Assessment of the Potential for Radioactive Pollution at a Phosphogypsum Waste Dump and Possibilities for Ra226 Removal

To assess the potential for radioactive pollution unique to the environmental conditions of the Bacau phosphogypsum waste dump, surface samples were taken, drillings were performed on the entire waste dump's height, and the Ra226 distribution on the height and surface considered to contain a medium content of the radium of 0.57 Bq/gr was studied. Thus, the waste dump's radioactive potential was estimated at 30-40 Ci in equivalent Ra226. Also analyzed was the granulometric composition of the phosphogypsum and the distribution of Ra226 on granulometric orders, which indicated that the radium was concentrated in the very fine fractions. Parameters were set up for the classification by hydrocycloning to obtain a fine class (less than 41 microns) having a radium content of more than 0.9 Bq/gr and a coarse class having less than 0.37 Bq/gr. A chemical process was devised for removal of the radium from the phosphogypsum with the possibility for recovering the contained sulfur.