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By Fathi Habashi

THE UNIT process of adsorption involves two steps: 1) Loading of the adsorbent. 2) Recovery of metal values from the adsorbent. Charcoal is the adsorbent commonly used in extractive metallurgy. The discovery of the adsorptive power of charcoal from solutions is generally accredited to Lowitz (1785), who observed that several dissolved organic substances were precipitated on charcoal. Graham was the first to demonstrate that inorganic substances were also adsorbed on charcoal. In 1830, he reported that iodine dissolved in KI solution was adsorbed on charcoal. Also calcium ions were adsorbed from limewater, as were lead ions from lead nitrate solution. The use of charcoal in metallurgy was first applied

Jan 1, 1970

By J. P. Hanten, G. Ramadorai

This paper presents laboratory and pilot plant data on the removal of heavy metals and molybdenum from mining-milling waste water. Molybdenum is removed as an Fe-Mo precipitate by proper addition of ferric sulfate. Heavy metals are lowered by lime treatment. Solid-liquid separation was achieved in both cases by flotation techniques. The Lectroclear electrocoagulation-electroflotation process was used to achieve the desired degree of metals removal. Good correlation was obtained on the laboratory and pilot plant scales. A two-step process consisting of the sequential removal of molybdenum and heavy metals was tested successfully using a mobile pilot plant. Preliminary data on sludge characteristics was obtained and the feasibility of recycling the iron sludge for iron and molybdenum recovery was established on the laboratory scale.

Jan 1, 1987

By V. T. Vacariu, P. D. Georgescu, N. Tomus

To assess the potential for radioactive pollution unique to the environmental conditions of the Bacau phosphogypsum waste dump, surface samples were taken, drillings were performed on the entire waste dump's height, and the Ra226 distribution on the height and surface considered to contain a medium content of the radium of 0.57 Bq/gr was studied. Thus, the waste dump's radioactive potential was estimated at 30-40 Ci in equivalent Ra226. Also analyzed was the granulometric composition of the phosphogypsum and the distribution of Ra226 on granulometric orders, which indicated that the radium was concentrated in the very fine fractions. Parameters were set up for the classification by hydrocycloning to obtain a fine class (less than 41 microns) having a radium content of more than 0.9 Bq/gr and a coarse class having less than 0.37 Bq/gr. A chemical process was devised for removal of the radium from the phosphogypsum with the possibility for recovering the contained sulfur.

Jan 1, 1999

By S. Donges, P. L. Dunstan, B. J. Huls

The commissioning of a distributed digital control system for the grinding circuit at Cuajone was completed by mid-August 1985. Development of a successful strategy, excellent operator acceptability, and the visual aspects offered by the display of the central console improved mill through- put significantly. The inherent features of a digital system enhanced the flexibility in grinding control and allowed the milk and classifiers to be operated at maximum capacity. This paper discusses the strategy development and the production restrictions encountered, and evaluates the overall performance of the digital control system.

Jan 1, 1988

By Sam H. Patterson

Fuller's earth and bentonite are two clay commodities that are interrelated either by mineral composition or use. Because of this interrelation and the sale of both for many different uses, some ambiguity in their classification has resulted. The term "fuller's earth" has no compositional or mineralogical meaning, and it is used more or less as a catchall for any clay or earthy material suitable for certain uses. Most, but not all, of these uses require absorbent properties. Bentonite by geologic definition must have formed from volcanic ash or tuff or the glassy material in volcanic rock; most bentonites consist chiefly of montmorillonite but other clay minerals may be present. In industrial usage the term "bentonite" is applied to any clay consisting chiefly of montmorillonite, irrespective of origin. Georgia and Florida have historically been the leading States in the production of fuller's earth; bentonite has been produced in Alabama on a small scale. The first major use of fuller's earth was in refining of oils. Other materials have replaced fuller's earth for this purpose to a major extent, but many new uses for fuller's earth have been found, and production has increased in recent years. The new uses include absorbent products, insecticide and pesticide carriers, drilling mud, and many others. The bentonite now produced in Alabama is of the "southern," "low selling," or "calcium" type and is used mainly as foundry-sand bond. Most of the fuller's earth mined now is in the Hawthorn Formation of Miocene age; a lesser amount is produced from the Twiggs Clay Member and other beds in the Barnwell Formation of Eocene age. Inactive pits from which fuller's-earth was produced from other formations occur at several localities. The bentonite now mined in Alabama is in beds of Cretaceous age; several years ago bentonite was produced from Eocene beds in this State.

Jan 1, 1972

By M. Dondi, M. Surracco, G. Alfano, P. Saba

Recent investigations on fine grinding with jet mill miprototypes of original design, constructed at the DIMM and Centro Studi of the National Research Council at Cagliari University, have led to the realization of a third generation micronizer characterized by large capacity and high efficiency. The new model and its distinctive features are described here and the results are presented of grinding tests on typical, high grade Sardinian minerals used for quality products. The operating principles of the jet mill are described in relation to the mechanico-elastic properties of the minerals treated. In particular the efficacy of the comminution process is demonstrated in terms of both solid treated and of impact, attrition and shearing forces generated in the micronizer. Particle size distribution of the finished products are reported, that satisfy the most stringent market specifications for the different minerals, as well as energy consumptions. The alternative operating options for solving particular grinding problems and minimizing energy consumption are discussed. Lastly, the main developments of the jet mill for a possible application at industrial scale are suggested.

Jan 1, 1995

By Joseph Cervik, Fred Garcia

Gob holes are routinely used by the mining industry to vent methane from gobs and to prevent it from entering the mine ventilation system. In some cases, flows from gob holes are measured by centering an anemometer on the end of the discharge pipe. These measurements are erroneous and tend to be high by as much as 30%. The Bureau of Mines determined correction factors (method factors) for anemometer measurements taken in this manner. Method factors for 10.2, 15.2, and 20.3 cm (4, 6, and 8 in) ID pipe are 0.68, 0.71, and 0.78, respectively. Comparisons between horizontal and vertical flows indicated no significant change in method factors. Consequently, the method factors for horizontal pipe flows can be applied to vertical upward flows.

Jan 1, 1987

By T. J. Harvey, W. van der Merwe, J. Joubert

GeoBiotics, LLC and Kumba Resources (Pty) Ltd are jointly developing the GEOCOAT® heap bioleaching technology and downstream processing technology for recovery of zinc from tailings at the Rosh Pinah Mine in Namibia. This paper outlines the development of a computer simulation for the bioleaching of sphalerite and the downstream processing. Computer modeling has shortened the product development cycle by allowing many flowsheet scenarios to be analyzed negating much of the expensive and time consuming laboratory testing. A model was developed using the Limn® system which is an Excel® Add-In flowsheet drawing and solution engine. Given that most engineers are familiar with Excel® this software is extremely easy to use and has less hidden calculations making model verification much easier.

Jan 1, 2003

By G. T. Adel

The flotation behavior of a -28 mesh Pittsburgh No. 8 coal sample is investigated through the use of Scanning Electron Microscopy in conjunction with Image Analysis. Release analysis is used to generate the flotation products, which are then characterized to provide the particulate composition in terms of pyrite, mineral matter and carbonaceous material. The results of this investigation indicate that the material recovered in the first stage of release analysis tends to be well-liberated carbonaceous material. This is followed by an increase in the recovery of middlings and fines in the later stages of the process. Any free carbonaceous material remaining in the tailings from the release analysis test tends to be associated with the very fine sizes (-400 mesh). Pyrite recovery is attributed to the hydrophobicity provided by small inclusions of carbonaceous material, since the amount of truly liberated pyrite particles (i.e., 100% pyrite) present in the sample is found to be negligible.

Jan 1, 1994

By Evangelos Spyridonos, Thomas Frommer, Wolfdietrich Skala, René Prissang

Operational grade modelling is a technique that uses production data to run daily updates of property models. It will enable mining engineers to use property predictions based on the most recently acquired data as support for quality control and decision making. The approach necessitates that the properties of the run- of-mine material can always be attributed to individual mining blocks or charges. The software employed must be highly reliable, because a system failure or the loss of data could seriously affect the mine's quality management. An operational grade modelling system has been developed for the Breitenau magnesite mine. It makes use of the Linear Octree Based Property Modelling system which was conceived and realised at the Free University of Berlin. This paper describes the system design and gives an account of the experiences during the first six months since system start-up.

Jan 1, 1996

By R. K. Steinhorst

Multivariate cluster analysis, MANOVA, canonical analysis, and discriminant analysis of hydrochemistry data were used to investigate the directions of ground water movement in basalts in the vicinity of the Hanford Reservation, Washington. The statistical analyses indicate that the hydrochemistry of the ground waters in these basalt formations is distinctly different on each side of the Columbia River. This suggests that the river is a ground water divide or that the river is roughly coincident with a hydrogeologic barrier boundary. The statistical procedures used in this study constitute a quantitative means for differentiating ground waters according to hydrochemistry.

Jan 1, 1990

By B. Govindarajan, T. C. Rao, M. Vanangamudi

The results obtained from hatch, flotation experiments on two coals were used to develop relationships between the recoveries of water and solids into the concentrate. When the recovery of non-ash material (RN) for any size fraction is plotted against a parameter X, defined as [x _ Amount of (W) recovered x Collector dosage (C)in the concentrate (cc)(kg/t)] a single "non-ash recovery curve" is obtained. Non-ash recovery curves thus obtained from different size fractions are used to get a unique "modified non-ash recovery curve" for a given coal, using the reduced efficiency curve concept. Similar observations have been noted in the case of recovery of ash material (RA) also. The amount of water recovered into the concentrate is plotted against a parameter "Water Recovery Factor (WRF)," defined as [WRF = T.F.(1+C)] where T is time (in sec) and F is frother dosage (in kg/t). Plotted in this form a characteristic water recovery curve, for a given coal is obtained that may be defined by the following equation: [W4=W_(1 pWRF-e] The above relationships have been verified against the experimental results obtained from three more coals and are found to give satisfactory predicted values.

Jan 1, 1992

By P. L. Dunn, G. T. Adel, E. B. Cruz

Automatic control of fine-coal cleaning circuits has traditionally been limited by a lack of adequate sensors. Although several nuclear-based analyzers are available, none have seen widespread acceptance. In this investigation, image analysis is used for the on-line determination of ash contents in fine-coal slurries. The ash content of a flotation tailings stream is correlated to the mean gray level of the slurry. Based on a 90% prediction interval, an analysis of sensor performance indicates an accuracy of 73[±] 4% ash over a range of from 65% to 90% ash. While the results are comparable, the video-based system costs only a fraction of what a nuclear-based analyzer costs. The sensor is now installed at the Middle Fork preparation plant, which is owned by Pittston Coal Co.

Jan 1, 1999

By Eddy J. Jacques

When the automatic control of a ventilation process is considered, and supervising expert systems need to be designed, an important problem to address is: what will be the optimal set points of the regulators that should meet a certain number of independently formulated requirements, distributed over a ventilation network? The set of these requirements, expressed in terms of air flow quantities or differential pressures in certain airways, need not be consistent. Their number is not limited by the number of available regulators, nor by their nature, i.e. passive or active. Moreover, they may be subject to upper or lower limit values. The method described here addresses this problem and tries to provide a tool that should allow to calculate the set points of all the regulators as a global and optimal solution with respect to this set of distributed requirements. The pure mathematical developments in this paper are kept as short as possible in order to allow more room for the description of a relevant example.

Jan 1, 1991

By S. Kelebek, G. W. Smith

Four samples of galena, each prepared differently, dry ground chalcopvrite and real gar have shown various quantities of liberated sulfur corresponding up to nine equivalent monolavers on their surfaces as determined by the solvent extraction/UV analysis of sulfur using ethanol. The pretreatment of a dry ground galena sample with acidified ammonium chloride or neutral, saturated sodium chloride solutions rendered the mineral readily floatable. The collectorless floatabilities of galena pretreated with the former solution and of drv ground chalcopvrite have been evaluated in reference to the natural floatability of sulfur using the critical surface tension of floatability approach with aqueous methanol solutions. It is shown that the amount of sulfur- on these samples can be correlated with their flotation rate, which was found to he first order within the critical surface tension range. The larger the concentration of surface sulfur, the faster the sulfide mineral floats, thus, the greater its flotation rate constant.

Jan 1, 1990

By Kalyan Saikia

An integrated statistical-geostatistical modelling of gold exploration data of Gurahar Pahar prospect of Mahakoshal greenstone belt in Central India has been attempted. Statistical modelling of gold accumulation and width reveal a positively skewed 2-parameter lognormal distribution fit with an estimate of mean gold as 0.84 gram/tonne. Geostatistical modelling provided a spherical semi-variogram function fit with mean kriged estimate and mean kriging variance of gold as 0.76 gram/tonne and 0.23 (gram/tonne)2 -respectively. Ore inventory and grade-tonnage relationships for a selected part provided an estimate of 3,36,000 tomes of ore with an average gold of 0.76 gram/tonne at 0.5 gram/tonne cutoff grade.

Jan 1, 2002

By Z. D. Hora, W. N. Hamilton

Evaporite units of the Western Canadian Sedimentary Basin are known to host native sulfur. In British Columbia, a large number of oil and gas exploration drilling holes reported intersections with native sulfur. The most important ones include 6 meters (20 feet) and 27 meters (90 feet) of native sulfur among 23 occurrences in Devonian Muskeg evaporite or adjacent Slave Point reef facies carbonates. A small Frasch sulfur deposit is known from Devonian Wabamun Group sediments near Camrose in South Central Alberta. Occurrences of native sulfur are common also in association with presently mined gypsum of Devonian Burnais Formation in southeastern British Columbia. Triassic sediments with evaporite members in British Columbia are also known to contain native sulfur showings. A widespread presence of anhydrite in many sedimentary units of Alberta and British Columbia together with oil and gas fields in the same areas and associated native sulfur occurrences point to a possibility for Frasch sulfur deposits in this part of western Canada.

Jan 1, 1992

By B. C. Paul, R. Q. Honaker, M. Huang

Froth flotation is now, the most commonly used method for cleaning fine-coal fractions in coal-preparation plants. Past research and industrial practice have demonstrated that froth flotation achieves excellent separation efficiencies for fine coals having only a small fraction of middling particles. However, the efficiency of froth flotation decreases sharply as the concentration of middling particles increases. This is due to the flotation of high-ash particles that have a small amount of hydrophobic coal present at the surface. Because gravity-based processes are much more efficient for the treatment of middlings, the application of centrifugal washing for fine-coal cleaning was studied with an emphasis on the primary cleaning of fine-circuit feed. Results are shown of a parametric study that used a semibatch Falcon centrifugal concentrator. The results of the study revealed that separation performance is a function of particle size, bowl geometry, feed solids content and feed rate.

Jan 1, 1996

By M. Manrique

Various pyrometallurgical methods for treating Ilmenite and Zircon concentrates are reviewed. Laboratory experiments, using a thermal plasma reactor, have been performed to evaluate: the conversion of ilmenite to TiC or TiC-Fe and the conversion of zircon to ZrC or ZrC-SiC. Results are examined and possible processing routes are identified.

Jan 1, 1996

By Keith G. Wallace

In 1982 the U.S. Congress passed the Nuclear Waste Policy Act (NWPA) to provide for the development of an underground repository for spent nuclear fuel. This development will be managed by the United States Department of Energy. In 1986, the President selected three areas for site characterization to determine their suitability for the development of an underground repository; those sites were: 1) A site in volcanic tuff located at Yucca Mountain in Nevada, 2) a site in bedded salt located in Deaf Smith County in Texas, and 3) a site in basalt located in Hanford, Washington. At present conceptual repository designs are being developed for each site. A key element of a repository design is the underground ventilation system required to support construction, nuclear waste emplacement, and potential waste retrieval. This paper describes the preliminary ventilation system designed for the repository in tuff. The concept provides separate ventilation systems for the construction and waste emplacement activities. The paper further describes the means by which acceptable environmental conditions will be re-established to allow re-entry into previously closed rooms for the purpose of inspection, maintenance or retrieval.

Jan 1, 1987