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By E. W. Mountjoy

THE Exshaw formation is a thin but very persistent black shale unit generally well exposed along the easterly scarp faces of the fault blocks comprising tl1e front ranges of the Rocky mountains. It is over lain by the Mississippian Banff shales and silty shales and underlain by the massive Palliser Limestone formation of late Devonian age. The Exshaw continues eastward under the plains of Alberta and on into Saskatchewan, with little change until it reaches the surface of the Palaeozoic-Mesozoic unconformity. During the summer of 1953, the writer was working- with a field party under Dr. J. L. Usher in the front ranges of the Alberta Rocky mountains. This party, sent out by the Mobiloil Company, conducted a geological survey of Devonian rocks between the towns of Banff and Jasper. The writer helped to describe and map these Devonian rocks and obtained first-hand information concerning the Exshaw shale and its relationship to the underlying and overlying sediments. Additional information was obtained from reference material and from a number of geologists whom the writer has consulted. Grateful acknowledgment is offered to them, to the Mobiloil Company for releasing field information, and to F. W. Beales and W. P. Hancock who helped edit the original paper for publication. Information from areas north and smith of that studied and from bore holes on the prairies is referred to. Localities mentioned may be found in Figure 1.

Jan 1, 1956

Proper water and thermal management is essential for obtaining high performance of Proton Exchange Membrane Fuel Cells (PEMFCs). A steady, two-dimensional water and thermal management model was developed, aiming at considering pressure drop, open circuit voltage variation with stack temperature, water vapor effects on membrane conductivity, which made the model physically more reasonable and more suitable for various operating conditions. The model could predict the distributions of a series of important parameters along the flow channel, and thus the effects of various operating and design parameters on the fuel cell performance could be investigated easily by numerical trial-and-error method. The modeling results compared well with the available experimental results from the literatures. The results also showed that the humidification is crucial for the performance of PEMFCs. The model could be a very useful engineering tool for the optimization of PEMFCs.

Jan 1, 2005

By E. Krause

The oxidation of Fe(II) with S(IV) and oxygen can be used advantageously in leaching systems requiring both Fe(III) and sulfuric acid; e.g., heap leaching of sulfide-containing ores or concentrates. The oxidation of Fe(II) with SO2/air is several orders of magnitude faster than with air alone; rates of up to ?20 g/L'h were observed at 25°C. The reaction proceeds via an intermediate orange-red mixed-valence Fe(II)/Fe(III) sulfite complex, which is present at an essentially constant concentration throughout most of the oxidation process. The oxidation rate of Fe(II) is approximated by the formula -d[Fe(II)]/dt = k [S(IV)] [02]0'3. The concentration of the mixed-valence complex, and thus the iron oxidation rate, decreases with increasing acidity. Certain impurities, such as SCN- and thiourea, negatively affect the rate. The oxidation reaction 2Fe2 + SO2 + 02 4 2Fe3+ + S042- is accompanied by the side reaction H20 + SO2 + 1/202 4 H2SO4. The side reaction becomes particularly important at low temperatures and whenever the oxygen mass transfer is insufficient with respect to the rate of addition of S(IV). Thus, effective oxygen mass transfer is essential for achieving high oxidation rates with minimal acid formation. The activation energy was estimated as 141 kJ/mol over the temperature range 10-35°C.

Jan 1, 2006

By Wm. D. Jr. Sheldon

THIS paper presents practical data to aid in the selection of a mine ventilating fan, and outlines considerations to be made to ensure satisfactory operation and optimum efficiency of the fan. Much has been published on the general subject of mine ventilation, but the writer has found few specific data on factors and considerations which govern the selection of a fan-data which should be available to the operator if his fan is to give satisfactory service within the range of the high-efficiency portion of its performance curve and deliver the specified air capacity when operating against the anticipated range of resistance of the mine. The total quantity of fresh air furnished by the ventilation system must be adequate to provide, and to ensure at all times, safe and healthful working conditions in the mine. It is assumed that the mine operator is able to determine the air quantities required for the various parts of the mine.

Jan 1, 1941

By C. S. Lord

"The Regal Silver mine is 5 miles north-northwest of Albert canyon; a station on the main line of the Canadian Pacific railway; 21 miles east of Revelstoke; British Columbia.Development, commenced in 1918, comprises more than 8,000 feet of workings from six adits, one of which extends into the Regal Silver property from the adjacent Snowflake ground. Production has been limited to a little tungsten concentrate recovered recently from a few r..undred tons of ore treated in a small underground mill. The property has received some attention as a possible source of tin. The deposits are large quartz veins containing irregular sulphide bodies. Ore minerals normally make up less than 1 per cent of the veins and include pyrite, galena, sphalerite, scheelite, and stannite. The veins are approximately parallel with the bedding of the enclosing graphitic, siliceous to calcareous, slates and argillites. These strata are of Precambrian age, strike about northwest, and dip northeast. No other rocks are known in the vicinity of the workings . Granitic rocks, intrusive into t'he sediments, outcrop 4 miles to the southwest and 7 miles to the northeast and may underlie the property at no great depth."

Jan 1, 1954

Overview n Why we audited the IRS n How we did it n What we discovered n What we learned n Where we are going next The unbroken chain of safety The Internal Responsibility System (IRS) The network of roles and relationships in a workplace, through which everyone works with mutual commitment to reduce or eliminate hazards.

May 1, 2003

By Magnus Evertsson, Johannes Quist

HPGRs have since introduced in the 1980s (Kellerwessel, 1993; Schönert, 1988), now become integral comminution units at several minerals processing plants around the world. Even though a lot of the initial issues concerning performance, availability and wear have been addressed and solved there are still phenomena and aspects which can be improved and understood further. Schönert and Sander (2002) presented experimental results and a mechanistic model including the internal force dynamics between the rollers and the compacted bed. They derived expressions for the pressure distribution involving most of the influencing terms and effects. However, in order to solve the differential equations several of the terms vanish by assumptions. The Schönert and Sander model reflects the experimental data in many aspects but the predicted shear force distinctly deviates from the experimental results at the angular position of the peak pressure level. This finding suggests that the particle to particle interaction and breakage process in the different zones seen in Figure 1 are complex and difficult to model using analytical models. A numerical modelling approach using DEM does not require the same amount of assumptions and simplifications of boundary conditions. Hence such modelling may provide further knowledge and vital understanding. In this paper the breakage process is simulated in order to investigate the shear slip behaviour and how it relates to different operating variables. A laboratory scale HPGR corresponding to the experimental setup used by Schönert (2002) have been modelled in EDEM (DEM-Solutions). The bonded particle model (BPM) is used for modelling quartz particles (Potyondy, 2004). The breakage model strength parameters are calibrated against interparticle breakage experiments in an Instron 400RD compression device. The contact model parameters are calibrated using calibration methods developed by Quist (2015). The floating roller dynamics are modelled using a spring-damper system. Results present insights regarding the interparticle slip behaviour as well as the frictional tangential force distribution on the rollers. The simulated roller pressure distribution shows good correspondence with previously reported findings in the literature.

Jan 1, 2016

By T. Krumins, L. Zunti, R. Frischmuth

Mercury is known to occur in sulphide-bearing refractory gold deposits in the form of sulphide minerals or elemental inclusions. These deposits typically require an oxidative pre-treatment process, such as pressure oxidation or roasting, to achieve economic gold recovery. However, these processes also have the potential to liberate mercury, a portion of which may then be released to the environment through gaseous emissions. Mercury emissions from mine processing operations have been of particular interest in recent years, as governments impose lower emission targets and organizations adopt better industry practices to reduce the environmental and health aspects of releasing mercury into the environment. This paper describes various mercury removal technologies with respect to pressure oxidation gas handling circuits, with a focus on key design variables and technology selection criteria.

Jan 1, 2014

By R. R. Song, Q. Li, H. Xing, X. C. Wei

Geomechanical modelling of fault stability is an important part of CO2 capture and storage (CCS) research program to ensure its viability and long-term safety. Storage of CO2 in deep subsurface reservoirs requires estimates of sustainable fluid pressures that will not induce fracturing or fault reactivation which could cause fault slip. More importantly, fault slip gives rise to seismic waves, which inflict severe damage to the cap rock of the reservoirs and may result in leakage pathways for the buoyant plume and thus compromise the integrity of seal formations. In this study, we generated a numerical model tuned towards conditions usually encountered in the Shenhua CCS demonstration project in Ordos basin. In particular, with the purpose of evaluating the sensitivity of the parameters as well as their relationships with the moment magnitude of the seismicity, a variance-based sensitivity analysis was adopted for importance ranking of the uncertain input parameters of the given model. However, such flow models could involve one or several spatial inputs, for instance, fault dip, distance between fault and the injection well, friction angle of fault, permeability of fault, Young's Modulus of fault, injecting pore pressure and the stress field. Studying the sensitivity to each of these spatial inputs motivated the present work. The results led to the following conclusions: fault depth and fault dip significantly affect the behavior of the fault and the fault slip becomes violent with the fault depth increasing and fault dip decreasing. Furthermore, the results indicate that slip time increases with the fault dip decreasing and decreases with permeability of fault increasing. In addition, the calculation of seismic moment and moment magnitude of an earthquake demonstrates that it rises significantly with the decrease of fault dip and the increase of fault depth, and it decreases with the rising stress field. The results show that variations of the only controllable parameter injection pressure do not show great influence to the fault behavior compared with other geological factors, which imply site selection is extremely important for the CCS projects.

Jan 1, 2015

By W. A. Gow, V. F. Harrison, H. H. Mccreedy

A semi-continuous bench-scale, countercurrent-decantation system, in which the ore was moved countercurrently to the flow of leaching solution, was used to conduct acid-leaching tests on uranium ore with the aid of bacteria. This method, which involved a low degree of agitation, was successfully applied to extract uranium in practical amounts and at practical rates. The acidity of the leaching solution was the main variable investigated in the bench-scale tests done at the Mines Branch, Ottawa. Over 90 11er cent of the uranium was extracted in a six-stage system. The results suggest that this technique could be ap-plied in the utilization of bacterial oxidation and leaching as a method for treating Elliot Lake uranium ore.

Jan 1, 1969

By Kazutoshi Haga, Batnasan Altansukh, Yasushi Takasaki, Mohd Yazid Bin Abdul Razak, Atsushi Shibayama

"In this study, the volatilization behaviour of arsenic (As) and antimony (Sb) from arsenicantimony bearing minerals such as tennantite (Cu12As4S13)/tetrahedrite (Cu12Sb4S13) in copper ore was investigated using a roasting process. Specifically, the thermal decomposition of tennantite and the arsenic volatilization were investigated under nitrogen and air atmosphere. The roasting experiments were performed at temperatures ranging from 500 to 1,200oC and different retention times using a laboratory electric furnace. The results indicated that over 95% volatilization was achieved at 700oC. On the other hand, when the temperature increased to 1,200oC, volatilization rate of Sb reached to 90%. Therefore, volatilization of Sb requires high temperature compared to As. It suggests that As and Sb can be separated using temperature difference. Selective removal of As is possible at 700oC, subsequently Sb can be recovered as a volatilized product by increasing the temperature to 1,200oC. Meanwhile, volatilization of Cu and Fe was not observed on these conditions. The content of As and Sb in the residues obtained from roasting at 700 and 1,200oC was less than 0.3 and 0.75 mass%, respectively. The Cu content in solid residue at 1,200oC increased to 34 mass%. The clean copper concentrate with lower amounts of arsenic and antimony was obtained from the process. INTRODUCTIONRecently, arsenic (As) and antimony (Sb) contents in copper (Cu) concentrates are increasing year by year. Arsenic and antimony are present with Cu minerals such as enargite (Cu3AsS4), tennantite (Cu12As4S13) and tetrahedrite (Cu12Sb4S13) that associate with copper sulfides [chalcopyrite (CuFeS2) and bornite (Cu5FeS4)]. They are normally concentrated by flotation and treated in copper smelters. However, treatment of copper concentrates containing high amounts of arsenic and antimony by a smelting process is difficult due to environmental implications of toxic arsenic and antimony. As demand for copper continues to grow, the need to source copper from several types of resources including those that contain high levels of As/Sb becomes necessary. Therefore, a novel processes for the treatment of As/Sb bearing Cu concentrates are required. Reviews on copper resources such as enargite, tennantite and tetrahedrite containing high amounts of arsenic and antimony are covered widely in literatures by many researchers (Padilla et al., 1998; Welham, 2001; Vinals et al., 2003; Guo & Yen, 2005; Balaž & Achimovicova, 2006a; Filippou et al., 2007; Mihajlovic et al., 2007; Lattanzi et al., 2008)."

Jan 1, 2016

By M. E. Holter

"Limestone-bearing strata are exposed in seven areas of Alberta, each situated adjacent to rail and road facilities. Six of these centers are located along the eastern edge of the Foothills and Front Ranges of the Rocky Mountains in western Alberta. The other is in northeastern Alberta, along the eastern margin of the Alberta Basin. High-grade limestones are present in Middle Cambrian, Upper Devonian and Mississippian strata. Middle Cambrian (Eldon Formation) limestones have been exploited only in the Exshaw area west of Calgary, where they formerly were used for lime production. Limestone beds of the Upper Devonian Palliser Formation are exploited at Exshaw and at Cadomin in west-central Alberta for the manufacture of cement. Reserves of high-grade limestone also are available in the Palliser Formation near Crowsnest Lake in southwestern Alberta and near BrUle, west of Edmonton. Upper Devonian limestones of the Waterways Formation are widespread in the Fort McMurray area of northeastern Alberta, but available data indicate they are of inferior quality to the limestone deposits of the Rocky Mountains regions. The Mississippian Livingstone Formation contains large reserves of high-grade limestone at several localities in the Rocky Mountains and Foothills. Commercial development of the unit is now underway at Crowsnest Lake and at Exshaw for lime production, and future exploitation of these beds is feasible at Blairmore and Nordegg."

Jan 1, 1973

By W. D. Madeley

Synthetic minerals were made from pure starting materials and galena samples were doped with the title metals. Microscopic, microprobe and X-ray examination confirmed that the dopeants were in solid solution. Paired flotations in a Hallimond-tube apparatus were performed to determine relative flotation response using Aerofloat 238 promoter. Results of these tests show that silver-doped galena floats more readily than pure galena and that galena doped with bismuth floats less readily than pure mineral to a 95% confidence level. Galena doped with both silver and antimony as AgSbS2 shows no detectable effect. Antimony-doped galena followed the expected trend, but not to 95% confidence. The results are consistent with the theory that flotation by thiol-type anionic collectors is enhanced by p-type semiconduction.

Jan 1, 1978

By L. B. Kilius

The composite cathode system based on Ce0.9Gdo.1O2_,5 electrolyte with a painted cathode was used for an intermediate temperature (500-700°C) solid oxide fuel cell. This cathode system was chosen due to its excellent thermal expansion match to the electrolyte, its relatively high conductivity (115 S cm-1 at 700°C), and its low activation energy for oxygen reduction (99 kJ/mol). It was found that the decrease of sintering temperature of the composite cathode system produces a significant decrease in charge transfer resistances to a level of 0.25 SI cm2. The conductivity measurements of porous samples produced values between 40 and 88 S/cm for porosities of 30-40%.

Jan 1, 2005

By M. Walawalkar, C. K. Nichol, G. Azimi

Rare earth elements (REEs) are essential to the production of technologically advanced products, including wind turbines, electric and hybrid cars, automotive catalytic convertors, hand held electronic devices, and military defense systems. Their application in environmentally beneficial technologies puts them at a high priority for ameliorating environmental concerns. Because of their increasingly high demand and limiting resources, it is highly beneficial to find new sources for them. The present study is focused on leaching REEs from a phosphate based fertilizer by-product, known as phosphogypsum (PG). Global estimated world production of PG is about 240 million tonnes that is stored in the form of wet stacks adjacent to fertilizer production facilities, occupying vast amounts of land. PG also contains trace metals, which are detrimental to the environment, and hence it is crucial to monitor these stacks. We obtained our PG sample from Agrium Inc. (a fertilizer manufacturing company in Canada). We performed a comprehensive characterization of the PG sample and found that it predominantly contains Y, La, Ce, Nd, and Sm. For leaching purposes, we used hydrometallurgical acid leaching techniques. We investigated three acids over a range of operating conditions such as acid concentration, temperature, solid-to-liquid ratio, and residence time. We achieved an average leaching of 81% with hydrochloric acid as leachant using operating conditions that can be easily replicated in industrial settings. If our process is implemented, not only will it reduce the size of the existing PG stacks (mitigating their environmental risks), but also enable the development of new innovative routes for extracting REEs, making countries like Canada less vulnerable to supply disruptions.

Jan 1, 2016

By Andrukaitis. E.

The increasing use of electronic equipment by the Canadian Forces has increased the importance of electric power. A power source that is packed with energy and yet light, small and durable is the common request of military users. However, this needs to be achieved while also addressing the requirements of safety, reliability and low temperature performance. The potential use of fuel cells in a military environment has become a possibility in several areas in the 21st century. Some examples of power source requirements and the materials related R&D required to give better, higher energy power systems in the future will be discussed.

Jan 1, 2005

By H. Blaha, H. Wagner

"Room and pillar workings in salt mines are preferred sites for underground waste disposal. A critical issue in selecting waste disposal sites is long-term behaviour of such workings. The long-term behaviour of salt pillars is controlled by the pillar geometry, i.e. the height, width and length of pillars and the level of pillar stress. The latter has a strong influence on creep characteristics of salt pillars whereas the width to height ratio of salt pillars determines the strength of pillars and the deformation characteristics of salt pillars.Three different regimes of pillar creep behaviour of salt pillars can be distinguished, namely a stress level below which the rate of creep approaches a value of zero, a stress range where the rate of creep is constant and finally a stress level above which the rate of creep accelerates. Long-term stability of room and pillar workings can be assured only when the pillar stress level falls within the first stress regime. Strength and creep tests on model salt pillars have shown that at stress levels below 40% of pillar strength the rate of creep approaches a value of zero, between stress levels of 40% and 65% the rate of creep is constant but increases with stress level. Above pillar stress levels of 65% the rate of creep accelerates.Long-term measurements of pillar deformation and surface subsidence above relatively shallow room and pillar workings in salt mines have confirmed these observations. Long-term strength of salt was found that be between 60% and 65% of short term strength. The evaluation of salt pillar behaviour on the basis of critical pillar stress levels was found to be superior to the traditional factor of safety concept because it allows relating pillar deformation measurements to actual pillar conditions. The approach described in the paper was used successfully to evaluate the stability of room and pillar workings in a salt mine and to design strategies to stabilise critical pillar workings."

Jan 1, 2015

By L. C. S. Dharmasiri, S. M. Shin, A. Senaputra, J. S. Sohn, K. H. Park, J. Avraamides

Reducing agents can be applied to leach metal values from natural and secondary resources such as laterite ores and deep sea manganese nodules and recycled materials such as spent batteries / catalysts which contain high-valent metal oxides of manganese, cobalt and iron. Selective leaching of some metals can be achieved by selecting conditions to control the saturated solubility and dissolution rates of metals from oxides or mixed metal/oxide matrices. The leaching results are rationalized on the basis of chemical species, Eh-pH diagrams and heterogeneous kinetic models. The role of reducing agents such as hydrogen peroxide, sulfur dioxide and iron(II) sulphate, in acid, alkali and in the presence of complexing ligands such as ammonia for the improvement of the leaching of metal oxides and metals is discussed. Previous studies on acid leaching of metals from nickel laterites, manganese nodules and spent catalysts/batteries in the absence or presence of reducing agents show that the rate controlling step involves the diffusion of protons through a thickening product layer on the particle being leached. It is shown that the leaching of nickel and cobalt from manganese nodules and zinc-carbon batteries in ammoniacal sulphur dioxide solutions also obey shrinking core kinetics.

Jan 1, 2014

By Dallas W. Davis

Twin - Kennecott Deal Announced April 15, 2004 ! Kennecott earns 56% interest, if in 4 years, spends C$10 million and recovers at least 200 cts of +1 mm diamonds in all dimensions from any contiguous body ! Earn-in can take up to 6 years, but incurs stepped reduction of interest from 56% to 46% or 0% if $C10 and 200 carats not achieved ! By funding all costs through feasibility study, Kennecott earns 71% in 7 years, or, stepped reduction to 62% if completed after 8 years ! By achieving production within 10 years and funding Twin?s share of development and construction costs, Kennecott earns further 4% ! If no election to develop a mine within 2 years of feasibility study completion, Twin may present development proposal which Kennecott has 60 days to elect to follow or transfer management to Twin and dilute to 49% ! Each party has one time right to elect to market its diamond share ! On signing and annually, Kennecott will purchase $C250,000 of Twin shares at 130% of then prevailing market price until achieved earn-in

May 1, 2004

By S. Balideh

A good understanding of the behavior of rock helps us to make more informed decisions regarding geo-structures. Engineers need accurate equations to calculate the strength and deformation of rock before and after failure. Previous studies explain the failure of rock to ultimate strength, and laboratory tests adequately determine the ultimate strength and deformation modulus of rock. However, there are few comprehensive equations to determine the post-failure strength and deformation of rock. Previous work shows that the post-failure behavior of rock depends on the behavior of the broken rock particles after failure. The following question is then posed: How can the post-failure behavior of rock be determined by the behavior of broken rock particles? In order to answer the question, this study pursues three objectives: (i) to explain the behavior of broken rock at low confining pressure; (ii) to estimate the behavior of broken rock via the extrapolation of scaled laboratory testing; and to suggest a procedure (iii) to outline the post-failure behavior of a rock mass at low confining pressure commensurate with the behavior of broken rock in a rock mass.

Aug 1, 2013