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By Seth C. Schaefer

The Bureau of Mines studied thermodynamic properties of liquid Al-Si alloys with the high-temperature galvanic cell Al(1)//Al+3(AlC13 in NaCl?KCl)//Al-Si alloy(1). Activities of aluminum and silicon (referred to pure liquid metals) show a pronounced negative deviation from Raoult's law in liquid Al-Si alloys containing 0.9 to 35.2 atomic-percent silicon. Activity coefficients and the properties [?Gi, ?GxS ,?H, ?G, ?Gxs , and ?S] have been derived from the experimental data and are summarized in tables and illustrations.

Jan 1, 1974

By H. C. Ko

As part of the Federal Bureau of Mines effort to provide thermodynamic data for the advancement of minerals technology, energy conservation, and environmental preservation, the standard enthalpies of formation of a-magnesium sulfate, a-magnesium sulfate, and magnesium sulfate monohydrate were determined by hydrochloric acid solution calorimetry. The values of the standard enthalpies of formation in kcal per mole at 298.15 K are -307.95 ± 0.13 for a-MgS04, -307.03 ± 0.13 for ß-MgS04, and -384.72 ± 0.13 for MgS04 .H2O.

Jan 1, 1979

By R. Barany

The heats of formation of goethite, ferrous vanadate, and manganese molybdate at 298.15° K were determined by solution calorimetry. For formation from the elements, the heat values were -133.7 ±0.3 kcal/mole for goethite, -453.8 ±0.5 kcal/mole for ferrous vanadate, and -284.8 ±0.2 kcal/mole for manganese molybdate. For formation from the oxides, the heat values were -0.9 ±0.1 kca1/mole for goethite, -19.4 ±0.3 kca1/mole for ferrous vanadate, and -14.6 ±O.l kcal/mole for manganese molybdate.

Jan 1, 1965

By David Hoadley, Kenneth R. Maser, Ashok B. Boghani, James E. Billar, D. Randolph Berry, Mackenzie Burnett, Robert H. Trent

APPENDIX F GOVERNMENT OFFICES CONTACTED DURING SURVEY 1. MESA Inspection Offices North Central District Duluth, Minnesota South Central District Dallas, Texas Rolla Subdistrict Rolla, Missouri Rocky Mountain District Lakewood, Colorado Salt Lake City Subdistrict Salt Lake City, Utah Spokane Field Office Spokane, Washington Osburn Field Office Osburn, Idaho Phoenix Subdistrict Phoenix, Arizona 2. MESA Research and Management Denver Technical Center Denver, Colorado Pittsburgh Technical Center Pittsburgh, Pennsylvania Metal and Non-Metal Office Washington, D C 3. State Offices (State plan States) Arizona State Mine Inspector Phoenix, Arizona New Mexico State Mine Inspector Albuquerque, New Mexico

Jan 1, 1976

By David A. Monaghan, Kenneth R. Maser, Adi R. Gurdar, D. Randolph Berry

8. Field Demonstration of the Remote Mine Sealing System in a Coal Mine 8. 1 Selection of Field Test Site Eastern Associated Coal Corporation (EACC) offered its Federal No. 1 coal mine in Grant Town, West Virginia as the site for field testing of the remote sealing system. The choice of Federal No. 1 mine was particularly appropriate as the first attempt at fire control by remote sealing was done in this mine in 1963. EACC provided the men and equipment required for much of the initial preparation. Considerable assistance, advice, and background on coal mining technology was given by Mr. William Laird, Vice President for Research and Development, EACC, and by Mr. Lawrence Jackson, Resident Engineer at the Federal No. 1 mine. District 3 USBM office, the West Virginia Bureau of Mines, the Technical Support Group of the USBM, and Local 4047 of the United Mine Workers of America also cooperated. 8.2 Preparation of Field Test Site 8.2. 1 Underground Site Preparation The underground site chosen for the field testing was in a non-working portion of the mine within a few hundred feet of the main haulage road, as shown in Figure 80. Known as "Seven Switch, " this area was a 20 minute walk or 5 minute "jeep" trip from the man-trip shaft. Ten years having passed since this area was actively worked, considerable effort was required for gob clearing, roof bolting, rock dusting, and rejuvenating the track from the haulage road to the test area. Three primary borehole locations were chosen for the test program. Borehole No. 1 was in a straight passageway

Jan 1, 1973

By Thomas W. Martin

This chapter includes tables from 1984 that were not available in time for publication of the 1984 Minerals Yearbook, but does not include corresponding tables for 1985. The value of raw nonfuel minerals produced in the United States during 1985 was estimated at $23.2 billion, an increase of $0.07 billion over the value for 1984. This is the third consecutive year that the value has increased, and except for a decrease in 1982, the value for each year has increased since 1971, or 13 out of 14 years. However. while the value of industrial minerals production continued to grow, reflecting the growth of the domestic economy, the value of metal mine production decreased in 1985 by 6%. This drop was more than offset by a 3% increase in the value of industrial minerals production because the value of industrial minerals produced was more than three times larger than the value of metals. The decrease makes 1986 the third year in the past 5 years in which a drop in the value of metal mining production occurred in the United States where production continued to lag behind growing world production. Domestic production of such major commodities 88 aluminum, copper, iron ore, phosphate rock, and zinc continued to decline owing to a number of international and domestic factors. Gold continued to be the most active commodity in the domestic metal mining industry. Despite lower prices, gold output increased to 2.5 million troy ounces, a 19% increase over that of 1984. The estimated annual production capacity of new gold mines beginning production exceeded 1 million ounces.

Jan 1, 1987

By Kevin Connor

During 1984, minerals exploited in Burundi included gold, kaolin, lime, and peat. Over 1,100 troy ounces of gold was extracted and traded during the year as a result of the lifting of the Government ban on gold mining in mid-1983 and the establishment of an artisan mining program and licensed trading counters. Almost 2,000 tons of kaolin was mined for the manufacture of insecticides. Lime production was for domestic fertilizer applications. Amoco International and the Government signed an accord late in the year for a petroleum exploration program covering 600,000 acres of Burundi's onshore Ruzizi Plain and part of northeastern Lake Tanganyika. Amoco was expected to begin the exploration program by mid-1985. Anticipated program costs could run as high as $200 million.2 The Finnish company Ekono Oy completed its peat industrial energy development studies for the Buyongwe peat deposits of northern Burundi by the end of the year. The project assessed the quantity and fuel quality of 13,000 hectares of peatland and was part of a larger study for developing the Musangati lateritic nickel deposits of Burundi, estimated at 3% of the world's reserves of nickel. The Buyongwe peat would fuel dryers and an electrical generating plant for supplying power to nickel ore processing facilities. Briquetted peat would also be used as a substitute for wood and charcoal, presently the main sources of rural energy in the country and rapidly depleting because of deforestation. The study also evaluated the most economical methods to harvest the peat bogs. The study was financed by the International Development Association (IDA), United Nations Development Program (UNDP), Finnish Aid-Finnida, and the Burundi Government.

Jan 1, 1986

By Eric G. Zahl, John P. Dunford, Hamid Maleki

Coal bumps are influenced by geologic conditions, the geometric design of coal mine excavations, and the sequence and rate of extraction. Researchers from private industry and government agencies around the world have studied mechanisms of violent failure and have identified individual factors that contribute to coal bumps. To develop predictive tools for assessing coal bump potential, the authors initiated a comprehensive study using information from 25 case studies undertaken in U.S. mines. Multiple linear regression and numerical modeling analyses of geological and mining conditions were used to identify the most significant factors contributing to stress bumps in coal mines. Twenty-five factors were considered initially, including mechanical properties of strata, stress fields, face and pillar factors of safety, joint spacings, mining methods, and stress gradients. In situ strength was estimated in 12 coal seams where uniaxial compressive strength exceeded 2,000 psi. Allowances were made for favorable local yielding characteristics of mine roof and floor in reducing damage severity. Pillar and face factors of safety were calculated using displacement-discontinuity methods for specific geometries. This work identified the most important variables contributing to coal bumps. These are (1) mechanical properties of strata, including local yield characteristics of a mine roof and floor, (2) gate pillar factors of safety, (3) roof beam thickness, joint spacing, and stiffness characteristics, which influence released energy,(4) stress gradients associated with the approach of mining to areas of higher stress concentrations, and (5) the mining method. By combining the strength of both analytical and statistical methods, new capabilities were developed for predicting coal bump potential and for building confidence intervals on expected damage.

Jan 5, 1999

The production of harmful pollutants from coal mines and/or from coal and associated strata has been a recognizable fact in the United States for over two hundred and seventy years. In 1698, Gabriel Thomas observed(l) that the colored water flowing from streams in this country was similar to that which flowed from the coal mines in Wales. Hence, water pollutants such as acid were being produced before any known coal mines were operating in this country. The coal mining industry has contributed to the increase of pollution by exposing large amounts of sulfide materials that enable the reaction of water, oxygen and sulfur containing materials to form acid. A map of the United States coal fields can be seen on Figure 1. The anthracite regions of Pennsylvania, although small when compared to the total reserves, have produced some of the country's major water problems. The map indicates the extent of bituminous reserves of the Appalachian and midwest regions. Also evident are the bituminous, subbituminous and lignite coal reserves in the west which have recently come into greater demand. Acid mine pollution is encountered in numerous states, but the major problem is found in the Ohio, Susquehanna, and Potomac River basins.(2) Most coal beds contain some sulfur which may be in the inorganic, sulfate, or sulfide form, and thus have the potential to produce sulfuric acid. However, much of the strata that overlays the coal beds also contains acid neutralizing materials. Therefore, the amount of acid produced depends upon the amount of both acid and alkali materials that dissolve in the water in any given mine. The common sources of sulfurous material in the seam or surrounding rock are generally called sulfur balls or "nigger heads" by the miners. Sulfur balls that have been observed(3) seem to be equally divided between those containing sulphuritic iron capable of producing sulfuric acid upon oxidation and those that are primarily calcium carbonate. It has been observed in many instances that two types of water, acid and alkaline, are being produced in the same mine. A study of the geological strata and a survey of subsidence, faults and sulfur balls will usually give some indication of why this happens. The reaction of pyrite (FeS2) with oxygen and water to form ferrous sulfate (FeSO4) and sulfuric acid (H2SO4) by a series of complex chemical interactions is well documented but not well understood.(4,5) However, it is well known that the reactions to form the acid cannot occur unless all three constituents are present. Since pyrite is inherent in most coal seams and air is needed to sustain the miner, the most logical answer is to eliminate water infiltration into the mine, or to remove it from the mine before acids can form.

Jan 1, 1970

By C. E. Saxon, F. E. Cash

"Adequate lighting for all mining operations would unquestionably tend to promote both safety and efficiency; this would be true not only for men but also for the animals that man impresses into service in mines. The Markeeta Coal Co. and the Alabama Fuel & Iron Co. both operating mines in Alabama, have found that equipping mine mules with portable electric lights is more efficient, much more humane, and far more safe for both men and animals then the more or less usual method of forcing the animal to do its work essentially in darkness.This report is intended to give the mining industry data, that will aid in trying to bring about safe and efficient operation of mines.The authors desire to thank Charles F. DeBardeleben, president, Fred R. Bell, general manager, Hewett Smith, C. H. Shepherd, and R. A. Sensing, superintendents for the Alabama Fuel & Iron Co.; and Charles F. DeBardeleben, Jr., president, and H. M. House, superintendent for the Markeeta Coal Co., for their cooperation in furnishing the data for this paper.The eight mines operated by the Alabama Fuel & Iron Co. and one operated by the Markeeta Coal Co. in Jefferson and St. Clair Counties, Ala., are the only mines in Alabama where mules are provided with portable electric lights, and there are few if any mines in other States in which this system is in use.These two companies are convinced that equipping all mine mules with good lights decreases underground haulage cost by animals by prolonging the useful life of the animals, increasing their efficiency, lessening haulage wrecks and delays on haulage, and increasing production. Last but not least of the advantages would be the more humane treatment of the animals.The nine mines are developed by slopes along the dip of the coal bed, with double-room entries on 200- to 300-foot centers turned right and left off the slopes and with approximately 1 per cent grade in favor of the loads. Rooms are driven up or diagonally up the pitch from these entries.A surface hoist delivers the empties from the surface to the entry sidetracks at the slope and pulls the loads to the surface. From these sidetracks, mules pull one to four wooden cars, each of which holds 1-1/2 to 2-1/2 tons of coal, deliver the empties to the rooms and entry faces, and pull the loads to the slope sidetracks. The mule haul varies from 100 to 3,000 feet; there are no locomotives or trolley wires in any of these nine mines, seven of which are rated as gassy and two as nongassy by the Alabama state Mining Department."

May 1, 1933

By M. J. Ankeny

All bituminous-coal mines, by the nature of their product and inherent gassy tendencies, are subject to explosions or mine fires. The evolution from large, hand-loading sections employing numerous men and containing open-type equipment, lights, and nonpermissible explosives to small, concentrated mechanical sections with but few well-supervised men utilizing modern preventive equipment has not altered this premise. Mine catastrophes such as Centralia and New Orient No. 2, as well as recent disasters of less magnitude, have refuted the trend of thinking that modern equipment, will prevent or localize explosions and prevent widespread or loss of life.

Jan 1, 1952

By A. J. Kraemer

The Bureau of Mines for a number of years has been carrying on an investigation of properties of crude petroleum from producing, fields in the United States and the Western Hemisphere, and has published a series of reports on these fields, including oil fields of Oklahoma2. Acknowledgements Thanks are due to R. R. Brandenthaler and Peter Grandone, of the Petroleum Experiment Station of the Bureau of Mines, at Bartlesville, Oklahoma, who reviewed the manuscript and contributed valuable suggestions. The samples were analyzed under the direction of E. C. Lane at the Bartlesville station of the Bureau of Mines.

Jan 1, 1927

The latest Active List of Permissible Explosives and Blasting Devices was published in July, 1929, as Bureau of Mines Report of Investigations 2947, 2 under the title or "Active List of Permissible Explosives and Blasting Devices Approved Prior to June 30, 1929.' Subsequent Reports of Investigations 2253, 2958, 2962, 2972, 2988, 2992 and 3000, were issued to record the official actions taken during July, August, September, October, 1929, and January, February, and March, 1930. No changes were made during November and December, 1929, and April, 1930. The following additional changes in the list recording the actions taken during May, 1930, are now authorized. [ ]

Jan 1, 1930

By H. E. Powell

The selective recovery of nickel and zinc from a waste phosphate solution by solvent extraction was investigated by the Bureau of Mines as part of a broad program to recover valuable metals and compounds from industrial wastes, and to reduce the associated land and water pollution caused by dumping these wastes. The waste, which resulted from the phosphation of automboile bodies, yielded 99 percent of both the nickel and the zinc by extraction with dinonyl naphthalene sulfonic acid (DNSA) and di-2-ethylhexyl phosphoric acid (EHPA), respectively. Dilute sulfuric acid was used to recover the metals and regenerate the solvents.

Jan 1, 1970

By Motohisa Kanda

The time and amplitude statistics necessary to adequately describe electromagnetic (EM) noise in mines are illustrated through computer software techniques. They are 1) Allan Variance Analyses (AVA), 2) Interpulse Spacing Distributions (ISD), 3) Pulse Duration Distributions (PDD), 4) Average Crossing Rates (ACR) , and 5) Amplitude Probability Distributions (APD) . These statistics are illustrated using data taken from a rather large store of raw analog data recorded in operational mines. The curves generated for the illustrations characterize the noise environment in the mines from which the corresponding data were taken, and should aid in the design of reliable communication systems for such mines.

By Basil Dimitriades

Five recently developed methods for determining nitrogen oxides in automotive exhausts have been evaluated from the standpoint of accuracy and applicability in current exhaust studies. Results showed that methods requiring conversion of nitric oxide to nitrogen dioxide as a part of the analytical procedure are subject to errors introduced by the instability of NO2. The extent of some of these errors has been determined and procedures have been developed to minimize undesirable influences. On the basis of the results obtained from this study, recommendations are made regarding procedures for batch type or continuous measurement of nitrogen oxides in exhaust streams.

Jan 1, 1968

By A. W. Henderson

Methods for converting WOCl4 to WCle were investigated in small-scale, laboratory apparatus to devise a method for preparing pure WCls suitable for conversion to tungsten metal. Chlorine, COCI2, and CCI4, alone and in combination with various forms of carbon, were tested as chlorinating agents at various temperatures. More than 95 percent conversion of WOCl4 to WCls was achieved with all reagents at 8000 C in the presence of activated carbon. Only CCl4 maintained its effectiveness in the absence of carbon at 800° C. The effectiveness of carbon was found to be related directly to its surface area.

Jan 1, 1968

By W. E. Anable

A 180° magnetic deflection residual gas analyzer mass spectrometer with a mass range of 2 to 200 amu was used to study the nature of gases evolved during arc and electron-beam melting of certain reactive and refractory metals. The partial pressure of residual gases over molten Mo, Hf, Ti, and Fe, was found to be similar: Water and hydrogen were evolved from the samples and from the furnace components, carbon dioxide and carbon monoxide resulted from deoxidation of some of the melts. Argon and acetone were residuals in the system, and methane was a decomposed organic compound from the oil diffusion pump.

Jan 1, 1969

By David Hoadley, Kenneth R. Maser, Ashok B. Boghani, James E. Billar, D. Randolph Berry, Mackenzie Burnett, Robert H. Trent

B 5 Typical Input - Ouput The input data and the printed output for case 8 of the simulations (Section A.4) are shown in the following. The branch, level, node, miner and hoist numbers mentioned in the input and output refer to the corresponding numbers in Figures A-3, A-4 and A -5, The plotted ouput, already shown in Figures A,11 and A-12 is not repeated. The input data shown does not include the following simulation parameters: DTIME = 0, 05 FTIME = 130 JPLT(K) = 1 for K = 1, 2, 3 0 for other K TPLSTR = 0.0 TPLST P = 130

Jan 1, 1976

By E. G. King

Low-temperature heat capacity determinations of the minerals goethite and pyrophyllite were made in the temperature range from 510 to 298° K. The entropies at 298.15° K were evaluated as 14.43 ±0.15 cal/deg mole for goethite and 56.6 ±0.5 cal/deg mole for pyrophyllite. The entropies of formation from the constituent oxides are -4.4 ±0.2 cal/deg mole for goethite and -12.3 ±0.6 cal/deg mole for pyrophyllite. The standard free energy of formation of goethite from its oxides is ?G°298.15 = 0.16 ±0.20 kcal/mole.

Jan 1, 1970