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By J. Y. Kim, Kenneth Stowe, Stephen Chryssoulis

"A series of flotation tests was carried out on Brunswick Mining ore with various pH modifiers (soda ash, lime, KOH) and added ions (ferric, nitrate, sulphate) in the copper lead rougher circuit. The main objective was to identify downstream effects on sphalerite activation and subsequent zinc rougher flotation. Some significant differences in zinc flotation were obtained. Most notably, soda ash and nitrate ions had a positive impact and ferric ions a pronounced negative effect on selectivity.Selected products from the flotation tests were deslimed at 400 mesh, washed with methanol, air dried, placed in teflon vials purged with nitrogen and stored at -15 degrees C. Numerous liberated sphalerite and pyrite particles were selected under a stereoscope and placed in rows on indium foil. The surface compositions of the particles were analyzed with an innovative laser probe (LIMS). The very small analysis area of the LIMS enables the surfaces of individual grains to be characterized. In addition, the rapid analysis time allows a statistically significant number of grains to be analyzed quickly.Surface lead appears to play a major role in zinc activation/flotation. Possible mechanisms are proposed to explain the variations in metallurgical performance at the different test conditions.IntroductionAlthough the bulk composition of mineral grains is an important consideration for the mineral processor it is ultimately surface composition and topography (edges and dislocations preferred sites for reactions) that control reactivity in flotation and cyanidation (passivation, encapsulation and preg-robbing). Determination of the surface properties of particles from process streams poses a particular challenge for the surface chemist for a variety of reasons, including:"

Jan 1, 1994

By A. Suzue, T. H. Okabe, Y. Taninouchi

Methods for the physical separation and enrichment of platinum group metals (PGMs) from autocatalyst scrap were studied in order to develop an environmentally friendly and efficient recycling process. In general, an autocatalyst has a honeycomb-structured ceramic substrate that is coated with a catalyst layer containing platinum (Pt), palladium (Pd), and rhodium (Rh). Therefore, physical separation of the PGM-containing catalyst layer directly from the ceramic substrate is favorable for upgrading the autocatalyst scrap. In this paper, the authors present a scrap-upgrade process consisting of electroless iron plating and magnetic separation techniques. Iron was plated on the surface of a catalyst sample used to represent an autocatalyst, which was then crushed and magnetically separated. The Pd in the catalyst sample was successfully extracted and concentrated in the magnetic powder. Under certain conditions, the process increased the Pd concentration by a factor of 4 and recovered 89% of the Pd in the autocatalyst sample.

Jan 1, 2014

By X. F. Liu, O. Buzzi, Y. Sieffert

This study falls in the context of underground coal fires (UCF) where burning coal can elevate the temperature of a rock mass in excess of thousand degrees. The objective of the research was to experimentally investigate the change in mechanical behavior of a rock when subjected to temperatures up to 900 °C. Several blocks of an Australian mudstone were collected from a mining site in New South Wales, Australia. X-ray diffraction and thermal-gravimetric analysis were conducted on powdered rock in order to determine the critical temperatures at which the main mineralogical changes occur. Then, cylindrical specimens were prepared from intact rock blocks for unconfined compression tests. These rock specimens were then treated by heating in a temperature-controlled furnace at temperatures varying from 100 °C to 900 °C. The heating process consisted of two stages: raising temperature with very slow rate of 1 °C per hour followed by a holding period of 24 hours and then a slow cooling process to room temperature. The compression tests were carried out on treated rock specimens to characterize the change in compressive strength. The macroscopical study was complemented by microstructural investigations via optical microscope, scanning electron microscope (SEM) and mercury intrusion porosimetry (MIP). Results show that the unconfined compressive strength of mudstone decreases with increasing heating temperature up to 450 °C, beyond which it increases. This can be explained by the combined effects of micro cracks and mineral thermal reactions caused by heating process.

Jan 1, 2015

By M. Härting, D. T. Britton, M. Nzikou Mamboukou

"Copper containing different types of nanocomposites have been characterized for nanolabelling and ID. Three types of the rare earth nanoparticles were used for this study, the oxide and the sulphur compound of the Eu and Tb. Characterization techniques uses SEM, and Raman for morphology, chemical composition, and optical characterization respectively. It has been shown that it is possible to include the rare earth particle in a copper matrix without damaging its physical properties. INTRODUCTIONThe development of new materials, often involves the addition of new properties without changing the beneficial properties of the original material (Chen et al., 2009; Khana et al., 2007; Patil et al., 2008). Nanocomposites are nanostructured materials, whose structural elements including clusters, crystallites or molecules, of dimensions ranging between 1 to 100 nm (Moriarty, 2001), or a composite material where one of the phases is a one, two or three dimensionally nanostructured material (Nanotechnology, 2006; Wang, 2001). Nanocomposite materials research is a fast growing area due to the high demand for materials for specialized applications (Edelstein & Cammarata, 1998), such as biolabelling, magnetic storage media, solar energy transformation (Jisen et al., 2004), and resistance welding applications (Bessergenev et al., 1997; Kwon et al.,2006).The properties of the nanocomposite materials depend not only on the properties of their individual parent materials, but also on their morphology and the interfacial characteristics. Thus, significant efforts have been focused on the control of the nanoscale structures via innovative synthesis approaches. Therefore, novel materials of unique properties may be obtained by combining properties from the parent constituents into a single material (Balan, 2006; Garcia et al., 2009). Possible effects of nanocomposites in the original material may include changes in the mechanical properties such as hardness , wear resistance (Rafaja et al., 1987), and electrical properties (Britton et al., 2003). The inclusion process may therefore be used to tailor materials to have particular mechanical, electrical and optical properties (Das et al., 2009). However, to fully understand the nanocomposite, it is necessary to study the fundamental properties of both the host matrix and the inclusions (Li, 2008)."

Jan 1, 2012

By Stephen Mullowney

Outline ? Setting the stage ? Deal activity ? Q1 2013 update ? Key deal sectors ? Deals by geography ? Outlook for 2013 Key Observations 2012 ? Major retreat in M&A activity ? Glencore-Xstrata deal dwarfs all other deals ? Gold & copper dominate deal activity

May 1, 2013

By B. K. Mishra, Subrat Kumar Padhy, B. C. Tripathy, I. N. Bhattacharya

Manganese is a difficult metal to electrodeposit due to its high electronegativity and continues to possess unique process challenges. Manganese deposits of high quality are electrodeposited on 316 grade stainless steel from sulphate solutions in the presence of organic additives such as tetra ethyl ammonium bromide (TEABr), tetra propyl ammonium bromide (TPABr), and tetra butyl ammonium bromide (TBABr). The concentrations of these additives were examined over a relatively broad range to evaluate their effect on current efficiency, specific energy consumption and deposit morphology of the electrodeposited manganese metal. A maximum current efficiency of 68% was achieved in the presence of TEABr in the bath. X- ray diffraction studies revealed that (330) (411) planes were the most preferred planes of crystal growth during manganese electrowinning at a current density of 500 A/m2 resembling alpha-manganese irrespective of the nature of additive. Scanning electron micrographs showed smooth and uniform deposit morphologies when manganese was electrodeposited in the presence of TEABr.

Jan 1, 2014

By N. A. Beier, N. Slingerland

"Oil sands tailings impoundments rank among the largest (spatially) in the world, covering a total of approximately 220 km2 of northern Alberta, Canada. A preliminary geomorphic design for an oil sands tailings storage facility (TSF) landform was completed with the goal of eventual closure and delicensing in mind. This paper outlines methods identified during the design process that streamline closure when implemented early in the mine planning and TSF design stages. With most oil sands TSFs currently in active operation (and some still in the planning stages), geotechnical engineers and mine planners have the opportunity to make operational and design decisions, such as those outlined herein, that are likely to improve the geotechnical and environmental performance of the landform post closure. ¦ KEYWORDS Alberta, Athabasca oil sands (AOS), Landform design, Reclamation, Sand dam, Tailings storage facility (TSF) RÉSUMÉ Les bassins d’accumulation des résidus issus des sables bitumineux font partie des plus grands (en termes d’espace) au monde, et couvrent au total environ 220 km2 dans le nord de l’Alberta, au Canada. Une conception géomorphologique préliminaire a été réalisée pour le modelé d’une installa¬tion de stockage des résidus (ISR) issus des sables bitumineux en gardant à l’esprit la fermeture et le retrait de permis à terme. Cet article présente les méthodes identifiées pendant le processus de conception qui simplifient la fermeture lorsqu’elles sont mises en oeuvre dès les premières étapes de planification de la mine et de conception de l’ISR. La plupart des ISR issus des sables bitumineux se trouvent dans des exploitations actives (dont certaines en sont encore aux étapes de planification), aussi les ingénieurs géo¬techniques et les planificateurs miniers ont la possibilité de prendre des décisions en termes d’exploita¬tion et de conception, telles que celles présentées ici, qui pourraient améliorer la performance géotechnique et environnementale de la phase suivant la fermeture du modelé. ¦ MOTS CLÉS Alberta, assainissement, barrage de sable, conception du modelé, installation de stockage des résidus (ISR), sables bitumineux de l’Athabasca (SBA)INTRODUCTION The Athabasca oil sands (AOS) underlie 140,200 km2 of land in northeastern Alberta, Canada. Oil sands located within 100 m of the original surface account for 4,800 km2 of the total area and are considered to be economically mineable (Figure 1; ERCB, 2009). Bitumen, the thick, tar-like substance contained in the AOS, is extracted through open-pit mining and in-situ methods. During mining, the overburden is first removed as waste and the sandy, bitumi¬nous ore (“oil sand”) is transported to processing facilities via conveyor belts and 400 t trucks. Warm and hot water, as well as process aides such as caustic soda, are mixed with the oil sand, creating a slurry from which bitumen is mobilized and extracted. The resulting slurry waste product is called “tailings” and contains mineral solids, process water, and small proportions of unrecovered bitumen (Masliyah, Zhou, Xu, Czarnecki, & Hamza, 2004; Sobkowicz & Morgenstern, 2009)."

Jan 1, 2019

By Arnfinn Prugger

"The construction of the new Scissors Creek shaft at the Rocanville mine, the first potash shaft successfully completed in Saskatchewan Canada since 1979, is summarized here. Located 15km from the existing Rocanville surface plant, this new 6 m inside-diameter, 1121 m deep service shaft was built for fresh-air ventilation and access. Shaft construction in the Saskatchewan sedimentary basin involves sinking through five different rock-types: glacial tills, shales, sandstones, carbonates and salts. The first four rock- types are all water-bearing, and the salts will dissolve in water. This results in five different sinking challenges and requires five different shaft lining designs. The upper 580 m of rock (the till – shale – sands sequence) was frozen before sinking, and grouting methods were used for water control through deeper carbonate levels. Challenges that were faced and overcome during shaft sinking are reviewed, and ideas that future operators working in sedimentary basin environments might consider in order to avoid these difficulties are discussed.INTRODUCTIONThe Nutrien Inc. (formerly Potash Corporation of Saskatchewan Inc. / PotashCorp) Rocanville potash mine in southeast Saskatchewan, Canada has been in continuous production since 1971. Devonian potash, formed approximately 380 Mybp, is mined in a sedimentary basin environment at approximately 1000 m depth below surface in this area of Saskatchewan. The predominant use for finished potash products is fertilizer: potash fertilizer is concentrated and nearly pure KCl (i.e. greater than 95% pure KCl). Currently 10 potash mines are in operation in Canada, all in Saskatchewan. In 2018 Saskatchewan mines produced ˜ 23 million tonnes of finished potash products, which is approximately 35% of World demand of ˜ 66 million tonnes for the year (e.g. Nutrien Inc., 2019).In November, 2007 it was announced that the Rocanville potash mine would be expanded to increase production from 3.0 Million tonnes per year (Mtpy) to approximately 6.0 Mtpy of finished potash products, requiring an increase in hoisting capability from approximately 9.0 Mtpy to over 18.0 Mtpy. The Rocanville potash mine has historically been accessed through two shafts: a production and ventilation exhaust shaft, and a service and ventilation fresh-air shaft located approximately 200 m from each other. All surface offices, processing facilities, etc. are situated near these original shafts.A very important part of the recent Rocanville expansion involved the construction of a new service shaft (6 m diameter, 1121 m deep) for fresh-air ventilation and access, approximately 15km west of the existing surface plant. Once this third shaft was completed in 2015, the historical service shaft was converted to a second exhaust and production shaft. Three shafts are now available for mine access, ventilation and ore hoisting at Rocanville. As of December 31, 2017, annual nameplate capacity for Rocanville was 6.5 million"

Jan 1, 2019

By R. V. Fox, L. K. Sinclair, D. L. Baek

"In this study, rare earth elements were recovered from bastnasite concentrate and waste fluorescent lamp phosphors using supercritical carbon dioxide extraction with a nitric acid/tributyl phosphate adduct. Several pretreatment methods were used to alter the crystal structure of the source materials, and thus improve rare earth element recovery. Pretreatment methods included 1) dry roasting of the source material at 730oC, 2) decomposition with 50% sodium hydroxide solution at 150oC for 4 hours, and 3) decomposition with 12 M sulfuric acid at 300oC for 4 hours. Treated and untreated samples underwent supercritical extraction at 24 MPa and 65oC for 1 hour. Untreated bastnasite and phosphor samples showed <10% rare earth element recovery, but sodium hydroxide digestion resulted in >60% recovery for most rare earth elements. Dry roasting of the bastnasite concentrate was also effective, resulting in >60% recovery for cerium.INTRODUCTIONRare earth elements (REEs) consist of the 15 lanthanides, scandium, and yttrium. Scandium and yttrium are included because they are in the same group as lanthanum, appear in many of the same ore deposits as the rest of the lanthanides, and exhibit many similar chemical properties. REEs are used in a wide array of applications including electronics, magnets, catalysts, glass, and solid-state lighting (Xie, Zhang, Dreisinger, & Doyle, 2014). Because of China’s continued dominance of worldwide REE production, the United States Department of Energy has sought to diversify domestic supplies of REEs (United States Department of Energy, 2011). A key part of this strategy is the development of improved extraction methods for both ores and recycled sources.Supercritical fluid extraction (SFE) is a promising technology for extraction and separation of rare earth elements. Contact with an acid adduct dissolved in supercritical carbon dioxide allows for the rapid extraction of REEs from solid matrices. Supercritical CO2 has several potentially useful properties as a solvent, including high diffusivity and the ability to tune solvation properties by adjusting pressure. Such tunability may have applications in separating the REEs once they have been extracted from the solid phase. Tributyl phosphate/nitric acid adducts (TBP:HNO3) are a particularly promising class of adducts for SFE extraction of rare earth elements. Using TBP:HNO3 adducts in supercritical CO2, several researchers have successfully extracted REEs from their oxides (Wuhua, Pijia, & Yongjun, 2010; Zhu, Duan, Xu, & Zhu, 2009). However, there is a complication in applying this technique to many types of ores and recycled sources: REEs are often locked in refractory minerals which are resistant to acid attack, resulting in limited recovery in supercritical extraction."

Jan 1, 2016

By M. Rafiee

Indoor physical security, as a perpetual and multi-layered phenomenon, is a timeintensive and labor-consuming task. Various technologies have been leveraged to develop automatic access control, intrusion detection, or video monitoring systems. Video surveillance has been significantly enhanced by the advent of Pan-Tilt-Zoom (PTZ) cameras and advanced video processing, which together enable effective monitoring and recording. The development of ubiquitous object identification and tracking technologies provide the opportunity to accomplish automatic access control and tracking. Intrusion detection has also become possible through deploying networks of motion sensors for alerting about abnormal behaviors. However, each of the above-mentioned technologies has its own limitations. This paper presents a fully automated indoor security solution that leverages an Ultra-wideband (UWB) Real-Time Locating System (RTLS), PTZ surveillance cameras and a Building Information Model (BIM) as three sources of environmental data. Providing authorized persons with UWB tags, unauthorized intruders are distinguished as the mismatch observed between the detected tag owners and the persons detected in the video, and intrusion alert is generated. PTZ cameras allow for wide-area monitoring and motion-based recording. Furthermore, the BIM is used for space modeling and mapping the locations of intruders in the building. Fusing UWB tracking, video and spatial data can automate the entire security procedure from access control to intrusion alerting and behavior monitoring. Other benefits of the proposed method include higher accuracy and robustness, more complex query processing, and interoperability with other BIM-based solutions. A prototype system is implemented that demonstrates the feasibility of the proposed method.

Aug 1, 2013

By J. C. Li, Y. Zou, L. He

"The effect of rock joints is significant in characterizing dynamic behaviors of discontinuous rock masses. To reveal the relation between the transmission coefficient and the contact situation of the joint surface, an experimental study on stress wave propagation across an artificial rock joint was carried out using a modified Split Hopkinson Pressure Bar (SHPB) apparatus. All the bars and specimens were norite cored from the same site, and one surface of the specimen which contacted to the transmitted bar was sawn with a number of notches to simulate the artificial rough joint. According to a wave separation method, two strain gauges were mounted on each pressure bar at a specific spacing, then the incident, reflected and transmitted waves across the joints were obtained from the test data. It was found that the contact situation of the rock joint surface makes a different on the wave propagation. Finally comparisons of the transmission coefficients with different contact area ratios and different joint thicknesses were made respectively. The results show the effects of contact area ratio and thickness of joints on wave transmission.INTRODUCTIONJoints affect the dynamic mechanical behaviors of the rock masses significantly. When propagates across the rock masses, wave usually attenuates in amplitude and frequency due to the presence of the joint as a discontinuous interface in the rock masses. Rock joints are the main factor that affects the behaviors and properties of rock masses. Many researchers have focused on the mechanical properties of rock joints under quasi-static conditions. Nowadays, the effect of joint dynamic properties on wave propagation across rock masses is gradually taken into account in theoretical and numerical studies.The effective contact area, joint roughness, and properties of the asperities and filling materials have been found to influence the normal stiffness of joints (Bandis et al. 1983). As suggested by the International Society for Rock Mechanics (ISRM), the roughness of the discontinuities can be generally characterized by large-scale “waviness” and small-scale “unevenness” (Brown 1981). Many researchers focused on the roughness of rock joints that affects the mechanical properties of rock masses and wave propagation. For example, Brown and Scholz (1985, 1986) presented theoretically and verified experimentally a closure model of contact between two random nominally flat elastic surfaces, which showed that the joint closure property depended both on the surface topography and material properties. Pyrak-Nolte et al. (1997) presented the quantitative aperture data for three-dimensional interconnected fracture networks, which were imbedded in intact opaque rock samples several centimeters in length, using x-ray computerized tomographic (CT) imaging. Fardin et al. (2001) systematically investigated the effect of scale on the surface roughness of rock joints and concluded that samples should be equal to or larger than the stationary limit for surface roughness to be accurately characterized on a laboratory scale or in the field. Zhao et al. (2006) conducted excellent ultrasonic tests across intact cement mortar specimens, singlefracture specimens, and two-fracture specimens."

Jan 1, 2015

By S. Y. Mostowy, P. W. M. Shibley

"When Texas Gulf Sulphur Company discovered the Kidd Creek ore body in 1964, a crash program began almost immediately for the design and construction of a modern concentrator. It was necessary to mill two distinct ore types; one containing copper and zinc, the other lead, silver and zinc minerals. The final concentrator design was to handle 9,000 tons of ore daily in three circuits. One circuit was to treat copper-zinc and another lead-zinc ore exclusively on a permanent basis. A central circuit was designed with adequate flexibility to treat either of the above ore types in accordance with planned mining schedules. Ecstall Mining Limited, a wholly owned subsidiary, now operates the mine and concentrator complexes for Texas Gulf. The mine is located 15 miles north of Timmins and the concentrator 15 miles to the north-east along Highway 101. The ore is hauled from the mine to the concentrator over a 17-mile railroad. Initial milling operations began in November, 1966.1 - ABSTRACTThis paper deals with bulk reagent handling at the Kidd Creek concentrator. The reagent section at Kidd Creek has operated excellently since milling began in 1966. The bulk handling techniques are satisfactory. They have contributed substantially to good working conditions, economical practices and metallurgical efficiencies. The bulk handling features described should be considered in existing and proposed concentrators."

Jan 1, 1970

By Y. Héroux, A. Chagnon, M. M. Savard

"Résumé - Le gite de Pb-Zn de Gays River s&apos;accompagne d&apos;anomalies des propriétés de la matière organique (MO) et des assemblages de minéraux d&apos;argile (AMA). L&apos;association entre la minéralisation, la distribution de la réflectance de la MO et des AMA suggère que ces traceurs peuvent servir à I ‘exploration des sulfures de métaux de base dans cette région.A I ‘emplacement du gîte, la réflectance varie considérablement (0,8% à 1,88%), pouvant même afficher une baisse avec I ‘enfouissement, ce qui est interprète comme une altération chimique de la MO. Les valeurs les plus élevées s&apos;accompagnent localement de quelques textures en mosaïque et délimitent une anomalie thermique au centre sud de la région. Parmi les minéraux des argiles identifies, I ‘illite et la chlorite sont terrigènes alors que la smectite, la kaolinite et la corrensite sont authigènes et, à l&apos; instar de I ‘altération de la MO, résultent des nouveaux équilibres chimiques créés suite à la précipitation des sulfures.Abstract - The Gays River Pb-Zn ore deposit is associated with anomalies defmed from the characters of the organic matter (OM) and from the clay minerals assemblages. The relationships between these anomalies and the mineralization at the mine suggest that these parameters can be used as new guides for the exploration for base-metal sulfides in this area.The vitrinite reflectance (RJ shows a wide range of values (0.8% to 1.88%) and exhibits an anomalous suppressive effect with depth of burial at the mine site, suggesting a chemical alteration of the OM. The highest R"" values are associated with mosaic textures and outline a therrnal anomaly at the south-center of the studied area. Among the identified clay minerals, illite and chlorite are terrigenous, whereas smectite, kaolinite and corrensite are authigenous and, like the alteration of the OM, are due to the new chemical equilibria resulting from the precipitation of the sulfides."

Jan 1, 1994

By C. Caballero, A. Warczok, K. Itagaki, A. Moyano, J. Font

The Codelco Norte Smelter process 2,500 tpd of arsenic-bearing concentrates with an arsenic content of up to 1.5% in one of its two main smelting units, the Teniente Converter. The product, 1,100 tpd high-grade matte or white metal, is traditionally fed to the PS converters, while the 1,700 tpd of slag is fed to the slag cleaning electric furnace for copper recovery. This is achieved in a very reductive environment which reduces the viscosity of the slag and enhances the sedimentation of the high-grade matte droplets. The behavior of arsenic in this non-oxidative environment was studied at lab-scale and fundamental thermodynamic data were obtained. Based on these data a thermodynamicbase model to assess the arsenic behavior in reductive environment was developed. It is based on a mass balance for the reduction and sedimentation stages performed in an electric furnace which allows the recovery of high-grade matte droplets after decreasing the viscosity of the slag. This model can be a very suitable tool for predicting fractional distribution of arsenic in the slag cleaning electric furnace, when the distribution ratio, vapor saturation degree, temperature, y As and pO2 are given.

Jan 1, 2007

By Jeffrey T. McGinty, Frank M. Wheeler

Plant layout is the arrangement of equipment, process areas, departments, infrastructure, and support facilities. Plant logistics is the flow of parts, people, resources, and information throughout the production process. This chapter: outlines key factors and provides checklists to facilitate layout development; presents risk management approaches to test the logistics and functionality of alternative layouts; and uses real-world examples to illustrate effective simulation modelling to assess plant layouts.

Jan 1, 2015

By A. L. Mackie

Arsenic is a highly toxic element and a known human carcinogen. It is often a contaminant in mine water discharges, particularly from gold mining and roasting operations, and has been found at concentrations as high as 4 g/L. Increasingly stringent controls on the concentration of arsenic allowed to be discharged into the environment cannot always be met by current treatment processes and thus enhanced technologies are required to achieve low treated effluent concentrations at reasonable costs. A novel two-step physicochemical treatment process was developed and tested at the bench-scale using synthetic mine water solutions (SMWs) in order to reduce arsenic concentrations in treated effluent to exceed current discharge regulations. The process includes chemical coagulation with ferric sulphate and ballasted flocculation for enhanced solid-liquid separation. The SMW contained 59 ± 2 mg/L arsenic with a slightly alkaline pH. The effect of arsenic speciation on the process was tested by using either arsenite, As(III), or arsenate, As(V), in the SMW solutions. Tests were performed at cold temperature (3 ± 1 °C) to ensure the process? efficacy year-round in northern climates. Arsenic in As(V) SMW solutions was removed to a final total concentration of 0.0054 ± 0.002 mg/L, almost half the current recommended allowable drinking water concentration of 0.010 mg/L. As(III) was removed to a concentration below the Metal Mining Effluent Regulations? (MMER) current limit of 0.50 mg/L, to 0.32 ± 0.06 mg/L, with double the coagulant dose used in Stage 1 for As(V) removal. Oxidant addition at a concentration of 5 mg KMnO4/L in Stage 2 resulted in final total arsenic concentrations of 0.017 ± 0.002 mg/L and pH adjustment with lime in Stage 2 resulted in 0.0415 ± 0.0007 mg As/L in treated As(III) SMW. Both of these modifications to the process reduced arsenic concentrations to below proposed new MMER limits (i.e., 0.10 mg/L). This two-stage treatment process was shown to reduce arsenic concentrations to well below current treatment guidelines while reducing or eliminating chemical oxidant demand.

Aug 1, 2013

By H. Lachmund, R. Bruckhaus

At Dillinger Hüttenwerke/Germany steel production of grades for linepipe applications especially for sour service has a long tradition. The BOF process after replacement of the vessels is optimized by a newly developed lime addition model and variations in lance tip geometry. Equipped with three state-of-the-art VOD tank degassers metallurgical requirements of lowest contents of e. g. sulphur, nitrogen and hydrogen can be achieved. Three continuous casting machines of vertical bending type with solid core even improve already high levels of cleanliness. The vertical part corresponds to the metallurgical length of 12 to 15 m and therefore assures a maximum of cleanliness after solidification before bending. Slab thickness up to 400 mm can be produced with model controlled dynamic soft reduction. The accurate alignments of the casters assure minimized segregation and microporosity. Surface and internal cracks can be avoided by special cooling, bending and straightening strategies.

Jan 1, 2005

By R. E. Gilmore

PREAMBLE THIS PAPER comprises material presented in two separate &apos;Papers at the British Commonwealth Scientific Specialist Conference on Fuel Research held in London, England, in July, 1950. These papers are now available for publication in Canada, since only essential parts of the conference discussions, in addition to the resolutions resulting therefrom, will be published in the official Proceedings of the Conference. Inasmuch as the information presented concerns Canadian organizations and training facilities for fuel research, it should be of general interest to Canadian scientists, and especially to the Coal Division of the Canadian Institute of Mining and Metallurgy. Part I, the alternate title of which is Facilities in Canada for Fuel Research and for Exchange of Information and Staff, does not include research on peat, oil shale, petroleum oils in general, and natural gas, and omits studies of the geology, constitution, and production of coal. Special reference is, however, made to research on the heavy crude oils and bitumen of the Western Prairie Provinces, and particularly to their production and treatment to produce crudes for oil refinery processing.

Jan 1, 1951

By J. G. Patterson

"The depressive action of sodium cyanide on chalcocite has been investigated and found to be unstable. Flotation results show that with the addition of sodium cyanide to the system chalcocite is initially depressed but rapidly recovers with time, provided there is sufficient oxygen present.lt is proposed that the unstable depression is due to the reaction of cyanide with adsorbed xanthate and copper ions at the chalcocite surface to form soluble copper complexes. When all the free cyanide has so reacted, xanthate anions can then re-adsorb on the chalcocite surface and the flotation will recover. Results are presented to verify the the above mechanism."

Jan 1, 1968

By L. Paulino, C. E. Zangiacomi, J. Yamamoto

"This paper presents the learning from Alcoa Po9os de Caldas Smelter in Brazil, after several energy restrictions resulting from the failures of three rectifier units at its power switchyard. Starting on December 27th, fuses and diodes failed in three rectifier units of Potline #1, causing a long and dangerous power interruption. Even after current was reestablished, amperage was only 70% of the line target leading to a bath freezing process that lasted for around 48 hours. The process engineering team played with several potroom parameters as pot resistance, bath and metal levels, alumina feeding and bath chemistry in an attempt to minimize impact on the potline metal output and energy consumption. As it will be illustrated, the first battle was to keep the pots running on a ""survival"" approach. After that, several changes took place on the procedures used to run at reduced current which were considered rather successful. Finally, some recommendations will be given to foresee and prevent transformers and rectifiers from undesirable failures."

Jan 1, 2006