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By J. R. Wait, D. A. Hill

A survey of the literature on ELF and VLF atmospheric noise has been made. Most measurements have concentrated on the vertical electric field and the horizontal magnetic field rather than the vertical magnetic field which is of interest in transmission between horizontal loops. The limited vertical magnetic field data indicates that the vertical component is generally 10 to 20 dB below the horizontal component. Three laterally inhomogeneous earth models have been analyzed for conversion of horizontal to vertical magnetic field. The rough surface model examines surface effects, the inhomogeneous thin sheet model treats volume effects, and the buried cylinder model treats localized man-made effects. All three models predict the possibility of significant conversion from horizontal to vertical magnetic field. A thin sheet model has also been used to examine transmission from a buried magnetic dipole source. It is found that the pre- dicted fields more nearly model the measured data than does the homogeneous half-space model.

By Marvin L. Whisman

A radiotracer technique developed by the Bureau of Mines extends to the parts-per-billion range the sensitivity for determining contributors of deposits formed in stored and thermally stressed jet fuels. The method depends upon measuring radioactivity associated with thermally induced deposits from fuels containing one labeled compound. The technique was applied to 88 test blends, representing 12 fuels and nine carbon-l4 labeled fuel constituents or fuel additives, or both. Data from results of these tests are included in this report. With this radiotracer technique, the contribution of fuel components and additives to thermally induced deposits in a variety of fuel environments was estimated before and after storage.

Jan 1, 1969

By Joseph Cervik, J. H. Perkins

The Bureau of Mines has conducted desorption work on fine coal particles at near atmospheric pressure. An apparatus has been developed that uses a capacitance manometer to measure desorption of methane from coal particles up to 2 inches in diameter and pressures up to 1,000 psi. This will make it possible to duplicate the desorption process as it occurs in its natural under- ground environment.

Aug 1, 1970

By D. E. Hirsch

A systematic procedure for separation, characterization, and semiquantitative analysis of high-boiling petroleum distillates was developed by the Bureau of Mines and applied to a 370° to 535° C distillate of Wilmington, Calif., crude oil. Separation procedures employed were isothermal and molecular distillation, chemical treatment, silica-alumina adsorption, and gel permeation chromatography. Characterization and analysis were accomplished by gel permeation chromatography correlations and mass and nuclear magnetic resonance spectrometry. These data should be useful in improving petroleum processing and utilization and in achieving the energy conservation inherent therein.

Jan 1, 1974

By J. W. Town

The Bureau of Mines studied the effects of reducing gas composition, tem-perature, and superficial gas velocity on the regeneration rate of alkalized alumina. Regeneration was assumed to follow the simple first order reaction for removal of sorbed S02: dµ/dt = -Kµ. An Arrhenius relationship can be plotted, which shows an activation energy of about 75 kcal/mole for simulated reformed propane. The general effects of the individual gases can be described as follows: (1) CO and H2 produced rates proportional to their con-centrations, up to about 5 percent for each; (2) addition of CO2 had no effects on the regeneration rate by CO; (3) the regeneration rate by H2 was lowered by the addition of H2O while the regeneration rate by CO was increased by 0 addition; (4) H2S showed a positive effect up to concentration levels of about 2 percent and then produced a rapid negative effect; (5) carbonyl sulfate (COS) increased the sulfur content; and (6) propane was as effective in regenerating the loaded pellets as was simulated reformed propane.

Jan 1, 1971

By J. D. Marchant

As part of its mission to assure the maximum recovery and use of the Nation's mineral resources, the Bureau of Mines, investigated an improved procedure for producing rare earth-silicon alloys. For example, a charge consisting of 681 grams of mixed rare-earth oxides, 309 grams of ferrosilicon (75 wt-pct Si), and 182 grams of aluminum metal along with a flux consisting of 681 grams of CaO and 45 grams of MgO was reacted at 1,500° C in an induction furnace. Good slag-metal separation was achieved. The alloy product contained, in weight-percent, 53 RE, 28 Si, 11 Fe, and 4 Al with a rare earch recovery of 80 pct. In current industrial practice rare earth recoveries are usually about 60 pct in alloy products that contain approximately 30 wt-pct each of rare earths and silicon. Metallurgical evaluations showed the alloys prepared in this investigation to be as effective in controlling the detrimental effect of sulfur in steel and cast iron as the commercial rare earth-silicon-iron alloys presently used in the steel industry.

Jan 1, 1980

By John C. Edwards

A two-dimensional, time-dependent, mathematical model has been developed that describes fire spread along the walls of a ventilated duct. The model is based on the assumption that the leading edge of the fire zone propagating along the wall surface coincides with the isotherm for the fuel ignition temperature. The model includes gas-phase energy transport via radiation and forced convection inside the duct and solid-phase energy transport by conduction into the fuel lining. Product gases emitted from the fire zone are assumed to mix uniformly with the ventilation gas to produce an optically dense gas mixture at the combustion temperature that enters the preheat region. Numerical solutions of the model equations for a coal-lined duct (simulated coal mine entry) have been used to investigate the effects of tube radius, air velocity, combustion temperature, and optical density of the soot-laden gas upon the terminal fire spread rate.

Jan 1, 1977

By Paul E. Loustaunau, Devah Galloway, Catherine Wetherby

This report describes a project in which Development of a Supervisory and Management Training Program for the Underground Coal Mining Industry was developed and evaluated. The project was carried out in two phases. The first phase was a research effort to develop specifications for the program. The second phase was a development and evaluation effort. In the second phase, training programs for first-line supervisors (section foremen) and for middle managers (mine/shift foremen and mine superintendents) were prepared in accordance with the specifications and evaluated by members of the industry. This report describes the project and presents the conclusions drawn there from.

Jan 5, 1983

By Robert F. Chaiken

A novel approach to eliminating environmental and public safety hazards that are associated with fires in abandoned coal mines and waste banks involves the use of in situ combustion technology developed by the Federal Bureau of Mines to accelerate the burning of the wasted coals in place. This technology would be used under exhaust ventilation control conditions that would allow for total management of the hot gases produced. Combustion stoichiometries would be optimized to minimize unburnt combustibles and to maximize the heat content of the gas products, which will be exhausted at one or more fan locations. When necessary, scrubber systems would be employed to remove air pollutants, such as sulfur dioxide; heat utilization systems (process heat, steam, and electricity) would also be employed to offset operational costs. Ultimately, complete burnout would solve the fire and acid water formation problems of the abandoned coal mine or waste bank. Pertinent technical data for burnout control are derived and discussed in terms of the important material and operational parameters. In general, it is believed feasible to operate a burnout system in an existing abandoned mine or waste bank fire at thermal power levels in the range of 10 to 100 Mw, and at exhaust gas temperatures of 1,000° C (1,830° F).

Jan 1, 1980

By C. H. Elder, Fred N. Kissell, S. D. Maksimovic

The Bureau of Mines evaluated the hydraulic stimulation of a gob-degasification borehole to determine if this procedure would aid in degasifying a longwall panel. The stimulated borehole did not degasify the longwall panel as expected either before or after mining of the panel started. It reduced the underground methane emission only 11 pct, considerably less than the reductions effected by two unstimulated boreholes in the same panel. Some probable reasons for the reduced methane flow from the hydraulically stimulated borehole are very low reservoir gas pressure, location of hydraulically stimulated zones within the grouted casing, a casing break caused by lateral shifting, possible vertical movement of rock strata during caving, grouting of a 4-inch pipe blocking three stimulated zones, plasticity of shales, and possible hole damage by swelling of water-sensitive minerals. The borehole was also located between two second-mined areas, which may have allowed partial degasification of the overburden and the coalbed in advance of mining. Finally, a period of 3 months is probably not long enough for the borehole to degasify the overburden before mining.

Jan 1, 1977

By F. N. Kissell

The Bureau of Mines used sulfur hexafluoride (SF6) tracer gas to evaluate the effectiveness of gob ventilation and/or sealing practices at three coal mines, each having different problems associated with their mined-out areas. The purpose of these ventilation studies was to better understand whether current techniques employed for ventilation or sealing are successful at minimizing the potential for gob fires and explosions. The work performed at each mine is discussed: One is a long-wall operation that uses ventilation to carry off hazardous gases, and two are room-and-pillar operations, each with far different concerns, that seal off the gobs to isolate them from the main mine ventilation. In all cases employment of the Bureau's SF6 tracer gas technique resulted in answers to questions raised by the mine operators concerning the effectiveness of their gob ventilation or sealing practices in preventing mine fires.

Jan 1, 1986

By M. L. Skow, Maurice Deul, M. G. Zabetakis

This Bureau of Mines report presents a brief summary of the explosion trends in United States coal mines for the past 160 years. These trends show that in spite of the overall improvements in mine safety, the number of fatalities from ignitions of methane has actually increased in recent years. Suggestions are made of procedures that can be utilized to reverse this trend.

Jan 1, 1972

By George R. Schottler

The Bureau of Mines investigated the distribution of uranium and various methods of ore sampling in a uranium deposit typical of those in the Morrison Formation sandstone of the Ambrosia Lake area, Grants mining district, north-western New Mexico. Chemical and radiometric assays of diamond-drill core samples are compared in detail by statistical techniques, and the assay data are correlated with the stratigraphy of the deposit. Conclusions applicable to ore-reserve estimation in geologically similar uranium deposits are drawn.

Jan 1, 1971

By C. H. Elder, M. C. Irani

Two degasification test boreholes were drilled to depths of 1,238 and 1,212 feet on Bureau of Mines property at Bruceton, Pa., as part of the Bureau's long-range coal degasification program. The holes provided detailed geologic information and geologic sections, which were correlated with regional stratigraphic cross sections prepared by the Pennsylvania Geological Survey. Gas content determinations and coal analyses were made on the Upper Freeport, Middle Kittanning, Clarion, Brookville, and Mercer coalbeds; gas content of the coalbeds ranged from 53 to 165 cubic feet per ton. Formation pressure and gas flow tests were conducted on selected coalbed intervals in borehole 1; formation pressures ranged from 292 to 473 psig. The middle Kittanning coalbed was hydraulically stimulated using very heavy gelled water, but gas production remained low because gel residue and formation water inhibited the flow of gas. Gas contents in the Clarion, Upper Brookville, and Mercer coalbeds were anomalously low owing to the proximity of porous sand- stones which act as reservoirs for gas migrating from coalbeds.

Jan 1, 1977

By S. D. Maksirnovic, Fred N. Kissell

The use of vertical surface degasification boreholes with bleeder systems and the use of a timbered bleeder system to degasify gob areas were studied by (the Bureau of Mines. This report describes three gob degasification studies ,conducted in the Pittsburgh coalbed. One study was conducted to determine the number of panels degasified with one large borehole . The study showed that the borehole provided degasification for three panels. Another study was conducted during the retreat of a 35-acre panel with a single-entry and a two-entry bleeder system and a large surface borehole. A major portion of methane emitted from the panel was carried away by the bore- hole, leaving the bleeder entries relatively free of methane. The last study was made to determine the effectiveness of a timbered bleeder system. The bleeder entries successfully degasified the gob area when enough entries were available and adequate pressure was available to force the air through roof falls.

Jan 1, 1980

By Arthur M. Hartstein

The Bureau of Mines through contract with Ultrasystems, Inc., obtained gram per gram data of products formed on thermal oxidative degradation of selected compositions, both under dynamic and static conditions. Four broad classes of materials were studied! Polyvinyl chloride compositions, neoprene compositions, rigid urethane foams, and variously treated woods. Whenever possible, comparisons between pure components and composites were attempted. Thermogravimetric and differential thermal analyses were performed to gain understanding of the processes occurring and to explore the feasibility of using these analyses as a method of material identification. The toxic products detected and quantitated included HC1, H2S, CO, S02, CS2,COS, HCOOH, CH3COOH, formaldehyde, acrolein, C 6H6, chloroprene, chloroethanol, benzyl chloride, aniline, and furfural.

Jan 1, 1974

By R. A. Guidotti

The Federal Bureau of Mines has studied the reaction of oxides of columbium, vanadium, and tantalum with ammonia in vertical, gas-solids reactors at temperatures ranging from 300° to 1,300° C with the goal of preparing nitride intermediates for subsequent preparation of the metals by a thermal-decomposition step. The best nitride conversions were obtained in nonmetal reactors. With Cb205, V2O3, and V205 , low-temperature maxima in reaction rates occurred at 800°,800°, and 450° C, respectively, during oxynitride formation (in A1203) at 1 atm of pure ammonia. Conversion of the oxynitride, in a second step, to the mononitride was optimum at 1,200° C for columbium and 1,050° C for vanadium. In the case of Ta205, the rate of reaction to form Ta3N5 (in a single step) was highest at 900° C, where the presence of up to 5 percent methane was found to be beneficial; improved results were obtained by conducting the nitriding in a rotary kiln. Optimum space velocities (in the vertical Al203 reactor) ranged from 5,280 hr-1 for Cba205 to 7,950 hr-1 for V203. Oxide particle size had little effect upon reaction rates. Under fully optimized conditions, products containing less than 1 percent oxygen were readily obtained in under 6 hours.

Jan 1, 1975

By Jack C. White

The purpose of this Bureau of Mines work was to develop information useful in improving copper recovery during copper milling operations. Eleven copper mill tailings from the Western United States were subjected to froth flotation and cyanide leaching to provide an experimental basis for comparing their beneficiation response. Recoveries in flotation concentrates made from mill tailings ranged from 65 to 15 percent, at copper grades of 13 and 2.2 percent, respectively. Liberated copper sulfide minerals present in two samples were readily recovered by laboratory froth flotation. Nine of the samples were less amenable to froth flotation because of physical locking between copper sulfide minerals and gangue. Correlations among tailings indicated that recovery of sulfide copper by flotation was directly related to the sulfide copper content. Empirical equations derived from flotation data provided average values for unrecoverable copper and for recovery efficiency. Flotation response of copper mill tailings may be predicted from the equations. Data from cyanide leaching provides an equation describing the limiting high values for removal of copper by this method.

Jan 1, 1974

By D. R. Douslin

This report describes an inclined-piston pressure gage that operates from a zero-pressure datum level. The gage is adaptable to accurate vapor-pressure measurements in the low and intermediate pressure range, 0.01 to 40 mm (mercury). Residual friction in the oil-lubricated piston-cylinder combination is eliminated by a unique oscillatory method that is free of end thrust on the piston and allows the full sensitivity of the gage to be realized. The axial component of the weight-to-area ratio of the piston is determined by measuring the angle of inclination with a goniometer that can be read to 1 sec. Accuracy of the gage proper is estimated to range from 0.001 to 0.012 mm from lower to upper pressure limits. Its highest practical sensitivity is about 0.0005 mm. As a test, the vapor pressures of ice and water were measured in the range -30° to +20° C.

Jan 1, 1963

By H. H. Schrenk, L. B. Berger

"INTRODUCTION The Bureau of Mines frequently receives requests for information and advice regarding the equipment necessary for establishing laboratories for the analysis of mine atmospheres. Such requests are made by mining companies, State mining departments, and other agencies concerned with the safety of mining operations. In many instances it is desired to install a complete laboratory, which will necessitate purchase of suitable gas-analysis apparatus and all the minor but important accessory equipment needed to carry on this type of work. Although publications that describe methods and techniques applicable to the analysis of mine atmospheres are available, it is not within the scope of such publications to give detailed information on laboratory equipment or design. Persons unfamiliar with laboratory practices and gas-analysis procedures may find it difficult to decide upon the proper equipment for their particular needs and to itemize the various accessories that must be obtained to set up a complete laboratory.The purpose of this circular is to discuss the different types of equipment that may be used in the analysis of mine atmospheres, with particular regard to the application and limitations of each type. Information on the various accessory equipment needed in a laboratory for the analysis of mine atmospheres is given also, and suggestions on laboratory design are included. As much of the necessary equipment may be obtained from laboratory supply houses, the information should aid in arriving at estimates of the cost of proposed laboratories.The procedures involved in the analysis of mine atmospheres are not described; such information is contained in publications referred to in this circular."

Feb 1, 1948