Search Documents

By Aldo Cipriano, Fernando Estrada

The mining industry is in search of control strategies that allow considering a global optimization of their processes, ensuring their stability. This has led to the application of recently developed control techniques on large-scale systems in the mining processes. One of the most important process of the mining industry is the mineral grinding, as the product particle size impacts, in a significant manner, the recovery rate of the valuable mineral in the separation stages. As a solution, a centralized hybrid model predictive control (HMPC) is presented; this control approach maintains the product particle size on a defined range and minimizes energy consumption, maintaining the grinding plant in a stable operation. As a comparison, a conventional model predictive control with an expert system to handle discrete events was developed, showing HMPC is a suitable solution that can used in the grinding process, with the benefit that it handles in the same controller both discrete and continuous dynamics and events.

Jan 1, 2014

By V. P. Yakushkin, B. S. Ksenofontov

"Multistage model designed and used for more detailed description of floatation process. The study develops a new model of flotation kinetics description. It defines flotation as process that consists of several stages: air bubbles and particles are separate, air bubbles and particles form a raising aggregate, aggregate raises to froth layer. This description significantly differs from commonly used model, which is much simplified. The multistage model gives an in-depth description and considers different aspects of flotation. Experimental approval of the new model resulted in its accuracy.The model is to be used for description of all flotation processes’ kinetics of wastewater treatment. It helps in accurate designing of flotation treatment plants and may be used for further research of flotation process. Columnar flotation installation was designed by using multistage model. This installation consists of new tubular aerators with special ejectors, froth pressing system as well as unit of thin-layering lighting to catch microflotocomplex “particle – bubble”. Usage of tubular aerators allowed to aerate the overall volume of pulp. Due to use of special ejectors with longer mixing camera we state higher volume of small-sized floto-active bubbles. Use of multistage model allowed to optimize and get higher technological results of potash salts enrichment. Tests were conducted on centrifuges-floatation installation system. Meanwhile, froth concentrate contained mainly thin hydrophobic particles sized circa 0,1 mm. As a result we set that during floatation cleaning process of froth concentrate 95-98% of chloride potassium (KCI) is derived from foam.The final product satisfies production quality. Columnar floatation installation productivity was 17 – 21 m3/m2h, which is a high technological result. Columnar floatation installation is one of the best examples of concentrating equipment using nearly all technological indices."

Jan 1, 2018

By Richter, E. Charikinya

"Mineral processing unit models require information on particulate properties such as particle size, solids flowrate and mineralogical composition to model their operations. Process models that describe the separation process can be classified based on the level of information required from the ore, i.e. the feed stream to the separating unit. The most comprehensive level of mineral processing models is the particle-based modelling approach. Particle based modelling describes a modelling approach where mineral composition, mineral liberation and textural information of particles making up the process streams is used in modelling. The advantage of this approach is that all model streams carry particle level information (size, liberation, shape). This information is obtained by applying automated mineralogy techniques such as Quantitative Evaluation of Minerals by Scanning Electron Microscopy (QEMSCAN) analysis which provide accurate and detailed information on process stream particle properties. Currently the use of liberation information in modelling and simulation is rare, due to the limited number of separation models that liberation data as input. The objective of this study is to develop a particle based model for a dry magnetic separator, where mineralogical information is used directly to simulate a dry magnetic separator operation. Magnetic separation tests were carried out on high, medium and low grade magnetite ores using a laboratory magnetic separator. Streams from the separator were sampled and sized for chemical and liberation analyses. A sized mass and elemental balance around the magnetic separator was carried out. The elemental assays of each stream were converted to mineral quantities and a sized mineral balance was done. QEMSCAN measured liberation data was reconciled to the mineral balance based on mineral quantities obtained from chemical assays. This was followed by the development of a particle based model that calculates the trajectory of a single particle based on its mineral composition and textural properties. The model was tested on experimental data and was able to predict the effect of variation in process feed stream mineralogical attributes (liberation, grade, particle size) on magnetic separation performance. Results of this study highlight the benefits of the particle based modelling approach. INTRODUCTION The extraction of mineral values from ore requires liberation of the value minerals from the gangue followed by their separation. Liberation is achieved by size reduction operations (Desmond, 2008; Fuerstenau and Abouzeid, 2002). Separation of gangue material from value mineral takes place in various mineral upgrading stages such as classification, magnetic separation and flotation. In these concentration stages value minerals are separated from gangue minerals based on the physical properties of the ore particles making up the feed such as size, liberation, volume of magnetic material and density. The success of separation is related to the liberation of the feed particles, the performance of the separation technology applied, as well as the inherent characteristics of the feed material (Leißner et al., 2013)."

Jan 1, 2018

By A. Kamali Moaveni, A. Boehm

"The current research study addresses a physical separation process of basic oxygen furnace slag “BOF-Slag” (also called Linz-Donawitz “LD” slag) for the removal of phosphorous. In order to recycle the LD-Slag into the steelmaking process, the physical dephosphorization methods are considered. The systematic geometallurgical investigation carried out on particle classes of decreasing size, which were further subdivided into susceptibility classes, shows intimate intergrowth beyond 40 µm due to slag´s fast cooling rate. Generally, LD-slag is constituted of oxide and silicate phases, among which di-calcium silicate “C2S” dominates. About 0.5 mass% of phosphorous was detected in the LD- slag, which is exclusively situated in the lattice of the C2S. The comparatively high grinding resistance (Rittinger index 12.9 cm²/J) of the LD-slag reflects the energy demand to liberate the phosphorous carrying phase from the iron containing minerals, while separation efficiency decreases in the very fine particle size range. Hence, the conversion of the phase intergrowth pattern was considered alternatively to re-build the mineral phase structure of the material to a separable interlock pattern. Carbon dioxide, as the most convenient substance in the steelmaking plants, was applied to digest the C2S in the presence of water and to reduce the basicity of the slag slurry. As a result of C2S-CO2 chemical reaction, calcite and calcium silicate are precipitated at the surface of the oxide particles and carried between 25% and 75% of the total phosphorous, respectively. Accordingly, the mobility of the phosphorous content phase to the top of the grains serves the possibility to separate the precipitated layer by mechanical attrition process. This paper is focused on the impact of the intergrowth pattern alteration on the slag´s separability characteristics. Moreover, the operating conditions of the carbonization process, such as temperature and pressure, on the deconstruction kinetics of the C2S and the generated products will be considered. INTRODUCTION The steelmaking BOF-Slag is a stony aggregate waste from the steel manufacturing process. The investigated slag by the current research work was provided by voestalpine steelmaking plant in Linz, Austria. The current legislative situation in Austria restricts the historical application of slag as construction material, due to the high level of heavy metals content and corresponded land-filling and transportation costs of slag, therefore the demand for recycling of BOF-Slag to the steelmaking process has raised, as an alternative application. Statistically, voestalpine steelmaking plant produces about 130 kg BOF-Slag per ton of final steel product, which serves annual BOF-Slag production of 700,000 ton, approximately."

Jan 1, 2018

By John Ralston, Jona Addai-Mensah, Patience Mpofu

The flocculation and dewatering behaviour of kaolinite (non swelling) and smectite (swelling) clay dispersions has been investigated using hydrolysable metal ions Mn(II) and Ca(II) and anionic polyacrylamide-acrylate copolymer (PAM) at pH 7.5 and 10.5. A pH-dependent, specific metal ion adsorption behaviour, accompanied by a marked reduction in particle zeta potential and slurry shear yield stress, was observed to have a profound influence on the colloid stability of both types of clays. Due to the differences in the cation exchange capacity, the smectite clay dispersion required a higher amount of metal ions than kaolinite dispersion to produce similar effects. The adsorption density of the anionic PAM at the negatively charged clay particle surfaces correlated well with metal ion hydrolysis and adsorption behaviour, all of which had a strong effect on slurry settling rate and extent of consolidation. At pH 7.5 where Mn(II) ions hydrolyse, metal ion and flocculant adsorption densities were both greater in the presence of Mn(II) than Ca(II) ions. At pH 10.5, however, where Ca(II) ions begins to hydrolyse, higher adsorption densities were observed for Ca(II) ions in comparison with Mn(II) ions, as the latter hydrolysed completely and precipitated. The metal ion mediated flocculant adsorption led to improved hydrogen bond driven particle bridging and facilitated charge neutralisation flocculation mechanisms which significantly enhanced the dewaterability of both clay dispersions.

Jan 1, 2003

By Hao Zhang, Dezhou Wei, Qiang Zhao, Caie Zhang, Baoyu Cui, Xuetao Wang

"Nowadays, long periods of relatively low iron ore prices have made the steel industry get the greater pressure. To develop appropriate processing technology based on characteristics of the iron ore, so as to reduce the beneficiation costs, is crucial to the improvement of iron and steel enterprise competition. For a typical low-grade iron ore from northeast China, beneficiation process research was conducted based on the in-depth studies of ore characteristics. Results show that the iron grade of the ore was 31.56%, the content of FeO was 6.59%, the main iron minerals were hematite and magnetite with fine dissemination sizes and partly scattering in gangue; With the grinding fineness of 65% passing 0.074mm, and regrinding fineness of 90% passing 0.074mm, the concentrate with 66.80% iron and recovery of 82.90% was obtained via the combined flowsheet of stage grinding – classification – gravity concentration – low and high intensity magnetic separation – reverse flotation. Ratios of gravity concentration and low intensity magnetic separation were 70.21% and 7.57% respectively in 40.42% of total concentrate yield; The loss of micro-size fractions can be reduced by feeding spiral tailings into magnetic separation and flotation; It’s helpful in reducing the dosage of reagents and beneficiation costs by increasing the throughput of gravity concentration and outputting concentrate of low intensity magnetic separation.INTRODUCTION Iron and steel industries are facing the increasing pressures in the continued falling iron ore prices. In order to improve the competitiveness, it is extremely urgent for them to develop more appropriate separation process for the reduction in iron ore beneficiation cost. As a typical low-grade iron ore, Anshan-type iron ore is one of the most important iron ore resources in China [1-3]. The flowsheet of stage grinding and separation contained the classification of the coarse particles and the fine particles, the gravity concentration, the magnetic separation and the anionic reverse flotation has been widely applied for Anshan-type iron ore. With the appropriate separation progress as well as equipment, satisfactory separation results had been obtained, and mineral particles with different size were recovered separately [4-7]. However, the low recovery of fine mineral particles and the relatively high beneficiation costs still prevented the efficient application of the process [8]. For a Anshan-type low-grade iron ore, a typical process flowsheet, as mentioned earlier, with stage grading, classification of the coarse particles and the fine particles, gravity concentration, magnetic separation, anionic reverse flotation was adopted currently. And the concentrate with 67.10% iron and recovery of 75.50% was obtained and the gravity concentrate accounted for 39% of the total concentrate. However, a large amount of fine liberated iron ore particles were lost in the tailings."

Jan 1, 2018

By Hillary Williams, Ronghao Li, Christopher Marion, Kristian E. Waters, Devin Hundt

"Zircon is an important mineral for ceramic, foundry, casting, and refractory applications; and it is the worlds primary source for zirconium. Zircon can also contain large and valuable proportions of other valuable metals, such as rare earth elements and hafnium. The Nechalcho deposit (Northwest Territories, Canad), is a hard rock REE deposit, which looks to recover zircon for its Zr and REE content. In this deposit, zircon is finely disseminated and associated with predominately silicate gangue minerals. Most of the work to date has focused on the beneficiation of mineral sand deposit, which typically remove silicate gangue minerals through physical separation steps. Therefore, the separation of zircon from silicate gangue, such as quartz, by flotation, has received little attention. This work used zeta potential measurements and microflotation experiments to understand the interaction between zircon and six different collectors (sodium oleate, sodium dodecyl sulphate, dodecylamine, SM 15, K-octyl hydroxamate and Florrea 7510). The results were compared with those of quartz. This study indicated that selective separation of zircon from quartz without the use of selective depressants or activators is likely challenging. The findings suggested sodium oleate and SM 15 only offered selective flotation of zircon in highly acidic conditions. Separation by the flotation of quartz is possible using sodium dodecyl sulphate, dodecylamine and K-octylhydroxamate. However, selective separation is highly dependant on collector dosage, for dodecylamine, and the selective activation of quartz, for sodium dodecyl sulphate and K-octyl hydroximate. Florrea 7510 offered poor recoveries for both zircon and quartz.INTRODUCTIONZircon (ZrSiO2) is a nesosilicate mineral which has a wide variety of applications, due to its hardness, opaqueness and resistance to heat and corrosion. Its major end uses are in ceramic, foundry, casting, and refractory applications (Bedinger, 2017). Zircon is also the most abundant zirconium (Zr) bearing mineral in the earths crust and is the principal economic source of Zr (primarily used in alloys for heat and corrosion resistance) and zirconia (ZrO2) (primarily used in ceramics) (Bedinger, 2017; Milnes and Fitzpatrick, 1989). Zircon forms in silicate melts and can often contain large proportions of other valuable metals such as rare earth elements (REE), and hafnium (zircon is the primary source of hafnium) (Bedinger, 2017; Belousova et al., 2002; Orlova, 2007). A common chemical formula showing the range of substitution in zircon is (Zr,Hf,Th,U,REE,Ca,Fe,Nb,Ta)(Si,P)O4 (Orlova, 2007)."

Jan 1, 2018

By Gus Van Weert, Samuel A. Bolorunduro, David B. Dreisinger

"Silver is currently lost as jarosite during the pressure oxidation of sulphides and cyanidation of the residues yields 5-10% of silver. Efforts to recover silver from complex sulphides, which contain economic fractions of silver require an understanding of the behaviour of acanthite during pressure oxidation. However, previous studies of acanthite (Ag2S) reaction have been complicated by the formation of argento-jarosite and uncertainties arise on the interpretation of the results.In this work, the acid pressure oxidation of high-grade natural silver sulphide mineral (acanthite) was carried out at 110-150°C and under the conditions similar to that of pressure oxidation of complex sulphide. The predominant product of reaction is elemental sulphur. The rate of reaction increases with increasing temperature and with the presence of ferric ions. The kinetics is controlled by chemical reaction with activation energy of 72.6 kJ/mol. The rate of reaction decreases with the presence of silver sulphate in the initial slurry. The proposed overall reaction is close to: []"

Jan 1, 2003

By Felipe Henríquez, Daniel Silva

"Traditionally, the implementation of an automated advanced process controller in any mineral processing complex is a challenge, mainly due to the quality of resources and technologies required, the uniqueness of each control solution and the uncertainty of the engineering hours needed to complete the task. Thus, the use of advanced and proven control technology becomes a key factor when deploying the control strategy. However, success would still not be possible without the presence of common sense, process knowledge and fundamental process data. Minera Los Pelambres, taking advantage of such factors and its accumulated process experience, implemented a novel and successful combination of MPC (Multivariable Predictive Control) and advanced control for secondary grinding and regrinding stages at its copper concentrator plant. In both cases, the control objectives are: being capable of processing a variable feed from the upstream process while at the same time avoiding to become a process bottle neck and yet, maintaining an adequate product quality (in terms of size distribution) to the process downstream. Additionally, for the case of the vertical regrinding mill (vertimill), the control system should also be capable of keeping an adequate circulation load and making an efficient use of the available grinding power. In either case, extending hidrocyclones availability while maintaining their performance is a must, since both factors are required for process and maintenance purposes. Thus, the process control problem becomes one with a multi-variable type of process with multiple control objectives to satisfy simultaneously. In trying to solve it, many mineral processing operations have implemented basic or conventional control or even better yet, expert systems. Minera Los Pelambres believes that better and faster results can be achieved using a combination of MPC and advanced control. Such strategy was successfully implemented, reducing considerably process variability while maintaining high throughput and keeping the process well within constraints limits. Their control philosophy, implementation process, main results and their key performance indicators are discussed here."

Jan 1, 2014

The introduction and subsequent ascendancy of autogenous and semi-autogenous milling for comminution circuits has undoubtedly lead to many economic advantages. From a process viewpoint, however, at least one downside has been the sensitivity of these machines to process input variations. Foremost among these is ore competence, though feed size comes a close second. This sensitivity is due to the reliance of ag/sag mills on the feed ore for their grinding media competence and size. Autogenous (ag) mills are the most sensitive in this respect with semi-autogenous (sag) mills being increasingly less so as the ball charge is increased. Increasingly designers and operators are recognising the importance of feed size and the benefits of manipulating it to improve performance. This has been achieved by installing additional crushing/screening capacity ahead of the ag/sag, better operation of the primary crusher, better control of segregation cased by stockpiles and bins and by changing blast design/practices to modify the ROM size distribution. This paper describes the influence of feed size distribution on ag/sag mill performance with reference to a range of plant data. It particularly concentrates on how changing blasting practice to modify ag/sag feed size can have a considerable overall benefit.

Jan 1, 2003

By Ping Fang, Dezhou Wei, Zichuan Guan, Wengang Liu, Yanbai Shen

A new cationic collector, bis(2-hydroxy-3-chloropropyl) dodecylamine (N23), that can be dissolved in water easily was synthesized successfully. Its flotation performance to quartz was investigated compared with dodecyl amine in hematite reverse flotation system. It was found that N23 showed stronger collecting performance to quartz than dodecyl amine. The maximum recovery of 98% to quartz was obtained at a collector concentration of 43.3 mg/L in the pulp pH range of 6-9. This collector can be used to float quartz from hematite when starch was used as depressant. Optimal separating results with 90.06% iron recovery and 66.3% iron grade to artificially mixed sample were achieved at a collector concentration of 43.3 mg/L and a starch concentration of 23.3 mg/L at neutral pulp pH when hematite and quartz were mixed at a mass ratio of 3:2. The adsorption mechanism of the collector on quartz surface was investigated by infrared spectroscopic analysis and zetapotential measurements, which revealed that electrostatic attraction and hydrogen bonding adsorption occurred between the collector and quartz surface.

Jan 1, 2014

By Jonas Addai-Mensah

In this paper, the results emerging from the several basic and applied studies performed to provide fundamental understanding of the interplay between clay pulp chemistry, orthokinetic flocculation performance, particle interactions, applied shear and dewaterability of fine clay mineral dispersions are presented, reconciled, and discussed. Modification of pulp chemistry and behaviour was achieved by using kaolinite and Na-exchanged (swelling) smectite clay minerals, divalent metal ions (Ca(II), Mn(II)) as coagulants and high molecular weight, anionic polyacrylamide copolymers: carboxylate substituted (PAM A) and 2-amido 2-methyl propane sulphonate (PAM S) (PAM S), non-ionic polyacrylamide homopolymer (PAM N) and non-conventional, non-ionic polyethylene oxide (PEO) as flocculants. Clear links between pulp interfacial chemistry, particle interactions and dewatering behaviour, resulting from the influence of hydrolyzable metal ion, pH, temperature, polymer structure type and shear, are established. Optimum conditions for improved, orthokinetic flocculation performance of negatively charged clay particles, reflecting faster settling flocs (>10 m/h) comprised: (i) coagulation, (ii) moderate agitation rate, (iii) shorter agitation time and (iv) anionic rather than non-ionic PAM. The optimum flocculation conditions did not, however, have a significant impact on the final sediment solid content of 20 ? 25 wt%. Further application of shear to pre-sedimented pulps improved consolidation by 5 - 15 wt % solid. Application of the findings and new knowledge gained to real plant tails? case studies for marked improvement in dewaterability through thickening is demonstrated.

Sep 1, 2012

By K. Haga

In this study, flotation tests were performed to investigate behavior of enargite and chalcopyrite ores from different sources synthetically mixed for separation of enargite. Flotation parameters including; pH, reagents concentration and type and flotation time were controlled to obtain an enargite concentrate with high As and chalcopyrite concentrate and final tailings with As content below 0.5 mass%. The copper ore bearing enargite mineral contained 5.87 mass% As and 16.50 mass% Cu while the chalcopyrite bearing ore contained 0.32 mass% As and 21.63 mass% Cu. The two ore samples were mixed at 7:3 (enargite: chalcopyrite) by weight ratio to prepare a mixed ore sample with arsenic content at 3.16 mass% and 18.25 mass% Cu for the flotation study. For enargite single ore flotation, the 38?75 µm size fraction showed that over 98% enargite was selectively recovered within 5 min at slurry pH of 4.0 and arsenic content in the final tailings was reduced to 0.22 mass%. In mix ore (enargite+chalcopyrite) flotation, 97% of enargite was first removed at pH 4 followed by chalcopyrite flotation at pH 8, and over 95% recovery was achieved in 15 min flotation time. Arsenic content in the final tailings was reduced to 0.1 mass%.

Sep 1, 2012

By M. Kanuchová, J. Briancin, M. Achimovicová

"Faculty of Mining, Ecology, Process Control and Geotechnology, Technical University, Košice, Slovakia An industrial eccentric vibratory mill was used for direct and short-time mechanochemical reduction of ilmenite concentrate (FeTiO3) and anatase (TiO2) with magnesium metal powder in order to reduce Fe and Ti resp. and hereby to convert them to the more soluble phases suitable for further hydrometallurgical processing. X-ray diffraction analysis of FeTiO3 after 60 min of milling with Mg confirmed the presence of Fe0 and Mg2TiO4 phases and for TiO2 after 180 min of milling the new TiO and MgO phases have appeared. X-ray photoelectron spectroscopy has detected Fe0 (metal) and Mg2+ species which are corresponding to the product of FeTiO3 mechanochemical reduction. The product of TiO2 mechanochemical reduction has revealed XPS spectral lines corresponding to Ti2+, Ti4+ and Mg2+ species on its surface. Morphology of mechanochemically reduced samples was studied by scanning electron microscopy analysis. Subsequent leaching of mechanochemically reduced FeTiO3 and TiO2 was performed in dilute HCl and H2SO4 at 80oC and compared with mechanically activated samples. The recovery of Ti has reached 100% for FeTiO3 and 79% for TiO2 after 60 min of leaching. Based on this study the flowsheet for possible processing of natural refractory titanium ores patented by author was adapted and documented. INTRODUCTION Ilmenite (FeTiO3), along with rutile (TiO2) represents the most important titanium resource necessary for titanium industry, for production of titanium metal, alloys and pigment grade TiO2 which are becoming more important and versatile for various industries such as an aircraft and aerospace, navy, chemical, automotive, medical and offshore wind industries, for machine and plant engineering and architecture as well, mainly due to high corrosion resistance. Pigment grade TiO2 is utilizing in pigment, plastic, glass, paper and rubber industries (Zhang, 2011). There are obvious research efforts for development of the potential alternatives to the expensive thermo-chemical commercial processes of titanium raw materials processing. Zhang (2011) has summarized conventional thermo- a electrochemical processes which involved a combination of pyrometallurgical, hydrometallurgical and electrometallurgical technologies and highlighted the improved hydrometallurgical routes promising for commercial application in the future. Such improvement could also be mechanical activation of FeTiO3, TiO2 by high-energy milling which causes their structural disordering, the changes of physical and chemical properties, consequently and has a positive effect on the dissolution kinetics (Achimovicová et al., 2014a, 2017, Baláž, 2008). The various types of mills such as a planetary ball mill, a vertical ball mill, a drum mill, an attritor were used for mechanical activation of FeTiO3 as a pretreatment process for subsequent leaching (Achimovicová et al., 2014)."

Jan 1, 2018

By Xumeng Chen, Yongjun Peng, Dee Bradshaw

Regrinding rougher flotation concentrates has become a common practice when processing low grade and complex ores. It not only reduces the particle size and improves mineral liberation but also modifies particle surfaces and pulp chemistry due to the strong electrochemical reactions taking place during regrinding. Therefore, the floatability of minerals in the subsequent cleaner flotation is influenced by the regrinding conditions. This paper presents the effect of regrinding conditions on the mineral floatability from both industrial studies in the plant and fundamental studies in the laboratory. Different regrinding conditions were considered, including grinding media, the electrochemical properties of minerals, pulp chemistry (pH, Eh, DO), and breakage mechanisms in tumbling and stirred mills. Results indicate that the selection of regrinding conditions and mill types should not only depend on grinding energy efficiency and liberation but also depend on the surface properties and pulp chemistry produced for effective mineral flotation and separation at the cleaner stage.

Jan 1, 2014

The multiphase reactive flow in process equipments, e.g., fluidized beds, involves complex coupling among flow, heat/mass transfer and reaction kinetics over scales ranging from molecules, sub-particle eddies up to equipments. Conventional two-fluid model (TFM) ignores the effects of meso-scale structures, and hence is not suitable for describing the intrinsically multi-scale heterogeneity within multiphase systems. To be consistent with the meso-scale structures, we proposed a structure-dependent multi-fluid model (SFM), and closed its drag force by invoking the stability condition defined in the energy-minimization multi-scale (EMMS) model. The SFM reduces to the conventional TFM if homogeneous distribution is assumed within each grid, and reverts to the original EMMS model if it is used to describe steady state, global behavior of a fluidized bed. The multi-scale computational fluid dynamics (CFD), which is characterized by coupling of TFM and EMMS drag coefficient, can then be viewed as a simplified solution of the SFM. We demonstrate that the SFM significantly improves the accuracy and at the same time enables higher efficiency by allowing for much coarser grid used than in TFM. Recent application of it in 3D, full-loop, transient simulation of industrial processes, e.g., fluid catalytic cracking, coal combustion, gasification, kaolinite clay calcinations, shows its advantages in helping design and troubleshoot multiphase process equipments. Keywords: meso-scale, SFM, multiscale, CFD, simulation, structure, EMMS, multiphase

Sep 1, 2012

By Lj. D. Andric

By the micronization-milling of the material, the size and the structure of its particles are changed and it comes to the increasing of the potential energy of the system as well as to the chem-ical activity of the material what is the result of an increased free surface and of the concentration of the grate defects, that is of the internal energy of the system. All these changes that are reached, show that new characteristics of treated materials are got by micronization process. Controlling the process of the micronization and by purpose directing of the new characteristics of the activated materials, we can have the positive effects and use them in more technologies. Talc is important nonmetallic mineral raw material that is widely used as either the basic raw material, or as filler. This has stimulated its technological investigation, as well as the investigation of its physical-chemical characteristics. In this paper are shown experimentally reached results of the physical-chemical characteristics of the talc during the process of the micronization in high energetic mill. In this paper, the optimum conditions of miconization of talc in high-energy-speed rotary mill and its influence micronization on a degree of Fe2O3recovery by hydrometallurgical methodes, are presented. The X-ray analysis of the obtained products showed that high quality talc with low content of can be obtained by these physical-chemical processes In this paper, the principles and application or fine and ultra-fine grinding high-energy attriton mill with small balls, enabling fast, efficient grinding, low energy consumption, short grinding time and easy handling will be described.

Jan 1, 2014

By Wang Xu, Tao Dongping, Zhang Jie, Tao Youjun

Based on the principle of fly ash triboelectrification, the mineral electrical index and testing method are introduced. The electric differences of various mineral components of fly ash are discussed in view of the results of chemical and mineral composition analysis of the fly ash sample acquired from the Xin-wen power plant. The dielectric constant and charge-mass ratio of carbon and ash in the fly ash are determined. The data were then used along with the rotary triboelectrostatic separator (RTS) testing results to investigate the charging characteristic of fly ash particles in different sizes. The results show that the dielectric constant of fly ash with different particle size decreased with the decrease in particle size, which led to a poor electrical conductivity. Thus particle size has an important effect on conductivity. The charges of carbon and ash particles increased with decreasing particle size. The charge-mass ratio of carbon and ash particles of the same size increased with decreasing particle size. This indicates that finer particle size is more favorable for triboelectrification separation from the charging efficiency point of view. The rotary triboelectrostatic fly ash separation tests show that the best decarbonization performance was achieved with particles in the size range of 0.038-0.074mm with which the decarbonization rate and efficiency index reached 38.93% and 120.83% spectively.

Jan 1, 2014

By Mojtaba Ghorbannezhad, Abbas Sam, Soroush Arabzadeh

One of the dewatering methods in mineral processing plant is filtration system. Disk filters are included the porous surface with pressure drop on both sides, Water in the pulp passes through the surface and solid particles remain as a cake on it. Wet concentrate production of magnetite processing plant at Golgohar Mining and Industrial Company with solid tonnage of 160 ton per hour and 49% solid amount contains 166 m3/h of water. In the present study, in addition to studying disc filter performance, the effective parameters on cake moisture were studied using Vacuum Bottom-Feed Leaf method (in the laboratory scale). Optimization was performed using the Taguchi method. The results showed that the cake moisture is reduced by increasing particle size and solid percentage (because of specific resistivity reduction), while the rate of cake formation and its thickness are increased. Also, it was found that by increasing pressure, the cake moisture is reduced and cake formation rate and its thickness are increased. In this study, the effect of fabric texture was also examined. Lowest cake moisture was obtained in condition of using compressed plain fabric with mono-multi filament fibres, pressure at 75kPa, solid percentage of 65 to 70, particle size (D80) equivalent to 123µm and disk rotation speed of 1.25 rpm.

Jan 1, 2014

By L. O. Filipov, N. E. Menad, A. Geneyton

"Zeta potential of synthetic monazites presenting various compositions were measured to investigate the effect of the main lanthanides substitutions on electrophoretic mobility and resulting IEP. The measurements are performed in a CO2 depleted and enriched solutions showing both reduced influence of monazite chemistry and strong influence of ions resulting from the solubilization and dissociation of CO2. The influence of oleic acid on the electrophoretic mobility of those monazites was also investigated. The influence of pH on oleate adsorption was studied using a bubble/particle adhesion system. Adhesion strength measurements were performed on pure synthetic monazite-(Ce) and monazite-(La). An extensive thermodynamic model of monazite in water was developed to highlight correlations between lanthanides hydroxides/carbonates species concentrations in the bulk solution and oleate adsorption. Based on electrophoretic measurements, advanced thermodynamic consideration and adhesion measurements, further details of the oleate adsorption model on monazite surface were proposed.INTRODUCTION Electrophoretic and potentiometric data on monazite and, a fortiori, other rare earth semi-soluble salts such as bastnaesite are extremely erratic (Chelgani et al. 2015). The isoelectric points measured with electrophoretic mobility methods range from 4.7 to 6.5 although sporadic data indicates an IEP (isoelectric point) far from that range. Different explanations are proposed in the literature to explain the IEP variability notably the numerous chemical substitutions that frequently occurred within monazite crystal lattice (Chelgani et al. 2015). Based on lanthanides speciation diagram, several authors highlighted the influence of specific lanthanide species on the flotation performance of rare earth semi-soluble salts when carboxylate or hydroxamate collectors are used. Although lanthanides ions have a great affinity for carbonates groups (Kragten et Decnop-Weever 1987), lanthanide (hydrogen) carbonates were not implemented in speciation diagrams. In this work, an advanced thermodynamic model is proposed to highlight correlation between flotation performance and lanthanide species predominance but also concentrations. Qualitative measurement of the monazite surface hydrophobicity are performed through tests of adhesion of coarse monazite particles onto bubbles. Since flotation and microflotation technics are highly influenced by hydrodynamic parameters, this method was investigated to obtain a sharp contrast between appropriate and inappropriate pH conditions. This paper is to investigate 1) the effect of lanthanides substitution on monazite surface properties through zeta potential measurements, 2) the mechanism of adsorption of carboxylates on monazite surfaces and 3) the effect of CO2 on monazite surface properties and carboxylates adsorption."

Jan 1, 2018