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By J. X. Guo, A. Pindred, J. Moore

"Two modified centrifugal flotation cells (CFC), Q2 and Q3 models, have been developed for froth flotation. The operating mechanism of Q2 uses a rotating bowl to create a centrifugal force on the feeding slurry. Froth concentrate is collected on the central top of the cell and tailing is discharged along the top edge of the rotating bowl. The Q3 utilizes a vertical rotating feed pipe to introduce the feed slurry into a stationary flotation column cell. A centrifugal force is also created by a rotating pipe for the feeding slurry. Froth concentrate floats over the cell and tailing discharges through the bottom of the cell. The centrifugal force causes the flotation recovery of fine particles from CFC to be higher than from the conventional cell. The major operating variables of CFC are the rotating speed, air flow rate into feed slurry, and slurry feeding rate etc. Flotation tests have been carried out on synthetic mixtures of galena-silica and chalcopyrite-silica, as well as some natural base metal ore samples. Parallel tests were also conducted on a conventional flotation cell. The comparative test results demonstrated that both Q2 and Q3 have the advantage of higher recovery of finer than 10 µm mineral particles, which are very difficult for the conventional non-centrifugal flotation cell to recover. The grade-recovery curves produced from CFC are equivalent to or better than the conventional flotation cell. There is a potential in the future for the CFC to be employed in slime flotation.1. IntroductionA centrifugal flotation cell (CFC) was originally developed by Clean Earth Technologies [I] to separate oil from water and was subsequently applied in froth flotation. Figure 1 illustrates the design of the original CFC, in which a vertical feeding pipe is attached to the center part of a rotating drum and a stationary shell encloses it to direct the float froth and tailing discharge. The slurry flows down to the bottom of the spinning drum, gets in touch with a screen of air bubbles and then migrates outwards under the effect of centrifugal force. After the mineralized froth enters the rotating cell, it is pushed back to the inner surface. The overflowing froth is collected in the froth launder while the tailing slurry is discharged through orifices along the outer rim of the drum."

Jan 1, 1998

By P. A. Riveros

This paper describes the leaching of the common copper minerals tennantite (Cu12As4S13), tetrahedrite (Cu12Sb4S13) and enargite (Cu3AsS4) in acidic media using Fe(SO4)1.5, FeC13 or 02 as oxidizing agents. At temperatures <100°C, tennantite dissolves slowly in Fe(SO4)1.5-H2SO4 media, and the rate is directly proportional to the area of the sized tennantite. The rate increases sharply with increasing temperature and the apparent activation energy is 69 kJ/mol. Increasing Fe(SO4)1.5 concentrations slightly increase the tennantite leaching rate. The kinetics of dissolution of disks of synthetic iron-bearing tetrahedrite in Fe(SO4)1.5-H2SO4 media are linear; the leaching rates are slow but increase significantly with increasing temperature, with an apparent activation energy of 120 kJ/mol. The dissolution of sized particles of natural Ag-bearing tetrahedrite in FeC13- HC1 solutions proceeds according to the shrinking core model, and both Cu and Ag dissolve at about the same rate, provided that the total chloride concentration of the solution is sufficiently high to solubilize the AgC1 reaction product. The leaching rates are slow, and the apparent activation energy is 116 kJ/mol. The addition of sulphate ions to the FeC13-HC1 system reduces the tetrahedrite leaching rate to values similar to those realized in the Fe(SO4)1.5-H2SO4 system. At <100°C, enargite dissolves slowly in either Fe(SO4)1.5 or FeC13 media, and the dissolution rate obeys the shrinking core model. The rate increases with increasing temperature and the apparent activation energies are 50-64 kJ/mol. The rate increases slightly with increasing FeC13 concentrations in 0.3 M HC1 media. The leaching of enargite at elevated temperatures and pressures was also investigated. Potentially useful leaching rates are achieved above 170°C, at which temperature sulphate, rather than sulphur, is produced. Lower temperatures (130-160°C) lead to fast initial leaching rates, but the dissolution of the enargite is incomplete because of the coating of the enargite particles by elemental sulphur.

Jan 1, 2007

By Wei Huang, Anh V. Nguyen

"Potash flotation is an industrially proven success of flotation of soluble salts, but its collector adsorption mechanism remains elusive. In this paper, specific ion effects in NaCl-KCl flotation with carboxylate collectors were investigated. Flotation recovery and contact angle were determined as a function of brine composition of NaCl and KCl. The experimental results have shown that wettability of KCl and flotation of the soluble salts with laurate collectors were dependent on brine ion composition. Specifically, adding Na+ to brines decreased hydrophobicity of KCl crystals and their flotation recovery. Both KCl and NaCl could be floated with laurate collectors. However, flotation of NaCl was greatly enhanced by adding K+ to brine whereas flotation of KCl was significantly suppressed by the presence of Na ions. The decrease in KCl recovery upon adding Na+ is attributed to the counter-ion binding in the pulp. The flotation recovery enhancement of NaCl in the presence of K+ is explained by two effects: 1) increasing K+ concentration leads to a better dispersion of collector colloids in the pulp and 2) K+ enhances the collector adsorption at NaCl crystal surfaces. The water affinity matching rule can explain the specific ion binding behaviors and supported by the SFG spectroscopic results.INTRODUCTIONPotassium is an important fertilizer. Its primary source comes from potash ores, which are a mixture of sylvite (KCl), halite (NaCl) and many other complex double salts such as carnallite (KCl·MgCl·6H2O), alkali nitrates such as KNO3 and NaNO3, and sulfates-langbeinite (2MgSO4·K2SO4) with water-insoluble minerals such as clay and carbonate minerals. Previously, these salts were recovered with a lengthy hot leaching method, with further crystallization of potassium salts from saturated saline solutions. Selective flotation has been preferred since 1940s. Various collector adsorption mechanisms have been proposed soon after the industrial introduction of potash flotation. These include the formation of the insoluble compound model (Halbich, 1933; Singewald, 1961), an ion exchange model (Fuerstenau and Fuerstenau, 1956), a heat of solution model (Rogers, 1957), the surface hydration model (Schubert, 1988), the surface charge model (Roman, 1966; Miller et al., 1992), the interfacial water structure model (Hancer and Miller, 2000) and the colloid adsorption model (Leja, 1983; Burdukova and Laskowski, 2009). Most of the early exercises attempting to propose a unified rule on collector adsorption mechanisms can be seen as heroic endeavors due to the consideration of a vast number of salts in the pulp including alkali halides, nitrates, and sulfates, even the practically insoluble heavy earth metals. Additionally, several types of surfactants with different polarization features and alkyl chain length have been employed. As for the recent models, due probably to the preferential application of long chain amines as collectors in industrial potash flotation, most researchers are only devoted to collectors with low polarization features like amines and sulfonates (Hancer and Miller, 2000; Du et al., 2014). Collector adsorption mechanisms are therefore proposed based largely on a neglect of carboxylates as collectors. However, carboxylates remain an important collector type in soluble salt flotation systems where both salt minerals can be floated using anionic collectors and cationic collectors. Fatty acid type collectors are still one of the widely used collectors for soluble salt flotation and also one of the first to be applied on an industrial scale for the separation of potash ore (Hernáinz et al., 2003; Titkov, 2004). Here we examine some recent models that are relevant to our study to reveal a long neglected specific ion binding effects in potash flotation."

Jan 1, 2016

By N. Djilali

Many of the transport phenomena encountered in proton exchange membrane fuel cells occur intrinsically at the microscale level. Physically representative models that fully account for the salient physico-chemical and transport processes in PEM fuel cells are necessary to achieve truly predictive models that can be used with confidence to: (i) gain a better understanding of in-situ processes and couplings, (ii) explore new concepts, and (iii) support design and optimization. The development of more general, rationally based macroscale models requires use of knowledge on the microscale level to provide guidance, and to determine the required parameters and coefficients (model "constants"). In this paper we present a new membrane transport model, the binary friction membrane model (BFM2), recently developed to account for coupled protonic and water transport in polymer membranes. This general model is based on rational and physical consideration, removes several of the limitations of the empirical models used to date, and is formulated for all purfluoro-sulfonic acid membranes. The use of the BFM2 in a fuel cell model is illustrated highlighting significant performance predictions compared to existing empirical model. The second part of the paper addresses the fundamentals of two-phase transport in hydrophobic gad diffusion media. Computational and experimental visualizations resolving the microscale dynamics of water transport between the fibres of a GDL are presented, revealing transport mechanisms that are, contrary to assumptions used to date, dominated by fingering and channeling.

Jan 1, 2005

By A. H. Winckers

"The Sullivan Mine and Concentrator are owned and operated by Cominco Ltd. and are located in the Rocky Mountain Trench, in Kimberley, British Columbia.The Sullivan Concentrator commenced operation in 1923 at approximately 2,500 tons per day. The concentrator was enlarged in several stages and by 1945 was treating 8,500 tons of ore per day. In 1949, the capacity of the concentrator was expanded to 10,000 tons per day with the completion of the sink and float plant, the installation of the rod mill, an underground crushing plant and a 4-mile underground and surface electric railway from the underground crushing plant to the concentrator. Throughput now averages 7,000 tons per operating day, or 2,400,000 tons per year.The concentrator operates 7 days per week, 24 hours per day while the underground crushing station operates 5 days per week, 24 hours per day. The ore is essentially a replacement deposit in argillaceous quartzite of Precambrian age. The ore bodies are massive deposits consisting of fine grained mixtures of sulphides, sometimes interbanded with the country rock and varying widely in their content of lead, zinc, iron and silicates. The principal economic minerals are galena and marmatite (7 ZnS:FeS). Iron is mainly present as pyrrhotite, and to a much lesser extent as pyrite. The intimate association of these sulphides necessitated the development of a successful differential flotation process before the ore could be beneficiated profitably."

Jan 1, 1981

By K. M. Sarkar

"In many plant trial s(1,2) it has been proven that very small amounts (10 to 20 ppm) of uranium dissolved in mine water can be effectively recovered by the use of ion exchange resins and this uranium recovery has many advantages. In this paper an economic analysis at different levels of uranium contamination and at different market prices of uranium are described.For this study an operating mine-mill complex with a sulphuric acid leach circuit, followed by solvent extraction (SX) process, is considered, where contaminated mine water is available in excess of process requirements. lt is further assumed that the sulphuric acid eluant containing uranium would be mixed with the mill pregnant liquor stream that proceeds to the SX plant for final uranium recovery.Recovery by Ion ExchangeMine water, in this study, is defined as the water coming from the underground mine, or mine pits, and the run-off water from stockpiles, mine shops, crushing plant , washdown areas, etc.In nature, uranium mainly occurs in two stages; reduced (tetravalent) and oxidized (hexavalent) . The oxidation of sulphides present in the orebody often causes the presence of S04- and acidity in mine water, and this acidic water readily dissolves U+6 part of the depo sit. The react ion between hexavalent uranium, which is dissolved in water as U02+ 2 cation and S04 producing uranyl sulph ate as,"

Jan 1, 1984

By L. Li

Iron removal is a common procedure in hydrometallurgy of non-ferrous metallic ores. Chemical precipitation and solvent extraction are currently the main methods employed for separation of iron from copper leach solution. However, chemical precipitation methods have the problem of producing large amounts of iron precipitates, and/or requiring high temperature and high pressure conditions for precipitation. The precipitates are difficult to separate from the solution. Emulsification is a general problem for solvent extraction, which causes loss of extractants and contamination of the electrolyte. A common problem for solvent extraction and chelating ion exchange processes is the difficult iron stripping process. Therefore, finding an efficient and environmentally friendly method for iron removal is of great significance. In this paper, new processes of using ion exchange resins to remove iron from copper leach solution have been investigated. Salicylic acid, amino carboxylic acid, amino phosphonic acid and hydroxy-oxime resins were employed to adsorb iron from a simulated copper leach solution containing 40 g/L of Cu2+ and 36 g/L of Fe3+. It was found that a hydroxy-oxime resin, named Z-Fe, has excellent adsorption selectivity on Fe3+. Desorption behavior of the resin was studied by two step elution using dilute H2SO4 and oxalic acid solution, respectively. After optimizing the adsorption-elution processes, the extent of removal of iron from the simulated copper leach solution using resin Z-Fe was 90%, while copper recovery could reach 100% in closed circuit processing.

Jan 1, 2016

By Anthony P. Makuch

Dynatec Corporation is an integrated mining services company, providing mine development, operations management, engineering, drilling and metallurgical services to the North American mining industry. Dynatec was the contract operator of the Ken Snyder Mine in Midas, Nevada from start of production in January 1999 to September 2001. This paper summarizes Dynatec?s experience and approach to the use of longhole stoping methods for mining to widths of 1.3 to 2 metres in a steeply dipping narrow vein orebody.

Oct 1, 2001

By Bob Rappolt

Discussion Points Part 1: Global Mining Industry/Related Issues ? Historical Metal Price Trends. ? Historical LME Metal Stockpiles. ? China?s Demand for Metal. ? World Population Growth, Demands and Development. Discussion Points (cont?d) Part 2: Canadian Mining Industry ? Where are we? And where are we going? ? What progress have we made in the past 20 years regarding: ? Safety -Employee Levels ? Labour -Relative Compensation ? Productivity - Technological Advance ? Where do we stand regarding mineral production? ? What does the future hold for us?

Apr 1, 2005

By CIM Mineral Resource, Mineral Reserve Committee

These Leading Practice Guidelines for Mineral Processing (LPGMP) were prepared by the Sub-Committee on Leading Practice Guidelines for Mineral Processing. The Sub-Committee reports to the Executive Committee of the Canadian Mineral Processors (CMP) which is a Technical Society of the Canadian Institute of Mining, Metallurgy, and Petroleum (CIM) and incorporates those members of the CIM who are concerned with the processing of mineral deposits. The LPGMP covers the involvement of mineral processing professionals, referred to as Practitioners in this document, in providing inputs to the estimation of Mineral Resources and Mineral Reserves and providing technical content for internal reports as well as public reports on mineral projects as required under National Instrument 43-101 Standards of Disclosure for Mineral Projects (NI 43-101). The LPGMP supplement the CIM Exploration Practice Guidelines (2018) and the CIM Estimation of Mineral Resources and Mineral Reserves Practice Guidelines (2019) which are referenced in Companion Policy 43-101CP to NI 43-101 and recognized internationally. The LPGMP consist of 3 sections: • Principles of Process Support in Mineral Resources and Mineral Reserves Estimation; • Appendix A – Use of Supporting Studies in Process Evaluation and Assessment for NI 43-101 Documentation; • Appendix B – Glossary of Terms Relevant to the LPGMP. The LPGMP deal primarily with the description of leading practice as it applies to the mineral processing and extraction of base metals, precious metals, and other mineral products by the application of mineral processing technology. Other commodities may be considered with future updates of these guidelines. It is expected that this is a ‘living’ document and that these guidelines will develop in the future to address the requirements of the mining industry, investing public, and mining professionals involved. Clarifications and changes to these guidelines will be done under the guidance of the Executive Committee of the CMP.

Nov 25, 2022

By Brian Mattie

Overview ?Overview of the mining area ?Description of the mining phases ?Risk assessment ?Design criteria and description for freeze drifts ?Freeze wall design ?Raisebore mining Four Main Phases: 1.Development of freeze drifts on the 520 and 590 levels 2.Freeze drilling and ground freezing to isolate the Zone 4 North ore body from water bearing sandstone. 3.Develop raisebore and extraction chambers including access drifts and ramps under freeze protection. 4.Start raisebore production mining of the Zone 4 North area.

Nov 1, 2011

By Roy Sage

Overview ? History ? background to current programs ? Kyoto status ? Support for technology development ? Support for GHG reduction ? Sources of information History ? 1988 - Toronto Conference - The Changing Atmosphere ? Proposed target ? CO2 levels reduced to 20% of 1988 levels by the year 2005 ? 1992 - Canada signed Framework Convention on Climate Change at the UN Conference on Environment and Development in Rio de Janeiro in June 1992 ? Canada launched the National Action Plan on Climate Change ? Kyoto protocol adopted in principle in 1997

Nov 1, 2002

By H. Ito, T. Takasu

A leaching process for recycling small car motor scraps dismantled from End- of - Life -Vehicles (ELV) was investigated using waste pickling acid in steel work. Steel parts of mortar scraps were leached by waste pickling acid and Cu wire was recovered as pure Cu in the process. Pickling acid solution after leaching could be recycled in an ordinary process for waste pickling acid solution. High grade FeSO4 agent could be produced using H2SO4 as a pickling solution.

Jan 1, 2004

By M. Jahazi, M. Brochu

This paper describes the advantages/disadvantages of electron beam freeforming using two different types of filler metal: (1) brazing paste and (2) solid wire. Sound buildups were obtained from both filler metal. The freeforms produced with the brazing paste showed a certain level of porosity, which was reduced by successive melting. In comparison, the solid wire buildup was practically free of pore. When compared with the solid wire filler, the brazing paste produced narrower buildups but a larger scattering of the width.

Jan 1, 2004

By Richard Samson

"RésuméComme l&apos;exploitation d&apos;un gisement à grande profondeur représente un défi de taille et que la profondeur à laquelle se situe celui d&apos;Ansil varie de 1200 m à 1460 m, nous avons dû mettre en place une infrastructure de surface d&apos;envergure incluant un treuil de production et un chevalement d&apos;une très grande capacité. De même, l&apos;infrastructure sous terre a été proposée en tenant compte de ce fait important; d&apos;ailleurs, l&apos;excavation de deux puits circulaires dont l&apos;un est en beton et acier et l&apos;autre exclusivement en béton en témoigne. De plus, la plupart des cheminées principales qui furent excavées sous terre sont de forme circulaire.L &apos;exploitation du gisement s&apos;effectue par une méthode chantier ouvert (abattage par longs trous), remblaye immédiatement âpres avec un mélange de roche stérile et ciment. Un taux de minage de 1750 tonnes par jour est requis pour assurer la production.L &apos;utilisation d&apos;une technologie de pointe tels: les ventilateurs et les portes de ventilation sous terre contrôlées de la surface, un système de relèves macroséismiques, de chargeuses-navettes contrôles à distance, en passant par le dessin et la planification assistes par ordinateur nous permet d&apos;optimiser l&apos;exploitation du gisement Ansil.IntroductionEtant donne la grande profondeur a laquelle le gisement Ansil se situe, no us avons à mettre en place une infrastructure souterraine et de surface d&apos;envergure pour nous permettre d&apos;atteindre nos objectifs d&apos;exploitation.Infrastructure de surfaceLa mine Ansil dispose d&apos;une infrastructure de surface d&apos;importance possédant une grande capacité (Fig. I). Les deux facteurs qui furent déterminant pour le dimensionnement des infrastructures furent le taux d&apos;extraction de 1990 t/jour et la profondeur a laquelle I &apos;exploitation s&apos;effectue, puis que cette dernière affecte le temps de cycle et la capacité de hissage.La première composante principale de I &apos;infrastructure de surface est un treuil de production a 2 tambours de 3.65 m de diamètre et de 2.0 m de largeur chacun. Ce treuil de marque Fullerton, Hodgart & Barclay construit en 1970, opère avec 2 moteurs de 930 kW a une vitesse de 700 m/min. et il a une capacité maximale de 32000 kg. Deux câbles d&apos;acier de 45 mm de diarnètre et de 160 000 kg de résistance a la rupture servant au hissage des bennes d&apos;une capacité de 12 tonnes. De plus, un moteur/générateur de 3000 kW (M.G. Set) raccorde au treuil de production sert a stabliser son alimentation électrique."

Jan 1, 1991

By K. E. Haque

"Radium is selectively leachable from uranium ores with various types of lixiviants. Among a number of lixiviants tried on Midwest Lake uranium ore, KCl provided the highest per cent of radium extraction (60%-65%). Leach results further confirmed that a certain portion of Ra is not amenable to KCl leaching. More than 99% of the dissolved radium could be removed by treating the KCl leach liquor with barite or with radium selective complex resin (XFS-43230 resin of Dow Chemical Inc.) or by precipitating as RaBaSO4. Uranium leachings from the Ra-preleached uranium ores indicate that radium leaching prior to uranium may be applied as an extension to the conventional or alternative (i.e. acid chloride) leaching process of uranium ores in order to yield environmentally acceptable tailings (in terms of radium in the solids).IntroductionAt present, radium is considered as an environmental issue, particularly for uranium ore mine mill operations, rather than a commercial commodity. Radium was once a highly priced commodity ($180/mg during the first great war) but now it hardly has any commercial value. Its principal applications were in the field of cancer treatment and in the manufacturing of lwninous dials for watches. Nowadays readily-available synthetic radioisotopes are finding applications in place of radium.Because of scarcity and high toxicity, further commercial applications have never been explored.Radium was first discovered and extracted from uranium ore by P. Curie, M. Curie and G. Bement in 1898. Radium is widely distributed in nature but in exceedingly minute quantities. It is one of the daughter products of uranium or thorium and its maximum concentration is 3.3 x 10-7 part/part of U(21). Because of its short half-life (approximately 1620 years) in a geological time scale, its occurrence in nature as a distinct mineral is most unlikely.The details of the original radium leaching process developed by the Curies and Bernont are in the literature. This process essentially involved the roasting of uranium ore with caustic. carbonate followed by sulphuric acid leaching. The precipitated RaSO4 and BaS04 were treated with boiling Na2CO3 to convert them into the corresponding carbonates which later were dissolved in HCI. RaCI2 and Ba02 were separated and concentrated from the chloride liquor by fractional crystallization. But, in the course of time several modifications were made or proposed to the original process. Regardless of the process employed 226Ra extraction from the uranium ore was seldom better than 90%, and further as much as 20% 2URa loss took place during the concentration and purification process."

Jan 1, 1987

By A. Mcdonald

"An X-Met Analyzer was purchased from Outokumpu in late 1983for use in the Hudson Bay Mining and Smelting smelter. Its first use was in the fuming plant to give zinc assays of each charge of slag tapped from the fuming furnaces. This quickly told the operators exactly when each charge had reached its economic tap-out point, and gave supervision a fool-proof method of identifying good operation. These and other factors led to major improvements in coal utilization in the fumers and to major increases in zinc oxide production. A second unit was later purchased for the reverberatory furnace to give silica and iron assays of the slag, and these were used to make adjustments in the feed composition to maintain the desired SiO2:Fe ratio in the slag. Since purchasing the units for the furnace, the oil consumption and copper content of the slag have dropped significantly. IntroductionSmelters have lagged far behind concentrators in process control by mean s of rapid product analysis. The on-stream X-ray analyzer was developed about seventeen years ago, and soon concentrators around the world were getting assays of the incoming ore, .concentrates and tailings every fifteen minutes, and using these to control reagent additions and other process variables. Almost always, the concentrate grade and recovery improved.In smelters, product streams are solids or molten materials, not the more easily handled slurries, and until seven years ago no inexpensive equipment was available to provide rapid analysis of this type of material. In approximately 1980, several companies developed instruments based on irradiating solid samples with low-intensity gamma rays from radio-isotope sources, and measuring the secondary X-rays emitted from different elements in the sample to provide an analysis of the elements desired.The smelter staff had a close look at what was needed and listed the following points as being critical:1. ability to provide Zn assays of a sample of slag within 15 minutes of taking it, in order to achieve optimum fuming times (zinc fuming , being a batch process, had the greatest potential benefit from rapid slag analysis);2. ability to give Cu and Fe assays on the slag, and on other smelter products, such as matte and converter slag;3. ability to give Si02 assays since the SiO2 content of the slag has a strong effect on fuming rate; and4. ability to stand up to an industrial atmosphere such as exists in the fuming plant."

Jan 1, 1987

By Andrew Artzer, Michael Moats, Jack Bender

Antimony and bismuth in copper electrorefining electrolytes can cause cathode contamination, leading to the careful control of their concentrations. This study examined the laboratory scale removal of bismuth and antimony from an electrorefining electrolyte using a solvent extraction mini-pilot plant. The ability of a proprietary phosphonic acid ester extractant (REX-2) in a commercial diluent was studied in a simulated commercial setting. Antimony and bismuth were both extracted effectively from the electrolyte (72% Bi and 70% Sb removed) and Bi was effectively stripped (92% Bi recovered) with 400 g/L sulfuric acid. A final strip solution was obtained from the SX circuit containing 0.36 g/L Bi, 0.043 g/L Sb, 1.3 g/L Cu, and 0.18 g/L As. Unfortunately, most of the extracted Sb remained in the organic phase. Following the pilot study, experiments were performed to examine the precipitation of bismuth from the aqueous strip phase and the removal of antimony loaded on to REX-2. INTRODUCTION For many years, antimony and bismuth have been some of the most problematic impurities in copper electrorefining (ER) (Bardwell & Lapee, 1933). Along with surface roughening, high concentrations of Sb and Bi can contaminate the copper cathode and precipitate at the copper grain boundaries. This drastically reduces the drawing ability of the metal (Bender & Emmerich, 2016). For these reasons, it is necessary to control Sb and Bi concentration in the cathode, which is done by controlling their concentration in the electrolyte. Conventionally, Sb and Bi concentrations are controlled by maintaining a proper As/(Sb+Bi) molar ratio in the anode and arsenic concentration in the electrolyte. Antimony and bismuth are removed during electrolyte purification using liberators (electrowinning cells) and/or ion exchange. Liberators treat an electrolyte bleed stream from the ER circuit and electrodeposit increasingly impure copper as the copper concentration of the solution decreases. Traditionally, first stage liberators reduce the copper concentration from ~45 g/L to ~15 g/L and produce saleable copper. Second stage liberators decrease the copper concentration to ~8 g/L (Biswas & Davenport, 1980) which results in contaminated cathode that is returned to anode production (Biswas & Davenport, 1980; Wang, 2004). Further electrolyte purification is not always required but third stage liberators can be used to reduce copper concentration below 2 g/L which results in significant removal of As, Sb and Bi and very impure deposits which are recycled to a smelter or used for As production. However, liberators do not have very high energy efficiency (Acharya, 2014; Ando & Tsuchida, 1997) and below 0.5 g/L copper, highly toxic arsine gas may form (Biswas & Davenport, 1980).

Jan 1, 2019

By Nawshad Haque, Leanne Smith, Hal Aral, Joseph Cho, Warren Bruckard

"Water availability is one of the principal parameters in determining the feasibility of mining projects in arid and semi-arid regions. The volumetric water footprint (VWF) of a conceptual model of a copper flotation plant was found to be 2.45 kL/t Cu ore, compared with an actual measurement reported in the literature of 2.72 kL/t Cu ore. The flowsheet considered included mineral processing stages such as crushing, screening, grinding, classification, separation, flotation, thickening and filtration. The effect of a number of variables on the VWF was evaluated, including solid/liquid ratio, feed mass flowrate, ore loss, water loss, moisture content of ore, ore grade and water recycling. The use of seawater with recycling provided the most environmental and economic advantage among several scenarios evaluated. The study assumed a price of $1/kL freshwater, $4/kL for transport over a 200 km distance at 2,000 m altitude and $4/kL for water treatment. The water related cost of the desalinated seawater use scenario was A$493/t Cu concentrate, while the water related costs of fresh water and blended water scenarios were A$308/t and A$268/t Cu concentrate, respectively. The water related cost (fresh water scenario) accounted for 44% to 49% of the entire mining and processing costs that included drilling, blasting, loading, hauling, crushing, grinding and concentrating. The total overall cost was A$435/t Cu concentrate for the seawater with recycling, compared to A$451/t Cu concentrate for the fresh water with recycling case.INTRODUCTIONReducing the water footprint (WFP) by utilising alternative water sources has been a focus of mining projects due to increasing concerns about water scarcity and growing energy costs. The global mining industry can expect to experience fresh water shortages in the future, and saline or hyper-saline water may be the only available water source to process minerals in arid regions. Extensive studies on alternative water sources (e.g. seawater, desalinated seawater, blended water) and the reuse of process water have recently been conducted (Moreno, Aral, Cuevas, Monardes, Adaro, Norgate & Bruckard, 2011; Aral, Mead, Cuevas, Davey & Bruckard, 2010). Such studies provide sustainable and economic strategies for mines and concentrators in the arid or semi-arid regions of the world such as in Chile, Peru, Indonesia, and Portugal. More work, however, is needed to confirm water consumption data for different base metal flowsheets and use this data to develop water models that can lead to reduced WFPs and more sustainable water usage in the mining industry."

Jan 1, 2016

By J. Bouchard, M. Levesque, D. Georges-Filteau, P. Radziszewski, G. LeBlanc

"Grinding mills are infamous for their extremely low energy efficiency. This paper reports the results of an investigation that characterized energy outputs in industrial grinding mill circuits. It identifies and discusses the potential for recovering energy from grinding circuits. Agnico-Eagle Goldex Division, Mine Canadian Malartic, and New Gold New Afton Mine participated in the study by providing operating data for three semi-autogenous grinding mills and four ball mills. Results showed that on average, 79% of the supplied electrical energy was converted to heat absorbed by the slurry, 8% was lost through the drive system, and approximately 2% was transmitted to the ambient air. Only 9% of the input energy was actually used for grinding. The remaining 91%—wasted as heat—could potentially be recovered using suitable technologies or integrated energy management systems. This topic remains to be further investigated. ¦ KEYWORDS Comminution processes, Energy recovery potential, Grinding mills RÉSUMÉ Les broyeurs sont tristement célèbres pour leur rendement énergétique médiocre. Cet article présente les résultats d’une étude qui caractérise les rendements énergétiques des circuits industriels de broyage et examine les possibilités de récupération d’énergie dans les circuits de broyage. La mine Goldex d’Agnico Eagle, Mine Canadian Malartic et la mine New Afton de New Gold ont participé à l’étude en fournissant des données de fonctionnement pour trois broyeurs semi-autogènes et quatre broyeurs à boulets. Les résultats montrent qu’en moyenne 79 % de l’énergie électrique fournie sont convertis en chaleur absorbée par la pulpe, 8 % sont perdus dans le système d’entraînement et environ 2 % sont dispersés dans l’air ambiant. Seuls 9 % de l’énergie primaire sont, de fait, utilisés pour le broyage ; les 91 % restants (perdus sous forme de chaleur) peuvent potentiellement être récupérés à l’aide de technologies adaptées ou intégrées dans des systèmes de gestion de l’énergie. Cette question demeure toutefois ouverte. ¦ MOTS CLÉS broyeurs, potentiel de récupération de l’énergie, procédés de comminution INTRODUCTION Grinding is largely recognized as a very inefficient process; energy efficiency estimates range from < 1 to 2% (Fuerstenau & Abouzeid, 2002; Tromans & Meech, 2002, 2004) when comparing the input energy to that required for generating new mineral surfaces. Criticizing an “ill definition of the reference for the output energy,” Fuerstenau and Abouzeid (2002) proposed a “more meaningful baseline” would be “the energy for producing new surface area by the ¬mens.” Based on this reference, they concluded that “the ball mill is reasonably efficient energetically,” exhibiting an efficiency of approximately 15% for quartz."

Jan 1, 2019