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By Adriana Ramirez, Bradford C. Wesstrom, Blanca Olave

The Freeport McMoRan El Paso Copper Refinery optimizes electrolyte quality using a number of systems. The facility controls copper, arsenic, antimony and bismuth using electro-winning cells within the Tank House and Nickel Carbonate Plant Liberator Circuit (NCP). The NCP manages sulfuric acid content utilizing recycled electrolyte in the slimes autoclave as well as operation of the Acid Purification Unit, APU. The El Paso Refinery removes common sulfates using metal hydrolysis with sodium carbonate. Finally, a Mechanical Vapor Recompression, (MVR), at the water recovery plant removes sodium sulfate generated by the NCP. This paper will provide a summary of these operations. INTRODUCTION In the mid 1920’s Nichols Copper Company, in Laurel Hill, New York, recognized the need for a modern copper refining facility in the southwest. Because of the many railroad heads, affordable power and abundant labor supply, and the close proximity to regional copper smelters in Mexico, Arizona, and New Mexico, El Paso became the ideal location. In December 1928, ground was broken for the joint venture refinery between the Nichols Copper Company, Phelps Dodge, and the Calumet and Arizona Mining Company. In September 1930, Nichols Copper Company became a part of Phelps Dodge Corporation after a stock exchange. In July 1938, Nichols Division officially became Phelps Dodge Refining Corporation. In March 2007, Freeport McMoRan Copper & Gold acquired Phelps Dodge. Water is a precious commodity in the desert southwest, making conservation of this natural resource an important goal for the El Paso Operations. In the 1980’s, work on the treatment of slimes was improved through the use of pressure leaching of the refinery slimes using an autoclave. Due to the high tellurium content in the leached slimes solution, it was crucial to implement a method for its removal before the solution returns to the tank house electrolyte. A copper telluride cementation operation was installed for tellurium recovery and the ability for the recycle of the leachate and wash water to the refinery electrolyte. In October of 1997, ground was broken for the construction of the water recovery plant using an MVR to reuse process water, reducing water consumption by 25%. In 2002, electrolyte purification was further improved with the installation of an Acid Purification Unit, (APU) (Sheedy, Pajunen, & Wesstrom, 2007). The APU recycles 90% of the acids (both sulfuric and arsenic acids) back to the tank house electrolyte. The solution that passes through the APU is treated with soda ash to precipitate metals out of solution as carbonates and generates a sodium sulfate solution. This sodium sulfate solution is easily processed in the new water recovery plant, where the majority of the water recycles back into the plant as pure condensate. In 2012, the power plant at the refinery upgraded its Reverse Osmosis System to provide RO water to the tankhouse. This insured that the refinery would not have to bleed electrolyte for metals contained in well water such as: calcium, magnesium, iron and sodium chloride.

Jan 1, 2019

By J. D. Galloway

The mining industry of British Columbia continues to grow steadily in importance. The gross value of the production in 1925, sixty-two and a half million dollars, was a record, and ali indications point to the 1926 output registering a still higher figure. In an industry such as mining, where production means the depletion of known ore reserves, the discovery and development of new 'ore-deposits is of the utmost importance. To maintain and increase production, steady development is essential. In this respect, the record of the last three years in British Columbia mining is most satisfactory, as in this period more real development has been carried on than in any similar period in the history of mining in the Province. Prospecting, or the search for new ore-bodies, has also been fairly active, but comparatively few important new discoveries have been reported in the past few years. The mineral output of British Columbia consists of Iode minerals, coat and coke, and building materials. In 1925 the value of the output of these three classes of products was, respectively, about 46, 13, and 3 million dollars. The industry as a whole embraces the mining of these materials, and the treatment and manufacturing processes involved in preparing the various products for the market.

Jan 1, 1926

The Silvermines area of north County Tipperary in Ireland has experienced mining activity for over a thousand years, with lead, zinc, copper, barite and sulphur being extracted from a series of Carboniferous limestones. The last mine to operate in the area was closed in 1993. A legacy of contamination and derelict surface structures remain. Following the death of cattle in the vicinity in 1999, a governmental Inter-Agency Group was established to conduct an investigation. The ?Silvermines Rehabilitation Project? resulted, and included a proposal for the development of a Mine Waste Management Facility (MWMF) to act as a repository for waste materials from problematic sites across the area. The nature of the setting supported an effective solution from both a cost and performance perspective; and with limited maintenance requirements. Locating the MWMF where most wastes were identified would help minimise handling and relocation of materials. This position coincided with an area of artesian groundwater pressures. The resulting MWMF design consisted of a perimeter engineered embankment with the crest elevation designed to just exceed the groundwater piezometric surface. The base would remain unlined and groundwater permitted to rise up into and saturate the contained in-situ tailings deposits and imported mine wastes. The proposed system thus benefited from the ?wet cover? approach to minimising further oxidation of wastes and metal leaching, but without the usual accompanying outward hydraulic gradient and leachate management issues. A sub cap drainage layer with downstream outlet was incorporated to prevent any possibility of hydraulic rupture following an unexpected rise in groundwater heads. Leakage rates from the MWMF were deemed to essentially be driven by surface infiltration rates alone (characteristic of a ?dry cover? approach), with the proposed composite capping system simulated to perform at an infiltration rate of less than 1 mm per year. A toe drain was incorporated with the perimeter containment system, and this collection together with diverted neighbouring drainage was directed under gravity to a dedicated Passive Treatment System (PTS). Overall, effluent water quality from the PTS has been predicted to reflect an annual mass metals removal in the order of 95% below baseline.

Aug 1, 2013

By J. Ouellet

The design of hydrostatic liner for a deep potash mine shaft in Saskatchewan poses tremendous technological challenges. Technology has evolved to a point where one could consider a new innovative approach to hydrostatic liner design. But there is still a place for conventional technologies such as cast iron tubbings. As will be discussed in this paper, improvement to manufacturing process, installation procedures and even new materials can bring this technology to an excellent level of performance. With the spur of new projects in the potash industry of Saskatchewan, the authors worked in various shaft liner designs from the conceptual stage through to the construction phase. They were either directly leading the design work on some of these projects or acting as an external reviewer on others. Most of these shaft liner designs involved cast iron tubbing technology and ground freezing. The major challenge in sinking potash shafts in Saskatchewan is to go through a water-bearing ground formation under high pressure, known as the Blairmore or Manville fm. The only proven stabilizing technology for these formations is ground freezing. For a potash shaft, dry shaft conditions are highly desired, so a fully waterproof hydrostatic liner is required. All the existing potash mine shafts in Saskatchewan, except for two with composite steelconcrete lining, used the cast iron tubbing technology. Two new shaft tubbing liners have been constructed recently, one in the Athabasca Basin and one for a potash mine in Saskatchewan. When the authors began working on these new projects, what became quickly evident is that the technological knowhow for designing and constructing tubbing liners was no longer available within Canada and that the past construction methods used to sink tubbing lined shafts was obsolete. The tubbing liner for the shafts sunk in the sixties were designed either by German or British companies. In both of these countries only few tubbing lined shafts were sunk in last 40 years and the technology used in the sixties was not improved. There are only few countries where tubbing is routinely produced and installed: China, Russia, Ukraine and Poland. Out of these countries Poland is the one where this technology is the most advanced. The authors, working in close collaboration with engineers from Poland, attempted to rebuild this knowledge for the mining industry in Canada. This process involved thorough analysis of old technical reports, literature review and study of current polish design and construction practices as well as site visits of existing shafts. Through actual construction experience, some lessons were learned as well as ideas for improvements. In this paper, the authors will present a succinct review of design and procurement process. But, the practical aspects of the construction and installation methodology will be treated with more emphasis, more specifically the practice leading to good liner performance. Some of the poorly understood technical aspects of tubbing installation will be discussed more thoroughly and some currently accepted myths dispelled.

Aug 1, 2013

By M. R. Coffin

Since the plant startup in 1972, the leaching and jarosite precipitation circuits at the zinc plant of the Kidd Metallurgical Division have been reconfigured several times to improve overall performance, and/or to respond to market conditions. For the most part, the circuit changes have been driven by two market factors: the price of zinc and the price of silver. Until recently, circuit modifications undertaken to improve zinc extraction and recovery came at the expense of silver recovery, and vice versa. In 2004, the plant was modified once again to produce a precious metals-bearing residue, but additional leaching circuits were added to ensure that zinc extraction and recovery did not suffer as a consequence. The development of the zinc plant of the Kidd Metallurgical Division is updated in this paper, with a focus on the recent circuit modifications and associated control strategies that were implemented to maximize zinc and precious metals recoveries, and control the quality of the jarosite residue.

Jan 1, 2006

By R. Shamsodini, A. Poor Zaeif Doost, H. Haji Amin Shirazi, M. R. Garmsiri

"With columns being installed in rougher section at Miduk Copper Complex, the rougher feed mainly reports to rougher-scavenger cells. To evaluate the efficiency of regrinding circuit, we conducted flotation experiments on samples of the feed and the products of the regrinding circuit. The grade difference of these products at 85% recovery was considered as the efficiency index. Results show that, with weight recovery of the rougher-scavengers the efficiency of the circuit increases. Exclusion of the rougher-scavenger concentrate from the feed to the regrinding circuit, resulted in an increase in the efficiency index from 10.12 to 17.6%.INTRODUCTIONThe flotation circuit at Miduk Copper Complex consists of five flotation columns as roughers and ten mechanical cells as rougher-scavengers. According to design criteria, 75% of the final product was expected to be produced by the rougher columns, while most of the feed consisting of liberated valuable particles is introduced into rougher-scavengers. To liberate locked particles, the rougher-scavengers concentrate is introduced into the regrinding circuit (see Figure 1 below). The regrind mill is in reversed closed circuit with a secondary hydrocyclones cluster, and the cyclone overflow is introduced into three parallel cleaner columns. Cleaners concentrate reports to concentrate thickener and the column tailings is introduced into six mechanical cleaner-scavenger cells. The cleaner-scavengers concentrate reports to the regrind circuit(Figure 1)."

Jan 1, 2012

This paper presents a case study where Cenozoic age detritals and an ancient buried landslide have been modelled in the final walls of an iron ore pit. Orebody 25 is located in Western Australia’s Pilbara region and is an operating pit where a redesign of the final wall cutback was required. The existing slope design utilised a simplistic geological model of mixed conglomeratic, calcretic and clay –dominated detritals overlying deformed bedrock sequences. This simplicity resulted in a conservative design that was not reflective of the slopes performance to that point. Further field investigation was carried out with the results assessed in conjunction with historic drilling, mapping and laboratory testing. A detailed geotechnical model was developed including three conglomerate and two clay dominated units and laterstage calcrete overprinting. The clay units were of significant importance to the stability assessment and resulting slope design due to the thickness and poor strength conditions indicated by the laboratory and field testing. However, the drilling investigation shed only limited understanding as to the origin of the clays and thereby how they should be treated as a component in the stability analysis. A comparison of the ratio of various geochemical elements measured by assay was made between the clays and 1) shale bedrock and 2) clays of known detrital origin from other nearby sites. This indicated the clays had a strong affinity with weathered bedrock. This and other textural features resulted in the interpretation that the clay units were relic debris preserved following ancient landslides in bedrock shale. Using laboratory testing data and calibration of results for a landslide origin, stability analyses were run, resulting in a steeper slope design being implemented. Excavation of the final cutback is now in progress with the model confirmed as appropriate.

Jan 1, 2015

By Jörgen Appelgren

Atlas Copco, a leading supplier of equipment and services to the mining and construction industries, is consistently pursuing its strategy to offer the most productive and economical solutions by continuously offering new innovative products. These are in most cases developed and tested in close cooperation with demanding end users before being officially launched on the international market. The demands for higher productivity and improved overall economy have resulted in systems for automation of the drilling cycle and also tools for integrating the Drilling equipment to the production control system used by the customer. In terms of improving the blasted material quality, Atlas Copco has placed emphasis on hole straightness and the need for hole logging and positioning. By applying state of the art technology to today?s computerized drilling rigs, major steps in improving overall drilling and blasting performance have been achieved. This paper will give some examples derived from the latest development of solutions for the Rotary drilling product line.

Oct 1, 2009

By J. Desroches, J. Burghardt, B. Lecampion, A. P. Bunger

"We present detailed comparisons between theoretical predictions and experiments for the initiation of radial hydraulic fractures transverse to a wellbore. Most of these experiments provide a measure of the time evolution of pressure, length, opening and flux entering the fracture during the test. We compare all these measurements simultaneously to our theoretical predictions, thoroughly testing hydraulic fracture initiation theory, which is shown to be predictive. These comparisons notably emphasize the difference between the initiation pressure (the wellbore pressure for which the fracture initiates) and the breakdown pressure (a misnomer which simply corresponds to the maximum pressure recorded during the test). INTRODUCTION In this paper, we will compare hydraulic fracturing laboratory experiments performed in different tight materials (PMMA, cement, shale) with the predictions from a numerical solution of the governing equations of hydraulic fracture mechanics (e.g. Geerstma & de Klerk, 1969; Detournay & Peirce, 2014). We focus on transverse radial hydraulic fractures initiating from a radial notch at the wellbore wall (see Figure 1). In particular, we will clarify the difference between the initiation pressure (the wellbore pressure at which the fracture initiates) and the breakdown pressure (a misnomer which simply corresponds to the maximum pressure recorded during a test, usually carried out at constant pump rate). This difference stems from the strong viscous effects at play during wellbore pressurization, fracture initiation and early propagation (i.e. fluid entrance in the newly created fracture). It has been observed on a number of experiments (e.g. Weijers, 1995; Zhao et al., 1996) and has a strong practical application, first because the maximum pressure is the most obvious value to report and second because that maximum value is necessary to specify injection systems."

Jan 1, 2015

By John L. Mero

"The ocean has served humanity as a source of raw materials for thousands of years, but only on a minimal scale relative to its potential. Exploration programs have shown the ocean to contain a large number of mineral deposits of great extent and attractive grade. Recent research has indicated that a number of these deposits can be economically exploited with present-day technology and that the cost of winning many industrially important minerals from the oceanic deposits is potentially much less than that of winning similar minerals from land deposits. Although the finding of mineral deposits in the sea is a relatively simple matter at the present time, the exploitation of many of these deposits has lagged due to the lack of the availability of specific mining techniques for the individual deposits. Within the past two years, however, several developments have taken place in the design and testing of ocean mining systems in depths of water as great as 12,000 feet which indicate that the problem of mining in the ocean may soon be solved.Within the next decade, the ocean should prove to be a major source of many minerals for society and should come to dominate as a source of such metals as copper, nickel, cobalt, manganese, etc. Within a few years of the initiation of the mining of the deep-sea metalliferous nodules, land sources of such metals as nickel, cobalt, copper, manganese, etc. will be seriously affected and it is conceivable that the present structure of the world mining industry will undergo a substantial change in character."

Jan 1, 1972

By G. L. Palmer

"Abstract- ln 1986, anomalous sampling results for heavy minerals were obtained at various sites in Namaqualand on the west coast of the Cape Province. Drilling in 1987 at Graauwduinen penetrated up to 35 meters of heavy mineral-bearing Tertiary sands which extend several kilometers inland from the coast. The heavy mineral suite includes ilmenite, rutile, leucoxene, zircon and monazite, along with garnet, pyroxene and amphibole. Three deposits are recognized, two of which comprise the resource to be mined by Namakwa Sands Limited, a recently formed Anglo American Corporation subsidiary company.Mineable reserves in excess of 500 million tonnes have been delineated, sufficient to sustain mining for over 35 years at projected production rates. During the feasibility study, on-site investigations included test mining at various sites to assess mineability and to provide material for metallurgical testing in a pilot plant located at the site. Ilmenite produced at the mine will be smelted at a new facility to be built at Saldanha Bay . Saleable products comprise titania-rich slag, pig iron, zircon and rutile.During the exploration phase, company environmental guidelines were established and monitored. The feasibility study incorporated a Class 1 Environmental Impact Report, the contents of which were made public following the principles of the Integrated Environmental Management legislation."

Jan 1, 1994

By E. Rezazadeh Azar

Dump trucks are the main mean for hauling earth material within and outside of the construction and open-pit mining jobsites. The real-time monitoring of the material transportation trips is beneficial for proactive equipment management, volume estimation, and productivity measurement. The traditional manual observation is tedious, non-real-time, and expensive; therefore remote sensing technologies, namely GPS and RFID, have been employed for this reason. Ordinary construction videos are another costeffective alternative to monitor dirt loading and hauling operations in real-time. A vision-based system has been developed to recognize and count hauling trips. This system has three modules including object detection, tracking, and action recognition. This system processes videos taken from access roads in which it recognizes dump trucks and then tracks them throughout the viewfinder. The action recognition module is designed to reject false alarms and also terminate tracking. This way, the system is able to count the number of hauling trips and also record the time between each trip. Several state of the art computer vision algorithms were employed to develop this system. Some of these algorithms were modified using spatiotemporal information to minimize the inherent errors of the vision-based methods. The experimental results showed considerable performance of the system for practical application in the construction and mining sectors.

Aug 1, 2013

By André Gobell

"La distribution des éléments majeurs dans une séquence de roches volcaniques felsiques, la formation de Waconichi, au sud de Chibougamau, indique que les roches pyroclastiques du secteur ouest de ce segment sont chimiquement anormales si on les compare à la composition moyenne des roches volcaniques de Chibougamau: elles sont caractérisées par une teneur anormalement élevée en f er, en magnésium et en potassium et une teneur anormalement basse en sodium et en calcium; ce chimisme caractérise les encaissants des dépôts de sulfures massifs d 'origine volcanique.Les coulées rhyolitiques massives sous-jacentes au gite de cuivre-zinc avec or et argent de Lemoine ne montrent pas ou très peu d’altération de ce genre. Le schéma de mise en place des dépôts de sulfures massifs d'origine volcanique et la nature des roches en présence permettent de croire que la zone d'altération mise en évidence à l'ouest de la mine Lemoine puisse être reliée à la mise en place de ce gisement d'ou l'im portance de tenir compte des caractères texturaux des roches lors de l'interprétation de données litho géochimiques."

Jan 1, 1980

By R. E. Whitehead, G. J. Prior

"Abstract -Biotite from aplite that appears to have crystallized simultaneously with disseminated Cu-Mo mineralization at MacLeod Lake in northern Quebec yields K-Ar dates in the range 2032 ± 44 Ma to '2f1:)1 ± 47 Ma. The mean value, 2065 Ma, is some 400 Ma younger than the 2485 ± 64 Ma date obtained from a hornblende concentrate separated from a granodiorite sill that is spatially, but apparently not genetically, associated with the disseminated Cu-Mo deposit. The mean biotite date of 2065 Ma at MacLeod Lake, a K-Ar date of 2055 Ma reported from an area 50 km east of MacLeod Lake and published dates of about 2000 Ma for galenas from the Chibougamau Cu-Au ores, suggest a widespread thermal and mineralization event, in that part of the Superior Province east of James Bay, that differs from the common late Archean mineralization that is related to volcanism and metamorphic-intrusive activity.Sommaire - Les datations au K-Ar sur des biotites qui auraient cristallisé en même temps que la minéralisation disséminée en Cu et Mo dans une aplite mise en place au Lac MacLeod, au nord du Québec, s'échalonnent entre 2032 ± 44 Ma et '2f1:)1 ± 47 Ma. La datation moyenne, soit 2065 Ma, est d'environ 400 Ma plus récente que la datation obtenue pour un concentré de hornblende extrait d'un fùon-couche de granodiorite qui est spatialement mais ne serait pas génétiquement as­ sociée à la minéralisation disséminée en Cu et Mo. La datation moyenne de la minéralisation au Lac MacLeod, soit 2065 Ma, la dataion au K-Ar à 2055 Ma citée pour une région à 50 km à l'est du Lac MacLeod, de même que les datations d'environ 2000 Ma établies pour des galènes qui se trouvent dans le minerai aurifère et cuprifère à Chibougamau, suggèrent un phénomène thermique répandu qui aurait produit la minéralisation dans cette région à l'est de la Baie James, dans la province du lac Supérieur. Ce phénomene serait différent de celui qui aurait produit la minéralisation répan­ due d'âge archéen tardif qui elle serait associée à l'activité volcanique et à l'activité intrusive accompagnée de métamorphisme."

Jan 1, 1992

By P. J. Lunder, R. C. Pakalnis

This paper presents the results of research that has been undertaken in order to develop an improved method of determining the strength of hard-rock mine pillars. Pillars are found in various shapes and sizes in all underground mining operations. Prudent engineering design requires that if pillars are to perform as desired, both the pillar strength and the pillar stress must be determined. A detailed pillar stability study has been combined with an extensive database of published pillar case histories (178)resulting in a new “hybrid” pillar strength formula, “The Confinement Formula”, that utilizes classic strength of rock methods combined with empirical methods. “The Confinement Formula” utilizes a “mine pillar friction term” calculated from the average minor/major stress ratio with-in the pillar core. Statistically, the new formula provides better results at predicting pillar strength for the combined database than the best empirically ft pillar methods that currently exist. “The Confinement Formula” allows for the determination of the strength of mine pillars with an increased level of confidence over previously applied methods.

Jan 1, 1997

By David A. Edgecombre

This paper discusses modern practices in the extrusion of steel. Particular emphasis is given to a description of the Ugine Sejournet method of extrusion, involving the use of glass as a hot work lubricant. Other methods are also mentioned. A brief history of extrusion is presented; present practices in the quality extrusion of tubing and solids are described; and the future potentials of the) process as a tonnage producer are briefly discussed. The advantages of extrusion and the reasons for the use of a glass lubricant, as well as the various methods of using glass, are given. The process, as described, is being used in the manufacture of large commercial quantities of stainless steel tubing and sections. This extrusion process is an essential and unique means of forming such atomic-age materials as titanium, zirconium, molybdenum and other super alloys all of which are materials required in the creation of nuclear installations.

Jan 1, 1963

By Y. -H. Cho, J. -M. Lee, J. -G. Jung

The effects of copper on the microstructure and mechanical properties of ultrasonic melt treated Al-xCu (x=0, 4) alloys were investigated. The densities of alloys were increased and their grain sizes were decreased by UST. The hardness and electrical resistivity measurements revealed that the amount of solute Cu within Al matrix was increased by UST. Both the yield and tensile strengths of Al-4Cu alloy were increased by UST. The improved mechanical properties of Al-4Cu alloy by UST were probably due to the reduced amount of casting defects (e.g. pore), grain refinement, and enhanced solid-solution hardening of Cu.

Jan 1, 2014

By L. Cáceres, G. Leinenweber, P. Bustamante

"Given the severe scarcity of fresh water sources in Northern Chile the use of seawater has become the only alternative to allow mining expansion. This option however poses several technological challenges as a result of the high concentration of natural salts that promote various forms of metal corrosion. Therefore the steel piping protection has been a constant challenge for design engineers responsible for solving the problems of corrosion. Known protection alternatives are varied and expensive, a few of them are rubber coatings, protection based centrifuged concrete, extra wall thickness of pipes in combination with corrosion inhibitors, extra wall thickness of pipes without using corrosion inhibitors, and the use of highly corrosion resistant steel materials.In this framework the aim was to study the corrosion kinetics of carbon steel pipe API 5L X70 under electrochemical and weight loss testing. The test conditions include a range of seawater velocities between 0.2 to 3.0 m/s.For electrochemical experiments the API 5L X70 steel specimen was a 4 mm diameter disk embedded in an 8 mm diameter Teflon rod and exposed to seawater. Duplicated coupons were placed in a standard test apparatus that was built according to the standard ASTM D 2688 – 94.The main results were: a) corrosion mechanism explained in terms of the counterparts partial processes which are the hydrogen evolution and oxygen reduction reaction; b) for the test specimen a corrosion band like feature that suggest a lateral dispersion of aggressive solutions from corrosion pits; c) a range of corrosion rates between 1 and 1.96 mm/year for flow rates between 0.2 and 3.0 m/s; and d) a convenient inhibitor dose between 20–25 mg/L for optimum inhibition efficiency to obtain a maximum value of 80% for corrosion efficiency."

Jan 1, 2016

By I. B. Lambert

The guide has been developed by officials from resources and environment agencies in the Australian Government and the South Australian and Northern Territory Governments. It elaborates on the Australian Government?s policy that new uranium mines are to be approved subject to world best practice environmental and safety standards. The guide outlines the best practice principles and approaches that apply generally to mining in Australia, before giving more detailed consideration to best practice environmental protection and regulation for ISR mining.

Aug 1, 2010

By E. O. Chisholm

Synopsis The colour changes effected in a solution of dithizone by trace amounts of copper, lead, and zinc mineralization provide a sensitive field test for these metals. The method has been used with success by the United States Geological Survey to trace zinc orebodies under residual soils. The dithizone test is used here on samples of non-residual soil overlying a gold-bearing zone in which the gold is associated with disseminated sphalerite, galena, and chalco-pyrite. A gold-bearing zone was successfully traced under overburden ranging from a few inches to five feet in depth by means of this method. The method may prove useful in guiding preliminary trenching through light overburden, by outlining the extent of copper, lead, and zinc mineralization. Introduction The dithizone test affords a rapid, simple, and delicate test for the presence of zinc in soil and water and is suitable for use under field conditions. It has recently been used with success by the United States Geological Survey to outline a zinc-rich area in the residual soil over a primary zinc deposit in Tennessee. The purpose of the present study was to ascertain whether the method could be used to trace a gold-bearing zone, containing associated zinc mineralization, under shallow, non-residual, glacial overburden. The results obtained indicate that the method can be used to guide preliminary trenching in overburden up to six feet in depth. Tests made of the water near lake-shore outcrops also indicate that favourable prospecting zones may be located from the water, within five feet of the shore. It is felt that this simple field test should find a wider use in prospecting, because, under certain conditions, it can outline favourable zones and thereby reduce the amount of blind trenching necessary. The following pages describe the type of deposit tested, the method used, the .results obtained, and the difficulties encountered by a novice in the use of this chemical procedure. The author is indebted to the officials of Nor-Penn Mines, Limited, for their co-operation while the tests were being made; to the late Richard Bouska, Kenora prospector, for helpful suggestions; and to F. W. McCamus, University of Toronto undergraduate student, who ably assisted with the work.

Jan 1, 1950