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By C. O. Hawk

As an exploratory effort to produce useful products from coal by a new path, the Bureau has made a few experiments on the fast heating of finely ground coal particles by irradiation with a flash of high intensity light. The flash was produced by an electrical discharge at high voltage through a xenon-filled tube. The flashes lasted from 2 to 3 milliseconds. The reaction took place in small sample tubes, ½ inch-dimeter by 4 inches long, and with small amounts of coal (total amount charged 0.1 gram, probable effective amount not more than 20 milligrams). Average particle size of the coal, estimated on a numerical basis, was 20 microns. Temperatures reached were evidently quite high, because all products obtained in quantity were characteristic of high temperature pyrolysis. Apparently, conversion of the coal was extensive where isolated particles received the full benefit of a flash. It seems particularly significant that acetylene was present in appreciable amounts--comprising almost 3 percent of the total gaseous product in one case. This is good evidence of a short heating period to very high temperature (well above 1,000° C) followed by rapid quenching. Although the results are interesting, they do not suggest any immediate practical application.

Jan 1, 1963

By Jon I. Voltz

The U.S. Bureau of Mines has conducted fundamental coal fragmentation studies to evaluate the effects of impact energy and direction of bedding planes on dust generation, size distribution, and impact-output energy relationships. Product size distributions were obtained for the fragmented samples by screening to minus 150 mesh. The minus lS0-mesh fines were analyzed with a light scattering photometer with a measurement range of 176 to 1.9 /.tm. Increased input energy produced a significant increase in the weight of plus 3/8-in material for impact perpendicular to the bedding planes. No significant trend was observed for parallel impact. Impact direction had little influence on dust size distribution, and input versus output energy relationships. As expected, total airborne dust measured at time of impact and percent particulates below 11 /.tm in size generally increased with increased input energy for both directions of impact. Energy used for sample fragmentation increased with increased energy input.

Jan 1, 1989

By Philip C. Good

The Bureau of Mines investigated the feasibility of utilizing low-grade phosphatic shale as a feed for phosphoric acid production. Present practice in the phosphate mining operations of southeastern Idaho is to remove and either stockpile or waste low-grade phosphatic shales as the high-grade phosphate beds are selectively mined. Acid digestion studies were performed on uncalcined shale and on shale calcined to remove free carbon to determine phosphoric acid quality, yield, and amenability to filtration. The untreated shale, containing 21.4 pct P205, was digested with sulfuric acid in a single-tank reactor to yield phosporic acid and gypsum residue. Although 96 pct P205 recovery was attained in digesting uncalcined shale, only the calcined product gave satisfactory filtration rates. Calcined shale yielded phosphoric acid recovery of about 93 pct of the contained P205. It was higher in impurities than commercially prepared acid derived from high-grade western phosphate rock. An acid filtration rate of 745 lb P205/ft2/day was attained. This value is lower than the rate of 900 lb P205/ft that is generally considered to be acceptable in industrial production of phosphoric acid from high-grade phosphate rock.

Jan 1, 1981

By Gerald W. Elger

To determine the feasibility of removing nonferrous metal impurities from automobile scrap by thermal treatment in a rotary kiln, the Bureau of Mines conducted four series of tests with synthetic scrap mixtures heated at various temperatures under oxidizing and reducing conditions. The treated scrap mixtures were melted in an electric-arc furnace and cast into small ingots for impurity evaluation. Analyses showed that the ingots were essentially free of residual metal impurities except for copper. Test data indicated that in an oxidizing atmosphere the percentage of copper removed increased with treatment temperature. Percent of copper removed in a reducing atmosphere was found not to be temperature dependent. A significant finding was that copper was embrittled under some of the operating conditions and was mechanically removed by fragmentation.

Jan 1, 1968

By E. W. Dean

This report on the physical and chemical properties of typical crude oils of Oklahoma is the sixth in a series of preliminary chapters of a bulletin covering the producing districts of the United. States. Preceding reports* may be obtained on request. The details of the methods used in this survey in collecting samples, making laboratory tests, and interpreting results are discussed in the first three papers. If any errors or omissions are noted by readers, it is hoped they will be brought to the attention of the Bureau of Mines for correction before the appearance of the permanent report. Samples of Oklahoma crudes analyzed in this report were taken from those fields representing the major production of the State. The Oklahoma Geological Survey designates 172 different oil and gas fields in the State, S1 being in Osage County, 14 in Tulsa County, 14 in Okmulgee County, 9 in Washington County. The list of samples collected by the Bureau of Mines represents only 5 fields in Osage County - Bigheart, Burbank, Hominy, Osage Junction, and Pershing - yet these samples, together with those from adjoining fields, are representative of nearly all crude produced in the county. The sample 'from the Pershing field, for example, is representative of the crude produced in several fields in that part of the county - such as Nelagoney, Pawhuska, Wyomona - and the sample from the Skiatook,

Jan 1, 1922

By Arthur Crowfoot

This paper describing t o concentrating practice of the Phelps Dodge Corporation, Morenci Branch, at Morenci, Ariz., is one of a series of articles on concentrating methods and posts being prepared by the Bureau of Mines. The Morenci concentrator, locally known as No. 6 concentrator, treats 5,000 dry tons of ore per 24-hour day by primary tabling followed by two stages of flotation treatment, at 48-mesh size and 65-mush size respectively.

Jan 1, 1931

By P. E. King

The U.S. Bureau of Mines is conducting an ongoing research project to better understand the phenomena involved within electric arcs utilized in electric furnace steelmaking. With a better understanding of the physical and electrical characteristics involved, dynamic or predictive control of electric arc furnaces may be possible. A mathematical model is presented, but not solved, and the system of coupled equations is analyzed. Characteristic parameters are used to determine relative importance. In this manner, significant quantities are dermed. The parameters found to contribute little to the system of equations of motion are ignored. A resultant simplified system is identified, and directions for further study are indicated toward control of electric arc furnaces.

Jan 1, 1990

Prevention of coal-mine explosions depends largely upon thorough knowledge of the causes that initiate explosions. A review of coal-mine explosions in one geographical area when supplemented by nationwide data of similar nature, should serve as a guide for the adoption of measures for explosion prevention. Explosions in bituminous-coal mines of the United States during the 10 years ended December 31, 1932, ranked third in the causes of fatal accidents and constituted 16.1 percent of all fatal accidents in bituminous mines. Kentucky now ranks fourth in coal output in the coal-producing States of this country; a study of the coal-mine explosions in this state will be of definite interest locally among coal-mining people, as well as to those in the coal-mining industry who are concerned in preventing coal-mine explosions. This circular reviews gas and dust explosions in Kentucky coal mines to show their hazards, to point out the influence of certain factors in causing explosions, and to indicate the effectiveness of preventive measures.

Jan 1, 1934

By W. H. Oppelt

The Federal Bureau of Mines investigated combustion of lignite in domes-tic heating equipment to obtain information on equipment performance and to evaluate testing procedures. Three types of domestic heating equipment were tested, ranging from a hand-tilled, magazine-type space heater to a ram-type overfeed stoker. Lignite was readily burned in each of the three units under various test conditions. Burnoff rates determined by adding weighed charges to the magazine were found to be in error because of shrinkage of the lignite when only a portion of the magazine capacity was consumed during a test. More reliable burnoff rates could be determined by carbon-nitrogen balances. A hand-fired magazine-type space heater (Booker heater) was operated without the furnace attachment at efficiencies to 75 pct. One test series was run with minimum supervision under conditions encountered in actual household operation. No mechanical trouble was encountered.

Jan 1, 1960

By H. L. Gilbert

Zircon sand may be reacted with sodium hydroxide at 600° C. to form sodium zirconate and sodium silicate. Sodium zirconate is water insoluble and so may be washed free of sodium silicate. The sodium zirconate may then be converted to zirconyl chloride by the action of hydrochloric acid and the zirconyl chloride crystals separated by cooling the solution. This approach produces zirconyl chloride of satisfactory purity with less cost than is involved in buying anhydrous zirconium chloride and converting it. A proposed design for a plant is given, INTRODUCTION This work was conducted by the Rare Metals Branch as a part of research on zirconium at the Bureau of Mines Northwest Electrodevelopment Laboratories, Albany, Oreg., under the guidance of S. M. Shelton, Regional Director. The work was supervised by W. W. Stephens, head of the Rare Metals Branch (now with Carborundum Metals Corp.).

Jan 1, 1954

By C. C. Hwang

The Bureau of Mines made time-dependent calculations to determine the size of a stationary source fire within a ventilated duct (or passage-way) necessary to ignite a combustible duct liner. The objective of this work was to gain more understanding of what occurs in duct fires and to determine critical conditions for ignition and propagation of mine fires. Heat transfer to the combustible surface includes both convective and radiated components, while the heat is conducted into the combustible and reradiated to the surroundings. The combustible is assumed to ignite when the net heat transfer to its surface is sufficient to raise the surface temperature to some minimum temperature, defined as the ignition temperature. A nondimensional parameter, which characterizes the source-fire intensity in the presence of ventilation flow, emerges as a parameter for a criterion of the critical conditions. The results of these calculations indicated that the minimum fire size necessary for ignition increases with the ventilation rate and duct cross section. These results are compared with experimental results obtained from fires in a 0.8-by 0.8-by Il-m-long duct and a full-scale gallery (2.4-by 2.4-by 65-m). Agreement between the theory and the experiment is good.

Jan 1, 1988

By Jr. Reed

The only known large deposits of talc in Alabama occur near Winterboro, Talladega County. Preliminary examinations were made, and work by the Bureau of Mines was recommended. The deposits were investigated to determine the amount and grade of talc present and to search for new talc deposits in the general area. Seventy-five holes, totaling 3370.4 feet, were drilled with Government-owned core drills from August 1, 1948, to February 11, 1949, and 27 samples were taken for assay. This report presents the factual data disclosed by drilling and the results of beneficiation of the talc.

Jan 1, 1950

By C. A. Komar

Laboratory-scale hydraulic fracture tests were conducted by the Bureau of Mines on directionally oriented sandstone material, along with measurements of directional rock properties such as tensile strength, permeability, ultrasonic velocity, and dynamic elastic constants. In these tests, fracture orientation was determined as a function of various combinations of stress, rock saturation, rate of borehole pressurization, and direction of minimum tensile strength relative to minimum horizontal compressive stress. The objective of the experiment was to investigate whether horizontal stresses always controlled the orientation of induced vertical hydraulic fractures, or if under conditions of small differences in stress and/or slow borehole pressurization rates, the induced fracture direction was influenced by directional properties of the rock matrix. This study shows that the expected influence of horizontal earth stress on the orientation of an induced hydraulic fracture becomes negligible when¬ever the magnitude of the difference between the compressive stresses is 200 psi or less. When this occurs, fracture orientation is controlled by the directional properties of the rock--primarily permeability and tensile strength.

Jan 1, 1973

By Causey J. Douglas

In 1988, at the request of the Bureau of land Management, the U.S. Bureau of Mines studied part of the 13,460-acre Owyhee Breaks Wilderness Study Area (OR-003-059) in order to evaluate its identified mineral resources. The study area is in Malheur County, OR, about 27 miles northwest of Jordan Valley. No mineral resources were identified in the study area during this investigation. There is an occurrence of jasper along Birch Creek and an associated occurrence of zeolite in some tuffs. In the northern part of the study area is an occurrence of bentonitic clay containing less than 40,000 tons. Much of the area is covered by landslide blocks, colluvium, earthflow deposits, and talus, composed of Tertiary-age volcanic rocks. The upper plateaus are capped by Tertiary-age basalt.

Jan 1, 1989

By B. W. Gandrud

In 1927 Coghill showed that there is considerable liberation of the iron oxide mineral from gangue when the Alabama red iron ores are ground to a size suitable for classification and tabling but that there is not sufficient to make possible a high extraction and a high grade of concentrate. Coghill states: High extraction and 'high grade of concentrate cannot be obtained without grinding to a size comparable with flotation or cyanide practice. If grade of concentrate be sacrificed the grinding need not be so severe. These ores slime readily during grinding, and in most instances the slimes are only slightly higher grade than the original ore. Not only do they carry a considerable percentage of the total iron in the ore, so that to reject them as tailings would result in prohibitively low extraction, but they are too fine to be amenable to ordinary methods of gravity concentration. In 1929 the Bureau of Mines published results showing that certain Alabama oolitic iron ores could be concentrated by classification and tabling after grinding, with rubber-covered rods. This selective grinding produced slimes of much higher grade than the original ore, and they were considered part of the final concentrate.

Jan 1, 1934

By Jasinder S. Jaspal

In underground room-and-pillar mining methods, the sectional conveyor belts are extended or retracted periodically to maintain shuttle car tramming distance to a minimum. A conventional conveyor belt extension or retraction is a heavy, arduous job that if mecahnized, has the potential to improve productivity and safety. To reduce the burden of heavy work of this activity and mechanize it, the Bureau of Mines developed a conveyor belt service machine (CBSM) through a research contract with Tractor MBA. The CBSM is a self-contained, battery-powered, rubber-tired vehicle capable of handling, storing and transporting conveyor belting, wire rope, and associated belt structures in seams as low as 48 in. Belt extensions and retractions are accomplished by moving the tailpiece of a belt conveyor with the CBSM to the next position while dispensing or retrieving the belt, wire rope, and associated belt structures. The CBSM improves the belt extensions and retractions by making them easier and faster, and it utilizes fewer workers. The CBSM was surface tested at the Bureau's Mining Equipment Test Facility (METF) to evaluate its performance and reliability. Modifications were made to the CBSM to correct deficiencies found during surface testing.

Jan 1, 1988

By M. J. Sapko

The pressure and flame development of the methane-air-nitrogen system was investigated in the Bureau's l2-foot-diameter sphere to define buoyancy effects and to develop relationships for predicting venting requirements. Pressure rise (?P) is defined as a function of time (t) and nitrogen dilution and is shown to deviate noticeably from the cubic law (?P = kt3), depending upon the period of combustion and the mixture composition. Corresponding flame speed (Sf) and burning velocity (Su) data are given which show that Sf is time dependent and that Na dilution has a greater effect than air dilution in inhibiting the flame propagation. The Su data agree with "accepted" values and are unique in that they are based on much larger flames than those used in other investigations. Downward propagation limits are shown to depend mainly upon buoyant forces, which can affect the burning of even stoichiometric CH4-air systems. Theoretical expressions, based on the mixture burning velocity and expansion ratio, are given for predicting the venting requirements for ignitions of hydrocarbon-air-nitrogen mixtures in spherical or cubical enclosures.

Jan 1, 1976

By E. G. King

Many of the existing thermodynamic values for the titanium halides are estimates, including all the entropies and high-temperature heat contents of their crystalline and liquid phases. This report contains the results of low-temperature heat capacity measurents (which lead to entropy values at 298.15° K,) and high-temperature heat-content measurements of four halides - trichloride, tribromide, tetrabromide, and tetraiodide. The new data are combined with selected heat-of-formation values at 298.15° K. to obtain improved values of the heats and free energies of formation of these halides at high temperatures, thus supplementing the previous data of Kelley and Mah.5/ ACKNOWLEDGEMENTS This investigation was conducted under a cooperative arrangement between the Federal Bureau of Mines and the Department of the Navy, Office of Naval Research. The work was done by Bureau of Mines personnel using Bureau of Mines calorimetric equipment. The Office-of Naval Research supplied the supporting funds and arranged for procuring the samples of the titanium halides. The samples were prepared and analyzed by the Inorganic Chemistry Section, Division of Chemistry, National Bureau of Standards.

Jan 1, 1961

By Abdo F. Bayazeed

A survey of the underground injection of steel processing waste pickle liquor (WPL) was made by Bureau of Mines engineers. Hydrochloric and sulfuric acids WPL are being injected into deep wells completed in the Cambrian age Mt. Simon Sandstone Formation in Illinois and Indiana. The Mt. Simon Formation ranges up to 1,800 feet in thickness. The average depth of WPL injection wells is 4,000 feet, and injection is mostly by gravity flow at rates as high as 4,000 barrels per day. The details of the design and operating history of a WPL well located near Gary, Ind., are discussed. Laboratory tests showed that the Mt. Simon Sandstone is sensitive to fresh water. The adsorption of iron and neutralization of acids by sandstone cores from deep wells and an outcrop were determined.

Jan 1, 1973

By E. S. Shedd

The Bureau of Mines investigated electrowinning and tapping lanthanum metal from lanthanum oxide in a fluoride bath. The electrolyte was composed of LaF3, BaF2, and LiF. Metal containing 0.2 percent impurities was produced at a rate of over 2 pounds per hour. Principal impurities were carbon, aluminum, and silicon. Low-carbon metal was produced by continually discharging the carbon oxide gases and maintaining 0.1-atmosphere pressure. Anode reactions and cell design were found to be important factors in cell operation. Both frozen electrolyte skulls and tungsten metal crucibles proved satisfactory for collecting the metal and did not react with the molten lanthanum.

Jan 1, 1966