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By E Oktay, I Yusufoglu, C Kahruman

Powder and spherical pellets of MoO2 were oxidised under controlled conditions in the temperature range 674-791 K at oxygen partial pressures of 8.1-30.4 kPa. Weight increase during the reaction was determined by thermogravimetric analysis. It was concluded that the reaction is 0.6th order with respect to oxygen concentation and that the activation energy is 148 kJ/mole. In experiments conducted with powder, fast transfer of reaction heat to the gas phase created isothermal conditions, but the temperature of pellets rose by a maximum of 54 K at 674 K and 105 K at 791 K. The rise in temperature caused structural changes such as sintering and crack formation, which had a considerable effect on the reaction rate. The findings should be taken into account in the design of equipment and choice of operating conditions for roasting MoS2

Jun 21, 1905

By M. A. Leosson, S. H. Bottrell, R. J. Newton

Sylvite at Boulby is mined 1 140 m beneath the sea and the mine suffers from the influx of water. This is of two kinds: persistent flows originating in the Sherwood Sandstone aquifer and entering the evaporite sequence through fractures in the intervening mudstone, and impersistent flows which are transient in nature and of uncertain origin. Water from the overlying sandstone has become enriched with NaCl and large amounts of KCl and some Mg and Br have been added by interaction with the evaporites. Waters from the transient flows are isotopically distinct from those in the Sherwood Sandstone, being enriched in H and O. They are also saturated with respect to halite and sylvite, but have higher K/Na than the persistent flows and are much more enriched in Mg and Br

Jun 18, 1905

By G. Adachi, K. Machida, T. Ozaki, K. Murase

The chlorination rate with CCl4 was unexpectedly slower than carbochlorination using chlorine under the same reaction conditions. Chlorination with CCl4 was topochemical and the amount of monazite reacted after different periods suggested that the kinetic control step was the reaction between CCl4 and the monazite core at the interface. The kinetic order of the reaction was 0.5. The presence of a complex former, AlCl3, promoted the chemical vapour transport of rare-earth chlorides as complexes

Jun 18, 1905

By T. Serradj

A study has been carried out to: develop a method for routine characterisation of rock strength and drillability through the particle-size distribution of crushed or drilled rock products, defined by the Protodyakonov index; establish correlations between the Protodyakonov index, uniformity coefficient and the constant grading equations; and propose an alternative rock characterisation index to classify rock strength and drillability for the northeast region of Algeria

Dec 1, 1996

By T. Yalcin

In the Box-Wilson method, the correlation between dependent and independent variables is represented by a polynomial response function, whose constant and coefficients are determined by applying regression analysis to the experimental data collected. The five levels used for each variable consist of a minimum, a maximum and three intermediate values. A study was carried out using Ni-Cu ore from Sudbury, Ontario, in which 15 experiments designed according to the Box-Wilson method were carried out in random order and in duplicate. The two sets of replicate data showed close similarity, with an overall variance of 0.311 for the five parameters studied. The response functions were used to optimise frother dosage, collector concentration and air flow rate and an experiment was then carried out under the optimised conditions; the results agreed closely with those predicted by the response functions

Jun 21, 1905

By A. F. Neil, A. S. Bahaj, P. Watkins, P. M. Hyslop, C. E. Kirby, P. A. B. James

The results of initial work indicate that for 3 of the 5 quarry sands bioleaching reduces the iron oxide content to a commercially acceptable 0.035 wt% Fe20 3, although the time taken to achieve this is 14-22 days against a target leach time of 7 day. Subsequent work has identified strains of Aspergillus niger that are more efficient at producing the array of complexing agents for iron and is yielding excellent and rapid reductions in Fe levels. Potentially, bioleaching offers a more environmentally friendly and energy-efficient process for the removal of Fe from glass-making sands than conventional routes but the production of organic acids by fermentation must be achievable with low-cost substrates such as sugar-beet molasses and lactose permeates for bioleaching to offer a commercially viable alternative to treatment with hot mineral acids. Silica sands usually contain three groups of Fe minerals: iron oxyhydroxides, which comprise crystalline types such as goethite and limonite tending to occur as thin, discontinuous coatings and in cracks and crevices on the surface of the quartz; the assemblage of heavy trace minerals, which include ilmenite, rutile, leucoxene, chromite and haematite, commonly present at levels of 0.1 wt% or less as discrete grains or sometimes cemented to the quartz; and clay minerals cemented in pits on the surface of the quartz and in association with weathered, discrete feldspars. The response of the assemblage of iron minerals to short periods of exposure to hot inorganic acids is broadly related to which group they belong to, those that form coatings being accessible to acid and tending to react rapidly whereas the trace minerals are usually resistant and react very slowly, if at all, and the clays are probably digested. The note reports on a preliminary study of the use of microorganisms to develop an alternative clean technology that will give results comparable to those achievable with hot inorganic mineral acids but with more environmentally acceptable procedures. Various fungi and bacteria produce organic acids when grown in certain media. When these acids come into contact with Fe-stained sand grains the iron is removed as soluble complexes. Several strains of Aspergillus niger have been found to produce organic acids from sugar, predominantly citric, gluconic and oxalic acids, their relative yields depending on cultivation medium and conditions. Sand samples were prepared from five quarries in the UK: Levenseat, Lothian; Redhill, Surrey; King's Lynn, Norfolk; Chelford, Cheshire; and Oakamoor, Staffordshire; ranging in iron oxide content from 0.035 to 0.153 wt% Fe203

Jun 18, 1905

By J. S. Coats, G. E. Patts, N. Hughes

Conventional sampling methods are known to suffer from the variable loss of fine gold by elutriation. Freeze sampling yields representative and quantitative data that, when combined with information on the sedimentology of gravel-bed rivers, may facilitate the development of improved dispersion models for source detection. It is suggested that freeze sampling may have particular application to the orientation stage of a large gold exploration survey

Jan 1, 1991

Two concentrates from Palabora, in South Africa, containing 0.056-0.068% undesirable Cu and 0.8 or 2.2% Ti, were chlorinated with air:chlorine ratios of 10:1, 15:1 and 20:1 at temperatures between 1 200 and 1 329 K. The resulting volatile chlorides were condensed and the solutions analysed for Cu, Fe and Ti. Recovery of Cu was less than 25% at low temperatures and short reaction times, but at 1 258 K almost all Cu was removed from the magnetite at all ratios of chlorine to air. At higher temperatures, the increased carrying over of iron as FeCl3 could be minimised by decreasing the partial pressure of chlorine. No titanium was detected in the volatile products and the percentage of Cu recovered was independent of Ti concentration in the concentrates, though as a function of Cl2 vol%, more Cu was recovered at 1 200 K from the low-Ti than from the high-Ti concentrate. In a fluidised-bed reactor, Cu recovery was 58-90% and iron carry-over less than 10 ppm

Jun 21, 1905

By E. H. Baker

Vapour pressures of sulphur have been measured over the temperature range 340-1039°C by means of boiling-point measurements, an internally heated pressure vessel being employed with argon as the pressure medium. The results are expressed satisfactorily by a four-term pressure-temperature relation. At the cited critical temperature of 1040°C the calculated critical pressure is 204 atm. From the pressure-temperature relation and available thermal data for the vapour, the approximate composition of the saturated vapour in terms of the various molecular species has been derived for the critical point

Dec 1, 1971

By J. C. Griffiths

There are two kinds of problems concerning the elements of a population : the first is to estimate the proportion of some specific kind of element in the population, e.g. the amount of gold in a block of ground (equals population) or the proportion of mercury in a sample; the second is to estimate the length, breadth, volume, etc., of a specific kind of element, e.g. the grain size of quartz grains in a beach sand or the size, shape and arrangement of lenses of ore in an ore deposit. Given a specific objective, a bounded population, identified elements and the element characteristics of interest, it is then necessary to select a sample of the elements from the population and the problem of sampling requires a decision on how to select the sample. It is also necessary to establish, either by heuristic analysis or empirically, based on long experience, the model frequency distribution of the desired element characteristics: in general, constant-probability models are used as models, the binomial or Poisson for count data and the normal distribution for measurements (or their transformed equivalents). The objective of sampling then becomes to obtain an appropriate statistical estimate of the desired population parameter: for example, the estimators may be the mean (X) and variance (a2): these should be unbiased sufficient estimators of their corresponding parameters (u, a2, respectively). Statistical tests are performed in order to determine that the estimators are of the appropriate kind: all statistical tests are designed to test against bias of a specific kind, although they are stated as tests against randomness. Given a random sample of some population, the estimators are usually stable and adequate to solve the sampling problem. Random samples are simple to define but exceedingly difficult to achieve in practice: in selecting a sample, if every element in the population has an equal chance of occurring, then the sample is a random sample. Interaction between the arrangement of elements in a population, i.e. its structure, and the sample selection process frequently introduces bias—that is, some elements have more chance than others of appearing in the sample and, hence, the sample is not random. An algorithm for dealing pragmatically with this aspect of the sampling problem offers one way of achieving random samples and, therefore, adequate estimators. Examples of the use of this algorithm on various kinds of geological populations, in both field and laboratory, illustrate the requirements for solving sampling problems and the achievement of appropriate estimators.

Dec 1, 1971

By L. T. Matthews, C. E. Loo, R. P. Williams

The behaviour of iron ores and fluxes in the high temperature zone of a sintering bed is extremely complex. Following a review of current knowledge, an attempt is made to define relevant terminology to describe the processes that occur in this part of the bed. A deformation temperature is used to quantify the initial formation of melt, which is produced predominantly by reactions between fine particles in the sinter mix. The subsequent assimilation of larger particles is considered to depend on the reactivity of the melt and the assimilation resistance of these particles. Novel laboratory experimental techniques are used to quantify these parameters. Results demonstrate that the properties of the raw materials used have an extremely important influence on the initial processes of melt formation and assimilation and also on the nature of the sintering reactions and sinter-bonding phases.

Jan 4, 1992

By G W. Clamp

The most traum atic event within the lUK coal industry during the last 30 years was its privatisation. Who were the relatively unknown people from RJB: white knights or robber barons? This paper highlights the strong safety and progressive engineering cultures th at existed and continues within the company. A long-term view of the business coupled with proven professionalism is amply developed. Quite dearly, to revert to private ownership is not a return to Victorian values but ‘back to the future’.

Jan 8, 1997

By T Atkinson, A Cobb, R AJIington

Risk management is concerned with the whole spectrum of financial, geological, engineering, legal, governmental, social and occasionally ethnic issues, concerned with mining projects. The inherent risks in mining operations are well publicised, but new issues and hazards arrive on the scene and lake precedence, but the older risks still remain, while insurance cover may not he ‘full cover’ in the future. It has long been recognised that quantitative approaches to risk analysis can play a major role, but although these methods are capable of considerable theoretical precision, the lack of sound risk input data and experienced personnel limits the usefulness of theoretical analysis. It can, however, greatly assist in comparing cases, in identifying areas of risk and help in the investment decision process. Its major contribution to a mining project is that it imposes an investigative discipline that also assists in improving the quantitative approach to risk analysis and hence risk management. Risk analysis and risk management also requires sound common sense and major inputs from experienced geologists, mining, mechanical, electrical and mineral processing engineers. The Engineering Council, in 1992, issued a ten point code of professional practice entitled ‘Engineers and Risk Issues’ (The Engineering Council. 1992), covering our professional responsibilities, the law, our conduct, the need for a systematic approach to risk issues, the use of professional judgement, communications, risk management, evaluation of risk, our professional development in this field and the encouragement of public awareness of risk issues. This is a specific area of training perhaps long neglected by our industry and academic institutions (Atkinson. 1983).

Jan 5, 1996

By P. R. Ineson, D. W. James

For a criterion to be useful it must either demonstrate directly the role of exhalative processes in the formation of a deposit or describe a unique attribute of exhalative deposits. Few of those employed in previous investigations entirely satisfy either condition. The limitations of three of the most frequently employed criteria are illustrated by studies of the geology of the King Island Scheelite deposit in Tasmania.

Jan 12, 1993

By L. J. Barnes, R. O. Koch, J. H. Versteegh, C. J. N. Buisman, P. J. H. Scheeren

Several water treatment options have been studied and piloted. A process based on activity of sulphate reducing bacteria combines sulphate removal and heavy metal removal in one process step. The anaerobic bacteria reduce the sulphate to sulphide and consequently metal sulphides will precipitate. The final design for the commercial scale plant is described.

Jan 12, 1992

By J. H. E. Jeffes, K. T. Jacob

The activity coefficients of oxygen in liquid Pb-Sn alloys have been measured between 550 and 1100°C by use of solid oxide galvanic cells: Pt, Ni-NiO | Zr02 Solid electrolyte | O (Pb + Sn), Cermet, Pt; and Pt, Fe-FeO | Zr02 Solid electrolyte | 0(Pb + Sn), Cermet, Pt. Alcock and Richardson's quasi-chemical equation, with the coordination number of atoms set to 2, is found to predict successfully the activity coefficients of oxygen in these alloys. The relative partial molar enthalpy and entropy of oxygen at 1 atom per cent in the alloys have been calculated from the variation of the activity coefficient with temperature. The addition of Sn to an unsaturated solution of O in Pb is shown to decrease significantly both the partial molar enthalpy and entropy of O. As the measurements were restricted to a narrow range between 750 and 1100°C in Pb-rich alloys, however, the pronounced variation of the partial molar enthalpy of O with temperature at constant alloy composition predicted by the quasi-chemical model could not be verified.

Dec 1, 1971

A study of the thermodynamic properties of magnesium chloride ammines was carried out with the ultimate objective that the thermal decomposition of the hexammine MgCl2.6NH3 may prove successful on a commercial scale for the manufacture of anhydrous magnesium chloride, which is required for the efficient electrolytic production of magnesium. The experimental data are presented in the form of an equilibrium diagram that aids the understanding of the conditions associated with the thermal decomposition of ammines

Jun 13, 1905

By J. H. E. Jeffes, K. T. Jacob

Solid oxide galvanic cells, of the type: Pt,Ni-NiO | Solid electrolyte | O(metal),Cermet,Pt, were used to measure the activity coefficient of oxygen in liquid Cu at 1 100 and 1 300°C and in Pb at 1 100°C. Similar cells were used to study the activity coefficient of oxygen in the whole range of Cu + Pb alloys at 1 100°C and in Pb-rich alloys at 900 and 750°C. The results obtained are discussed in terms of proposed solution models. An equation based on the formation of 'species' of the form M(2)O in solutions of oxygen in binary alloys is shown to fit the experimental data

Dec 1, 1971

By M. G. Fleming

The professional mineral engineer is an individual of personal integrity who has undergone rigorous intellectual instruction in the scientific disciplines fundamental to his vocation; he has learnt to apply these disciplines to the discovery, mining and treatment of mineral resources and, through practical training and experience, has acquired competence and judgment to fulfil his undertakings. In the course of this development he has recognised and accepted a threefold responsibility to society, to his employer and to his profession

Dec 1, 1971

By L. J. Barnes, R. O. Koch, J. H. Versteegh, P. J. H. Scheeren, F. J. Janssen

Following two years of laboratory research with bench scale reactors, a 9 m3 experimental process demonstration reactor was installed at Budelco's zinc refinery to treat their underlying groundwater. A 600-fold scale-up was successfully achieved. It has demonstrated that this anaerobic microbial process can remove a wide range of heavy metals and sulphate to the required levels. Extended operation of the demonstration unit has shown that the process is robust, can withstand wide variations in feed composition, rapidly recovers from operational upsets and is easy to start up and shut down. The metal sludge produced can be processed in a metal refinery to recover both metals and sulphur.

Jan 12, 1992