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By R. H. Walton

"In recent years the recovery of copper from low grade oxide ores has received widespread attention. The cost of treating such ores using conventional technology, such as milling and flotation, is frequently prohibitively high and copper recovery is generally low. The introduction of heap leaching, solvent extraction (SX) and electrowinning (EW) has resulted in high recoveries, good copper cathode quality and low production costs. This technology has now been successfully applied on a worldwide basis.This paper reviews the various process and design options and gives approximate capital and operating costs for a 1.0% copper ore.INTRODUCTIONAs a result of the low copper prices that prevailed for much of the last two decades, aggressive attempts were made by the industry to cut operating costs. Under such circumstances heap leaching, solvent extraction and electrowinning, to recover low cost copper from oxide ores, has received particular attention and ultimately widespread acceptance.Low grade copper ore (typically containing less than 1.0% Cu), which could not be economically treated by other methods, is placed on heaps and leached with dilute solutions of sulphuric acid. The copper rich, pregnant solution, drains from the heap into a collecting pond and is pumped to a solvent extraction plant where it is purified and upgraded. The resulting solution, termed the pregnant electrolyte, passes to the electrowinning section where the copper is recovered as high grade cathodes and sulphuric acid is regenerated, (Figure 1).This paper specifically describes the processing of copper oxides. Other copper minerals such as chalcocite and chrysocolla are also leached by dilute solutions of sulphuric acid. In practice the oxide minerals are frequently associated to varying degrees with less easily leached sulphides, such as chalcopyrite. In some cases, once the oxidized capping of the ore body is removed, the oxides are totally replaced by more refractory sulphides. Under these circumstances the leaching recovery is significantly reduced. However the principles described here for solvent extraction and electrowinning are also applicable to solutions received from heaps containing sulphide minerals, which are leached more slowly and involve bacterially induced reactions."

Jan 1, 1990

By Jean-Marc Simard, Richard Genest

"La mine Agnico-Eagle, localisée près de Joutel, a été découverte en 1962 par le forage d'anomalies électromagnétiques. Exploitée à partir de 1974, elle a déjà produit près de 30 tonnes d’or à partir de 2 puits, le puits Eagle et le puits Telbel, distants de 1,3 km.Le gisement est situé entre le sommet du complexe volcanique de Joutel, à dominante felsique, et la base de l'ensemble sédimentaire de la rivière Harricana. Ces deux unités ont une extension régionale; elles sont orientées NW-SE avec une polarité NE et des pendages subverticaux. Une faille majeure, la faille Harricana, passe de façon subconcordante au contact de ces deux ensembles.La minéralisation aurifère, de 2 à 5 m d’épaisseur moyenne, est liée a une zone carbonatée, comprise entre des tufs felsiques, argilites et sédiments chimiques (éponte inferieure) et des argilites carbonatées (éponte supérieure). Le minerai est constitué habituellement de 20% de fine pyrite disséminée. L’or est en fines particules associées directement à ces grains de pyrite de texture cataclastique.Deux modelés ont été for mules jusqu' a présent pour expliquer la genèse du gisement: une thèse syngenetique (Barnett et a/.1982) et une thèse épigénétique (Wyman et al. 1986). Cette dernière apparalt comme la plus probable du fait de la présence de la minéralisation dans les zones cisaillées a carbonates secondaires et pyrite cataclastique."

Jan 1, 1990

By Y. Bai, J. J. Liu, D. Q. Li, S. Z. Liu, X. T. Wang

"This paper presents the results of an industrial test using 8 t/d of Baotou concentrate (50% REO) of a clean metallurgical process, which includes: 1. Roasting with H2SO4 at low temperature (220~260 0C) in a batch roasting furnace followed by water leaching to obtain a leach liquor as feed with a yield of >95% RE and Th, recovering F as fluoride, producing a leach residue amounting to 1/3 of an equivalent high temperature residue and containing <0.03% Th and radioactivity < 3×104 Bq/kg compared to the normal high temperature residue containing 0.2-0.3% Th and 1×105 Bq/kg. 2. Separating Th with N1923 and extracting RE by P507 has been completed in mixer-settlers. Test results indicate that the ThO2 product has a purity of > 95% with a yield of 99%, and the RE has a yield of >95%, in which ThO2/REO <5×10-6, and that P507 loaded RE connect straight with separating RE using P507-HCl system. 3. Treatment and multipurpose use of "three wastes" (water, gas and solids) are discussed in some detail."

Jan 1, 2014

By Patrick Frenette

The Goldex Mine is an underground gold mine using a unique mining method where a single very large stope is being created. In order to maintain stability of the walls and roof of the stope which is 450m, 250m high and up to 120m thick, ore is left in the stope as long as possible and acts as backfill would do. At many occasions during the mining sequence, the walls will be exposed on height ranging from 30 meters up to 250 meters. A monitoring system comprising in-stope laser surveys, a seismic system and an array of extensometers and sloughmeters all remotely connected to surface is used to observe the shape and evolution of the stope. This paper will focus on the results obtained following some of the large blasts and on the long term monitoring of the stope.

May 1, 2011

By D. Settles, R. Rose, P. L. Dunn

"A new mineral sands operation is being developed in Georgia by Southern Ionics, Inc. (SII). Prevailing mineralogy and certain design constraints required detailed testing and circuit analysis to create a robust separation processes. The floating wet concentrator plant (WCP) and mineral separation plant (MSP) flow sheets were designed based on historical testing information and recent SII test campaigns on various composite feed samples. The flow sheets were finalized through rigorous process and orebody sequence modeling.The process uses traditional physical separation equipment; however a new MT spiral, the MG12, was selected for use on board the WCP for roughing duty. The MG12 spiral is a two-stage, twelve-turn spiral that has been proven to achieve very high recoveries of heavy minerals. The floating plant includes feed desliming operations, a central MT surge bin for optimum spiral circuit feed control and ancillary operations for concentrate and tailings handling. Scrubbed heavy mineral concentrate (HMC) is then transported to the MSP for concentration of the titanium and zirconium bearing mineral fractions.The testing, flowsheet development, and plant design will be described and explained, and a brief summary of the current project status will be given.IntroductionSouthern Ionics Inc. (SII) is a privately held chemical manufacturing company, founded in 1980 by Milton Sundbeck. SII focuses primarily on the sale of specialty and intermediate inorganic chemicals. Core markets include cement and refinery catalysts, molecular sieves, zeolites, pulp and paper, pharmaceuticals, TiO2 and water treatment. SII is built on the four cornerstones of service, quality, technology and delivery with all SII facilities ISO certified and key products used in potable water treatment certified to NSF standards. SII owns and operates its own transportation fleet and is focused on being a low cost producer, committed to safety and the environment."

Jan 1, 2015

By D. M. May

"Cut-and-fill mining is a stoping method that has been widely utilized in the mining industry over the past forty years. It took preference over shrinkage methods at Levack in the early 1930sbecause of its safety aspects; i.e., prompt support of the stope sidewalls, good working floors and better accessibility to support poor back areas. In addition, higher recoveries of ore were possible because of the flexibility of the method in that silling could take place easily at any horizon; low-grade ore could be sorted and left in the stope as fill and certain zones of rock could be left unmined. With modern techniques, a steady production rate can be established, as filling and mining can be carried out stimultaneously.AIthough there are numerous variations of cut-and-fill mining throughout the world, this paper reviews the original type of mining, with modifications and improvements through the years to present modern practices, with the Levack West operation appearing to be the most productive at this time. Stoping efficiencies have also increased substantially from the original 10 tons per manshift to the present 55 tons per manshift.The paper also outlines the many improvements that have been made with respect to mucking and ground support operations; from hand mucking in a single stope to the use of frontend loaders and haulage trucks in fully accessible stope complexes; and from timber props to roof bolts of various types. Although present methods are extremely satisfactory, experimentation is continually being conducted to improve safety and productivity for future mining.IntroductionThe major mining operations of the Ontario Division of Inco Limited are located in the Sudbury Basin (Fig. 1). Around the rim of this geological formation and within 30 miles of the City of Sudbury are nine producing mines and one &apos; open pit operated by the company .Ore production currently approximates 11.5 million tons per annum from underground and open-pit operations. Underground mining methods include sub-level caving, shrinkage, cut and fill, undercut and fill, blasthole and vertical retreat. The Levack Complex, the main plant of which is the central Levack Mine, produces 11,000 tons per day.The first prospecting in the Levack area, in 1887, was conducted by James Stobie, who examined rock cuts along the route of the Canadian Pacific Railway to the northwest of Sudbury. However, it wasn&apos;t until 1913 that operations commenced at Levack under the Mond Nickel Company."

Jan 1, 1981

By Marc C. Bétournay

Hydrogen fuelcells are a known technology, having been applied to stationary (e.g equipment, buildings, power plants) and vehicle applications (e.g transit buses, space shuttles). There is currently a growing need to provide alternate power systems to diesel fuel for underground mining vehicles to improve underground air quality and reduce production costs and green house gas emissions. To date, however, fuelcells have not been exposed to underground mine air and physical conditions. A testing program was carried out to provide information on the vulnerabilities of fuelcells as part of a number of proof-of-concept projects to apply hydrogen power to underground mining vehicles. The fuelcell type of choice for the industry, the Proton Exchange Membrane, would function at the range of temperatures encountered in underground and surface operations, and use hydrogen that is stored under low pressure and risk. A small fuelcell stack was tested in a cooperative project between CANMET, the Fuelcell Propulsion Institute, INCO, the Ontario Ministry of Labour, Sandia National laboratories and H-Power. This article will review the tests carried out to measure the effects from high humidity, mineral dust, diesel emission gasses and diesel particulate matter as well as from shock and vibration provided to the unit in underground conditions, at INCO?s 175 Orebody minesite and INCO?s Stobie Mine. The test results provided will show that the unit was not affected by the underground conditions: physically and electrically the unit performed without any reduction in operation or adverse effects imposed.

May 1, 2003

By P. R. Day, W. K. Webster

"The introduction of large boreholes underground initially involved taking the techniques of open-pit bench blasting to the production stope, but with deeper boreholes and narrower stopes more controlled techniques must be developed in order to maintain good stope walls and prevent dilution of ore or structural damage to pillars due to blasting overbreak. The points discussed are drilling accuracy and drill pattern, the relationship between open-pit wall control and underground mining, the varied explosives products and initiation devices available, and some of the many ways that variations in loading, such as deck charging, etc., can produce desirable results.IntroductionThe use of large-diameter blastholes for underground mining began ten years ago and today they are widely employed in a variety of orebodies and stope configurations. These big blastholes, which range in size from 4.5 to 8 inches in diameter, were originally employed in the same manner &apos; as open-pit bench blasts; that is, the stope was silled out to full width and all holes were drilled vertical and parallel. This was suitable for competent, massive orebodies, however the popularity of the big drills saw their usage in more narrow stopes, often with poor ground conditions. The dipping orebodies and small drill sublevels resulted in inclined drilling.Today, there is full-ring drilling of 4.5-inch holes. Some 6.5-inch holes are drilled up to 350 feet deep. A 350-foot borehole may contain 6000 to 7000 pounds of explosive. The detonation of this size of charge weight within the confines of an underground stope can have considerable effect on the stability of stope walls and adjacent pillars. Obviously, precautions must be taken to minimize the damage which would result from the large charge weights possible with these big boreholes."

Jan 1, 1982

By Gianni Bartolacci, Patrice Nadeau, Szatvanyi. Gerard, Carl Duchesne, Claude Chrétien

"Combustion is used throughout the mineral processing industry to produce steam in boilers, to dry concentrates in rotary dryers, and to apply heat treatments in pyrometallurgical furnaces. Tight combustion control is very important in latter type of furnace since the combustion conditions directly affect final ore quality. However, achieving tight combustion control is not straightforward since most of the flames encountered in industry are turbulent non-premixed flames, they are affected by several unmeasured disturbances and are often produced by burning several types of fuel simultaneously, some of them coming from other parts of the plant. A novel method is proposed in this paper to improve process and product quality control as well as to optimize the combustion conditions based on digital flame color images. Multivariate Image Analysis and Regression is to used extract the flame color characteristics from images to predict the solids discharge temperature of an industrial rotary kiln. It is shown that this method yield extremely good 10 minutes ahead forecast of the temperature and should lead to a substantial reduction in product quality variability as well as in fuel consumption.INTRODUCTIONFuel-fired furnaces are often used in the mineral processing industry for various purposes, such as for the production of steam (utility boiler), in conjunction with rotary dryers to dry mineral concentrates or in pyrometallurgical processes for induration, roasting, and so forth. These furnaces are necessary in the supply chain from the mine to the metals, but their operating costs are constantly rising due to the fluctuations in fuel prices. Moreover, these processes are now targeted by the Kyoto Protocol since they are energy intensive and they produce significant amounts of CO2 and other pollutants such CO, NOx and SO2. To achieve both a reduction in operating costs (i.e. fuel consumption) and in pollutant emissions while maintaining or improving product quality, one needs to have a very good control of the combustion process."

Jan 1, 2005

By Michael Young, Peter Allum, Mingwei Gao

"Tough economical conditions and high grade but fine-grained ore processing have forced the mining industry to look for more efficient processes. Isa Mill Technology for ultra-fine and fine grinding is one such process employed at several mining operations in Australia including Mount Isa Mines Limited in Australia. Mount Isa Mines is a business unit of MIM Holdings Limited. MIM is an Australian-based international mining and mineral processing company with around 8000 employees worldwide. Major products include copper, gold, zinc-lead-silver, coal and technology sales.The Isa Mill is a horizontal stirred mill with sizes up to 3 m3 chamber net volume and 1 120 kW installed motor. It was jointly invented by Mount Isa Mines of Australia and Netzsch Feinmahltecknik GmbH of Germany for ultra-fine and fine grinding duties in the minerals industry. Isa Mill operations started in 1994 at the Mount Isa Mines Leadzinc Concentrator and then at MIM’s McArthur River Mine in 1995. These Isa Mills have been used to liberate sphalerite and galena at Mount Isa and silica at McArthur River by grinding to less than 7 micron.This paper discusses the Isa Mill Technology and reports on the metallurgical performance of the Isa Mills at Mount Isa Mines, including work done over the last 9 years to improve mill design, process efficiency and maintenance, which has resulted in the current state-of-the-art Isa Mill Technology.INTRODUCTIONThe current leadzinc deposits at Mount Isa Mines (George Fisher, Hilton and Isa) have an average grade of 10.5% zinc, 7.2% lead and 165g/t silver. Fine grinding, in particular in the zinc retreatment circuit requiring a milled product P80 of 7 micron, is essential to treat the ores from the Mount Isa Mines deposits. Every one micron size reduction in the zinc retreatment circuit below a P80 of 10 micron improves the overall plant zinc recovery by 1%, resulting in an increase in revenue of about 1 million dollars per annum."

Jan 1, 2002

By Guy Chevalier, Jean-Guy Chartrand, Louis Barrette, Daniel Michaud, Michel Fortin

"COREM has developed, specifically for the mineral industry, a mobile laboratory using the Laser-Induced Breakdown Spectroscopy (LIBS) technique. It has been used to perform onstream analysis (OSA) of the chemical composition of slurries in both gold-ore and iron-ore processing plants. Industrial tests have been carried out respectively at La Mine Doyon (Cambior), a gold-ore processing plant near Rouyn-Noranda, Quebec, and at QCM's iron-ore pelletizing plant in Port-Cartier, Quebec. The aim was to demonstrate that the LIBS technique is capable of providing information that meets the needs for process control. C, Si, Ca, Mg, Mn and Al were the elements targeted on iron ore while Cu, Fe, Ag and Au were targeted for gold ore. The results obtained meet or exceed the requirements for process control and consequently clearly show that the LIBS technique is suitable for industrial applications.The feasibility of OSA, through in-plant validations using COREM’s LIBS mobile laboratory, has been demonstrated in four essential aspects: slurry sampling, LIBS chemical measurement, robustness for continuous operation, and functionality for industrial operators.INTRODUCTIONThere is a general need for optimization in the mineral industry. Process control is a favoured means to achieve this goal (McKee 1991). Real-time knowledge of process status is the key to effective control (Da Silva 1994). Only a few techniques, such as XRF, NMR and digital imaging, are currently amenable to chemically monitor industrial processes (Braden 2002). LIBS is an emerging technique with appealing characteristics for on-line and real-time measurement of bulk material (Lorenzen 1992, Palanco 2000). While our ultimate goal is to provide our industrial partners with performing monitoring tools, a shorter-viewed objective is to demonstrate the feasibility of developing a LIBS system for OSA. The LIBS technique has shown interesting capabilities for measuring solids, liquids, dusts and gases. Our work has focused on mineral slurries (Barrette 1999 and 2001, Turmel 1999). Special equipment is needed to perform in-plant validations. A mobile laboratory based on the LIBS technology has been assembled for this task."

Jan 1, 2004

By Rob Stewart

Acknowledgements ? Josef Macek(Manitoba Geological Services) ? Sally Goodman (SRK) ? Inco Geologists ? Rogerio Montiero ? Thompson Mine Geologists Introduction ? Regional Geology ? Thompson Geology ? Stratigraphy ? Sulphide Characteristics ? Conceptual Model ? Structural History ? Belt ? Thompson Mine ? 1D Deposit ? Ore Controlling Structures ? Using Structural Data to Guide Exploration ? Summary

May 1, 2006

By S. Bellec, P. Champagne, J. Châteauneuf, A. Berton, S. Fortier

"The start-up of new plants, extending from the commissioning of equipment to the production ramp-up, is a critical period where the processing circuit operation must be done in a structured and well controlled way to enable the gradual, safe and rapid achievement of production targets. The magnitude of the many risks associated with this pivotal period is accentuated in the actual context of low commodity prices. However, the implementation of a method that analyzes risks associated with a start-up, their probability of occurrence and their impacts leads to the identification of a series of preventive actions that can be applied in order to reduce potential negative impacts.Soutex has been involved in numerous start-ups over the last few years and has developed a structured methodology to assess this crucial period, maximize the pre-start-up preparation, ensure a smoother and safer ramp-up period and minimize the time needed before reaching commercial production.This paper describes a method to identify preventive actions to apply in order to reduce risks related to a plant start-up. Then, the various steps of the method are demonstrated using the industrial case study of the Canadian Malartic gold plant situated in Abitibi, Québec. The specific preventive actions, during start-up, the organisational measures and the ramp-up plan are detailed as they were effectively achieved. Finally, the post start-up actions are presented as well as some key results illustrating the achievement of their prior defined objectives.IntroductionPlanning a new plant or new circuit start-up in a mine installation involves various risks, both at the economical and safety levels. Unprepared staff and equipment can lead to safety issues that could threaten plant staff as well as the environment. Moreover, a poorly prepared start-up could often lead to equipment break-down, production stoppages and delays, leading to important economic impacts, delaying commercial production and therefore affecting directly the profitability of mining projects.It is common in the industry to have structured commissioning procedures for major equipment taken separately. Technical personnel from the equipment manufacturing company would usually come on site in order to perform the pre-operation verification, dry runs and the first hours of operations. This kind of assistance is usually focussed on one piece of equipment and neglects the interactions between the various equipment of the production chain. The commissioning phase is usually maintenance oriented and the information given by the manufacturing representative seldomly flows through the operation staff (in the case of this paper, the denomination “staff” refers to both managing and operating employees). The global process is usually not taken into consideration by the technical personnel sent on-site by the manufacturer during the commissioning phase. Many papers can be found describing the commissioning of new equipment focussing on the technology (Côté and Adante (2009), Wells et al (2007)) but without dealing with its integration process in the complete production chain."

Jan 1, 2016

By Y. L. Su, S. Vongpaisal, H. A. Smith

"It is extremely difficult for a mine&apos;s central control room operator to control peakpower demands and to maintain normal materials handling operations at the same time. An investigation of the Falconbridge Strathcona Mine &apos;s central control room has revealed that there are more than eight thousand possible combinations of ""situations"" that can arise. For such a circumstance, an expert system can become a very valuable tool to assist the operator in taking the most appropriate and timely action.A forward chaining expert system module has been developed for this application. The module is based on Level 5 ObjectTM software. It is graphics oriented and user-friendly. Training requirement is minimal.ForewordThis paper has arisen out of work carried out by YLS Associates and Falconbridge Limited as part of a contract between Falconbridge and the Department of Energy, Mines and Resources, Government of Canada, on the application of expert systems in mining operations.IntroductionThe electrical bill charged to large consumers by Ontario Hydro is based upon two elements: demand and energy consumption. The demand is the peak kilowatt level that the consumer has required during a monthly period. It is not uncommon for the demand portion to be as much as one third of the monthly bill. Energy consumption is the total kilowatt-hour s (kWh) consumed during the period.Ways to reduce the energy consumption part of the electrical bill involve utilizing energy-efficient equipment and operating machines in off-peak hours when a lower energy rate is charged. Maintaining the peak power below a critical level may require that simultaneous usage of major pieces of equipment be avoided. A 3000 kW skip run at an inopportune time could cost a company an extra $30,000 in that month&apos;s power cost.Potential disadvantages associated with peak power control are lost production due to work stoppage and increased operating costs due to the need to employ extra personnel. Most companies find these matters relatively easy to deal with and with incentives provided by Ontario Hydro, actively pursue this facet of energy savings (Harju , 1991)."

Jan 1, 1993

By C. H. Lee, K. Adham, D. Lemieux, J. P. Mai, A. M. S. Hussein, S. Francey

Copper concentrates contain an increasing amount of arsenic, as the older sources of cleaner ores are depleted. At the same time, the market-determined price penalties on arsenic rich concentrates are rising due to limited arsenic treatment capacity at smelters and increasingly stringent environmental emissions limits, necessitating arsenic removal from the copper concentrates. Heating the concentrate to about 700°C can remove significant amounts of arsenic (as elemental and/or sulfide); however, it is important to achieve that removal economically and with due consideration to post-roasting arsenic (toxic waste) treatment. A comparison is made among different roasting options (kilns, multi-hearths and fluid beds) to qualify their potential application to arsenic roasting of copper concentrates. Both direct and indirect methods of heating as well as inert, air and oxygen atmosphere options are considered. Technology comparisons are made with respect to the roaster’s operation, its off-gas treatment and arsenic stabilization. INTRODUCTION In the last twenty years, the arsenic content in globally produced copper concentrates have risen steadily due to the depletion of cleaner ores and the increase in complex concentrate production. Smelter contracts typically limit arsenic to less than 0.5wt%, with a penalty paid per unit of additional arsenic and other contaminants such as antimony. While penalties can vary, they can be on the order of $70/dry metric tonne of concentrate per 1% of arsenic. Strategies used by miners to avoid the price penalties have been to blend clean and complex concentrates, and to remove arsenic from complex concentrates to achieve smelter limits. Arsenic can be removed from copper concentrates by the heat-induced decomposition of the predominant enargite mineral (Cu3AsS4) at ~700°C. Roasting at such elevated temperature is a commercially proven option, but still suffers from process, cost and environmental challenges. After roasting, the released arsenic sulfide fumes can be separated from most of the entrained concentrate dust in cyclones. Then, the As2S3 laden off-gas can be oxidized to generate a still volatile oxide (As2O3), which can be further separated from the residual concentrate dust in a hot electrostatic separator. Next, the off-gas can be cooled with air or water, to either deposit the arsenic oxide in a dry or dissolved state. Dissolved arsenic acid can be oxidized to As(V) and reacted with iron to yield a stabilized ferrihydrite precipitate or scorodite that can be safely disposed. In the case of dry arsenic trioxide, it can be mixed with reactants (e.g. iron) and fluxes before thermal stabilization in a glass matrix, thus eliminating the need for costly oxidation.

Jan 1, 2019

By M. Drozd, M. Somppi, Z. Yamak

"Granular activated carbon is widely used in the gold mining industry for gold extraction from aurocyanide-containing slurry. The extraction process can employ carbon as part of the gold recovery operation for various circuit designs including carbon-in-pulp (CIP), carbon-in-column (CIC), and carbon-in-leach (CIL) circuits. However, various qualities of activated carbon exist and the durability of the material can change significantly from source to source. Handling this expensive reagent can pose challenges when fine carbon losses occur in the CIP, CIC, and CIL circuits. Additionally, any gold that is adsorbed to these carbon fines can also be lost by various mechanisms including carbon attrition and fracturing, inefficient coarse-fine separation, and poor carbon fines capture. With the above in mind, a series of tests were conducted to investigate standardizing simple laboratory methods for testing carbon quality. A standard procedure beyond or enhancing ASTM methods can serve as additional starting points for evaluating carbon specific to the gold industry. The investigation focused on size distribution, flatness, wet attrition resistance, surface area, gold kinetics, and gold loading. The final results provided information to generate an equation for ranking carbon samples to plant performance.IntroductionActivated carbon for use in gold extraction is amongst the most commonly found processes in modern gold-milling plants. Although gold losses are inevitable in the milling process, operators often focus on the importance of maximizing gold recovery. One focus area that is important in gold recovery is optimizing the use of activated carbon and examining potential changes to realize improved economics for carbon-in-pulp (CIP), carbon-in-column (CIC), and carbon-in-leach (CIL) processes."

Jan 1, 2017

By J. D. T. Steyl, C. A. Biley

"The chemistry of electrolyte systems containing iron remains generally poorly understood despite their prevalence in many natural and industrial processes, particularly in hydrometallurgy. These systems are typically challenging to study and model due to their affinity for complex formation and precipitation even at low pH. Recent developments in the hydrometallurgical processing of nickel laterites at Anglo American have called for a deeper understanding of the fundamental chemistry of the Fe2(SO4)3–FeSO4–H2SO4–H2O system. This paper details the development of an internally consistent, Pitzer ion-interaction model of this system, with explicit recognition of important contact ion pairs (CIPs). The primary application of this model is a thermodynamic framework for the interpretation of kinetic processes occurring during iron(III) reduction with SO2. Adopting a rigorous thermodynamic basis for the system chemistry facilitates the formulation of simple rate expressions that are capable of inherently capturing complex effects. While the iron(III) reduction case study remains the focus of this work, the developments have more universal applications and the thermodynamic speciation model can be extended into other systems containing acidic ferric sulfate.INTRODUCTIONIron is present in nearly all hydrometallurgical refining circuits typically as both a necessary and unwanted impurity and needs to be removed and disposed in a safe and efficient manner. This is generally performed by precipitation to form a range of solids such as hematite, goethite or jarosite. Numerous studies in the open literature have focussed on the removal of iron from refractory gold sulfide ore (Berezowsky & Weir, 1989; Berezowsky et al., 1991) and zinc pressure leaching (Buban, 1999; Ismael, 2003), and PGM matte sulfide circuits (Dutrizac & Monhemius, 1986). Moreover, since ferric iron is a strong oxidizing agent, it has been used extensively as a leaching agent for sulfide minerals (Dreisinger, 2006). Given the outlook of challenging economic conditions, declining ore grades and increasing levels of impurities, effective iron management is going to become increasingly critical to all hydrometallurgical processes.Against this background, and considering the widespread importance of acidic iron sulfate systems throughout natural and industrial processes, it is unexpected that the knowledge of the fundamental solution chemistry of these systems contains such significant gaps, particularly at the conditions typically found in hydrometallurgical applications. Existing literature describing the measurement and modelling of solution speciation in these systems have highlighted their significant chemical complexity (Magini & Caminiti, 1977; Magini, 1979; Lee & Tavlarides, 1985; Stipp, 1990; Papangelakis et al., 1994; Gil et al., 1995; Majzlan & Myneni, 2005; Kormanyos et al., 2008; Yue et al., 2014). Partially responsible for the lack of quantitative speciation measurements is the strong tendency of ferric to hydrolyse at even low pH (Flynn, 1984), complicating the laboratory study of such systems. Moreover, the large number of aqueous species that may co-exist simultaneously makes the study of individual species and the modelling of the numerous interactions between these species extremely difficult (Dry & Bryson, 1988; Stipp, 1990; Majzlan & Myeni, 2005; Kobylin et al., 2007)."

Jan 1, 2016

By Derek Ettie

"In the Hydrometallurgical processes, the presence of the so-called "crud" is a constant challenge in solvent extraction. Crud is a stable emulsion which forms along the interface between the aqueous and organic phase. The spread is influenced by the following parameters: first, wind blows the dust and impurities into the open sedimentation tanks. Second, the undissolved solids such as sand transported in the PLS causing problems in conjunction with incorrect agitator design.The crud fraction can decisively impact the efficiency of the hydrometallurgical extraction because the phase interface can constitute a large fraction and the sedimentation tanks cannot react flexibly to it. In the downstream process of the series-connected sedimentation tanks, they are thus all contaminated with crud. At the same time, the necessary mass transport is significantly impeded at the phase boundary between organic phase and aqueous phase due to the crud formation.The transfer of the organic phase into the electrolysis cell can result in a "burnout" of the cathode. The carryover of this electrolyte into the extraction can cause problems with the pH regulation. The carry-over of the organic components into the raffinate also leads to contamination of the leaching circuit. The continuous treatment of the crud with a 3-phase decanter centrifuge is extremely effective in combating this problem. This technology splits all three phases from each other and they are consequently continuously separated. All subsequent process steps exhibit a stable, uniform effectiveness. The main advantage for the customer is that fluctuations in the process are eliminated and the organic phase can be recirculated back to the extraction. The recycling of the solvent alone justifies the investment in less than 6 months as examples from South Africa and Chile show.To operate solvent recovery in daily operation fully automated online at the optimum limit, the decanter centrifuge is equipped with a concentration-dependent pond adjustment called DControl® by this means, we can guarantee our customers the maximum possible solvent recovery and minimize the solvent costs in this process step. This system is presented in detail in this paper."

Jan 1, 2014

By H. Zhu, Y. Sato, O. Takeda, K. Nakano

Recycling of rare earth magnet wastes is essential to insure the stable supply of rare earth resources. For the development of a novel recycling process, the removal of rare earth oxide from an off-spec alloy magnet was investigated by melting the alloy magnet at 1503 K together with fluoride flux, LiF-50 mol% NdF3 and LiF-?25 mol% NdF3-25 mol% DyF3. After melting, the separation of magnet alloy from the fluoride flux was achieved, and neither suspension of alloy in the flux nor suspension of flux in the alloy was observed. Oxygen concentration in the alloy decreased from 5000 mass-ppm to 160 mass-ppm by utilizing 1.5 times of equivalent amount of flux needed to completely dissolve the oxide. The investigated process is suitable for mildly contaminated waste such as a used (end-of-life) magnet because of its simplicity, low energy consumption and small limitation on location for operation.

Jan 1, 2014

By Willemijn Husslage

Tata Steel Group At a glance ? Part of the Tata Group ?Tata Steel Group: ?Fortune 500 company ?Top 10 global steel producer ?Annual crude steel capacity of 28 million tonnes ?More than 80,000 employees ?Manufacturing operations in 26 countries across 5 continents ?Serving customers all across the globe ?Turnover 2009-10: $22.8 billion

May 1, 2011