water system, forming chemisorbed and solution products. The chemisorbed species is a surface mineral cation-collector anion salt, Chemical analysis of solution resulting from the adsorption reaction indicates that the adsorption process causes displacement of mineral anions, namely, fluoride, carbon ate, and sulfate from the surface of these minerals.

Jan 1, 1963

By L. J. Kane

Several processes being developed by the Federal Bureau of Mines to provide new and more efficient uses for coal require practical methods for removing dust from hot gases. Filters provide such means. The efficiency of filters made of aluminum silicate fibers and porous stainless steel was determined. The results obtained with the fibers were previously reported.5 In this investigation tests were made with three porosities of stainless steel filter material (grades C, D, and E) at a gas flow of 1,000 std. c.f.h./sq. ft. of filter, temperatures of 75° and 1,000° F., and dust loadings (as represented by cumulative dust fed) of 100, 1,000, and 10,000 gr./sq. ft. of filter. Pressure drop during the runs ranged from 0.1 to 21 in. of mercury, and dust removal from 25 to 99.93 pct. Filters having the finest pores gave the greatest pressure drop and percentage of dust removal; however, their dust-holding capacity was slightly lower. Usually, their ability to remove a higher percentage of dust at the same pressure drop more than compensated for the slightly lower dust-holding capacity. With increase in temperature, for the same weight rate of flow of gas, the pressure drop increased and the percentage of dust removal decreased. The effect of temperature was probably due to the accompanying change in the linear velocity and viscosity of the gas.

Jan 1, 1961

By A. J. Keast

This circular is one of a series dealing with the exploration, equipping, and development of mining properties, prepared and published by the United States Bureau of Mines in cooperation with various mining and exploration companies in the United States and Canada. This series of papers will supplement an earlier one which covered the methods and costs of mining and milling at a large number of producing mines. The present paper describes the exploration, equipping, and developing of a group of 18 claims remote from rail transportation, and the transport of equipment and heavy supplies for a distance of 120 miles by tractor over ice and winter roads, and of men and lighter supplies by airplane.

Jan 1, 1933

By R. V. Ramani, K. Bode

"IntroductionThe theory of particle dispersion and deposition in turbulent flow is important to many fields of science and engineering. Dispersion has been studied in some detail since the early fifties (Taylor, 1954; Fischer, 1967; Osipov and Grekov, 1968; Skobunov, 1970 and 1973; Klebanov and Martynyuk, 1974). A broad research effort has also been underway in studying the mechanics of dry particle deposition. Friedlander and Johnstone (1957) proposed a theory, according to which particle deposition from vertical pipe flow could be described by an eddy diffusion transport followed by a final flight to the surface. There have been numerous revisions and additions to this original theory (Owen, 1960; Liu and Agarwal, 1974; Liu and llori, 1974; El-Shobokshy and Ismael, 1980) The mining process essentially consists of breaking in situ materials and transporting them out of the mine. An inherent characteristic of this process is the generation of fine particles. Fine airborne particulates are associated with a number of threats to the health of the miners; fine coal dust can also result in mine-wide catastrophic incidents such as dust explosions. For these and other reasons, it is important to understand the behaviour of airborne dust particulates, particularly their generation, entrainment, transport, dispersion, and deposition in the mine environment for their control.Mine related studies on dispersion and deposition have been few. Yet, several studies of gas and dust dispersion, diesel exhaust contamination, and methane ingress into mine workings have recognized the need for developing reliable parameter values for fundamental understanding of the phenomena (Da""Yes and Slack, 1954; Hodkinson, 1957; Hodkinson and leach, 1958; Mass and Wildschut, 1966; Airey, 1969; Courtney et al., 1986; Stefanko, Ramani, and Thakur, 1974; Stefanko, Ramani and Kenzy, 1977; Bhaskar, 1987, Bhaskar and Ramani 1990; Qin and Ramani, 1989; Shankar and Ramani, 1990)."

Dec 1, 1995

By Fred Kissell

The Bureau of Mines has developed the shearer-clearer--a new type of dust control system for longwall shearers. The system partitions the airflow around the shearer into a clean split and a contaminated split. The dust cloud is confined to the vicinity of the coal face, while the shearer operators remain in the clean split on the gob side of the machine. The shearer-clearer operates on the principle that each water spray moves air like a small fan and can be positioned to direct the dusty air towards the face. The hardware is inexpensive and can be installed in a single shift. It consists of several strategically mounted water sprays and one or more passive barriers. Laboratory testing indicates reductions 1n shearer operator dust exposure as high as 97 pct. Preliminary results from an underground demonstration in one mine also indicate that considerable dust reductions at the shearer may be obtained. In conjunction with the development of the shearer-clearer, dust surveys were conducted in three other mines to determine if some shearer spray systems currently in use partition the flow in a manner similar to the shearer-clearer, and if so, whether this partially accounts for markedly cleaner conditions on some longwalls. Results from these surveys indicate this to be the case. A feature of the cleaner longwalls was a downwind orientation of their water sprays, which is a key element of the shearer-clearer system. The shearer-clearer system described in this report was designed for an Eickhoff EDW 300 shearer working a 7-foot coal seam. The testing to date has concentrated on cutting directions counter to the primary airflow. The development effort continues for different mining equipment and conditions. It is expected that different systems will be required to accommodate the range of conditions occurring underground. Application of the system presented here to conditions different than those described is not likely to produce the same results.

Jan 1, 1981

By W. N. Cathey

Many materials including carbides, silicides, phosphides, borides, nitrides, oxides, and metals were studied by the Bureau of Mines as potential fuel cell catalysts for electroreduction of oxygen in a 1[N]H2S04 electrolyte. The objective of this study was to assess the potential of abundant, low-cost materials as substitutes for platinum or to increase the catalytic efficiency of platinum. Several compounds were rejected because of their reaction in the corrosive environment of the oxygen electrode. However, some of the remaining were the most active catalysts. Activity of carbides such as tungsten carbide could be improved by doping with platinum-group metals, by varying stoichiometry, or by sputtering on a layer of platinum. While no catalysts were found with activity as high as platinum, some compounds were shown to be deserving of further investigation.

Jan 1, 1979

By R. Hogg

"Particles play an important role in our environment and in many aspects of human activity. Much of the Earth's surface - sand, soil, rocks - consists of particles, as do clouds in the atmosphere, smoke from fires, and dust in our homes. Many of the foods we eat - cereals, flour, instant coffee - and everyday items such as pharmaceuticals, cosmetics, detergents and other cleaning products are encountered in the form of particles. Inks and paints consist of very fine particles dispersed in liquids. Modem agriculture uses huge quantities of fertilizers and pesticides, largely in particulate form. The list could be extended almost indefinitely; particle systems are obviously an important part of our daily lives. But what do we know about them? For most people, the answer is probably: not much.We are all familiar with the three common states of matter: gas, liquid and solid. In many respects, particle systems should be regarded as a distinct class of their own. The particles themselves may be solid but we all know that a heap of sand is quite different from a solid rock. A cloud of liquid droplets - fog - has much more in common with a cloud of solid particles - smoke - than it does with a bucket of water. There are certain characteristics and properties which are unique to the particulate state. The behavior of any particle system is determined not only by the material from which the particles are made, but also by interactions among the particles and with their environment. These interactions become increasingly important as the size of the particles decreases, and for exceedingly fine particles, smaller than about one micrometer (0.000001 meters or 0.00004 inches), these interactions dominate and we enter the realm of colloidal systems.Particle SystemsA system in which discrete entities - particles -are dispersed in a continuous medium can be regarded as a particulate system. The particles and the medium can consist of a solid, liquid or gas. The various combinations and some common examples are listed in Table 1. The properties and behavior of these systems depend on the characteristics of the particles, the nature of the medium, and the relative abundance of the two phases. In general, it is the latter which determines the kind of behavior exhibited by the system.As a general rule, the behavior of particle systems follows that of the dispersed phase (the particles) at high concentration, and that of the continuous phase (the medium) at low concentration. For example, both powders and smokes consist of solid particles in a gaseous medium. However, in a powder the solids typically occupy over one half of the total volume; in many respects powders behave like solids. In a smoke, on the other hand, the particles may take up only a few parts per million of volume, so that these systems generally behave like gases."

Jan 1, 1989

By D. G. Kuehn

Positive ion sampling studies have been conducted on do discharges containing 0.33 percent sulfur dioxide in helium. Measurements were made for normalized gas pressures from 0.45 to 6.8 torr and discharge currents from 5 to 40 ma. Ion species observed included SO+, S+, SO2+, SO3+; O+, and 0+, 02+. Studies were conducted on the functional dependence of the various ion species with respect to axial distance, pressure, current, and gas flow rate. Interpretation of these results is consistent with the assumption of SO2 dissociation. Deposition of sulfur compounds was observed in the plasma container during these studies. The present results are compared with previous studies which have been conducted in SO2.

Jan 1, 1971

By E. C. Lane

Although motor gasoline marketed in the United States in January of this year was, on the average, slightly more volatile than that sold in January 1925, the improvement in quality is too small to be of importance. In other words, there is no evidence that any radical change in the quality of gasoline is being made at the present time. During the past six years the Bureau of Mines has made semi-annual surveys of the gasoline marketed in the United States, the survey just completed being the thirteenth in the series. The cities in which samples have been collected have been chosen as representative of the more important marketing territories as it is obviously impracticable to obtain a sample of every gasoline sold in the entire country.

Jan 1, 1926

By Victor E. Kral

"SUMMARYFollowing a magnetometer survey on the McCoy iron deposit, a trenching and drilling program was carried out by the Bureau of Mines in August 1944.This deposit is 32.3 miles southwest of Battle Mountain in the McCoy Mining District, Lander County, Nevada, and lies on the east flank of the Fish Creek Mountains at an altitude of 5,400 feet, about 1 1/2 miles south of the gold camp of McCoy.Total production from the deposit has been 400 tons of magnetite, mined by hand and shipped to the west coast for ship's ballast.Bureau drilled two holes to a total depth of 92 feet and excavated 12 feet of trenches. Both holes were drilled in the same ore body and engineered magnetite ore 14 and 11 feet thick. Trenching was used successfully to show the lateral limits of the ore.Magnetite ore bodies were found to occur as replacements of a limestone bed in quartzite. They outcrop near and parallel to the exposure of a diorite entrusting that forms a long westward-trending ridge. Although magnetic outcrops can be traced for 5,000 feet trenching definitely proved the ore bodies to be disconnected to have little or no lateral extent beyond their outcrops. Only two ore bodies more than 10 feet thick were found; one of these is the inaccessible to and the other was drilled by the Bureau."

Jan 1, 1947

By Constantine C. Popoff

During 1946 several limestone deposits near Fortson, Snohomish County, Wash., were examined by the Bureau of Mines. These examinations were part of a long-range investigative program of regional mineral supplies required by the anticipated industrial development of the Pacific Northwest. The .study outlined in the following paper was specifically undertaken to disclose new sources of high-purity limestone and to appraise, their economic aspects. The deposits examined -namely the Galbraith, Climax, and Hi, Hi -are somewhat similar in physical features and geologic environment. They are lenticular and belong to the same formation of metamorphosed sediments that underlies the prominent Whitehorse Ridge.

Jan 1, 1949

By Homer J. Ballinger

The Rex mine is one of several zinc deposits in Ozark and Howell Counties, Mo. It is the second of these deposits investigated by the Bureau of Mines in an effort to demonstrate reserves of sulfide ore underlying the shallow carbonate ores from which the district's major production has come. The initial investigation was made during 1945-46 on the Alice mine, Ozark County, Mo.21 The investigation reported herein was conducted during 1947. The Rex open pit is about 250 feet long, 100 feet wide, and about 25 feet deep (average). Three caved shafts are evident in the bottom of the pit, but the extent of the workings from these shafts is not known. The Bureau of Mines drilled five churn-drill holes in and around the Rex pit to test the grade and the vertical and lateral extent of the deposit. Two of the holes indicate notable zinc mineralization ranging from less than 1 to more than 10 percent metallic zinc, but largely in the oxidized condition.

Jan 1, 1948

By H. C. Ko

Calorimetric determinations of low-temperature heat capacities and the standard enthalpy of formation were made by the Bureau of Mines for aluminum sulfide, A12S3. The standard entropy (S°), enthalpy of formation (?Hf°), and calculated Gibbs energy of formation (?Gf°) at 298.15 K are 27.93±0.05 call deg-mole, -155.6±0.9 kcal/mole, and -153.0±1.0 kcal/mole, respectively.

Jan 1, 1976

By Donald W. Mitchell, John Nagy, Edwin M. Murphy

To increase safety and productivity in mining , the potential uses and hazards of rigid foam were investigated by the Bureau of Mines Experimental Coal Mine . This research resulted in the development of chemical formulations , spraying equipment , and application procedures that permit safe and effective use of urethane foams for improving mine ventilation , for reducing weathering of mine rock and steel , for constructing seals in fire areas , and for thermal insulation .

Jan 1, 1964

By Albert E. Long

Since December 10, 1945, the Mount Weather Branch, Mining Division, Bureau of Mines, has been maintaining detailed performance and cost records on the diamond coring bits used throughout the United States by the Bureau of Mince. Figure 1 is a copy of a typical master record sheet showing the scope and type of information recorded for each bit. It is the intention of the Bureau of Mines to issue analytical reports covering the effects of diamond size and quality on the cost of core drilling in different rocks as the information on a significant number of bits used in any one type of rock is accumulated. This report is the first of such a proposed series and is based on the diamond loss and bit costs incurred in the use of 539 AX bits in coring operations on 10 different projects involving 6,097 feet of drilling in gneiss. The 10 projects were located in New York, Pennsylvania, and New Jersey (fig. 2). As a result of the information accumulated on the use of diamond-coring bits in drilling in gneiss, it has been found that the type of bit, the matrix, the percent of core recovered, and the size and quality of diamonds used have a definite effect on the cost of bits per foot drilled.

Jan 1, 1950

By R. J. Bielicki

A sorption apparatus for measuring the equilibrium sorption isotherm and the rate of diffusion of methane from fine-sized coal was designed and constructed. Preliminary work that used Pittsburgh and Pocahontas No. 3 coal shows that the diffusion coefficient varies with pressure and that the fracture spacing in these two coals is substantially different.

Jan 1, 1972

By W. J. Fullerton

This paper is one of a series prepared for the United States Bureau of Mines discussing the methods used in crushing and grinding materials for cement manufacture, and deal particularly with the methods used at the Howes Cave plant of the North American Cement Corporation. These papers are designed to disseminate technical information regarding the methods used. The cost tabulations represent local operating expenditures only and not total production costs. It is recognized that publication of total production costs might in many instances cause embarrassment to individual producers as well as to the industry as a whole. On the other hand, operating costs are essential to the technical discussion and study of methods employed. The attention of the reader is specifically called to this differentiation in order that no misunderstanding of the scope of the cost tabulations shall ensue.

Jan 1, 1932

By F. N. Kissell, R. J. Bielicki, J. H. Perkins

A sorption apparatus for measuring the equilibrium sorption isotherm and the rate of diffusion of methane from fine-sized coal was designed and constructed. Preliminary work that used Pittsburgh and Pocahontas No. 3 coal shows that the diffusion coefficient varies with pressure and that the fracture spacing in these two coals is substantially different.

Jan 1, 1972

By M. S. Seehra, R. S. Pandurangi

"INTRODUCTION Silica and kaolin (a layer aluminosilicate) are among the major constituents of most coal mine dusts.' Whereas kaolin is cytotoxic in vitro but nonfibrogenic in vivo in humans and experimental animals,2-4 the cytotoxic and fibrogenic potential of silica is rather well established.5 Wallace and co-workers 6-8 have studied the cytotoxic potentials of both native and surface-modified silica and kaolin and inferred that retoxification is slow in the case of occluded silica vis-à-vis native silica. Recent epide¬miological studies indicate that silica concentration alone in a mine dust, as determined by transmission IR spec¬troscopy (TIRS), does not correlate well with the pro¬gression of coal workers' pneumoconiosis. 9 This obser¬vation has led to the suggestions that silica particles occluded by clays such as kaolin may not be fibrogenic. This proposal requires accurate estimations of kaolin, silica, and occluded silica. The current method of silica analysis in a mine dust sample employs TIRS of the 797- cm -1 band of silica, although its accuracy, as well as that of x-ray diffraction studies, is no better than 25 % , even in a laboratory-generated dust.° In this paper we have employed the techniques of diffuse reflectance spectros¬copy (DRS) and photoacoustic spectroscopy (PAS), in conjunction with an FT-IR spectrometer, for the quan¬titative determination of silica in laboratory-generated silica-kaolin mixtures.One of the main advantages of DRS and PAS is that, in these techniques, problems arising from sample prep¬aration of the KBr-based disks used in TIRS are avoided. There are, however, several other considerations (e.g., particle size effects and saturation phenomenon) which complicate the use of DRS and PAS for quantitative work. 10-25 In this paper, we have carried out a systematic comparison of the quantitative abilities of the two tech¬niques, as applied to the silica-kaolin mixtures, with par¬ticular attention to the saturation behavior of several bands with different absorption coefficients. In particular, we show that a weaker band for silica at 1875 cm-1 is suitable for quantitative purposes, and that quantitative accuracy is higher in DRS than in PAS. Details of this work are given below."

Mar 1, 1992