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By D Teyhan, J Kirsch

Traditionally, most Australian iron ore mining operations have been surface-based. Processing plants were designed to handle dry ores. In recent years mining operations in the Pilbara have progressively moved below the water table exposing wet, sticky ores which have caused lost efficiency in screening operations as particles tend to agglomerate and adhere, blinding screening media. Miners and vibrating screen manufacturers have experimented with a shift from linear motion to elliptical motion screens. Elliptical motion conveys and lifts particles. Effective on flat deck (horizontal and inclined) or sloping decks it can be configured to provide a controlled transport rate, applying pressure in all directions to maximise screening efficiency. In practice, elliptical motion screens have proven to be effective in dislodging sticky particles from screening media, reducing blinding rates and improving screen efficiency. Moisture and clay content change during the life of a mine. These changes are sometimes the effect of seasonal rainfall, in other cases due to increased groundwater and clay content as mining operations go deeper. To compensate for such changes and optimise screen efficiency, changing the ‘shape’ of elliptical screen motion is required. This has traditionally required shutting down processing plants and making mechanical screen adjustments. Plant downtime is costly and machine adjustment has been a ‘trial and error’ practice. This paper will explore the results of a field trial that is currently underway in Brazil of a next generation elliptical motion screen design that allows operators to make changes to exciter rotational direction, speed and screen stroke angle, through electronic drive phase control. The machine’s electronic drive system synchronisation is enhanced for stability with a unique mechanical timing system. Operating at up to 6 g, screen adjustments can be made on the fly without stopping production. Early trial results are showing up to 50 per cent improvement in screen efficiency compared with traditional elliptical motion machines under certain feed conditions.

Nov 8, 2021

By D Teyhan, J Kirsch

Traditionally, most Australian iron ore mining operations have been surface-based. Processing plants were designed to handle dry ores. In recent years mining operations in the Pilbara have progressively moved below the water table exposing wet, sticky ores which have caused lost efficiency in screening operations as particles tend to agglomerate and adhere, blinding screening media. Miners and vibrating screen manufacturers have experimented with a shift from linear motion to elliptical motion screens. Elliptical motion conveys and lifts particles. Effective on flat deck (horizontal and inclined) or sloping decks it can be configured to provide a controlled transport rate, applying pressure in all directions to maximise screening efficiency. In practice, elliptical motion screens have proven to be effective in dislodging sticky particles from screening media, reducing blinding rates and improving screen efficiency. Moisture and clay content change during the life of a mine. These changes are sometimes the effect of seasonal rainfall, in other cases due to increased groundwater and clay content as mining operations go deeper. To compensate for such changes and optimise screen efficiency, changing the ‘shape’ of elliptical screen motion is required. This has traditionally required shutting down processing plants and making mechanical screen adjustments. Plant downtime is costly and machine adjustment has been a ‘trial and error’ practice. This paper will explore the results of a field trial that is currently underway in Brazil of a next generation elliptical motion screen design that allows operators to make changes to exciter rotational direction, speed and screen stroke angle, through electronic drive phase control. The machine’s electronic drive system synchronisation is enhanced for stability with a unique mechanical timing system. Operating at up to 6 g, screen adjustments can be made on the fly without stopping production. Early trial results are showing up to 50 per cent improvement in screen efficiency compared with traditional elliptical motion machines under certain feed conditions.

Aug 24, 2022

By Gao K, Wu C, Langley J. M, Waugh B, Farrell K

The dissolution of carbon from carbonaceous materials into molten iron is a key step in various ironmaking operations. For example, in new direct smelting processes, carbon in the form of coal is injected into the molten iron bath, which leads to the dissolution of carbon. In foundry operations, typical recarburizer materials can range from high purity graphite to chars. The dissolution performance of these" materials is critical to the operation and could dictate the efficiency and economics of the process.Dissolution kinetics has been studied by various investigators to explain the influence of melt conditions and carbon type (Sahajwalla et al, 1994; Shigeno, Tokuda, and Ohtani, 1985; Orsten and Oeters; 1988; Ganguly and Reid, 1992; Wright and Taylor, 1993). The influence of melt sulphur content on the dissolution kinetics has been characterised (Sahajwalla et al, 1994), with sulphur retarding the rate of carbon dissolution. The carbon dissolution from different sources is seen to vary significantly even under similar melt conditions. This observation has been explained by investigators on the basis of the varying ash content present in the carbonaceous materials. However, ash content alone cannot account for the variability in dissolution kinetics reported in other studies. One such study is presented below.In a recent study (Sahajwalla et al, 1994), pulverised carbonaceous materials were injected into the molten iron bath and the" dissolution kinetics was established. The dissolution of graphite and glassy carbon, which contain almost 100 per cent carbon, was seen to be significantly different when the molten iron contained sulphur. The influence of melt sulphur content was explained on the basis of different wetting behaviour observed.Importantly, the study showed that even pure carbon sources dissolved at significantly different rates. Hence, their performance could not be explained on the basis of ash content.The key difference between graphite and glassy carbon is in their atomic structure. Graphite is highly ordered whereas glassy carbon has relatively poor ordering in its atomic structure. This study showed that the atomic structure in carbonaceous materials can have a significant effect on their dissolution performance.The focus of the present investigation which stems from the past study described above (Sahajwalla et al, 1994), is to investigate the influence of atomic structure of carbonaceous materials on their dissolution into Fe-C-S melts.The specific objective of this study is to determine the relationship between dissolution kinetics and crystallographic character of carbon sources. In order to accomplish this goal, a range of different materials representing a spectrum of carbon sources have been chosen for the investigation. These materials include brown coal char, two types of Auscarb (A and B), and commercial graphite. Auscarb is prepared by calcining Auscoal at 1000°C. Auscoal is made from chemically cleaned Australian coals (Bowling, Chandler and Waugh, 1990). Part 1 of this paper details the dissolution performance of the materials studied, while Part 11 describes the X-ray diffraction study. The relationship between the atomic structural dimension and dissolution rate constant is discussed in light of the results obtained.

Jan 1, 1996

By S DeKruijff

The Mount Isa Mines Copper Mine in Mount Isa started producing copper in 1966. The Copper Mine gradually increased production rates to nearly six million tonnes per year. Over the last three years the mine has been in a gradual ramp down due to the reduction of primary ore sources and head grade. The majority of ore sources are predominantly in pillar retreat sequences bounded by multiple fill masses. There also a substantial lower grade resource delineated to the south of the main orebody. These remaining ore sources present significant engineering challenges to obtain a safe and cost-effective extraction. Stope designs have become increasingly complex and require additional engineering and operations input and analysis. This paper describes the major planning and operational challenges and issues associated with the stope design and extraction of an orebody in the later stages of mine life.

Jan 1, 2000

By H Chalcraft, T D. Mullen

Conditions encountered at a recently completed brownfields mining project provided valuable insight into, and development of, techniques for working in and around known underground mining voids in an open cut environment. The careful application of underground blasting principles to a pit environment and successful excavation whilst maintaining appropriate stand-off distances were two primary areas of innovation enabling the success of the project.Mary Mac Hill is a gold deposit situated less than 2 km south-west of the town of Laverton, Western Australia. It is owned and mined by Crescent Gold Limited. Previous underground mining by various other mining companies has left an extensive network of underground horizontal development, subvertical stopes and shafts, some of which daylighted at surface. This was identified as potentially posing substantial risks, which would prevent the application of conventional mining methods. Two major stopes were located under a hard banded iron ridge topped by a peak of cap, connected variously by narrow drives and vertical development. Due to the proximity of the first of these stopes to the surface, its dimensions and governed by procedures and advice provided by externally engaged engineers, Crescent Gold could not access the area of the ridge immediately overlying the stope using conventional open cut mining methods. This was the first of many hurdles surmounted in mining this deposit.The following report outlines how the challenges this geometrically complex deposit presented. Solving these problems enabled the team to mine the contained gold ore to a completed design, without subjecting personnel or mining equipment to harm due to a void breach incident. This paper outlines the numerous complications and difficulties Mary Mac Hill posed and explains the strategies developed to overcome them. The report also presents technical mass blasting details explaining two of the critical crown pillar blasts.CITATION:Mullen, T D and Chalcraft, H, 2012. Mary Mac Hill - The challenges and strategies of successful open cut mining: A complex underground gold deposit riddled with a network of complicated voids, in Proceedings Eighth Open Pit OperatorsÆ Conference , pp 89-96 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 18, 2012

By Littlewood E

We offer these notes as a practical contribution. All the arguments we advance have been tested by practical experience.In its preparation we realised that our subject was one of such importance and covered so wide a field that, dealt with by one of us alone, it might easily have been too much for him, so we have endeavoured, by mutual criticism and advice and a pooling of ideas, to bring forward a few points that may be of advantage to members. If any of the paper is of benefit to mining on the "Golden Mile," or elsewhere, we shall feel amply repaid for our efforts.It is obvious to all that the longer the machine is working productively per shift the greater the return, to all concerned; the machine-man himself and the company. Furthermore, if a man commences a shift with a definite objective in view; for instance, to bore and fire a specific cut, which he recognizes will give him a good financial return, then that man will exercise all his capabilities to attain that objective.In this paper we hope to demonstrate the value to the machine-man of the knowledge of the capabilities of each hole he bores, so that he will be enabled to utilize his drilling time to the greatest advantage. Also, we hope to show that such drilling time can be advantageously extended.After the war, with the influx of new men to the industry, some education on the finer points of machine work may be desirable, and any instruction in this branch must stress the realization of the value of each hole.We realise that most of those present have a sound workable knowledge of machine-mining, and we are not trying to teach anyone the fundamentals of machine work, but we would like to bring to their attentIon some of the finer points which we believe are very important.The machine-man has control of gear of a capital value of over £150, and the use or misuse of that material has a direct bearing on working costs. Therefore it is imperative that the capital outlay is gainfully employed.A "bogger" in charge of a 5/- shovel engaged unproductively is bad enough. How much worse for £150 worth of gear to be not fully productive.Figs. 1 and 2 demonstrate angles of break, and the full realization of the importance of this angle is essential to our paper. Although these Sketches are two-dimensional, we hope they will be sufficient to demonstrate our meaning. We will pass over them as briefly as possible.Fig. 1 shows three holes asked to perform an identical task.(a) 7-ft. hole bored 2 ft. into solid ground-will not come out.(b) 4-ft. hole bored 1 ft. from solid ground-will come out easily.(c) 5-ft. hole bored to solid ground-the best that can be expected under general conditions encountered.The angle of break is a right-angle, normal to direction of hole.

Jan 1, 1944

By S Mitra, D O’Dea, N Barrett, S, T Honey, M M. Hoque

The steel industry is currently exploring hydrogen-enriched blast furnace operations as a means to reduce the greenhouse gas emissions. However, there is a need to investigate the gas permeability behaviour of mixed burdens comprising of lump and sinter as the current knowledge regarding their behaviour is limited, particularly with regards to hydrogen enrichment. In the present study, a series of interrupted softening and melting (S&M) under load tests were carried out in a hydrogen rich gas environment (~15 per cent) in the temperature range from 1000 to 1300°C by placing different types of ferrous ore layer including Newman Blend Lump (NBLL), sinter and sinter-NBLL mixed burden in between two coke layers. X-ray computed tomography (CT) was then used to scan the interrupted test samples. Scanned images were first analysed using an image processing workflow implemented in ImageJ and the material simulator GeoDict (v2022) to segment different phases such as coke, ferrous and void based on their grey scale values. A quantitative analysis was then performed on the segmented images to estimate the phase volume fraction as well as bed permeability. Bed void fraction thus obtained agreed well with the bed contraction data obtained from the S&M test. It was further noted that both ferrous layer void fraction and bed permeability decreased linearly with increasing temperature for all ore samples. The mixed burden voidage changed in a similar fashion to the sinter, demonstrating a high temperature interaction between the two materials

Sep 18, 2023

By X Li, M-F Zhou

"An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation. The Yinachang deposit in south-west China contains large amounts of Fe, Cu and rare earth elements (REEs). Apatite in this deposit records complex REE mineralisation and remobilisation processes.Fe-Cu-(REE) mineralisation at Yinachang occurred at ~1700 Ma, and three stages of alteration and mineralisation are identified: Na-(Fe) alteration, Fe-(REE) mineralisation and Cu-(REE) mineralisation. In the Fe-(REE) mineralisation stage, REE-rich apatite formed together with magnetite. In the Cu-(REE) mineralisation stage, fluids undersaturated with REEs interacted with early-formed REE-rich apatite, during which large proportions of REEs, especially light REEs (LREEs), were leached from apatite.At ~840 Ma, apatite experienced a second interaction with fluid. In that process, REEs were removed from the apatite structure but immediately reprecipitated into new phases within the apatite. Thus, numerous REE mineral inclusions including bastnaesite, monazite and minor Y-phosphate occur in the apatite. There are also a very small portion of LREEs that were transported out of the apatite, resulting in the growth of bastnaesite and monazite grains outside the apatite.This study demonstrates that REEs can be mobilised in multistage hydrothermal activities and highlights the significance of fluid compositions for REE transportation and deposition behaviours in hydrothermal systems.CITATION:Li, X and Zhou, M-F, 2015. Hydrothermal rare earth element mobilisation processes in the Yinachang Fe-Cu-(REE) deposit, south-west China, in Proceedings PACRIM 2015 Congress, pp 265–270 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Mar 18, 2015

By S Sullivan

The key skills for a competent geologist are observation, documentation, analytical thought and the ability to communicate. These attributes have served the geological world for the past two centuries since the field of geology was separated out from natural philosophy. The understanding of the structural setting, lithologies, alteration and 3D distribution of the target mineral species are essential precursors to resource evaluation and potential economic extraction. The advent of artificial intelligence and machine learning has matured to the point where observation by dedicated sensors and analysis by customised AI algorithms can replace manual processes and deliver credible results. In combination with analytical data such as assays, various sensors now collect physical properties of rocks which are used as proxies for mineral identification and rock mass classification. These sensors include X-ray and infra-red spectra, magnetic susceptibility, gravity/density, EH/pH measurements, conductivity, colourimetric readings, porosity, fracturing and fracture intensity. Analysis using machine learning techniques trained using known data sets can determine rock type classification, rock density, quantification of grade/quality attributes, mineral alteration, weathering and geotechnical attributes such as rock quality. This type of data relies on calibration and quality control of a variety of different types of electronic hardware. The resulting data is non-additive, has error ranges and will be suitable for consumption by fast AI methods providing probabilistic analysis. A second stage could include geometallurgical constraints to provide an ‘extractability index’, which is of more interest to miners than pure geotyping. Using resultant interpreted geological criteria, 3D domain models with spatial attributes will be built.

Sep 1, 2024

By I Gipps

Each of us has a vision of what the future mine will be and, generally, these visions have many similarities and some differences. One of the major discrepancies in visions of the future mine is not the ultimate goal but the path to achieve it. Many of the future concepts require a radical re-thinking of how things are and will be done yet. So how do we reach this visionary future mine? We need a path that satisfies both our future aspirations of a high tech gee-whiz operated from our iPads and the unfortunately mundane approach that says ‘we must know the method works, ie nothing new’.This paper explores how, within a research based organisation, we firstly set our ultimate goal and then divide the path into realistic technology development chunks that would appeal to mining companies to progress within their organisational constraints. Through examples, such as, automated LHDs, communications systems, surveying and localisation, rock cutting and geological sensing, we illustrate how this path will get us from the here and now to the out there future.This paper also demonstrates CSIRO’s short, medium and long-term research in many of the areas needed to create the Future Mine: mining methods, automation and remote control, mine communications, mapping and mission planning, geological sensing and, importantly, human-system integration, which examines how to effectively present data as information to operators and supervisors in an intelligent and useful manner.

Nov 22, 2011

This paper explores options worthy of consideration in the management of S02 produced from the gold roasting operations at Kalgoorlie. Some of the options have relevance to other sources of SO2 in the region, eminating from nickel smelting operations. The paper considers the following options: 1. Capture of SO2 within the roaster where sulphur-containing reaction products are mixed with the calcine. 2. Processes in which the sulphur-containing products are bled separately from the stack for further treatment or for dumping as a waste. These include: Seawater-based scrubbing of SO2; Sulphuric acid manufacture as a feedstock for fertiliser production or for leaching of bauxite; its use as Caro's acid: and the production of value-added sulphur-containing reagents eg liquid S02 and sulphonic acid.

Jan 1, 1992

By S Fityus, K Koosmen, J Simmons

The purpose of this paper is to therefore investigate the hydrogeological characteristics of tailings, coarse and mixed rejects from coal processing to enable better understanding of the potential for undrained behaviours in coal mine spoil piles. This is achieved by analysing the results from permeability and oedometer testing of tailings, coarse rejects and mixtures thereof. Focus is given to the effect that tailings content has on the behaviour of mixed rejects, the transition point between drained and undrained material behaviours, and the evolution of properties with increasing stress that would occur with increased depth of burial in a mine spoil pile. The implications of the findings are discussed with respect to spoil pile stability.

Jul 1, 2021

By D Audeyev

The Cooljarloo North Mine has been shaped not only by operational and processing challenges, but by climatic and economic factors. This paper outlines some of these challenges and discusses how the operating strategy has been altered over time to mitigate the impacts.Since commissioning the wet concentrator in 1999, there have been many typical operational challenges to maximising valuable heavy mineral (VHM) recovery. These include: varying in pit feed grades, different slimes types and volumes, sizing extremes between VHM and trash minerals and decreased equipment reliability handling rocky ore. These issues were successfully mitigated by: in pit extraction strategies, upgrade of the de-sliming circuit, thickener modifications and flocculent changes, installing upgraded and additional spiral capacity, and various Feed Preparation Plant screening initiatives. Combined with the ingenuity, persistence and patience of the operating team, VHM recovery >95 per cent has been achieved.However, typical processing challenges have not been the only hurdles. Reduced rainfall and water availability has necessitated the strategic co-disposal of tailings and slime to increase the speed of water recovery: groundwater abstraction and water storage strategies have also been altered. With an observed reduction in the speed and magnitude of groundwater recharge, overburden backfill scheduling has become a priority mine planning function.Combined with the above challenges, the prevailing foreign exchange rate and mineral product prices have impacted profitability. At the height of the Global Financial Crisis in 2009, major changes to the operating strategy were made to maintain a viable dry mining operation in 2010. Working with the mining contractor the existing scraper and semi-fixed Feed Preparation Plant set up was replaced with a movable in pit dozer trap facility. The end result of changes to the mining method and primary screening was a ten per cent reduction in unit costs. This article will elaborate on some of the above mentioned challenges and successes achieved over the past ten years of operating the Cooljarloo North Mine.

Oct 5, 2011

By R Pozo, F Reyes

Codelco Chile is currently developing the El Teniente û New Mine Level Project (NMLP) in order to increase ore production by seeking to mine the ore deposit located under the current operational orebody. Reserves of 2000 million tonnes (Mt) have been quantified, which will be extracted as from the year 2017 by using the panel caving and progressive sinking method. Codelco and SKM Minmetal (SKM) jointly developed the project prefeasibility stage (PFS), closing these studies in March 2008. The first part of the project approach is to replace mine production currently feeding the Colon concentrator facilities with 137 000 tonnes per day (t/d), focusing attention on a production increase from the year 2026 up to 180 000 t/d. Project efforts have also been centred on maximising the contribution of new technologies for both construction and operational phases of the New Mine Level, together with selecting the best mine infrastructure to keep El Teniente operations going on for the next 50 years. Implicit in this is the inherent improvement of a variety of current Mina El Teniente process and management practices. The plan is to reduce actual mine operational risks and take advantage of new opportunities afforded by the project, which is in effect a greenfield project with respect to the implementation of fundamental changes in the labour and business environment. In addition, issues related to human resources, maintenance and management, materials handling, establishing centralised operations and accesses, automation and remote operations control and power efficiency could also be addressed. The project, beyond the New Mine Level exploitation, considers the mineÆs future potential, with a second deeper exploration in prospect named Deep Level. Finally, the project identifies features that would add value to the mine operations, in an initiative named æSpace for Future TechnologiesÆ. This will allow the eventual implementation of new electrical equipment and the application of mechanised technologies and other process improvements for the mine development.

Jan 1, 2008

By M W. N Buxton, M T. Bootsma, J Benndorf, C Alford

Research in the field of cut-off grade optimisation has shown a relationship between cut-off grade, project life and net present value (NPV). Lane’s theory demonstrates that cut-off grades can be optimised in order to maximise project profitability. Although the theory forms the basis for many open pit mining projects, application of the theory in underground mining remains limited to-date. The main reason for this is the complex interaction between all processes in underground mine planning, which makes it difficult to apply Lane’s mathematical optimisation approach.Recently a new stope optimiser product was released. The AMS Stope Optimiser automates the design of underground stopes at user-defined cut-off grades and allows for rapid evaluation of mine designs at different cut-off grades. Using this software, an optimisation approach was developed and validated on an underground gold deposit in northern Sweden. Potential project NPV increased by approximately 30 per cent when using this new approach.Spatial grade uncertainty in mineral resources was identified to be a major risk in underground stope design. The optimisation approach was further extended to account for grade risk using estimated and stochastic simulated resource models. The resulting optimisation process accounts for grade risk early in the design process and reduces the risk of a stope not meeting the cut-off grade with subsequent financial loss.CITATION:Bootsma, M T, Alford, C, Benndorf, J and Buxton, M W N, 2014. Cut-off grade-based sublevel stope mine optimisation – introduction and evaluation of an optimisation approach and method for grade risk quantification, in Proceedings Orebody Modelling and Strategic Mine Planning Symposium 2014 , pp 281–290 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 24, 2014

Twelve years ago, Jeffrey Mining Machinery Division of Dresser Industries Inc. developed the 120H HELIMINER. This machine was the world's first fixed-drum continuous miner and soon became the standard among manufacturers of continuous miners throughout the mining machinery industry. This paper will first outline a brief history of continuous miner development, then discuss significant parameters which are essential to a successful continuous miner design, and finally describe a number of specific applications of Jeffrey continuous miners in a variety of materials, such as coal, potash, iron ore, and trona, around the world.

Jan 1, 1978

(Quality can be defined as that which is acceptable to the market and can be supplied with a predictable degree of uniformity and dependability at a low cost. The market for any mining product is downstream processing, whether it be an alumina refinery, a gold processing plant or a flotation plant. The cost of that downstream process is partly dependent on uniformity of its feed material both in physical and chemical terms. With more operations adopting procedures which require quality assurances in line with International Standards, from their raw material suppliers, miners must look to their grade control processes to provide uniformity and predicability.This is not a new concept. The mining industry has constantly been working with ahighly variable raw material supplied by Mother Nature, from whom we cannot demand quality assurances. Through the processes of exploration, resource and reserve definition, long and short term mine planning and day to day grade control an end product has been supplied which consistently meets our customers requirements, in an economic fashion. When any of these processes fail, then penalties are incurred which can range from increased mineral processing costs to loss of markets and in the ultimate case, failure of a mining operation.

Jan 1, 1992

Up to 80 per cent of the copper in a bornite ore can be quickly leached with percolating acidified ferric sulphate solutions. The upper limit for rapid copper extraction is set by the conversion of bornite to slowly dissolving chalcopyrite. The dissolution occurs in two stages: a rapid linear initial stage, followed by a slow, non-linear stage. The initial step is largely controlled by the rate of oxidant supply (Fe2(S04)3); temperature is not an important variable during the initial reaction. The second leaching stage is controlled by chemical and physical factors and is temperature dependent. The initial copper leaching rates are insensitive to both the concentration of the ferrous sulphate reaction product, and the sulphuric acid concentration.

Jan 1, 1973

By J C. Small

Time-dependent deformation occurs when geo-materials are under an applied load; this may lead to additional deflection of a tunnel structure and the stress redistribution in the surrounding rock, shotcrete lining and rock bolt support system over time. A better understanding of this creep behaviour can improve the reliability of design, construction and maintenance of tunnels. Hence, the present investigation was carried out on the time-dependent properties of rock, shotcrete and the combined tunnel support system. Tunnels constructed in different ground conditions were modelled. The closure changes of the tunnel with time and the redistribution of stress in the surrounding rock, shotcrete lining and rock bolts due to the creep deformation were analysed. Results of the present analysis were compared with the results from the commercial program ABAQUS.

Jan 1, 2008

By Garrigan J. S, Oakes I

Current operating practice in a plant commissioned some five years ago to treat ferritic zinc plant residue by the "Jarosite" process is described. Major problems overcome include obtaining reliable pH measurements at 100¦C, prevention of scale build up in spent electrolyte heaters, blinding of jarosite filter cloths and the deposition of gypsum in filter presses.

Jan 1, 1977