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By S. Feinstein, I. Reznik, Y. H. Hatzor, O. Shitrit, Y. O. Rosenberg, H. J. Vinegar, S. Nguyen

"We report the effects of porosity and total organic carbon (TOC) content on the mechanical behavior of organic-rich chalks, based on laboratory measurements. The organic-rich chalks are from the Senonian Ghareb and Mishash formations. This deposit is an immature oil-prone source rock, about 300 meters thick, situated at shallow depths (several hundreds of meters) in the Shefela basin in central Israel. The study is based on core data collected from the Zoharim borehole.Three main phases comprise the bulk volume of this rock: 1) carbonate mineralogical phase (predominantly calcite); 2) pores (mostly saturated with brine); and 3) solid organic phase (type IIS kerogen). The mechanical effects of porosity (23-45%) and TOC (4-19%) are evaluated based on bulk incompressibilities vs. volumetric fractions analysis. Volumetric fractions of mineralogical and organic phases were obtained by porosity, density and TOC measurements. Saturated rock bulk moduli were measured through ultrasonic velocity measurements. Saturated rock bulk moduli correlate best with the sum of kerogen and pore volume fractions, rather than each of them separately. The volumetric fractions were also used to define the range of bulk modulus of the organic-rich chalk, using the Hashin-Shtrikman upper and lower bounds. Based on Marion's Bounding Average Method (BAM), the normalized stiffness factor of the chalk averaged at w=0.197, indicating a soft pore geometry. Using the average normalized stiffness factor, the BAM predictions showed excellent match with the saturated rock bulk modulus and the sum of kerogen and pore volume fractions. Based on our findings, it is inferred that kerogen grains do not support the solid skeleton but are distributed between the minerals grains. We also propose here a straightforward approach for calculating the Hashin-Shtrikman bounds, based on TOC and porosity measurements. The mechanical effects of porosity and TOC indicated here are very important for the understanding of the influence of immature kerogen presence in highly porous chalks, as the Ghareb and Mishash formations."

Jan 1, 2015

By Mark Sherman, M. Dennis, Raj Rajamani

"The two Alumbrera 36ft (10.97m)dia. SAG mills were sized, using the FDW ""Grindpower 'I program, to treat an average of 1852 tph each. This paper describes how modelling of the shell lifter design, using the Millsoft program, identified milling inefficiencies caused by poor charge motion. This explained the ""as built"" circuit's inability to achieve the throughput rates predcted by the circuit's designer. Use of the Millsoft program to design a new, dramatically different lifter configuration, in conjunction with a different approach to variable speed drive utilization, has resulted in an improved charge motion and a 30% increase in hard ore milling rates. The new lifter design has allowed the designer's predicted average throughput rates to be achieved.IntroductionThe Alumbrera project grinding circuit consists of two 36ft dia. X 17ft EGL, 13 500 kW, variable speed, gearless drive SAG mills coupled to four 20ft dia. X 30ft EGL, 6 000 kW fixed speed, gear driven, ball mills. The circuit is configured as two identical grinding aisles, each consisting of one SAG mill and two ball mills. No pebble crushing circuit was installed due to the expected absence of a critical size fraction in the first years of production. However, the grinding circuit layout does incorporate space for a pebble crushing retrofit. At present, only about 5% - 10% of the new mill feed reports as trommel oversize and is recycled back to each SAG mill using a water cannon.The circuit was designed to be ball mill limited and to treat the four major Alumbrera ore types at rates varying between 68 000 tpd, and 89 750 tpd, depending on ore hardness. Average throughput rate, and hence nominal design rate, for the grinding circuit was 80 000 tpd (1 852tph per line at 90% availability)."

Jan 1, 1999

By E. O. Reinbold, J. H. Johnson, D. E. Keski-Hynnila

A field laboratory for use in monitoring underground mine air quality has been developed and proven in underground service. The laboratory includes two separate monitoring systems and data analysis computer programs. One is the Mine Air Monitoring Laboratory (MAML). This is an enclosed trailer-mounted laboratory capable of monitoring CO2, CO, NO, NO2 particulate matter, S02, NH3, temperature and air velocity in the mine drift. The MAML can be up to 1000 feet away from the area being monitored. The second system is the vehicle data system, mounted on the load-haul-dump (LHD) vehicle, which monitors engine speed, engine fuel rack position, exhaust gas temperature, ambient temperature, vehicle speed, CO2 concentration near the operators' breathing zone and the mode of operation of the vehicle. The two computer data analysis programs and the two field instrument systems comprise a complete Mine Air Quality Laboratory (MAQL) for underground pollutant studies. Data from the systems have been used for studying vehicle duty cycles, ventilation systems, exhaust after-treatment devices, vehicle exhaust system design and portable instrumentation. Descriptions of the laboratory are presented along with a summary of some of the experiments performed. The capabilities of the lab are discussed, along with future potential uses.

Jan 1, 1981

By V. Labiouse, M. Souley, N. Lafrance, C. Auvray

"Chalk rocks have been used for centuries as a strong building material and for the production of lime. The shallow underground room-and-pillar quarries where the chalk was extracted are now abandoned and endure the effects of time and weathering, increasing their risk of collapse. The risk of instability, involving natural or anthropic underground structures, is an issue for more than 10 000 towns in France.In order to investigate the causes of underground quarry collapse and to aid prevention strategies, we carried out a study of the physico-mechanical behaviour and ageing of chalk in abandoned pillars in two underground quarries, in situ-instrumented by INERIS, in the Parisian Basin, France. Core samples were drilled horizontally from pillars in the Saint-Martin-Le-Noeud dolomitic chalk quarry (Oise, France) and the Estreux glauconitic chalk quarry (Nord, France).Uniaxial tests were performed on dry and saturated cylindrical plug samples extracted perpendicular to the cores at regular distances along their lengths. Physical and mechanical properties were obtained. The dolomitic chalk (Saint-Martin-Le-Noeud) exhibits variation in mechanical and physical properties with horizontal pillar depth. Both density and compressive strength seem to increase outwards from the pillar-core to the pillar-wall. This is the opposite of that would be expected from a purely mechanical point of view. SEM analysis revealed progressive degradation and homogeneity of the grains from the edge to the inside of the pillar. At the pillar wall, the crystal faces are well-defined, almost euhedral, and the grains are of variable size. In contrast, at the inside of the pillar, crystals are finer-grained and are anhedral with highly degraded edges. In the physico-mechanical tests and SEM analyses performed on the Estreux samples, no significant variation was observed between the pillar-walls and pillar-core. However, dissolution marks were observed along the entire length of the half-pillar core."

Jan 1, 2015

By J. Fellowes, Z. Liang, J. Robson, M. Kenyon

"Dispersoids play a significant role in the recrystallization and texture development for wrought Al-Mg-Si (6xxx series) alloys by inhibiting grain boundary motion. It is therefore important to understand the precipitation kinetics of such particles. It is the additions of Mn and Cr in Al-Mg-Si based systems that can lead to dispersoid phases being formed. These phases are currently thought to nucleate on ß’-Mg2Si via an intermediate semi-coherent precipitate. Scanning transmission electron microscopy (STEM) has been conducted to study the precipitation of a-Al(CrFe)Si and a’-AlCrSi dispersoids. Corresponding electron dispersive spectroscopy (EDS) has been used to distinguish the dispersoids. The volume fraction and size distribution of dispersoids has been measured as a function of distance across a grain. Electron probe microanalysis (EPMA) has been conducted to study the inhomogeneity of elements in the cast structure and the effect on dispersoid precipitation. Dispersoid free regions have been observed in the microstructure correlating to regions depleted in the dispersoid forming elements.INTRODUCTION Al-Mg-Si (6xxx series) based alloys are increasingly being used in the automotive industry. The primary reason is to reduce the weight of vehicles, resulting in a reduction of CO2 emissions and increased fuel efficiency. The demand for 6xxx series is predicted to increase over the coming decade. Due to the high cost and CO2 emissions produced by raw extraction of aluminium, close loop recycling of these alloys becomes a more important process. However recycling of automotive alloys can be difficult due to pick up of impurity elements such as Mn, Cr and Fe. The addition of these elements can form dispersoid particles during early heat treatment processes. Although a controlled population of dispersoids is necessary to control the grain structure during thermo-mechanical processing, a significant change to the dispersoid population due to a composition change could profoundly influence the final microstructure, affecting the final properties of the material. More research is required on the precipitation and effect of additional minor alloying elements; in order to increase the 6xxx series alloys recyclability."

Jan 1, 2018

By T. Plikas, L. Gunnewiek

Computational fluid dynamics (CFD) modeling was used to evaluate the performance and optimize the design of a potroom ventilation system in an aluminium smelter facility. The ventilation system must ensure the inflow of fresh air to the workplace by natural draft and the removal of heat and hazardous emissions generated from the pot cell process. A full-scale, three dimensional CFD model of the potroom was developed to predict the air temperature distribution and contaminant concentrations throughout the potroom for the purpose of verifying that the industrial workplace hygiene standards will be met by the proposed ventilation system design. The modeling work was used to optimize the size of the floor gratings around the pot cell and roof ventilator, as well as determine damper settings in the roof ventilator. The effects of outside air temperature and external wind on the performance of the ventilation system was evaluated to ensure the design performs adequately in response to seasonal variations in climatological conditions.

Jan 1, 2006

By Edgar Dernedde

Cryolitic melts at a temperature of about 960 °C are used in reduction cells to dissolve alumina and to produce primary aluminium. At these temperatures cryolitic melts with an acidic composition have a significant vapour pressure, which contributes substantially to the evolution of fluorides from these cells, The Antoine equation is commonly used for relating vapour pressure data of liquids at different temperatures, It is also applicable to cryolitic melts, Published equations have at least 20 numerical constants, in order to allow for the effects of melt composition. In the present work a simplified equation with only 12 numerical constants was developed and is applicable for multiple additions to molten cryolite up to 30 wt %, The simplified equation was compared with the published equations of Haupin & Kvande and Gustaysen & Ostvold using 472 vapour pressure data of cryolitic melts. Results showed that the simplified equation has the same accuracy as the published equations in the composition range of interest to industry.

Jan 1, 2004

By Nirmal Weerasekara

Mill liners serve the dual purpose of protecting the shell from wear and transferring the rotary motion of the mill to an effective grinding action. As the liners wear, the efficiency of energy transfer changes, so there is balance between liner profile for wear and for milling efficiency. A tool that can simultaneously predict the evolution of the liner profile and the associated change in milling efficiency should prove most useful in optimal liner design. This paper presents such an approach, based on measured 3D liner profile data informing 3D DEM simulations of charge motion and liner wear modelling.

Jan 1, 2012

By M. Alvarez-Silva, A. Uribe-Salas, J. A. Finch, M. Mimezami

The point of zero charge (PZC) of electrokinetically anisotropic minerals (chlorite and serpentine) was determined using the Mular-Roberts (M-R) titration technique, and compared to isoelectric point (IEP) obtained from electrophoretic mobility measurements. To validate the M-R technique, the point of zero charge and isoelectric point of two isotropic minerals (alumina and silica) were shown to be comparable. For serpentine and chlorite, respectively the PZC was found at pH 4.3 and 4.6, while the IEP occurred at pH 3.2 and <3. Settling tests showed that the maximum settling rate, which corresponds to aggregated particles, for chlorite was around pH 3, i.e., close to the IEP; lizardite did not show a conclusive maximum.

Jan 1, 2009

Open pit production planning is a procedure consisting of multiple stages. Although all the planning stages rely on the geostatistical block models, long- to short-term plans each require their appropriate resolutions and levels of details. The main motives behind using different resolutions are the tractability of the models and the practicality of the generated schedules. The current approach in the mining industry is to use nested pits generated by Lerchs-Grossman as the basis for long-term planning and to use manually generated polygons, within those pushbacks, as the units of production control in mid- and short-term planning. However, the nested pits generated by Lerchs-Grossman algorithm and the polygons drawn by mining engineer do not provide control over the value and tonnage of ore and waste inside the planning units and therefore cannot lead to optimum solutions. In this paper, we first present a pushback determination approach which maximizes the profit of the mine with control over the tonnage of ore and waste within each pushback. We then propose a clustering approach with size and shape control that determines aggregates within those pushbacks; and finally, we introduce a mathematical programming model which uses the generated pushbacks and aggregates as the planning basis and generates production schedules that maximize the net present value of the operation and are practical from the operation?s point of view.

Aug 1, 2013

By R. Holmestad, M. Gazizov, S. Wenner, R. Kaibyshev, J. K. Sunde

"Mechanical properties and microstructure of an Al-4.7Cu-0.74Mg-0.51Si-0.48Mn-0.10Cr-0.09Ti-0.02Fe (wt. %) alloy subjected to various thermomechanical processing (TMP) have been investigated and compared to conventional ageing at 170°C (designated T6). Three TMP routes involving cold deformation of solution treated samples were tested. These were (i) 3%-stretching (T8-3%), (ii) equal-channel angular pressing (ECAP) to true strain (e) of ~1 (T8-1) and (iii) ECAP to e~2 (T8-2), all with subsequent ageing at 170°C for 0-96 h. At peak age conditions, both yield stress, ultimate tensile strength and elongation-to-fracture decreased for the T8-3% state as compared to the T6 condition. Intermediate ECAP (T8-1 and T8-2) lead to significant increase in maximum yield stress, ultimate tensile strength and elongation-to-fracture. The changes in mechanical properties were related to microstructure evolution, encompassing changes in grain sizes, dislocation densities, precipitate morphology and phase fractions, which were characterised using transmission electron microscopy. Relations between TMP, precipitation behavior and contributions to different strengthening mechanisms are evaluated.INTRODUCTION Al-Cu-Mg-Si alloys are widely used as structural materials in aerospace industry due to their attractive combination of high specific strength, good fracture toughness and enhanced creep resistance. These properties are largely due to the formation of a large number of nano-sized metastable precipitates during artificial ageing (Polmear, 2006; Eskin, 2003; Gazizov, Dubina, Zhemchuzhnikova, & Kaibyshev, 2015). The precipitation behaviour in these alloys is complicated and depends among other things on Cu concentration and the Mg:Si ratio (Wolverton, 2001; Chakrabarti, & Laughlin, 2004). In general, the precipitation sequence has been presented in a prior study (Eskin, 2003) as follows:"

Jan 1, 2018

By A. G. Scobie

A spectrographic method for the determination of small amounts of gold and the platinum metals in ores has been developed. By means of this method, an assay of 0.001 ounce per ton on one assay ton samples is possible, and by seecrrographic adjustments the sensitivity may be increased to 0.0001 ounce per ton. All the prec10us metals may be determined from one spectrographic arcing with an accuracy of about 5 per cent average deviation from absolute values, and the complete analysis of an ore or similar product may be reported five or six hours after receipt of sample.

Jan 1, 1945

By Parissa Mirjafari, Ron Martel, Susan A. Baldwin, Luke Moger

Mine drainage contains metals and sulfate, which may be toxic to aquatic life at certain concentrations and should be removed to acceptable levels before release of any drainage to the environment. One method for treating mine drainage is passive treatment, which is increasing in popularity due to lower construction and operating costs. This method is based on the activity of sulfate reducing bacteria (SRB) respiring on sulfate while using fermentation products from decomposing complex organic materials. The product of this biological process is hydrogen sulfide, which reacts with metals in mine drainage and precipitates them as metal sulfides. However, in practice passive treatment systems are not always effective, reducing the reliability of this approach. In this study, a mixture of hay, cow manure and wood chips was tested in continuous flow experiments for efficacy at sustainable treatment of sulfate and selenium containing water from a mine tailings pond. Factors that contributed to a decline in performance included lowering of the pH due to acids leaching out of the organics, re-oxidation of sulfide back to sulfate and a reduction in dissolved organic compounds over time. In this paper methods are described to overcome these problems so that treatment is made more reliable.

Jan 1, 2011

By A. S. Nortjé

At South Deep Gold Mine longhole stopes are backfilled using a cemented Cyclone Classified Tailings in its hydraulic state. The need to contain the hydraulic fill until cured requires a barricade. Due to the massive size of the stopes, the tailings can exert enormous forces on any such barricade. Barricades have long been in use, but recent failures in Australia and the large rate of filling required at South Deep solicited a robust design. A robust design must examine all foreseeable failures and the barricade must be able to resist all expected and, within limits, unexpected loads. The design should also be simple to construct and cost effective, limiting the impact of construction errors and unnecessary delays to production.

May 1, 2007

By Lawrence Devon Smith

"This paper examines the impact of the various assumptions that go into an economic evaluation, and shows how these can be combined to show an exciting result that may not really exist. An example of an embellished case (the kind that one frequently sees when projects are being promoted) is developed and the cumulative impact is analysed to show the actual project underneath. The paper also points out some areas to watch for overly optimistic assumptions such as prices, inflation, and debt. The concept of a ""bare bones"" base case is proposed (constant metal prices, constant dollars, no inflation, no debt, no interest, on a project basis, after tax) as a common reference point.As well, the discount rate is examined as a fundamental means of reflecting risk in discounted cash flow evaluations. Current industry practice is discussed, and a methodology for the analysis of risk levels is proposed that assesses the constituent components of the discount rate: real interest, mineral project risks, and country risk.INTRODUCTIONOften, the first time that all of the technical and economic data for a mineral project comes together in one place is when the economic evaluation is developed. This typically happens when work on the project has progressed to a sufficient level of detail that the effort to produce a year-by-year cash flow is justified, usually at the pre-feasibility or feasibility study stage. The data involved will include:• production; tonnes waste and ore mined, ore grade, mining recovery, metallurgical recovery, metal sold• revenue; metal price, smelting & refining charges, marketing costs• operating Costs; mining, milling, administration, fees, royalties• capital Costs; exploration, development, construction, indirect costs (engineering, management), contingencies, start-up, inventories, working capital, replacement and sustaining capital, closure costs• taxes and royalties• exclusions; depreciation (this is not a cash item), sunk costs (only costs going forward)."

Jan 1, 2003

By A. C. Headon, K. W. Lam, D. P. Dautovich

"Microbiological activities affecting the performance of materials have been encountered in diverse situations within Ontario Hydro. Case histories of bacterial problems which are presented include ground rod corrosion at transformer stations, corrosion of a bare steel cooling water intake structure in Lake Huron and corrosion of steel components in a nuclear generation station vacuum building. Possible microbiological activities which may affect the corrosion behaviour of containers for the disposal of nuclear fuel waste in the future are discussed, as are bacterial actions suspected of causing an odour problem in residential water heaters.IntroductionBacteria are ubiquitous. Except by use of sterilization methods, bacteria -free environments are no t possible to find. Bacteria lie dormant in hostile environments, spread easily through air and water currents and reproduce rapidly under favourable conditions. Although different types of bacteria have different preferable conditions for growth, they are highly adaptive and in general, whenever there is a source of water and carbon (carbon dioxide or organic matter), there will be bacterial activities . These activities often induce or enhance costly metallic corrosion in industries and water odour problems in rural water supplies . Underground structures and systems in contact with natural water or water containing organic matter are most susceptible to bacterial attack.The types of metal-degrading bacteria , their characteristics and the conditions for growth have been reviewed extensively in the literature(1,2,3). There are several often encountered groups of bacteria which, through their metabolic processes, may lead to the degradation of metals. A large variety of bacteria produce corrosive in organic or organic acids as waste, such as the well known formation of sulphuric ac id by aerobic sulphur oxidizers . Anaerobic sulphate reducers produce hydrogen sulphide which is corrosive and has an obnoxious smell, slime-forming bacteria from slime which shelters sulphate reducers and iron bacteria oxidize ferrous to ferric ion which precipitates as hydrated oxides creating oxygen concentration cells . The following are bacterial problems encountered in Ontario Hydro. Although the number of recognized cases has been few, they show the diversity of location and environment where bacterial problems could arise. These include ground rod corrosion at transformer stations, corrosion of bare steel in a water intake structure, corrosion of steel in a nuclear generation station vacuum building and an odour problem in residential hot water tanks. In addition, possible bacterial- enhanced corrosion in containers for future disposal of nuclear fuel wastes are also discussed."

Jan 1, 1984

By V. ?. Chanturiya, G. P. Dvoychenkova, ?. Ye. Kovalchuk

"Several mineralogical investigations have revealed the composition of modified kimberlites and the mud generated during treatment of diamonds, which contains up to 50% clay minerals (e.g., talc, talcsaponite, chlorite-saponite, Na-saponite) and X-ray amorphous phase. We investigated the composition of the natural diamond surface in relation to the diagnosed minerals and established the sequence and conditions for mineral formation on the crystal surface under kimberlite processing conditions. This article suggests a method to destroy and further dissolve minerals on the crystal surfaces using water system electrolysis products, which makes it possible to restore the diamond hydrophobic properties. The application of chemically treated water in the foam separation cycle under the conditions of high recovery of diamonds made it possible to increase the content of the factory concentrate by 8.0%.INTRODUCTIONThe high content of the modified minerals in the kimberlite ore results in the formation of hydrophilic slicks on the surface of the crystals which decreases the diamond’s hydrophobic properties and increases the losses thereof in the process of grease and foam separation to 20-30% (Kurenkov, 1957; Chanturiya et al., 1998, 1999, 2005; Duikarev et al., 2000).The previous researches have revealed the fact that the prospective way of solving the problem of intensity of mineral impurities formation on the surface of the crystals and the increase of concentration parameters is reached due to application of physical and chemical stimulation techniques on the solid and liquid pulp (Stricland-Constable, 1971; “Improvement of the technology…”, 2006; Makarskii, Adodin & Tarasova, 2011; Chanturiya, Dvoychenkova & Trofimova, 2012). However, the main task of investigations to stipulate the objective achievement is the studying and justification of the reasons of the diamond surfaces covering by the mineral slicks"

Jan 1, 2016

By Michel Épiney, COREM, Mario Drapeau, Caroline Olsen, Claude Bolduc, Benoit Levasseur

"Several metal sulfide minerals (such as copper, zinc and iron), generally abundant in precious metal-containing ores, are known to dissolve during the cyanidation process. These unwanted reactions consume a significant amount of cyanide and oxygen, which is required for the extraction of gold and silver. Leaching kinetics of sulfide minerals are very fast in contact with oxygenated cyanide solutions. Therefore, the solution quickly becomes charged with oxidation products that are mostly metal ions, metallo-cyanide complexes, metal oxides and other sulfur species including thiocyanate, sulfides, polysulfides, thiosulfate, sulfites, sulfates, etc. COREM’s Extractive Metallurgy team has been conducting a research program on the improvement of the gold cyanidation process. As a part of this program, the current study aims to investigate the effect of certain operating parameters on the reactions involved during pre-oxidation and cyanidation. The effect of pre-treatment under ozone was investigated using an industrial pulp recreated from process water (charged with thiocyanates) and homogenized flotation tailings material from Agnico Eagle's LaRonde mine. In terms of mechanisms, the ozone treatment provides a complete deactivation of the material surface (characterized by EDTA extraction) and the solution (characterized by Ionic chromatography). This resulted in a lower reactivity of sulfide minerals that led to substantial gains in terms of consumption of cyanide and thiocyanate formation during the cyanidation process. The ozone-pre-treatment edges the classical pre-oxidation treatment (such as oxygen, hydrogen peroxides, etc) providing a quicker deactivation of the sulfide matrix and higher reagent savings in subsequent cyanidation process.INTRODUCTIONThe presence of sulfur in the process of gold leaching by cyanidation is a major drawback to optimizing the reagents consumption with suitable operating conditions. The coexistence of sulfide mineral species, such as pyrite, chalcopyrite, pyrrhotite or sphalerite along with the gold-bearing ore have, indeed, a negative impact on the extraction of precious metals by cyanidation (Bayat et al., 2003), (Azizi et al., 2010). These minerals are known to dissolve with cyanide under alkaline conditions and release in the slurry different kinds of sulfide by-products like polysulfides, thiosel, sulfite and sulfate (Seal II & Hammarstrom, 2003) (Breuer et al., 2008a), (Marsden & House, 2006) (Ghasemian Langeroudi et al., 2013). Once these sulfide by-products are released in solution they react with cyanide to form thiocyanate (Marsden & House, 2006) (Breuer et al., 2008b). The consequence of the dissolution of these cyanicides, is a significant increase in cyanide consumtpion as well as a slow-down of gold extraction."

Jan 1, 2016

By S. Amira

The corrosion behavior of high pressure die-cast and thixocast AXJ530 magnesium alloys has been investigated in 0.05M NaC1 solution at pH 6.0 using potentiodynamic polarization tests, electrochemical noise (EN) technique, electro-chemical impedance spectroscopy (EIS) and scanning reference electrode technique (SRET). The behavior of die-cast and thixocast specimens were compared using each of these techniques and the results discussed. Further tests have been carried out with die-cast AZ91D alloy to better compare and interpret the results. Experiments indicate that the thixocast specimens of AXJ530 alloy have a better corrosion resistance than those of die cast alloy in neutral solution.

Jan 1, 2006

By I. Filippova, L. Filippov

"The by-product potential of light rare-earth elements (LREE, La, Ce, Nd) and rare-metals (W, Nb, Sn) within the St Austell kaolin deposits (UK) is related to the kaolinisation process, which liberates the accessory heavy minerals of the host granite in the clay matrix and allows their separation in the waste streams. As a consequence these minerals are pre-concentrated in the micaceous residue which displays relatively high LREE content (around 170 ppm) hosted by monazite which is mainly distributed (up to 95%) in the -100 µm fraction. A combined gravity/flotation concentration flowsheet, starting with classification of the residue into 3 size fractions (+150 µm, 150-53 µm and -53µm) was developed. This study presents the results of the clay-rich -53 µm size fraction beneficiation by flotation using sodium oleate and hydroxamate as collectors.The effect of dispersant addition during de-sliming operations on flotation efficiency was also investigated. The LREE grade in the floated product obtained with sodium oleate increased from 3370 ppm to 5350 ppm and recovery from 30% to 80% with dispersant which is attributed to clay coating. Comparison of flotation performance and Falcon Ultra-Fine (UF) concentration of monazite to previous results obtained with Falcon Semi-Batch (SB) gravity concentrator on the unscreened raw residue clearly shows that flotation of the fine residue is more efficient than Falcon UF and Falcon SB. Indeed Falcon UF produced high recoveries (87-95%) but with almost no enrichment (1.3-1.4 ratios) whereas Falcon SB concentration of unscreened residue produced higher grades (up to 0.6 % LREE) but with low recoveries (17-22 %). These preliminary results show that LREE can be pre-concentrated suggesting that the micaceous residue stream (and the associated tailings dams) could be considered as a potential resource for these metals."

Jan 1, 2016