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Spectroelectrochemical Investigation of Hydroxamate Reagents on Copper Oxide Minerals

Sep 13, 2010

By Víctor Quinzano

San Juan es una de las principales provincias exportadoras de minerales en Argentina, cuya actividad minera le proporciona mayores recursos. Sin embargo, sus plantas de fabricación (molienda, trituración) producen polvos en el exterior que contaminan el medio ambiente. Por ello, los productores incorporaron nuevas tecnologías limpias que no afecten ni el desarrollo de la producción, ni el medio ambiente. En este sentido, el presente trabajo señala las aplicaciones que el Instituto de Investigaciones Mineras de la Facultad de Ingeniería de la UNSJ ha diseñado a nivel laboratorio, a través de un recuperador electrostático de polvo, el cual responde a las necesidades de los productores y cumple con el objetivo de vinculación y transferencia con el medio productivo. Asimismo, se describe el diseño de un método de recuperación de polvos y el filtro recuperador del mismo, reduciendo el nivel de polvo a un 90% y logrando un precio de venta en el mercado.

Sep 13, 2001

By R. R. Oder, R. E. Jamison, E. D. Brandner

This paper presents preliminary test results obtained with a 0.38 kg/s (3000 lb-hr) beta prototype MagMill™. In processing Upper Freeport coal the beta prototype recovered 82% of the weight of the feed and 91% of the heat content while reducing the potential emissions of sulfur, kgSO2/GJ(lbSO2/MBtu), by 61%. Pyritic sulfur in the MagMill™ product was reduced by 78% compared to that in the feed. For all runs, the mill product was controlled between 70 to 80% finer than 74 µ particle size. Recoveries of mercury, arsenic, and selenium ranged from 35 to 45% of that in the feed. Power draw was reduced by 26% and mill throughput was increased by 9% compared to the pulverizer operating with no magnetic separator attached.

Jan 1, 2000

Experimental studies on viscosity of titanium bearing slags have been reviewed and the assessed data were used in extending the capability of the structurally related viscosity model for silicate melts, developed by the present authors. Experimental data on ternary and higher order systems containing CaO, MgO, MnO, FeO, Al2O3, TiO2, Ti2O3, SiO2were assessed and used. The newly extended viscosity model represented the viscosity behaviour over broad temperature and composition ranges. The structural role played by TiO2and Ti2O3in silicate network structure is discussed with respect to their effect on viscosity of melts. Keywords: viscosity model, TiOx containing silicate melts, silicate network structure.

Jan 1, 2004

By R. Bellotti

The theory of cavity expansion in an infinite frictional soil mass whose strength is represented by a curved Mohr-Coulomb failure envelope has been used to predict with some confidence the cone resistance of a clean dry sand. Experimental data were obtained from cone penetration and pressuremeter tests on two sands, conducted in a large calibration chamber (CC) under carefully controlled placement and boundary conditions. A plane strain bearing capacity theory was developed, and to convert the results to axi-symmetric conditions, an empirical "shape factor" was used. In the paper, the theoretical background, experimental data, calculation procedure, and the results of the analysis are presented. In general, a reasonable validation of the cavity expansion approach to the bearing capacity of deep foundations has been obtained.

Jan 1, 1987

By Richard L. Stotlar

Introduction During the last decade, the metallic minerals segment of the industry could be categorized as a "feast-or-famine" business. It is no secret that metallic minerals are cyclical. Employment opportunities greatly depend on the supply and demand for its mineral products. It is also not unusual for there to be a lag between the industry's manpower requirements and academia's ability to produce new graduates. Due to this lag, there will be years with manpower shortages, as in the mid-1970s. At other times, supply will exceed demand. The question is where will the jobs be in the years to come? This presentation will review reasons why employment opportunities have declined within the metallic minerals industry. It will also predict future demand for mineral engineering graduates. And it will outline strategies for obtaining an employment offer. Historical Review - Employment From 1977 through 1983, about 75% of all metal mining employees were directly engaged in production activities, down from 83% in 1965. This decline reflects increased use of labor saving equipment, and more government regulation and foreign competition. Metal mining's employment decreased from 74,000 jobs in 1982 to fewer than 68,000 in 1983 - an 8% decline. The overall industry is having these problems because of the general downturn in the economy. For example, at the beginning of this decade, US automobile and steel industries were in trouble. Interest rates were too high and volatile. This adversely affected construction, housing starts, and manufacturing. All these industries, being large users of base metals, drastically affected the metals industry. US copper companies are still having problems. Reports indicate that many copper employers have cut production, laid-off workers, and permanently closed mines, refineries, and smelters. A decline in the demand for US produced metal products, such as copper, obviously affects some mineral engineering employment opportunities. Other factors to consider when looking at employment opportunities and why it has become difficult for US metal producers to compete in the world market include: • The grades of ore bodies of many US minerals are considerably lower than the grades of ores being mined elsewhere in the world. • The grades of ore bodies currently being mined in the US are steadily declining. • Foreign producers are largely government controlled and are not necessarily subject to the realities of supply and demand. • US environmental regulations have considerably added to production costs. Foreign producers in most countries do not have to worry about these additional costs. • US mines are getting deeper. This adds to the cost of production because of the increasing distance the ore has to be transported. • Plants and equipment are outdated. Many companies find themselves operating with equipment and plants that need modernizing or replacing. This obviously hinders competitive productivity. • Labor and management have had problems. Work stoppages in certain mining businesses and high wage and benefit costs in relation to foreign producers place US producers at a disadvantage. • Much land is unavailable. The US government owns most of the land considered to have the best potential for minerals development. Most of this land is unavailable for mining or exploration. Therefore, it appears that finding employment with a company whose primary business is mining and processing most metals, such as copper, in the US will be quite restricted and competitive. Future Demand It is difficult to anticipate what key employment opportunities within the next few years will be available to mineral engineering graduates. The Engineering Manpower Commission estimated that US engineering schools awarded 72,471 undergraduate degrees in 1983 vs. 66,990 in 1982. This was the eighth consecutive year in which the number of baccalaureates awarded has increased. On a brighter note, the US government's Occupational Outlook Quarterly stated that the growth rate through 1995 for all engineers is an encouraging 49% over present levels. The estimated number of engineers employed in 1982 is 1.2 million. The numerical in-

Jan 2, 1985

By Harry Verakis, Thomas Lobb

Over the past decade, approximately 5.1 billion pounds of explosives were used annually, on average, in the United States. Most of the explosives were used by the mining industry. The coal mining industry was and still is the dominant user of explosives. About two-thirds of the explosives consumed was used in coal mining.

Jan 1, 2003

By Paul H. Johnson

Resource Engineering and Development, Inc. is desigining and building a portable 150 to 225 tpd, flotation-cyanide leach plant with unitized, skid-mounted components. This plant design, with its portability, low capital investment, and high recovery of silver and gold from many partially oxidized ores, is well suited to treat many small, highgrade deposits, old waste dumps, and old mill tailing piles. A description is given of flotation and/or cyanide leach tests run on 18 partially oxidized, newly mined ores; waste dump materials; placer slimes; and old mill tailings.

Jan 1, 1981

By B. V. Knelson

"GENTLEMEN:This paper will deal with centrifugal separation - theory and practical, and since the Knelson Concentrator is the only centrifugal concentrator with a properly fluidized bed, this paper will cover the Knelson Concentrator and its technical and structural advances over the last five years. As I am the person with the most experience in this line, I guess I am some kind of an expert; what kind I’m not sure, but some kind.This type of concentrator truly was developed because I’m lazy and I constantly look for easier ways to do things. My experience in the mining industry was very limited but I did realize in looking at placer operations, which is the application where I spring from, that it was tremendously labour intensive and my first reaction that ""my god, there must be some method or way-of handling product in a more efficient (and you can read that as being able to quickly recover very fine particle gold) way than was being shown at that time"". So, the Knelson Concentrator was born - about 6 or 7 years later. Our first attempt was a cone with about the same degree of slope as our present machine and since we had no knowledge of vibration dampening and centrifugal forces at that point, it was just an idea that this should work.Our first run was one of twenty minute duration. We did make that first machine variable speed by a mechanical belt system and we found that at about 240 rpms we were virtually shaking the gravel plant apart that we were attached to. So the first run was twenty minutes and back to the drawing board. However, that first run produced a concentrate so superior to anything we had seen previously, that we knew without any question, we were definately and accurately on the right track."

Jan 1, 1985

By S. K. Chan, C. Badeen, S. Goldthorp, H. Feng, I. Alilovic, R. Turcotte

Over the last few decades, water-based explosives and their precursors, despite their apparent insensitivity, have been involved in a number of accidents around the world. A large proportion of these accidents occurred when these emulsions were pumped either for their manufacture, transport, or handling. In Canada, this has led to the development of “Guidelines for the Pumping of Water-Based Explosive”, which state that “using pumping pressures well below the laboratory measured minimum burning pressure (MBP) of the corresponding emulsions or watergels is a good safety practice”. However, in the above document, there is no description on how the MBP should be measured. In the last few years, a research program at the Canadian Explosives Research Laboratory (CERL) in collaboration with Orica has been focused on the development of a validated measurement protocol for realistic MBP measurements.

Jan 1, 2014

By A. Steinmüller

Introduction In the design and operation of gravity concentration circuits, the application of process models for spiral concentrators offers significant benefits. A substantial amount of work has been produced over the last 30 years in the field of modeling the metallurgical performance of spiral concentrators. It is not the aim of this contribution to add to the refinement of modeling technique but to share some of the experiences and potential improvements which can be achieved in a relatively simple way. The design of spiral circuits usually requires extensive testing. This is often conducted in batch operation only, either due to lack of suitable continuous testing facilities, the unavailability of sufficient quantities of sample, or other constraints. Typical problems arising during circuit development from batch testwork are the extrapolation of results to different feed conditions, and resolving of internal recycles. Model selection and development The classic approaches in spiral modeling technique range from fundamental fluid dynamics, based on the Navier-Stokes equations in combination with expressions for local slurry properties, to fully empirical and statistical models. With the initial objective of developing an in-house tool for gravity circuit optimization and development, mathematical model types from each category, available either commercially or in the published literature, were evaluated. Model selection For the desired purpose, an approach proposed by Holland-Batt (1990) was found suitable, which was adopted and modified. Holland-Batt reported that the shape of release curves in spiral applications could be described by a combination of a linear function in the initial recovery zone, and a power law function outside this zone. The proposed recovery function was formulated as

Jan 1, 2005

By S. J. Frank

The development of feedforward semi-empirical control models for furnaces and the evaluation of mass balances are based on plant data. The models can only be as good as the data and it is therefore required to know the inherent uncertainty associated with the plant data. This uncertainty stems mainly from the fact that the slag, alloy or dust, have a distributed nature that depends on the degree of mixedness. It is commonly accepted that melts from open bath furnaces are well-mixed, and submerged arc furnaces less so. The impact of this assumption is significant, as a reasonably homogeneous melt could be represented by one sample only. As so much of metallurgical control depends on the assay information of the alloy and slag melts from furnaces, it was decided to characterise the possible variation in melt chemistry and temperature. Sampling campaigns and continuous temperature measurement of the melts were performed for different alloy and slag taps at a major ferrochrome producer. Both a submerged arc furnace and open arc furnace are evaluated in this way, by way of comparison. The slags of both open arc and submerged arc furnaces were found to be of similar degrees of homogeneity, with much spatial variance in the reducible iron and chromium oxides. However, it was found that the alloy melts deriving from open arc furnaces were significantly less homogeneous than the alloy derived from submerged arc furnace alloy production. The compositional variance could be related to the furnace operating conditions and it affects both metallurgical accounting and process control. In all cases it was found that the variance in melt solute components are larger than can be ascribed to analysis instrument error. It will be shown how this predetermined variance in melt composition could be included in process modelling and control.

Jan 1, 2004

By C. N. Harman, N. S. S. Rama Rao

Production of Ferro-alloys through submerged electric arc furnace involves use of electric power as one of the major inputs. Hence the production by this power intensive process can be made economically more competitive if the specific power requirement for smelting each ton of the product is brought down. This becomes all the more necessary where the power cost is comparatively high, like in India. Since the day FACOR started production of Ferro Chrome in 1968, briquetted chromite fines along with lumpy ores were used as feed. Subsequently the increase in the proportion of briquettes and reduction in lumpy ore helped in increasing the use of chromite fines and also brought down the specific power requirement. Meantime FACOR had been closely watching the technical development of use of sintered pellets in Outokumpu and SRC Processes which need still lower specific power. But the high capital requirement for a pelletisation plant kept FACOR from introducing pellets feed to their Ferro chrome furnaces. So this was postponed to be adopted in future. In February 2004 in the ?1st Ferro-Alloys India?, a paper [1] was presented by Dr. Amit Chatterjee. In the questions period after the presentation of the paper there came up a discussion in which it was revealed that with the Indian high grade chrome ores it was not possible to make sufficiently strong pellets, unless a larger percentage of bentonite is used as binder. This is because the Indian high grade Chrome ores have different mineralogy of gangue content compared to low grade ores in Finland and South Africa. Higher usage of bentonite gives rise to higher slag volume and this would result in increased specific power. Since FACOR had plans to go in future for sintered pellets feed, this gave rise to a doubt on success of pelletisation for Indian high-grade chrome ores. This prompted FACOR to take up experimental production of sintered chromite pellets and use of the same in one of their existing furnaces for production of high carbon Ferro chrome. The results are encouraging and are summarized in the paper.

Jan 1, 2007

By Mingju Liu

China has been suffering from coal and gas outbursts since 1950s. Nowadays, the situation has become worse than ever with the need to mine deeper coal deposits at higher production rates in a more complex underground mining environment. In the year 2006 alone, 37 outbursts occurred in underground coal mines with a death toll of 232. This paper describes a case study of an outburst event, which occurred in July 2006 during the shaft development of the Mengjin Coal Mine, Henan Province, China at a depth of 768m below surface. Detailed analysis of the possible causes that led to the occurrence of the outburst is reported. These include the study of complex geological features, gas storage conditions, possible improper technical management practice as well as incomplete prevention and control measures. Based on the case study and the observation of outburst occurrence in China in the year 2007, suggestions have been put forward to help prevent and control future coal and gas outbursts.

Jan 1, 2007

By Ken Cross

This paper aims to demonstrate that explosives organizations and workers have a legal, moral and financial duty to be able to demonstrate their competence when required, and how that may be achieved at any level from explosives storekeeper to senior explosives engineer on a major project. The concept of competence is outlined, as are the benefits to members of staff, management and the organization, particularly in a regulatory regime that includes competence management as a key performance indicator.

Jan 1, 2013

Flotation of Smithsonite by Using Siloxane Cationic Surfactants as Collectors

Sep 13, 2010

By Peter (Yunqing) Zhang

Longwall recovery under weak roof conditions could have considerable delay if the immediate roof is weak and deteriorates during screening. A pre-driven longwall recovery room is a feasible solution to minimize the impact of longwall move on production. In this longwall recovery project, a 16-ft recovery room was pre-driven to cover screening, and the shearer cut another 16 ft outby to reach the final recovery line. The pre-driven recovery room was carefully monitored as the face was approaching it. The longwall face operated very well as it cut into the recovery room. The recovery process took about 13 days, and considerable time was saved compared with the previous panel. The support in pre-driven recovery room was designed to handle both front abutment pressure and weak immediate roof conditions. Pumpable standing support was used to support the cantilevered roof as the fender pillar narrowed and collapsed when the face cut into the recovery room. To ensure the stability of the recovery room, 3-D computer modeling was used to evaluate the support system. Abutment pressure, critical fender pillar width, bolting system, pumpable cribs and shield support were considered in the model. The recovery room was carefully monitored during longwall recovery. Roof-to-floor convergence and crib convergence were recorded every shift as the longwall face was approaching the recovery room. Roof, floor and pillar activities and crib performance were also observed as the face cut into the recovery room. This paper presents the support design for the recovery room, evaluation of the support system through computer modeling, and details of the monitoring results.

Jan 1, 2006

By R. M. G. Machunter

Computer models of metallurgical circuits are extensively utilised in design, and prediction of overall plant separation performance. As always, in the final optimised flowsheet design there is a compromise between the recovery of values and grade of the circuit output. This paper mathematically examines various circuit options for the generation of a heavy mineral concentrate from a generic mineral sands wet concentrator plant. Based on data derived from testwork, any particular mineral sand has a unique release curve describing the separation performance of the heavy mineral suite. Models are constructed that combine particular stage output streams as feed to other stages in various configurations. The ramifications of each option are discussed and reasons why one particular option is selected over the others examined.

Jan 1, 2005

On. Tuesday, Apr. 8, the Rocky Mountain Club held its 12th annual dinner at the Waldorf-Astoria, New York. In reporting the dinner the Evening Telegram says: "General Coleman du Pont was sort of master of ceremonies, and he conducted the affair at the end of a Colt .45. It was the General's `forty-five' which filled the banquet hall of the Waldorf-Astoria with the brand of smoke which Uncle Sam showered so generously upon Germany's hordes. It was General du Pont's `forty-five' which bellowed and thundered and echoed through Fifth avenue, scaring horses and shell shocking pedestrians: But no one was hurt or badly shocked except those who could not discern the artistry of Miss Doraldino's dance. "There were Western men around the table who have just come hack from over there. For instance, there were Brigadier General G. H. McManus, General Shanks and a score of others. And there were Thomas H. Watkins, who is said to own half the State of Pennsylvania and is known as the `Coal Baron'-of Pennsylvania,, and Alba B. Johnson, president of the Baldwin Locomotive Works, each one a Westerner, with personality and type suggestive of some of the wonderful men Bret Harte wrote so much about. "It seemed as though General du Pont, who was chairman of the Reception Committee, tried to eclipse all former meetings, and he succeeded if congratulations are a criterion. " General du Pont startled the management of the Waldorf and surprised the diners by staging a three-round bout between Frankie Fay and Phil Wagner. The clash between these two featherweights made Waldorf history, because it was the first boxing contest ever held in the hotel. Tex Rickard, who is going to chaperone Jess Willard and Jack Dempsey in a fight in the near future,-was scheduled to referee the contest, but at the last moment, for some obvious reason, M. E. Schermerhorn was sent in as third man. The bout was a slashing one. Miss Amparito Farrar, lately returned from France, where-she sang for the 'dough-boys;' Eleanore Wetmore, the Rath Brothers and Phil Baker were among the others who entertained.

Jan 5, 1919

By Tariq B. Hamid

Deep excavation is commonly associated with construction of different deep below-grade structural elements (e.g., basement walls and slabs, tunnels, retaining walls, tanks, utilities, etc.) Deep Excavation Retaining Systems (DERS) are required when open cuts with safe slopes are not possible. Careful analysis, design, and planning of the DERS are required to provide safe below-grade construction and secure nearby structures from damaging effects that may result from the deep excavation. Selection and design of temporary or permanent DERS (e.g., soldier pile and lagging, sheet piling walls, secant pile walls, tie backs, etc.) can have significant impact on time, cost, and performance. In order to design DERS using conventional methods, it is necessary to obtain shear strength parameters, angle of internal friction (ø), and cohesion (c), of retained soils. Residual shear strength parameters (ø'res, c'res) obtained from drained direct shear tests and triaxial tests on saturated samples have been commonly used in practice for the analysis and design of DERS. However, there are cases where ground water table remains at or below the base of excavation during the design lifetime of DERS. In such cases, the soil above the ground water table is in an unsaturated state. Therefore, it is important to account for the unsaturated conditions of soils in order to optimize the design of DERS. This paper is focused on implementing the basic concepts of unsaturated soils mechanics including matric suction and soils-water characteristic curve (SWCC) to estimate design shear strength parameters of unsaturated soils (i.e., ø°, c', and ø') for the design of a cantilever sheet pile walls, a typical case of study of the DERS. The results of this study indicate that the determination of unsaturated soil strength shear strength parameters is simple. In addition, using unsaturated soil mechanics theories has an outstanding impact on the design of retaining systems.

Jan 1, 2006