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By Diankun Lu, Ganfeng Tu, Edouard Asselin, Feng Xie

A novel separation process for detoxifying cadmium-containing residues arising from zinc hydrometallurgical processes has been developed. An initial investigation indicated that a high concentration of zinc in the sulfate solution can be effectively separated from cadmium by solvent extraction with P204 (di(2-ethylhexly)phosphoric acid, D2EHPA). The mixture of sulfuric acid and ammonium citrate ((NH4)3C6H5O7) is thus used to extract metals from the residue at room temperature. Copper in the leachate is recovered by solvent extraction (SX) with LIX 973. Cobalt in the raffinate from the copper SX process is recovered by precipitation with a-nitroso-ß-naphthol. The results show that more than 50% of the copper and virtually all the zinc, cadmium and cobalt in the residue can be leached under the experimental conditions used here. Virtually all dissolved copper and cobalt can be recovered in the subsequent solvent extraction and precipitation processes. The presence of (NH4)3C6H5O7 could significantly facilitate the extraction of zinc by D2EHPA in the subsequent separation of zinc and cadmium. More than 97% of the dissolved zinc can be recovered through a two-stage counter current solvent extraction process. After separating copper, cobalt and zinc, cadmium can easily be recovered from the solution either by cementation with zinc powder or by electrowinning, while the purified solution can be recycled back to the leaching process.

Jan 1, 2014

By G. A. Mallory

"The South Bay Division of Selco Mining is located fifty-four miles northeast of Ear Falls Ontario on Confederation Lake. The concentrator operates five days a week and processes six hundred tons per day of copper zinc silver sulphide ore. The concentrator is comprised of crushing, grinding, differential flotation, thickening and drying circuits. The major constituents of the concentrator feed are: chalcopyrite 7%, sphalerite 20%, pyrrhotite 3%, pyrite 25 - 30% and felsitic volcanics 40 - 50%. The mine went into production in March 1971 with an anticipated three year life and is now scheduled for closure in the summer of 1981. Recent mine production has been limited to three cut and fill stopes which have widely varying ore grades, therefore mill feeds vary from 0.25 to 4% copper, 3.5 to 27% zinc, 0 to 0.4% lead and 15 to 30% iron.In mid 1977 Selco negotiated a six month rental purchase agreement with Outokumpu Instruments Canada Limited for a five stream analyser system. The Minexan 202 probes were the first Outokumpu probe type analysers installed in Canada although Outokumpus' Courier systems are well known. Installation of the system took place in April 1978 and after numerous hardware faults the six month evaluation began in August. By December it was obvious that the Minexan 202 probes with proportional detectors did not have adequate resolution to determine low copper values in either of the tailings streams. Outokumpu offered to replace the tailings analysers with a new prototype solid state detector probe the following summer. The evaluation on the five Minexan 202 probes continued until August 1979 when the new solid probe was installed. The Minexan S (solid state) probe was evaluated with the three remaining Minexan 202 probes until December 1979 when Selco elected to purchase the system."

Jan 1, 1981

By A. H. Marquis

Since the start-up of its first Direct Reduction Module in April 1973, S1DBEC has produced over 2 million tons of prereduced iron. During this period, SIDBEC has acquired comprehensive experience in the operation of the direct reduction process and at the same time has learned to recognize the characteristics that the oxide should have to constitute an adequate feed for the process. A comparison is made as to the design and operation of the two direct reduction units now operating at Contrecoeur, Que. A description is given of a method of evaluation of a direct reduction unit, which takes into account the main process variable sand which permits comparison ofthe results on a daily basis. The paper defines the characteristics that the iron oxide and the prereduced iron pellets must have to meet the specific requirements of the direct reduction and the electric arc furnace processes. A simple model makes possible a rapid evaluation of the technical and economic effect related to the use of a given raw material. Finally, the paper outlines the advantages of prereduced iron in the steelmaking process and on the quality of the steel products.

Jan 1, 1979

By X. Louw

"This paper examines the change in surface properties of the Polyurea used on spirals at different operational times: unused spiral, 28 months in operation and 58 months in operation. This is being done to investigate the alleged statement that spirals have a decrease in spiral separation efficiency after a certain period of operational time. Observing the surface characteristics under 1.5x and 36x magnification it can be concluded that the surface roughness decreases with increased operational time. This may be explained by a decrease in air inclusions and streak lines as the spiral surface wears. Decreased surface roughness should in theory have a beneficial effect on spiral separation performance. This leads to the conclusion that if a decrease in spiral separation performance is observed after a certain period of operation, it can’t be attributed to the change in surface properties. Uneven wear of the spiral surface, material creep or application of force to the spiral will change the profile of the spiral and could cause an adverse effect on spiral separation performance. The metallurgical test work showed that the best results are obtained at 30 - 35% solids by mass in the spiral feed. The iron recovery was significantly higher in the new spiral in comparison to the 2012 and 2010 spirals. The mass yield to concentrate in the new spiral was approximately three times more than for the older spirals. In conclusion, the yield combined with the grade, which equals the recovery was the best for the new spiral.IntroductionAn investigation was launched to research the common belief that spirals experience a decrease in efficiency, and therefore recovery, after a certain period of operation (a period of seven years has been used in the industry). The properties of the spiral that may have an effect on the efficiency are:"

Jan 1, 2017

By B. G. Cousins, B. O’Rourke, C. Spence

"Some non-flotation chemistries are added to flotation circuits directly and indirectly to control issues such as scaling and dust. Since the dosage levels are generally not very large, a standard laboratory float test may not be able to determine the effect a specific chemical has on the productivity of the flotation circuit. Hudbay and Ashland Water Technologies developed a laboratory testing protocol that uses kinetic float studies to test the effect of normal to extreme doses of antiscalant and dust chemistries (5 ppm to 500 ppm). Laboratory results indicate that this protocol helps to predict the potential interference that a particular chemistry will have on the flotation circuit.INTRODUCTIONFrom a chemical perspective, flotation is a very complex system involving more than the reagents used for flotation. Along with collectors, frothers, modifiers, suppressants and activators, there can be antiscalants for water treatment, dust suppressants used in the mining process, residual flocculants from recycled thickener overflows, grinding aids, and many other types of chemicals that are added upstream of a flotation circuit. Although these other chemicals are usually used at very low doses, it is important to know if they affect the flotation process detrimentally in the event of a spill or a build up from recycled water.Laboratory flotation testing of these chemicals characterizes their effects, but testing at expected doses in the float can mask the effects of the chemicals in the plant. Also, simple tests that do not measure the kinetics of flotation do not reveal the effects the other chemicals have on the flotation circuit. Thus, a new flotation protocol was needed to expose the full effects of chemical additives and to assist in choosing the chemical with the lowest potential for a negative effect.FLOTATION KINETICSMeasuring recovery kinetics in a laboratory flotation cell is a well-established procedure: analyzing concentrates taken in a timed sequence to determine the recovery rate of individual cells in a flotation circuit. The recovery from the early flotation cells are a true measurement of how well a flotation chemical is performing. The principles of kinetics can be mathematically determined by the following functions (Houston, 2006):"

Jan 1, 2013

"The effective thermal conductivity (ETC) is one of the most important thermo-physical properties of porous media. Due to the lack of higher precision influence of temperature on thermal conductivity, we took 6 groups of experiments on rock samples (including igneous rock, sedimentary rock and metamorphic rock) under different operating temperatures from 20? to 50? by 7 acquisition points. The general equation of thermal conductivity drives the value of it increasing along with the decreases of the temperature. While in our experiments, it is easy to find a singularity among them for each sample. The experimental investigations we attempted to observe and interpret the alteration mechanism. According to the Heat Capacity Theory in solid state physics, this research gives the explanation about the “singularity” from 3 understanding of specific heat, average free path, and thermal conductivity. Our research divided the condition of the rock thermal conductivity into 3 different types. INTRODUCTION The effective thermal conductivity (ETC) is one of the most important thermo-physical properties of porous media(Huang & Han ,1988; Peierles ,1955). This parameter is necessary for analysis of heat transfer(Vaferi et al, 2014;Hans-Dieter & Rudiger,2003). It’s well known that a general equation for ?(T) was set by Sass et al. (1992) which based on the coupled effect of composition and temperature on the thermal conductivity(Jesse et al, 2013; Mongelli et al,1982).The equation was further successfully verified for other rock (Zumrud et al,2010;Abdulagatova et al,2009;Seipold& Huenges,1998).Thermal conductivity is also related to other physical proper ties of porous rock, such as thermal diffusivity, heat capacity(Brettmann et al,2011;Abuel-Naga et al,2008). It is well known that ETC and other thermo physical properties of rock materials are affected by various factors, such as temperature, pressure, mineralogical composition, porosity, stratification, size and shape of the components, and nature of pore fluid, etc. (Tiedje & Guo, 2014; Touloukian et al,1970).The understanding of heat transport processes still requires the knowledge of thermal properties of rocks."

Jan 1, 2015

By G. Styles, K. Lye, R. Tenbergen, M. Mayhew

Requirements to produce a higher bulk concentrate grade have necessitated extensive use of on-stream analyser data and computer programming to obtain the targets set for Frood Stobie Mill as required by overall milling considerations.A brief history of milling process changes associated with the changes from a low grade (3% Ni) bulk concentrate in the sixties to a high (6 to 8.5%). Nil bulk concentrate currently will be presented.The heart of the presentation will be the computer control schemes for ""self optimisation"" of the distinct flotation sections in the plant within certain restraints to achieve targets set by the mill metallurgist.

Jan 1, 1985

By Donald Leroux, Dave Scott, Giovanni Di Prisco

"The Lady Loretta lead-zinc deposit in Northwest Queensland, Australia contains an average of 5.9% lead, 17.1% zinc and 97 g/t silver. Ore mineralization is mostly comprised of fairly complex intergrowths of pyrite, sphalerite and galena. Starting in 1998, Noranda Inc., the major joint venture partner of the project, conducted extensive metallurgical test work, which culminated in July - August 2000 in a series of Pilot Plant tests. A common thread to all the metallurgical work has been the deportment of a large portion of silver into non-payable metallurgical products. Average silver distribution from four Pilot Plants shows a distribution of silver in lead concentrate of 28%, whereas silver in zinc concentrate was 49%, and 23% in the final tails.The consistently poor silver recovery as well as the fairly unusual silver distribution, particularly in zinc concentrate, was considered an issue to be thoroughly investigated. A mineralogical plan was devised to determine if these particular metallurgical results were somewhat related to the nature and mode of occurrence of silver carriers. Work was performed to determine discrete silver-bearing minerals and/or silver contained in solid solution in a suite of commonly occurring sulphides. Ore microscopy, SEM methods, Electron Microprobe and Ion Microprobe analyses were all used to answer these questions, and to find the silver carriers, so a metallurgical plan could be devised to improve silver recovery.INTRODUCTIONPotential economic exploitation of the Lady Loretta deposit in Queensland, Australia is driven by revenue derived from zinc and lead flotation concentrates and co-product silver recovery in lead. Relatively low recoveries of payable silver to lead concentrate, and high silver distribution to zinc concentrate necessitated an investigation into the natu"

Jan 1, 2002

By Arthur L. Holloway, James C. Mugford

"The Underground Research Laboratory (URL) is located in southeastern Manitoba, in the Lac du Bonnet granite batholith of the Canadian Shield. It was constructed by Atomic Energy of Canada Limited (AECL) to conduct geotechnical research for the Canadian Nuclear Fuel Waste Management Program, assessing the concept of permanent disposal of nuclear fuel waste deep in plutonic rock.One of the primary objectives of the research program at the URL is to develop a nondestructive rock mass characterization method that can be used during siting, design and construction of a used fu el waste disposal vault. An experimental program was established to assess radar reflection profiling as a technique for fracture characterization in granite. The highly resistive, homogeneous nature of the Lac du Bonnet granite is ideal for the propagation of electromagnetic energy at the radar range of frequencies and water-filled fracture zones act as excellent reflectors because of their contrasting electrical properties.Radar reflection profiling was undertaken to characterize a major fracture zone located between 5 m and 10 m below Room 211 on the 240 m level of the URL. The profiling was done at a frequency of 120 MHz, on a 1m grid laid out on the bare rock floor of the room. Reflectors identified in the analog data were correlated between the profile lines, digitized, and a three-dimensional surf ace for each recognizable reflector was constructed. These surf aces were then compared with data obtained from the examination of numerous cores from adjacent boreholes intersecting the fracture zone. A very good correlation was found between the major radar reflectors and the most intensely fractured regions of the zone. Modelling studies also showed that a series of prominent shallow radar reflectors were caused by a borehole drilled close to Room 211."

Jan 1, 1990

By Pierre Boileau

Outline ? Who are We? ? Canada?s GHG Emissions 1990 - 2000 ? Emissions from the Petroleum Sector ? Emissions from Petroleum Exports ? Emissions from Manufacturing Industries ? Emissions from Mining and Metallurgy ? Conclusions Greenhouse Gas Division Key Functions: ? National GHG Inventory Report, Emission & Removal Trends Analysis, and Indicator Fact Sheets ? Scientific and Engineering Guidance, Technical Advice, Data Quality Assurance & Quality Control and Methodological/Data Development ? International Negotiations (FCCC) & scientific/technical guidelines (IPCC & ISO) ? Expert Review Teams (ERTs) ? Outreach ? GHG Verification Centre ? Clearinghouse ? Protocol Development

Nov 1, 2002

By Roussos Dimitrakopoulos

Conventional approaches to estimating reserves and optimizing mine planning and production forecasting result in single, often biased forecasts. This is largely due to the non-linear propagation of errors in understanding orebody attributes from a limited finite number of drilling data, throughout the chain of mine planning and mining. A new mine planning paradign is considered herein to include two interacting and potentially fusing elements: stochastic simulation and stochastic optimization. These two elements provide an expanded mathematical framework that allows the modelling of orebody uncertainty and its direct integration to mine design, production planning and valuation of mining projects and operations. This stochastic framework has shown to increase the value of production schedules in the order of 25%. In addition, case studies show that stochastic optimal pit limits are about 15% larger in terms of total tonnage, compared to the conventional (deterministic) optimal pit limits. This difference extends life of mine and adds approximately 10% of net present value (NPV) to the NPV reported above from stochastic production scheduling within the conventionally optimal pit limits. Furthermore, results suggest a potential new contribution to the sustainable utilization of natural resources.

Oct 1, 2009

By J. F. Archibald

This paper reviews the formation of the Canadian Mining Education Council (CMEC) and its terms of reference. CMEC considers that Canada?s mining schools represent a distinct competitive advantage to the Canadian Mining Industry. The core objective of CMEC is to reinforce the links between the constituent schools and their individual Industry Advisory Committees. The latter traditionally provide the schools with a great deal of guidance on a range of planning issues, including recruitment, curriculum, research and infrastructure. Beyond those bounds CMEC intends to improve its ability to network with the industry and government. It is concerned overall with the objective to raise the quality and level of its educational and research contributions to meet the needs of industry and society.

May 1, 2002

By Paul H. Atkinson

"Sampling in the mineral processing industry has always been a subject which has received considerable discussion. There have been many volumes written on theory, techniques and practical application of sampling. However, until recently, the companies were not completely aware of the potential savings available with properly designed sampling systems both to assist in pieces: control and final product values.Definition In our discussion today, we will define sampling as the operation of removing a part, convenient in quantity for analysis, from a whole, which is of much greater hulk, and removing it in such a way that the proportion and distribution of the quality to be tested, i.e. size of particle, moisture content, specific gravity content, mineral and chemical composition, are the same in both the sample and the whole.Application It has been well established that undetected errors can result in large economic losses, thus most firms depend upon some type of sampling and sample analysis as a control in their continuous processing of materials. Despite the large investment in facilities and personnel the ""analysis"" of a sample can be no more accurate or reliable than the sample on which it is being based. The importance of sampling is recognized by a great many but it is appreciated by only a few, largely because it is sometimes one of the items which is taken for granted."

Jan 1, 1976

By E. J. Fuller, J. C. Monette

"Gold and silver cyanide complexes are presently desorbed from activated carbon by means of hot caustic elutions. These solutions may or may not contain additional sodium cyanide. There are several parameters which affect the rate of stripping. Some of these include pH, ionic strength, and temperature. (1) Stripping is conducted in recirculating (ZADRA) or once through (AARL) circuits.This paper describes the development of a new chemical eluant which significantly increases the rate of stripping of both gold and silver cyanide complexes from activated carbon. Two case history applications are also described.INTRODUCTIONAdditional cyanide is used in strip circuits in order to prevent its depletion which could lead to precipitation of base metals or lead to a change in the nature of the gold cyanide complex to one which does not strip as easily. (2)The strip circuits that are able to function efficiently without the use of cyanide are mostly those where the carbon is acid-cleaned after stripping.Once the minimum cyanide requirement to maintain the complexes in their proper state are fullfilled, any futher incremental increase in the level of cyanide will have no bearing on the rate of stripping. (3)DEVELOPMENT OF THE NEW ELUANTGeneral DiscussionVarious carboxylated materials were investigated including octanoic acid, polycarboxylic acid (various molecular weights), salicylic acid, polymaleic acid, acetic acid. benzoic acid, terephthalic acid, 4, bi-phenyl carboxylic acid, phosphoric acid and stearic acid.The initial work was done on medium activiiy, non acid-cleaned carbon. The silver to gold ratio on the carbon varied greatly.Two different blanks were used. The first was an elution using a 2% caustic and 0.4% cyanide solution while the second was a 2% caustic elution."

Jan 1, 1992

By B. St. Pierre

"The alchemists' symbol for antimony is a diamond with a dot in the centre. The latin name ''stibium'' gives this mineral its chemical symbol ""Sb"" and the name to the principal ore containing antimony. This is Stibnite, a sulphide of antimony, and the valuable mineral at the Consolidated Durham operations. Stibnite chemically pure contains 71.69% antimony metal.Antimony is used in many forms, as an alloy in the production of metal products and as chemical compounds of oxides and sulphides. In Biblical times, antimony was used as a medicine and as eyebrow makeup.Today, the largest single use of the metal is as a hardener and strengthener of lead, and corrosion inhibitor in storage batteries. New applications for antimony in its oxide form as fire retardants are broadening the overall demand especially in the chemical, plastic and fabric industries. Other users include the Military for such things as tracer bullets, shrapnel, smoke screens and flame throwers. An unusual property of the metal is that it contracts when heated which has made it a valuable alloying metal in the printing industry, for heat shields on re-entry vehicles used in the space programmes, and also for the manufacture of bearings."

Jan 1, 1977

By É. Roberge, S. Makni, G. Gagnon, F. Lavoie, A. Faucher

"Feed particle size is an important variable for the primary grinding mill operation. Several commercial vision systems have proven to successfully measure online many types of ores and are used for automatic control. However, due to limitations associated with segmentation algorithms, these systems fail to provide good measurements when the feed is composed of a specific bimodal particle size distribution: very big rocks and a large amount of fine particles. This is typically the case for crushed iron ore. This paper presents a technique to overcome the limitations of existing vision systems by using 3D cameras and appropriate processing methods. It provides online particle size distribution indicators and bulk volume flow rate measurement. It is designed to be very cost-effective, robust, precise, easy to install and to maintain. The 3D system was validated in two iron ore processing plants and the results clearly show that it can be used to optimize primary grinding mill operation where 2D segmentation vision systems fail.INTRODUCTIONFragmentation measurement using digital image processing has successfully been applied in mining and mineral processing operations. Several maintenance and operating applications are already deployed in the industry: Measurement of rock fragmentation after blasting (Maerz, 1999; Palangio, 1999) (Pragyan, 2012) Truck inventory (Palangio, 2005) Monitoring of crusher mantle wear Automatic control of crushers and SAG mills (Bouajila, 2000) (Bartolacci, 2001)Commercial technologies like WipFrag (Maerz, 1999), VisioRock and others proved to be very efficient to precisely measure the particle size distribution of many types of materials. These products are mainly composed of a camera, a lighting system and an image processing system based on a segmentation algorithm. By controlling adequately the lighting conditions and with periodic maintenance on the segmentation algorithm calibration parameters, it is almost always possible to achieve reliable measurements.However, the segmentation algorithm is not adequate when the particle size distribution contains big rocks and a large amount of fine particles. In this case, the area containing the fine particles is accounted as a big rock while big rocks get segmented as multiple smaller sized particles, leading globally to a wrong measurement. This situation prevails for crushed iron ore and coke, among other materials. Figure 1 shows a picture of a material which is typically very difficult to process through segmentation techniques."

Jan 1, 2015

By E. W. Johnson

"The title of my paper is ""I 'Wonder Where The Yellow Went"". As you can readily guess, it is not related to an old-fashioned ""Pepsodent"" sales pitch! Rather, it concerns a situation which arises all too frequently in some gold milling operations, namely when actual ounces of gold production do not come up to estimated or projected ounces. The boss man scratches his head and wonders where the missing gold has gone and how it has disappeared. The problem, if one exists, is amplified if one forgets that an estimate is just that - an estimate - and not a hard fact - even though the numbers are produced by computers. And yet, from the point of view of engineering; financial and production planning and security; it is most desirable to tie together all data relating to production estimates, losses and actual production.In the course of this paper reference will be made to the term ""variance psychology"", to a few of the physical properties of gold and to the nature of its occurrence in Canadian ores, in relation to the topic under consideration. Activities which have a bearing on production estimates will be reviewed. These include: weighing, sampling, assaying, estimating residual losses and, in cyanide plants, gold precipitate production. Mention will be made of apparent, unaccounted for and unknown losses. In conclusion, I shall draw from personal experience and relate three examples of ""Where the Yellow Went''."

Jan 1, 1986

By Zorigtkhuu Davaanyam, Bern Klein, Stefan Nadolski, Amit Kumar

"The High Pressure Grinding Rolls (HPGR) is a relatively new comminution technology that has been shown to be more energy efficient compared to semi-autogeneous (SAG) mills. Full and fair consideration cannot be given to HPGR-based comminution circuits in early stage projects, because presently pilot scale testing is required for assessing and sizing; pilot scale testing requires bulk samples weighing more than one tonne. A CAMIRO research program was conducted at the University of British Columbia to develop bench scale tests that would reduce the quantity of sample required to assess HPGR.Three test procedures were developed.1. The Direct Calibration Methodology calibrates piston press test results to pilot scale test results such that piston press tests can then be used to determine the energy–size reduction relationship for a range of ore types.2. The Database Calibrated Methodology, which is similar to the Direct Calibration Methodology except that it calibrates piston press tests against a database of pilot scale and piston press tests.3. The Semi-Mechanistic Methodology was developed to use piston press test results as an input for an HPGR based energy-size reduction performance model.Through utilization of these methodologies, the energy–size reduction performance of an HPGR can be predicted with minimal sample requirement. In addition, piston press testing is far more cost effective, faster, and accessible than pilot-scale HPGR testing.IntroductionOne could argue that in the future, decisions regarding selection of comminution circuits will be made primarily on the basis of energy consumption. The following facts and predictions support the argument:"

Jan 1, 2015

By Mehmet Canbazoglu, Kaarlo Haavanlammi, Hannu Laitala

Cobalt is currently a critical metal because of the increasing number of electrical vehicles forecast for production. Copper and zinc are base metals that are used in many everyday applications, including vehicle production. Eti Bakir Co. Mazidagi Phosphate Plants in the Mazidagi district of Mardin, Turkey is a multi-product facility that produces cobalt, copper, and zinc, as well as fertilizers, from the roaster calcine. Roaster off gas is treated in a sulfuric acid plant (SAP) and the acid itself is utilized in fertilizer production. The comminution circuit, roaster, SAP, and calcine leaching process were developed by Outotec and integrated with the fertilizer production process implemented by Eti Bakir A.Ş. This paper describes the hydrometallurgical calcine leaching process used at the plant, with a focus on the oxidative pressure leaching of the cobalt, zinc, and copper-containing calcine. The cold and hot commissioning phases of the pressure leaching autoclave start-up are discussed together with experiences from the ramp-up period. The production processes of the copper cathode and cobalt and zinc-containing salts are also presented together with some of the plant’s operating parameters. INTRODUCTION The ETI Bakir A.S. fertilizer plant, Turkey, is located in Mardin Province near the border with Syria, (Figure 1). The leaching plant project was started in 2012. The purpose of the plant is to separate the valuable metals from the calcine produced by the pyrite roasters, which are used to produce a SO2 containing gas for the new sulfuric acid plant. Fertilizer production requires sulfuric acid, and for this reason a sulfuric acid plant was built; customer already had access to pyrite concentrate, which is used as the roaster feed. During the engineering phase of the roaster and acid plants it was noticed that the roasted calcine contained considerable amounts of valuable metals like cobalt, copper, and zinc. To recover these metals, a calcine leaching process was developed at the Outotec Research Center in Pori, Finland. The main process connections of the Mazidagi site are shown in Figure 2.

Jan 1, 2019

By Anand Raman, Steve Dixon

"Industry practice for defining acid consumption is based on column tests. Freeport-McMoRan (FCX) has adopted a practice of leach operation using a defined pH or gpl acid in the raffinate based on the column test program. The acid consumption can be easily calculated using the leach operating parameters of SX-EW efficiency, lift height, bulk density, irrigation rate, primary leach cycle time, acid cure dose and acid concentration in the raffinate. The column leach test results and a column to heap efficiency factor are used to define the copper extraction. The maximum acid consumption will occur when zero acid is contained in the raffinate. The term Net Extracted Value (NEV) is to define the maximum extracted value relative to acid consumed.This paper presents the operating logic and method used to calculate acid consumption based on column tests and operating parameters.INTRODUCTIONIndustry practice for defining acid consumption is based on column tests. This may result in lower economic value if the tests are not designed to account for operating variables. A test program is described to assist in defining lift height and the influence of gangue on solution chemistry. A simple spreadsheet is presented that will use the leach operating parameters of SXEW efficiency, lift height, bulk density, irrigation rate, primary leach cycle time, acid cure dose and acid concentration in the raffinate to calculate the acid consumption for a proposed operation.A review of current leach operations solution chemistry will help to define acid consumption. This is recommended for all current leach operations.DISCUSSIONThe current practice at Freeport-McMoRan (FCX) is the use of column test results to define operating parameters. The monitoring of operational solution chemistry and copper production addresses any changes needed in operational parameters. This practice maximizes the value extracted from each tonne of ore leached."

Jan 1, 2008