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By Kousuke Takahata, Hirofumi Yoshimura, Jun Nakahigashi

Studies of a protium treatment for grain refinement of a + ß type titanium alloy are reviewed and recent experimental results are introduced. Protium treatment consists of the following three processes: (1) protium absorption, (2) martensitic transformation and hot working, and (3) final treatment for protium desorption and recrystallization. A combination of these processes results in the ultra-fine grains of 0.3 to 0.5 µm in diameter with high angle boundaries. The ultra-fine-grained material exhibits superplastic elongation of over 9000%. Superplastic forming was successfully used to fabricate a denture base. These materials may be widely applicable as biomaterials in various medical industries.

Jan 1, 2004

By Lastram Rolando, Larry J. Hulbert, Louis J. Cabri, J. H. Gille Laflamme, John L. Campbell, Soey H. Sib, Chris G. Ryan

"The mineralogy of samples from the Wellgreen Cu-Ni-Pt-Pd deposit, Yukon Territory, is complex and the metals of interest are contained within fine-grained minerals which vary in size and mineral associations from sample to sample.The major Ni carriers are pentlandite and violarite; the major Cu carrier is chalcopyrite. About 700/0 of the major Ni carriers and 78% of the major Cu qurier will be liberated at a grind of 80% -U,.7 ,an (-500 mesh) for typical low-grade gabbro (West zone, sample No.1). For typical ""clinopyroxenite"" (West zone, sample No.2) and typical ""clinopyroxene-rich peridotite"" (East zone, sample No.3) the liberation would be 71% and 65% for Ni, 74% and 60% for Cu, respectively. Fine grinding, however, cannot liberate the Ni contained in silicates and pyrrhotite, estimated to total 24.5% for typical low-grade gabbro (West zone, sample No. I), 15% for typical ""clinopyroxenite"" (West zone, sample No.2), and 12% for typical ""clinopyroxene-rich peridotite"" (East zone, sample No.3).The principal Pt carrier (sperrylite) varies considerably in grain-size between samples and fine grinding, required to liberate the major Ni and Cu carriers, may be counterproductive in samples where sperrylite is relatively coarse-grained, as some would then be unrecovered (e.g. sample No. 1). In addition, sperrylite in samples No.2 and No.3 is closely associated with magnetite. Palladium occurs in diverse ways. It occurs in the form of several Pd minerals (e.g. sudburyite, testibiopalladite, merenskyite), as a replacement for Ni in several tellurides, antimonides and tellurantimonides (e.g. melonite), or as very low concentrations in pentlandite (up to 34 ppm), chalcopyrite (up to 9 ppm), and pyrrhotite (up to 5.6 ppm). Palladium minerals and Pd-bearing minerals are strongly associated with chalcopyrite in sample No. 1 and will thus report to a Cu concentrate.However, 22% of the total Pd is in solid solution in pentlandite in this sample and will thus report to the Ni concentrate. In samples No.2 and No.3, less Pd occurs in solid solution in pentlandite, and the PGM are distributed mainly among pentlandite, chalcopyrite, and magnetite in sample No. 2, and among pentlandite, pyrrhotite, chalcopyrite, and magnetite in sample No.3. Therefore, the feasibility of magnetic concentration should be investigated for samples like No. 2 and No.3, in order to improve Pt and Pd recoveries. Rhodium was found to occur as rare hollingworthite, in sparse cobaltite (up to 2.7%) and, as low concentrations in chalcopyrite (to 10 ppm) and pentlandite (to 12 ppm) by proton microprobe. Iridium occurs in hollingworthite (up to 7.8%) and very rarely as the native metal or in an undefined Re-Ir-Qs..Ru alloy. Ruthenium was determined by proton microprobe analyses to occur in pentlandite (up to 13 ppm) and chalcopyrite (up to 10 ppm), in addition to rare laurite and Re alloy."

Jan 1, 1993

By Mark W. Masson, David B. Stevenson, David W. Broughton, Douglas R. Cruji, Steven E. Parry

"Abstract-The Amalgamated Kirkland gold deposit is located at Kirkland Lake, Ontario, within the Archean Abitibi Greenstone belt of the Canadian Shield. It lies on a fault or "break", termed the Cyprus Break, which is a splay off a regional structure termed the Cyprus-Battle Mountain Break. The Cyprus Break merges with the Cyprus - Battle Mountain Break above the -250 m level, as it was not encountered in shallow drilling or surface exploration. These structures lie 1.5 km south of the 727 000 kg (23 million ounce) Kirkland Lake Main Break and 0.5 km north of the 872 000 kg (30 million ounce) Larder Lake Break.The deposit is hosted by alkalic Timiskaming Group volcanic and sedimentary rocks which are overthrust by older Larder Lake Group tholeiitic and komatiitic flows along the Larder Lake Break. Timiskaming syenitic intrusives, similar to the host rocks for the Kirkland Lake Main Break gold deposit, intrude both suites.The Amalgamated Kirkland deposit consists of lode-style gold mineralization which is mainly hosted by altered and pyritized Timiskaming trachytic volcanics which wedge out or thin at depth, between two sedimentary units. The intersection of the Cyprus - Battle Mountain and Cyprus Breaks, in conjunction with the westward plunge of the volcanic wedge, appears to control the westerly plunge of the Amalgamated Kirkland deposit at approximately 50º.Mineralization is characterized by blue-gray brecciated and "wormy" quartz-ankerite veins which contain up to 10% fine-grained pyrite and, in decreasing order of abundance, minor galena, chalcopyrite, sphalerite, molybdenite and visible gold. The sulfides and gold commonly occur along fractures and wallrock inclusions within the veins. Native gold occurs as fine pinpoints distributed in 1-mm to 5-mm size clusters of up to ten or more grains.The auriferous veins occur within a quartz-ankerite-sericite-pyrite alteration assemblage which is enveloped by a broader zone of ankerite-sericite±hematite±quartz-pyrite alteration up to 60 m wide. This latter assemblage overprints the regional greenschist-facies chlorite-calcite assemblage.The Amalgamated Kirkland property has had a long history of exploration activity beginning with the first discovery of mineralization in 1911 on the Hunton Shaft claim located in the northeast corner of the property. Since that time various prospecting, mapping, trenching, geophysical surveys and diamond drilling programs have concentrated on either carbonate zones along the Larder Lake Break or quartz veins along the northern side of the property in association with complex trachyte flows and syenite dikes.Battle Mountain Canada Inc. located the Cyprus - Battle Mountain Break through a prospecting, trenching and geophysical program in 1989. Drilling by Battle Mountain and Cyprus Canada under the surface showing, coupled with several revisions to the structural interpretation of the Cyprus - Battle Mountain and Cyprus Breaks, resulted in delineation of the Amalgamated Kirkland deposit. Location of an auriferous structure through basic surface exploration within 1 km of a world-class orebody demonstrates both the subtle nature of Archean gold deposits and the potential for finding new mineralization in heavily prospected camps."

Jan 1, 1995

By Mark W. Masson, David B. Stevenson, David W. Broughton, Douglas R. Cruji, Steven E. Parry

"The Amalgamated Kirkland gold deposit is located at Kirkland Lake, Ontario, within the Archean Abitibi Greenstone belt of the Canadian Shield. It lies on a fault or “break”, termed the Cyprus Break, which is a splay off a regional structure termed the Cyprus-Battle Mountain Break. The Cyprus Break merges with the Cyprus – Battle Mountain Break above the -250 m level, as it was not encountered in shallow drilling or surface exploration. These structures lie 1.5 km south of the 727 000 kg (23 million ounce) Kirkland Lake Main Break and 0.5 km north of the 872 000 kg(30 million ounce) Larder Lake Break.The deposit is hosted by alkalic Timiskaming Group volcanic and sedimentary rocks which are overthrust by older Larder Lake Group tholeiitic and komatiitic fows along the Larder Lake Break. Timiskaming syenitic intrusives, similar to the host rocks for the Kirkland Lake Main Break gold deposit, intrude both suites.The Amalgamated Kirkland deposit consists of lode-style gold mineralization which is mainly hosted by altered and pyritized Timiskaming trachytic volcanics which wedge out or thin at depth, between two sedimentary units. The intersection of the Cyprus – Battle Mountain and Cyprus Breaks, in conjunction with the westward plunge of the volcanic wedge, appears to control the westerly plunge of the Amalgamated Kirkland deposit at approximately 50º.Mineralization is characterized by blue-gray brecciated and “wormy” quartz-ankerite veinswhich contain up to 10% fne-grained pyrite and, in decreasing order of abundance, minor galena,chalcopyrite, sphalerite, molybdenite and visible gold. The sulfdes and gold commonly occur alongfractures and wallrock inclusions within the veins. Native gold occurs as fne pinpoints distributed in 1-mm to 5-mm size clusters of up to ten or more grains.The auriferous veins occur within a quartz-ankerite-sericite-pyrite alteration assemblage which is enveloped by a broader zone of ankerite-sericite±hematite±quartz-pyrite alteration up to 60 m wide. This latter assemblage overprints the regional greenschist-facies chlorite-calcite assemblage.The Amalgamated Kirkland property has had a long history of exploration activity beginning with the first discovery of mineralization in 1911 on the Hunton Shaft claim located in the northeast corner of the property. Since that time various prospecting, mapping, trenching, geophysical surveys and diamond drilling programs have concentrated on either carbonate zones along the Larder Lake Break or quartz veins along the northern side of the property in association with complex trachyte flows and syenite dikes.Battle Mountain Canada Inc. located the Cyprus – Battle Mountain Break through a prospecting, trenching and geophysical program in 1989. Drilling by Battle Mountain and Cyprus Canada under the surface showing, coupled with several revisions to the structural interpretation of the Cyprus –Battle Mountain and Cyprus Breaks, resulted in delineation of the Amalgamated Kirkland deposit. Location of an auriferous structure through basic surface exploration within 1 km of a world-class orebody demonstrates both the subtle nature of Archean gold deposits and the potential for finding new mineralization in heavily prospected camps."

Jan 1, 1995

By S. Esmaeili

The yield strength model developed by Esmaeili, Lloyd and Poole [1] has been adapted to model isothermal aging in Cu-containing AA6xxx alloys, with (a) a moderate and (b) a very low Cu content in the solution-treated, as-quenched, condition, Isothermal calorimetry has been used to analyze the kinetics of precipitation in these alloys, While the kinetic parameters for the low Cu alloy has been derived from the present experiments, the previously determined kinetic parameters for the high Cu alloy AA6111 has been used to model the precipitation kinetics in the moderate Cu alloy. The age hardening responses of both alloys have been well predicted by the model.

Jan 1, 2005

By A. I. A. Salama, M. W. Mikhail

"A comprehensive software package has been developed at the Western Research Centre to meet many of the coal preparation requirements in the Canadian coal industry. This package performs three main functions: (1) data handling and manipulation; (2) data analysis, including the generation of washability data, performance evaluation and prediction, density and size modelling, evaluation of density and size partition characteristics, and attrition curves; and (3) graphics output.The software described in this paper is potentially a valuable tool for coal preparation plant engineers and operators for evaluating process performance and adjusting plant density separator cutpoints. Moreover, the analytical laboratory technician could find this package very useful in manipulating and presenting laboratory results."

Jan 1, 1997

By A. Singh

Deformation structures after tensile and compression tests on Mg926Zn64Y alloy extruded at 250°C and 400°C are studied, in as-extruded and heat treated conditions. The icosahedral phase particles stimulate recrystallization during extrusion, resulting in fine grain size. Tensile and compression tests at room temperature show comparable yield strength, with a yield asymmetry ratio up to 0.98. c-type dislocations are observed in the grains near the submicron size icosahedral phase particles. The source of these dislocations is believed to be dissociation of <c+a> type non-basal dislocations. No dislocation pile-ups on icosahedral phase particles are found. {10 1 2} type twinning occurs in compression.

Jan 1, 2006

By Michele L. Kimble

A fast-flow reactor mass spectrometer has been utilized to investigate the reactions of gas-phase gold cluster anions with CO and oxygen. Addition of CO to Aun - produces species of the form Au(CO)m -, where m = 2-5. However, CO does not bind to Au2 - or Au3 -. With oxygen addition in the cluster source, gold oxide species with both molecular and atomized oxygen are produced. The addition of carbon monoxide to these preoxidized gold cluster anions reveals that select species with 1, 2, and 3 gold atoms participate in the oxidation reaction to produce CO2. Bimolecular rate constants for the reactions between these species and CO are also discussed.

Oct 1, 2003

By Shae K. Kim

The aim of this study is to manufacture magnesium alloys with alkaline earth metal oxides (BeO, CaO, MgO or SrO) additions with the objectives of (1) ensuring safety during processing and applications by raising the ignition temperature and reducing oxidation, (2) protecting the environment by reducing or eliminating use of protective gases, (3) maintaining or improving elevated temperature properties with lower amount of Ca or Sr or rare earth metals when compared with conventionally developed high-temperature magnesium alloys, (4) developing cleaner strip casting and continuous casting processes without hot tearing and (5) obtaining all of these objectives without sacrificing mechanical properties or increasing the cost of magnesium alloys.

Jan 1, 2006

By F. Parada

During copper smelting and converting processes, slag generated is pyrometallurgically cleaned and then disposed, containing around 1 % of this metal. However, important amount of molybdenum initially contained in concentrates also goes to the slag phase. Research on molybdenum recovery from water granulated slags using acid leaching at low temperatures was conducted to find an efficient way for molybdenum extraction with lower magnetite in the slag. However because of the high fayalite content high acid consumption was found. Molybdenum can be recovered from solution using ionic exchange resins, but high silica content interferes with extraction. Some studies addressed to minimize silica extraction as well as alternatives of selective silica precipitation in order to develop a technically feasible process.

Jan 1, 2007

By Ian L. Price

Description of the Springhill Coal Field The Springhill coal basin, which lies in the approximate centre of Cumberland county, Nova Scotia, is of Carboniferous age, and forms a syncline plunging to the westward at an angle of 32° at the outcrop but gradually flattening to the dip. It contains several workable seams of varying thicknesses, a generalized section of the measures in descending order from the surface being: [] The 1,114 feet of strata is composed of shales and sandstones, and all of the coal seams mentioned, with the exception of No. 4 and No. 5, have been mined commercially. The coal is said to be the best steam and domestic coal in the Province of Nova Scotia.

Jan 1, 1946

By RAYMOND C. HARTVIKSEN

The Drumbo Mine is located near Highway 401 between Woodstock and Kitchener in southwest Ontario. The tabular flat-lying gypsum bed is between 1.5 to 2.4 m thick and is situated near the base of the Salina Formation, about 116 m below surface. The mine is owned and operated by Westroc Industries Limited. The 3.8 m diameter shaft was drilled using a Hughes CSD 820 drilling rig and a liner sinking technique new to the North American continent. The shaft was completed in the fall of 1977, and remaining facilities were finished in the fall of 1978. Gypsum production started in December 1978, employing the conventional room-and-pillar method of mining.

Jan 1, 1984

By D. Murray

A 2-hectare uranium tailings area has been reclaimed. The exposed tailings of 1.4 hectares were capped with glacial till and vegetated with grasses and legumes. The water running through the tailings was diverted around the tailings in a line ditch and treated with sodium hydroxide and barium chloride. Difficulties occurred in placing the till capping because of the low bearing strength and the uneven surface of the tailings. This led to varying thicknesses of till and the need for manual labour in some areas. Total reclamation costs were $32,200, with vegetation establishment costs at $13,700 per hectare. This report provides a record of work for use in assessing the long-term suitability of these treatments.

Jan 1, 1979

By J. H. Baek, D. W. Lee, B. K. Kim

Nanostructured Cu-Al203 composite powders were synthesized by thermochemical process for an electrode application. The synthesis procedures are 1) preparation of precursor powder by spray drying of solution made from copper and aluminum nitrates, 2) heat treatments to evaporate volatile components in the precursor powder and synthesis of nanostructured CuO+Al2O3, and 3) CuO reduction by hydrogen into Cu. The suggested procedures stimulated the formation of the gamma-Al2O3. The mean particle size of the final composite powders was 20nm, and the electrical conductivity and hardness in the hot-extruded bulk were competitive with Cu/Al2O3 composite by the conventional internal oxidation process.

Jan 1, 2004

By R. von Bonsdorff

Electrochemical and quartz crystal microbalance (QCM) methods were used to investigate the dissolution rate of gold in a solution similar to those utilized by the Outokumpu HydroCopper® process. The measurements were conducted in an electrolyte solution where [NaCl] = 2.8-280 g/L, pH = 1-2.5, [Cu2+] = 0-30 g/L and T = 70-95°C. According to these measurements, the solution flow has the greatest impact on the dissolution rate of gold in the HydroCopper® process. Under adequately acidic conditions (pH < 3), the dissolution rate of gold increases with increasing cupric concentration, increasing chloride concentration and increasing temperature. The results and trends observed compared well with the literature.

Jan 1, 2007

By M. Azzaz

In this paper, we report on new mechanical tests, at high temperatures, performed with a supposed better aluminium nitride (A1N) material, containing fewer oxygen. Our purpose was twofold: (i) check whether creep resistance is modified and hopefully enhanced and (ii) determine the elementary mechanisms controlling plastic deformation through transmission electron microscopy (TEM) observations of deformed samples up 10% strain in compression at elevated temperatures (1823-1923 K) under constant stress in the range 150¬250 MPa. Stationary rates are lower by an order magnitude than those previously measured in MN with higher oxygen content. All dislocations imaged by TEM look undissociated, which clearly relates the formerly observed wide dissociation to oxygen in excess.

Jan 1, 2004

By Fathi Habashi

Teaching mining, metallurgy, and geology preceded that of the other engineering disciplines. The first School of Mines was founded in 1756 in Potosi (Fig. 1) in New Spain (now Bolivia), 38 years before the first Polytechnic School (École Polytechnique) was founded in Paris. The schools of mines were also pioneers in the teaching of chem- istry. The teaching staff at these schools cre- ated the basic literature on metallurgy, mining, and geology. They analyzed and dis- covered numerous minerals and discovered the metals tungsten, beryllium, chromium, uranium, zirconium, vanadium, indium, and germanium. The history of some of the first schools is given together with biographies of some of their distinguished teaching staff.

Nov 1, 1997

By Y. Turen, Y. Karakas, E. Candan, C. Sahinturk

In this study, wettability between sprayable tundish lining (MgO) and molten steel was investigated by using sessile drop method. Content of glass fiber (SiO2) in the MgO varied between 0 to 8 wt% whereas mean particle sizes of the MgO were 25, 75, 150 and 300µm. Experimental results revealed that contact angle (0) of sessile drop on the MgO was not altered by the addition of glass fiber up to 1 wt.% whereas above 2 wt.% addition decreased the 0 considerably. Contact angle, 0, increased considerably with increasing MgO particle size. SEM analysis showed deposition of glass phase was present at the interface as the finer MgO particles were used.

Jan 1, 2004

By C. S. Touchard, F. Bourgeois, L. Cassayre, Julcour-Lebigue C.

Developing a hydrometallurgical process that can overcome the refractory nature of chalcopyrite (CuFeS2) to leaching still eludes the minerals industry, despite major research efforts spanning decades. The several leaching experiments of this ore in sulfuric acid tend toward the same conclusion that the precipitation of elemental sulfur or iron containing species are the main dissolution inhibitors. Describing both the electrolyte composition and the various solid phases in equilibrium for the Fe-H2SO4-H2O system is essential to overcome this issue and to find an operating window. According to the thermodynamic models and to the thermodynamic data, we demonstrate, in this study, the need to use the Specific ion Interactive Theory (SIT) model to describe complex electrolytic systems through a limited number of parameters. Hence, the binary interactions for our case study have to be defined and estimated. This work develops a methodology to determine these parameters of the SIT model up to 90°C and an acid concentration of 1 mol/kg from published data for H2SO4-H2O and Fe(II)-H2SO4-H2O sub-systems or from new experimental data for the Fe(III)-H2SO4-H2O one. This method will eventually be applied to copper systems to lead to a thermodynamic description of the complete CuFeS2-H2SO4-H2O system. INTRODUCTION A leaching process consists in the dissolution of a solid phase into an aqueous medium in order to extract compounds of interest. It is a key step in the hydrometallurgical processes used in the primary production and recycling of metal components. One of the main leaching issues is the formation of passivating layers on the surface of solid particles, whose consequence is a partial or total hindrance of the dissolution. The leaching of chalcopyrite (CuFeS2) in sulfuric acid is a prime example. No industrial solution for the atmospheric pressure leaching of this ore has been developed to date because of passivation phenomena caused by the formation of elemental sulfur or iron-containing precipitates on the surface of the particles (Li, Kawashima, Li, Chandra, & Gerson, 2013). In the 1970s, the Pourbaix diagrams established for the Cu-Fe-S-H2O system at 25°C for low concentrated solutions (Garrels & Christ, 1965; Peters, 1976) agreed that copper and iron are fully dissolved at high potential and in acidic medium (pH < 4). However, they neglected the many stable solid phases that can form in these conditions. In addition, the Pourbaix diagrams of chalcopyrite in water, calculated with two recent databases (FactPS and Thermoddem 2017) associated to FactSage and PhreeqC softwares respectively, show large discrepancies at 75°C (Figure 1). Indeed, at high potential, FactSage predicts the formation of goethite FeOOH at a pH value of 1, while PhreeqC predicts the formation of jarosite (H3O)[Fe3(SO4)2(OH)6] for pH greater than 2.5.

Jan 1, 2019

By L. E. Young

"The Red Dog deposit of the western Brooks Range, Alaska was discovered in the 1970s. Two mineralized areas are present, the Main and Hilltop deposits. With indicated and inferred reserves of 77 million tonnes of 17.1% zinc, 5.0% lead and 82 g/ tonne silver, the Main deposit of Red Dog represents one of the world&apos;s largest zinc-lead deposit s. Since serious evaluation by Cominco commenced in 1980, a better understanding of deposit geology has been gained through 10 715m of diamond drilling and concurrent geologic, geophysical and geotechnical studies. The Red Dog deposit is of Mississippian to Pennsylvanian or Early Permian age, and straddles a redox transition in fine-grained and chemical sediments of the Red Dog structural sequence.The Main deposit has been modified by regional Mesozoic thrust faulting and isoclinal folding, resulting in complex interrelationships between silica rock, sulphide rock and barite. Multiple lines of evidence suggest the Main deposit contains both a syngenetic stratiform and a replacement component. Ore fluids were probably derived by regional lateral movement of brines through a coarse clastic footwall aquifer, then upwards along block faults to the site of the Red Dog deposit.Historical PerspectiveThe region in the vicinity of the Red Dog deposit (Fig. 1) was first prospected by J. W. Kelley in the late 1880s (Orth, 1967). The first coordinated inland exploration was conducted by the U.S. Geological Survey in 1910-1911 and 1923-1926 (Smith, 1913; Smith and Mertie, 1930). The earliest reports of zinc-lead mineralization in the region include reference to samples collected at unknown locales by Eskimo prospectors (Anderson, 1944). In 1955 stratiform pyrite was discovered 19 km west of Red Dog by I.L. Tailleur of the U.S. Geological Survey (Tailleur, 1970). The first reported visit to what is known as Red Dog was by I.L. Tailleur in 1968, who was field checking a colour anomaly noted by B. Baker, a local bush pilot (Tailleur, 1970; Moore et al., 1986) ."

Jan 1, 1989