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By F. Baerhold

Recycling of hydrochloric acid from the pickling of mild steel using pyrohydrolysis is a state-of-the-art technology. Recent developments have focused on the production of a high value iron oxide by-product, where the chemical purity and physical properties are the main issues. New processing routes, especially for TiO2 and Ni production, use leaching operations with hydrochloric acid. The feasibility of those processes depends on the availability of an economic and reliable process for the recovery of the acid. Depending on the level and type of impurities and the required specification of the by-product, pyrohydrolysis in a fluid bed or in a spray roast reactor can be the ideal solution. In stainless steel annealing and pickling lines, a mixture of nitric and hydrofluoric acids is used to remove the scale from the surface after heat treatment. Nitrate emissions from the pickling and the rinsing processes have to be avoided because of more stringent environmental regulations. An annealing and pickling line that is totally wastewater-free was developed, where not only the nitric/hydrofluoric acid but also the rinse water, is completely recycled. New developments to increase the HNO3-recovery rate and to obtain a metal oxide by-product that is easier to recycle are presented.

Jan 1, 2006

By L. Veleva, Garcia. A., G. Perez

Aluminum is a metal used for the transmission of electricity of high voltage, in the construction industry and other areas. In atmospheric conditions aluminum forms an oxide layer (Alz03'H20) as a result of its corrosion, entering the passive state. The oxide layer can be destroyed by the presence of ions (Cr, SOx-n) developing localized (non uniform) corrosion attack by pitting, difficult for evaluation. The concepts of fractals and self-similarity were used in this study for the characterization of the development of localized corrosion. Images obtained with a scanning electron microscope (SEM) of samples of electrolytic aluminum wire that have been exposed during one year in ruralurban and marine-coastal environments of the humid tropical climate of Mexico, have been processed. The development of pitting has been studied as a function of time, making a statistics of the frequency of appearance of pits versus the area occupied by them. The data show that the distribution of the pits follows a power law. Therefore, the concept of self-similarity can be applied for the study of the phenomenon of localized corrosion, describing their development with time.

Jan 1, 2006

By V. Estrada, G. Aguilera

"Since the most of mineral processing are wet, and for more specific applications where it is necessary to increase the purity through leaching and / or concentration, the proper dispersion is the first, and perhaps more crucial stage in the whole chain of processing. This specific process is based on the formation of a dispersion or suspension of mineral, trying to make the mixture as homogeneous as possible, and with specific rheological conditions. Sometimes it is not enough agitation to make it happen, so that chemical additives are used as an aid. However, the addition of chemicals strongly alters the viscosity and other rheological properties of the suspension factor to consider for subsequent steps to ore beneficiation. In other hand, in a process where no chemicals used often employ large quantities of water to achieve dispersion. But if an efficient chemical agent, which optimizes said dispersion through a specific physicochemical effect on the particle surface is used, also it can generate rheological advantages, besides achieving rational use of water and increase the recoveries of the product main about also optimal costs. The aim of this work is to find the optimal rheological conditions for a dispersion of kaolin as study case, looking for stability, best disaggregation, viscosity and pseudoplasticity.To find the optimal additive, the evaluation parameters were: 1) Best degree of dispersion of the suspensions according to the analysis of the flow curve; 2) Best level of disaggregation of particle chemical analysis delaminated by Particle Size Distribution; and 3) Best thixotropic rheological parameters and pseudoplasticity. Finally the optimum additive as one that meets the best combination of parameters is proposed.INTRODUCTIONKaolin is a clay material formed by altering of feldspar composed mainly for kaolinite. Depending on the application, the kaolin as raw material must be refined and processed because the ores of clays contain usually a lot of impurities derived of its sedimentary source, such as feldspar, mica and quartz (Torres, et. al., 2011). According to the experience on the plant floor and the publication of several scientific papers, it is known that the dispersion is a crucial stage in mineral processing (Greene, Duke, & Hunter, 1965) (Raghavan, et. al., 2004), not only because of the disaggregation of particles, besides because of the humectation of them. Is clear that disaggregation of particles give to the suspensions rheological stability, and the humectation improves the effect of further processes like grinding or chemical treatment. The dispersion process involves making a suspension of the mineral with a solvent which is usually water, to obtain a homogeneous dispersion, with the aid of energy of stirring. Sometimes is not enough the agitation (even with high energy) for this to occur, so is necessary the use of dispersing substances which introduce ions and molecules as modifiers of chemical potential, forcing the molecules of the material to disperse. Sometimes their use even could affect the pH of the suspension in a non-desirable condition. (Flores, 2013)."

Jan 1, 2016

By H. Karakul

Determination of P-wave velocity (Vp), which is closely related to intact rock, is a nondestructive, easy and less complicated procedure. Due to these advantages, there is an increasing trend to predict the geomechanical properties of rocks from Vp. In addition to mineral content, cementing material and porosity, degree of saturation (Sr) are also other factors influencing geomechanical properties of the intact rock. However, up to the present, in the studies on the prediction of geomechanical properties of rocks from Vp, the effect of Sr has not been investigated. By considering this issue, in this study, it was aimed to correlate strength properties (uniaxial compressive and tensile strengths) and Young’s modulus with Vp of various rock types under different degrees of saturation. In addition, geomechanical properties of rocks were estimated from theoretical P- and S-wave (Vs) velocities, which were calculated based on their mineralogical compositions. For this purpose, fourteen different rock types were collected from several parts of Turkey and a comprehensive laboratory testing program was conducted. In the statistical analyzes, a series of different prediction relationships were developed by using independent variables such as Vp, Sr and effective clay content (ECC). Simple regression analysis results indicated that although prediction of the geomechanical properties of rocks from Vp at different degrees of saturation was possible, the equations developed would yield some under- or over-predictions. On the other hand, the multivariate equations developed have very high prediction performances and are very useful tools to estimate the geomechanical properties from the measured Vp at any Sr value. In addition to mineralogy, the variation in geomechanical properties with increasing Sr is also associated with the combined effect of porosity and clay content, which is first described in this study by the term Effective Clay Content (ECC). It is also noted that strength properties of rocks at any Sr may also be estimated using the empirical relations based on the theoretical Vp and shear-wave velocity (Vs) values, which are calculated from their mineralogical compositions.

Jan 1, 2015

By Sherwin F. Kelly

With the progressive exhaustion of ore deposits easily discovered by surface prospecting, the attention of scientists is being turned more and more to the employment of mechanical means for the location of ore bodies whose outcrops are not visible. The dip needle, the Eotvos Torsion balance, and various methods of electrical prospecting are illustrative of the modem tendency. Interest in the possibility of applying electricity to the solution of many of the prospector's problems dates much farther back than is usually realized. The first person to notice an abnormal intensity of electrical activity in the region of certain ore bodies was an Englishman, R. W. Fox, who experimented on the Cornwall copper and tin veins about 1830. Dr. Barus, in the United States, carried the early experiments a step further in his work on the deposits of Eureka, Nevada, about 1880. He made the very definite suggestion that the phenomena noticed would be of material aid to the prospector. Not until Professor Schlumberger, of the Ecole des Mines, Paris, took up the matter, shortly before the war, was any definite effort made to put electrical prospecting on a commercial basis. His work resulted in the establishment of sound principles and practicable field technique, for two distinct methods of prospecting.

Jan 1, 1924

By D. D. Macdonald, G. Engelhardt

The accumulation of damage due to localized corrosion [pitting, stress corrosion cracking (SCC), corrosion fatigue (CF), crevice corrosion (CC), and erosion-corrosion (EC)] in complex industrial systems, such as power plants, refineries, desalination systems, etc., poses a threat to continued safe and economic operation, primarily because of the sudden, catastrophic nature of the resulting failures. Of particular interest in managing these forms of damage is the development of robust algorithms that can be used to predict the integrated damage as a function of time and as a function of the operating conditions of the system. Because complex systems of the same design rapidly become unique, due to differences in operating histories, and because failures are rare events, there is generally insufficient data on any given system to derive reliable empirical models that capture the impact of all (or even some) of the important independent variables. Accordingly, empirical models have generally failed to provide a robust basis for predicting the accumulation of corrosion damage in complex systems under realistic operating conditions. The alternative prediction philosophy is determinism, in which the development of damage is described in terms of valid, physico-electrochemical mechanisms with the output being constrained by the natural laws. The differential damage is then integrated along the corrosion evolutionary path for the system (i.e., over the future operating "history") to yield the desired integrated damage, which is the quantity that is most useful to an operator. In this paper, we review the theory of predicting corrosion damage within the framework of Damage Function Analysis (DFA), with particular emphasis on the pitting of aluminum in chloride solutions and on the accumulation of damage from SCC in Type 304 SS components in the primary coolant circuits of Boiling Water (Nuclear) Reactors (BWRs). These cases have been selected to illustrate the various phases through which localized corrosion damage occurs.

Jan 1, 2005

By E. Gaucher, M. St-Amant

"Among the electromagnetic surveys performed by SOQUEM in the last three years, a certain number of the more instructive cases have been chosen to illustrate the theory of electromagnetism by field examples of: (a) The depth penetration of the TURAM as compared to the SLINGRAM (Ronka) method. (b) The limitations of the TURAM as compared to the SLINGRAM method when a conductor dips the wrong way, or when it is small in size. (c) The expression of a shallow-dipping conductor in a SLINGRAM survey. (d) The effect on the SLINGRAM survey of deep ditches or reef structures.(e) A comparison between the CRONE and the SLING-RAM method in the Abitibi clay belt, by means of field and model studies, indicating a usually better signal-to-noise ratio for the SLINGRAM method. From the above and from other experiments, different electromagnetic methods are now being used by SOQUEM, depending on field conditions."

Jan 1, 1970

By R. C. Hartviksen, B. H. Boyum

"The Sherman Mine, Temagami, Ontario, is an iron ore pellet operation rated at one million tons per year capacity. Mining is done from three open pits in two bands of Keewatin iron-formation intercalated in a 'greenstone belt' thought to be part of the Archean 'Abitibi Belt'. The bands of iron-formation are tabular and steeply dipping, averaging 75 degrees. The principal ore mineral is magnetite.Blast holes, 1214 inches in diameter, are drilled on 28-foot centers, each hole being sampled and assayed for both total iron and magnetic iron. Concentration tests are made in the laboratory to determine the anticipated concentrate grade. Two classes of ore are recognized -'liberating' or 'refractory'. Blending is done on iron con-.tent, degree of ease of liberation (i.e. grain size) and chunkiness. The latter is important, as primary milling is done in autogenous mills. Actual daily mill results are compared with predicted grade from blast holes, exploration diamond drill holes and pit inspection. Hourly mill samples are analyzed by the X-Ray Fluorescent Analyzer, with emphasis on silica grade. In 1969, the pellet grade was improved from 7 .01 per cent silica natural to 5.50 per cent silica natural."

Jan 1, 1970

By H. H. Bird

Kilembe is situated in the foothills of the Ruwenzori Mountains in Uganda. Precambrian stratiform copper de-posits are currently being mined at a rate of 90,000 tons per month. Complex ore structures and variable ground conditions have led to diverse mining methods in the past. New mining areas contain more shallow-dipping, highly contorted orebodies, in heavy ground. Cut-and-fill mining will be practised in the future. The geology, mining and milling are described.

Jan 1, 1968

By C. R. Ross

"The purpose of this paper is to review the activities of international organizations concerned with the problem of dust hazards in mines and to indicate the extent of Canadian participation in these activities. The work of the International Labour Office in sponsoring conferences and reports on the appraisal and control of dust hazards and in the development of standard radio-logical classifications is considered in some detail. Also discussed are the role of technical societies, such as the American Conference of Government Industrial Hygienists, in the development of proposed standards for dust exposure and the functions of international committees concerned with particular hazards, such as the U.I.C.C. (Inter-national Union Against Cancer) Committee on Asbestos and Cancer."

Jan 1, 1969

By A. W. Jolliffe

DESPITE the widespread occurrence of scheelite in Canada, domestic production of this strategic mineral is still quite insufficient to meet wartime needs. Two difficulties have invariably arisen in prospecting for or developing scheelite deposits: scheelite is a difficult mineral to identify, and secondly, its distribution is commonly so erratic that the value of a deposit cannot be determined without arduous and expensive methods of sampling and wet assay. Scheelite's property of fluorescing under certain ultra-violet lamps overcomes the first difficulty and is the basis for a quantitative method developed to overcome the second. It is found that, by use of an ultra-violet lamp, the value of many scheelite deposits may be accurately and speedily determined. The method requires neither elaborate apparatus nor exceptional skill on the part of the operator, and is most applicable to those deposits where the bulk of the scheelite occurs in fairly pure aggregates that are at least one-tenth of an inch across. It has been used in grading some two hundred scheelite-bearing veins in the Yellow-knife-Beaulieu region, Northwest Territories, and various occurrences in the Porcupine district, Ontario. The method requires the measurement of the total area of scheelite exposed in any reasonably large measured cross-section of a deposit. From the areal percent of scheelite so obtained, the tungstic oxide (WO,) content of that part of the deposit may be calculated by means of equations of simple derivation.

Jan 1, 1942

By G. Kipouros, M. Dadvand, A. Dadvand

"A novel methodology was developed to obtain a 3D porous layer with a high aspect ratio of porosity on a titanium electrode. The porous structure allowed more active material such as hydrous ruthenium oxide to be accommodated during the fabrication of the supercapacitor, resulting in an exceptionally high capacitance per surface area. The electrode demonstrated a remarkably high capacitance of 4,800 mF/cm2. The porous layer was composed of functionalized nanoparticles of TiO2 organized in a perfect 3D hexagonal close-packed array that resulted in a highly porous 3D structure. The layer was used as a template to electrolessly deposit a thin layer of silver prior to the electrodeposition of active material. KEYWORDS Capacitance, Porous, Ruthenium, Silver, Supercapacitor, Titanium RÉSUMÉ Une méthodologie innovante a été mise au point afin d’obtenir une couche poreuse tridimensionnelle (3D) affichant un rapport d’aspect élevé en termes de porosité sur une électrode en titane. La structure poreuse permet d’utiliser une matière plus active telle que l’oxyde de ruthénium hydraté durant la fabrication du supercondensateur, ce qui se traduit par une capacité exceptionnellement élevée par surface active. L’électrode affichait une capacité remarquablement élevée de 4 800 mF/cm2. La couche poreuse était composée de nanoparticules fonctionnalisées de dioxyde de titane (TiO2) organisées dans un arrangement regroupé parfaitement hexagonal en 3D, qui a engendré une structure en 3D hautement poreuse. Cette couche a servi de modèle pour le dépôt autocatalytique d’une fine couche d’argent avant l’électrodéposition de la matière active. MOTS CLÉS argent, capacité, poreux, ruthénium, supercondensateur, titaneINTRODUCTION There is a growing demand for integrating compact energy storage elements into electronic circuits due to the miniaturization of electronic circuits, sensors, and actuators, and the increasing importance of portable and wear-able devices incorporating more advanced electronic technologies that operate in controlled or uncontrolled environments to gather, process, store, and communicate information (Deng, Ji, Chen, & Banks, 2011; Beidaghi & Wang, 2012; Chen, Ramachandran, Mani, & Saraswathi, 2014). The manufacturing of compact energy storage elements needs to be compatible with the electronic circuit microfabrication processes. Recently, interest in integrating miniaturized supercapacitors into electronic circuits has increased due to their high charge–discharge rate and long operating life; however, ultra-high power miniaturized supercapacitors suffer from low energy density, hence requiring significant enhancement in their energy density for various applications (Deng et al., 2011; Beidaghi & Wang, 2012; Chen et al., 2014)."

Jan 1, 2019

By S. C. Ellis

THE bituminous sand of northern Alberta has already an extensive literature, and most of the reports dealing with the subject are still available (see Selected Bibliography at end of paper). A phenomenon so striking and, as regards its extent, so unique, as the deposit in the vicinity of McMurray settlement could not fail to attract the notice of the early explorers, and we find references to it as far back as the latter part of the eighteenth century. However, scarcely a thought had been bestowed upon the possible economic value of minerals in the the remote northern parts of Canada before the second decade of the present century, and practically no detailed mapping had been done north of the town of Athabaska. The late Wm. Ogilvie made a track survey of Athabaska river in 1884, and surveys of certain lines-including the 23rd base line-had been completed by 1911. Between this base line and lake Athabaska, nothing had been attempted. Actually, no definite information at all was available regarding the character and extent of the bituminous sand when, in the earl y summer of 1913, a reconnaissance party set out from Athabaska for McMurray. At that period, the journey was made in summer by scow or canoe. No telegraph line had been laid, and a casual mail service by canoe or dog team once in three months formed the only means of communication with the outside world. The investigation has begun by the Mines Branch was continued during several subsequent years. The sand deposits were studied and sampled, the bi rumen was extracted from the sand and studied chemically and physically, and the economic significance of the deposit was given exhaustive study.

Jan 1, 1937

By Mahmood Alemrajabi, Ake Rasmuson, Kerstin Forsberg, Kivanc Korkmaz

"In the present study, the recovery of rare earth elements (REE) in the nitrophosphate process of fertilizer production is investigated. The apatite has been recovered from iron ore tailings by flotation. After digestion of apatite in concentrated nitric acid, Ca(NO3)2.4H2O is first separated by cooling crystallization and then the REEs are recovered by precipitation. Optimum conditions in these steps have been determined in a previous study. The precipitate mainly consists of CaHPO4.2H2O and REE phosphates.In the present study, selective dissolution and re-precipitation have been studied in order to obtain a precipitate that is more concentrated in REEs. The precipitate was selectively dissolved in nitric and phosphoric acid at different acidities (pH 6 to 0) with the liquid /solid ratio of 100 mL/g. It is shown that most of the CaHPO4.2H2O and other calcium containing compounds will be dissolved at pH 2 while the REE phosphates are not dissolved above a pH of approximately 2. Thus, by partial dissolution of the REE precipitate at pH 2.5 most of the solid calcium phosphates will be dissolved and the remaining solid phase, which is more concentrated in REEs, can be filtered off as a fairly concentrated REE solid mass and the liquor can be recycled back to recover more P nutrients. Alternatively, the REE enriched precipitate was dissolved completely in nitric acid and re-precipitated again by addition of ammonium hydroxide to pH 1.2. A chemical equilibrium software, MEDUSA (Puigdomenech, 2013) has been used to evaluate the experimental results and to estimate the optimum conditions for selectively dissolving the precipitate."

Jan 1, 2016

By M. C. Ethier, A. L. Laramie

"The Granisle and Bell Copper mines were officially put into production in 1966 and 1972, respectively. The Granisle Mine was purchased in late 1979by Noranda and the two operations were amalgamated as one division. Both mines were closed in 1982after sustaining heavy financial losses during a period of low copper prices beginning in 1981.This paper describes the resumption of operations at the Bell Mine in 1985 after its shutdown period of three years and the dramatic and sustained improvements in productivity and efficiency realized as a result of a commitment by employees and management to the application of Participative Management and Employee Involvement principles. After a general description of the effects of such a philosophy on the operation as a whole, and a comparison to the operation's last full year as a producer, it deals with the practice of this philosophy in the maintenance department at the Bell Mine and the superb results realized.IntroductionThe Bell Copper deposit was discovered in 1963 and came onstream as a 10000 ton s per day open pit mine in the fall of 1972. Identified reserves at that time were 46 million tons of ore containing 0.50% copper. The mine shared facilities of the townsite of Granisle with the nearby Zapata-Granby mine which had established the community six years earlier.Because of easy grinding ore and improvements to milling circuits, Bell's throughput rate was increased to 17 000 tons per day by the late 1970s. In the open pit, improvements resulted in mining of additional reserves with higher stripping ratios. At startup, a half ton o f waste was mined for every ton of ore processed.By the end of 1982, with 48.2 million tons already mined, the Bell Mine had identified additional mineable reserves of 39.4 million tons containing 0.52% Cu.In November 1979 the Granisle Mine was purchased from Zapata-Granby. The two mines, with a total of 700 employees, were operated under common management as the Babine Division until 1982 when low copper price s forced the closure of both for an indefinite period.The outlook for copper prices remained bleak and only 50 people were retained on the payroll to maintain the two plants, most of them working on a part-time schedule.The population of the Village of Granisle dwindled from over 1500 inhabitants to under 500, as people moved away to seek other employment.Prior to the shutdown, the Bell Mine employed 370 people and pit extraction averaged nearly 50000 tons per day of which 16000 tons was mill feed, and the remainder waste. Total cost to produce a pound of copper was C$1.36 in 1982."

Jan 1, 1990

By V. P. Mehrotra, D. W. Fuerstenau, A. -Z. M. Abouzeid

The use of pulverized coal for electric power generation results in the production of vast amounts of fly ash. One potential use for waste fly ash is the production of pellets for lightweight aggregates. This paper is concerned with the role of the physical and chemical characteristics of two different fly ashes in governing their agglomeration or pelletization behavior and their strength characteristics. In batch balling experiments, fly ash pellet growth was found to be extremely sensitive to the amount of moisture added. One ash (Mohave) exhibits marked pozzolanic activity whereas the other (Jim Bridger) does not. The pozzolanic activity has a very pronounced effect on pellet growth kinetics, moisture requirements, and the effect of various additives on growth kinetics. Slow drying under ambient conditions produces strong pellets from Mohave ash whereas Jim Bridger ash pellets lacking in pozzolanic activity are weak. Rapid drying at high temperatures results in weak pellets because water necessary for hardening is driven out of the pellet. Steam curing enhances pellet strength. Locked-cycle pelletizing experiments exhibit expected oscillation in pellet production rates and attendant fluctuations in pellet green strength.

Jan 1, 2004

By D. J. Cheung, V. N. Kazakidis

ABSTRACT Seismicity and rockburst problems in hard-rock mines negatively impact safety and profitability. The authors propose a design risk methodology as a relative risk assessment for underground excavations vulnerable to rockburst damage. It considers rock mass conditions relating to mininginduced stress, geological structure, rock mass properties, and mining influence. Application of the methodology to rockburst cases involving seismically active fault zones at the Craig mine in Sudbury, Ontario, Canada, demonstrates that design changes can reduce exposure and economic risks. Mines with high geotechnical risk can use the design risk methodology to evaluate design alternatives as a risk management strategy.

Jan 1, 2014

By Y. Duna

The reliability of mine ventilation systems is critical to normal and safe production in a mine and includes reliability of the following parts: ventilation system branch (or passage), ventilation structures, ventilation network, and the fan. Among these, the reliability of a ventilation branch may be considered the foundation of the whole ventilation system. The branch ventilation flow includes four parameters: air volume; toxic and hazardous gas concentrations; temperature, and dust concentration. The calculation model for the reliability of a branch was established based on the analysis of normal distribution of flows in any one branch. Then, the efficiency of the ventilation structures and fire risk compromising the reliability of branch was studied. The results obtained were as follows: if the air volume, toxic and hazardous gas concentrations, temperature and coal dust concentrations of the branch are within reasonable limits, set at any stable state and at the same time, then this branch is reliable.

Aug 1, 2013

By Chr. Krause

Within the scope the collaborative research centre 599 (Medical University of Hanover, University of Veterinary Medicine Hanover, University of Hanover) the behaviour of the degradation of magnesium materials as implants are investigated by using animal experiments (rabbits). Thus extruded cylindrical pins from the magnesium alloys MgCa0.8%, WE43 and LAE 442 were implanted intramedullary in the tibiadiaphyses. The implantation duration was 3 and 6 month. After the explantation 3 point bending tests were carried out to investigate the possible changes of the mechanical properties. Clearly changes in dependence of the implantation duration could be determined. The three magnesium alloys show a decrease of the mechanical resistance with an increasing implantation time. To evaluate the degradation process, wich is the reason for the changes, micrographs and element analyses (EDX) have been accomplished after the 3 point bending tests. The micrographs show for all used magnesium alloys corroded surfaces but no preferred corrosion on the grain boundarys. The element analyses show beside a layer which is rich in calcium and phosphorus an agglomeration of rare earth elements in this layer. With these results a using of magnesium alloys as a material for implants can be announced.

Jan 1, 2006

By H. Al-Kazzaz

The 2-mm butt joints of ZE41A-T5 sand castings were laser welded using 1.6 mm EZ33A-T5 filler wire and a continuous wave Nd:YAG system at a power of 4 kW, surface defocusing and various welding speeds, Compared with the base metal, the fusion zone showed significant grain refinement due to high cooling rate, No grain coarsening was observed in the heat affected zone (HAZ). The porosity area percentage and total solidification crack length in the fusion zone (FZ) were reduced as the welding speed increased from 4 to 7 m/min, Fusion zone area, total penetration depth, and weld width decreased with increased welding speed, The hardness in the FZ was similar to or higher than the base metal after a natural aging of about one year, but there was a drop in the hardness of the HAZ, The HAZ width decreased with increasing the welding speed, Tensile test showed that a joint efficiency of approximately 75 ? 90 % was obtained.

Jan 1, 2005