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By R. I. Jaffee, C. M. Craighead, G. A. Lenning

Hydrogen forms a beta-stabilized system with titanium, with a beta eutectoid at about 300°C and 44 atomic pct H2. 'The solid solubility of hydrogen in alpha decreases from about 8 to about 0.1 atomic pct from 300°C to room temperature. Hydrogen has little effect on tensile properties, but decreases notch-bar toughness to a large degree. This latter effect appears to be the result of increased notch sensitivity. PRIOR to this investigation, only a small amount of information was available on the effect of hydrogen on the mechanical properties of titanium. The effects of the other interstitially soluble elements, carbon, oxygen, and nitrogen, had received detailed study. Jaffee and Campbell1 indicated that hydrogen up to 1 atomic pct did not affect tensile properties deleteriously. Pitler' indicated that 1 atomic pct H, in titanium reduced the impact strength appreciably, but his alloys contained appreciable amounts of oxygen, and it was difficult to attribute the embrittlement entirely to hydrogen. The high temperature portion of the equilibrium diagram for the Ti-H system was established by McQuillan," and his data generally corresponded with the results of Kirschfeld and Sieverts," Gibb and Kruschwitz," Bevington, Martin, and Mathews," and other investigators. The lower concentration limit of the hydride phase varied considerably among investigators, and Gibb and Kruschwitz9 ad shown that small amounts of contaminants in either titanium or hydrogen caused considerable variation in this lower limit. In view of this pronounced effect of contaminants, the extrapolated value of McQuillan's, about 48 atomic pct at the 325°C eutectoid, appeared the most reasonable. McQuillan's lowest experimental value was 54 atomic pct at a temperature of 450 °C. The density of titanium had been shown to decrease with increasing hydrogen content, but discrepancies were noted among the various investigations. The best values indicated that the density was decreased from 4.56 grams per cc at 0.27 atomic pctl to 3.84 grams per cc at 61.3 atomic pct? This investigation was conducted to determine the effects of hydrogen on a titanium, both in high purity and commercially pure metals, and on high purity a titanium alloys. Material and Fabrication The literature indicated that impurities in either the hydrogen or the titanium must be kept to a minimum. For this reason, the initial studies were made with high purity iodide-refined titanium. The vendor's analysis of the iodide titanium and the hydrogen content of the as-fabricated Y4 in. diameter rods are shown in Table I. Two 1 lb ingots were prepared by arc melting under argon in a water-cooled crucible, using a water,cooled tungsten electrode. This equipment has been described.' As-cast Brine11 hardness numbers of 88 and 58 for these ingots were low enough to insure that the high purity of the metal was maintained during arc melting. The ingots were hot forged to % in. diameter rods at 800°C, cleaned by grit blasting, and then cold swaged to Yz in. diameter rods. The rod was then air annealed at 725 "C, ground to remove scale, and cold swaged to Y4 in. diameter (75 pct reduction in area). The material was then annealed for 1 hr in argon at 800°C to develop an equiaxed a grain size of about 0.05 mm. Micro tensile specimens and microimpact specimens were machined from this rod prior to treatment in the Sieverts-type absorption apparatus. Two lots of commercially pure RC-55 titanium were also used in this investigation to determine the effects of hydrogen and the normal impurities on mechanical properties. The commercially pure RC-55 alloy was obtained in the form of % in. diameter rod. The analysis of this material is also given in Table I. The % in. diameter rods were hot swaged

Jan 1, 1955

By Robert :H. . Lesemann

I recently gave a talk at a seminar on mine development in the Eighties. I had to present CRU' s long-range market outlook for copper, lead, zinc, nickel, molybdenum and silver. In reviewing the recent history of each metal, and our projections, I tried to find some common pattern of behavior that could prove a guide in projecting future market behavior. When you sweep aside your input-output models and econometric equations, what you seem to be left with is this: "When a market goes through a prolonged period of price weakness, you can usually look forward to a period of considerable improvement. " "When a market goes through a prolonged period of price strength, you can always anticipate a prolonged period of price weakness." Stated another way, "The better things are, the worse they will get."

Jan 1, 1982

Plans have been completed with only details to be arranged for the first Metals Branch Conference in the Northwest. The two day meeting will be held jointly with the Industrial Minerals Div. on Friday and Saturday, May 9 and 10, 1952, at the Davenport Hotel in Spokane, Wash. For, some time the metals activities in this area have been neglected. Expansion of metal producing and fabricating industries in Washington and neighboring states has brought sufficient interest to insure the success of such a meeting. A committee has been hard at work for several months. Nonferrous extractive metallurgy men will find an extensive program in the April issue of JOURNAL OF METALS. Sessions for iron and steel producers, physical metallurgists, and educators will make the Metals Branch picture complete. Metals Branch members residing in Washington, British Columbia, Oregon, Idaho, Montana, Wyoming, Nevada, and Utah, or who can be in the Northwest at this time should make plans now to attend. A Metals Branch luncheon is planned for Friday and a dinner jointly with the Industrial Minerals Div. is planned for Saturday according to F. R. Morral, metallurgist with the metallurgical research div. of Kaiser Aluminum & Chemical Corp., P. O. Box 1451, Spokane, Wash.

Jan 1, 1952

By Viney K. G, Molinia A. B

The Hellyer Pb-Zn-Ag orebody in western Tasmania was discovered in 1983, and mine production at a rate of 250 000 tonnes/yr commenced in 1987. Expansion to 1 million/yr will be completed by early 1989. Exploratory development to gain access to the orebody, to provide a 20 000 tonne bulk sample for pilot plant work and to confirm mining conditions and orebody continuity was undertaken using conventional drill and blast techniques and large diesel trackless equipment. A ventilation shaft was raisebored. Development in this phase totalled 2 815 m and provided a sound basis for rapid expansion of the mine.

Jan 1, 1988

By H. A. Davies

DURING a current program of research on the structure and properties of liquid sodium alloys, the need arose for information on the solubilities as a function of temperature of several B subgroup metals in liquid sodium. In the absence of reliable information in the literature for several of these systems, par- ticularly at temperatures in the range 100° to 300°C, an apparatus was constructed to determine solubilities by a direct melt-sampling technique, followed by wet-chemical analysis for both sodium and the solute metal. The details of the technique have been described previously.' The solubility of indium in liquid sodium was determined at eight temperatures in the range 100° to 270°C. The solubility as a function of temperature is shown on Fig. 1; this represents the liquidus line over this composition range. A cooling curve was plotted after the completion of the sampling and an arrest was observed at 94.9°C which must be interpreted as being the result of a eutectic reaction. By extrapolation of the liquidus to this temperature, the eutectic composition was estimated to be about 0.25 at. pct In. The present estimate of the eutectic temperature and composition are in good agreement with the values of 96.0° to 96.2°C and between 0.28 and 0.45 at. pct In, respectively, which were reported by Heycock and Neville.2 However, no further information on the liquidus of this system at the sodium-rich end could be found in the literature for comparison. One compound: NaIn, has been reported in this sys-

Jan 1, 1968

By William O. Macha G

El presente trabajo describe la molienda y flotación como etapas de mejoramiento en la metalurgia del plomo en Paragasha. Para ello, se revisa los principales problemas de la metalurgia, como el de los minerales encontrados en la superficie, entre otros. Asimismo se describen los circuitos pertinentes de la planta piloto, como de la planta Paragasha y los resultados metalúrgicos en los meses de enero a marzo en 1965. En el primero, se señalan las dos etapas de molienda y flotación en el Pb, mientras que en el segundo, se muestra el circuito stándard: molienda y flotación.

Aug 20, 1965

By Trudinger JP

Mt. Newman Mining Company Pty. Ltd.3 oper ates the Mt. Whaleback iron ore mine in the Ham- ersley Iron Ore Province of Western Australia. The present rate of production of high grade hematite iron ore is 33 million tonnes per year. Mining is by open cut quarrying,with 15m high benches. The present quarry operations will be extended to a large oval pit to win over 1400 million tonnes of iron ore. The pit slopes will extend up to 500m in depth and the perimet- er of the slopes will exceed 15km. Sixty per- cent of the ore is below the water table, which presently lies 45m below the general plain level Dames & Moore, rock mechanics consultants designed the pit slopes during early mine devel- opment to ensure an economic and safe operation.

Jan 1, 1975

By S. P. Singh, V. J. Hucka

There are a number of problems associated with underground coal mining, but the most serious and important are often related to the ground control. The influence of the prevailing geological conditions and features on the stability of underground mining has been outlined in this paper. Special emphasis has been given to the importance of geological techniques in the evaluation of coal mine roof conpetency prior to and during the mining operations. In addition to this, typi- cal ground control problems owing to the geological abnormalities have been depicted by appropriate case histories from coal seams in the State of Utah. The interdependence between longwall design and road- way stability on the one hand and geologic features on the other hand are shown in this study.

Jan 1, 1983

By Robert L. Stephens

"It can be argued that one of the most important property of any material is cost, since this property detennines the applications for which a material can be considered. Despite growing demand and production for commodity metals such as copper, nickel, zinc, lead, and tin, the cost of these metals has been steadily decreasing in real terms. The only way that metal miners and producers can remain financially viable in the long term is by continuing to lower their cost curve through the implementation of new metals production technologies. This paper reviews technological developments in the production of copper, nickel, zinc, lead, and tin that have or threaten to redefine the cost curves for these metals.DisclaimerThe opinions expressed in this paper the author's, and are not necessarily those held by the author's employer, Cominco Ltd.IntroductionThis meeting will discuss many novel technologies and processes for producing metals and materials with specific properties that will enhance the applications ranges for the material or will allow entirely new applications to be developed. However, in every real-world case, the cost of the new material or process is an important property that determines which applications the material or process can be used in. Other properties that are important depend on the applications.A recent press report (1) discussing the potential replacement of aluminum radiators with copper radiators in pickup trucks and sport utility vehicles provides an interesting example to reinforce the importance of cost in materials selection. In this case, the displacement of aluminum by copper is being considered because of the more favorable heat dissipation characteristics of copper. Heat dissipation has become more important due to the development of hotter-burning V-8 and V-6 engines. For this application, engineers also consider cost, weight, size, durability, and manufacturing process. The report stated that the development by the International Copper Association (ICA) of the ""CuproBraze"" manufacturing process for heat transfer products was an important development. This technology produces 845 radiators that weigh less, are more uniform in quality, and are potentially more compact. They are also expected to cost less in high production quantities than copper units produced in the past, last three to four times longer than soldered copper radiators, and the process also eliminates the use of lead solder from the manufacturing process."

Jan 1, 2000

By J. J. Hoeppner

Accurate determination of moisture in coals of various ranks has long been a subject of intensive investigation. Excellent reviews of methods developed over many years are given by Brown (9)4/ and, with experimental comparisons, by Goodman, Gomez, and Parry (11). As pointed out in these and other writings, one of the principal difficulties in assigning absolute merit to one or another procedure is the multiplicity of conditions under which water may exist in coal and the difficulties involved in obtaining sharp separation and distinction between these classes. Gauger (10) states: Water recoverable from coal is obtained from the following sources: (1) Decomposition of organic molecules (sometimes called combined water), (2) surface adsorbed water, (3) capillary condensed water, (4) dissolved water, and (5) water of hydration of inorganic constituents of the coal.

Jan 1, 1956

By Payne AR

The high cost of gateroad repairs and maintenance in U.K. longwall coalmining is a clear indication of the failure of permanent support systems to fulfill their prime function, i.e. control of strata movement. The main component of gateroad support is the pack, the design and materials of which have experienced an important development process during the last 10-15 years. More recently, research investigators have attempted to give a design basis to pack quality and dimension, and reference is made to two theoretical approaches. In the course of a current research programme based upon in situ monitoring, interim design recommendations have been proposed as a means of effecting improvement in support efficiency. Identification of characteristic deformation behaviour forms the basis of the recommendations made and the subsequent improvement in gateroad performance reported.

Jan 1, 1986

By Roger G. Haga, Richard P. Campbell

Introduction Project scheduling . . . . • What is it? • Why is it done? • Who does it? • How is it done? • When is it done? These are some of the questions that will be addressed in this paper. It is intended that by exploring these questions, an understanding of project scheduling, its purpose and benefits can be achieved. The purpose of this article is not to describe in detail "how to schedule", but rather to give an overview of the scheduling function on a project. A successful scheduling effort is dependent upon the people responsible for developing, implementing, and monitoring the schedule, and the tools and procedures that are used. These three elements are integral components of project scheduling. What is it? A schedule is the integration of network relationships, resource constraints and the calendar. The schedule identifies when the activities "will" be done, while the network states when they "must" be done. Networking techniques are the most widely accepted scheduling tool for complex projects. The benefit of the network is the simplicity in illustrating, presenting and analyzing the dependency relationships of a project. The logic network is the foundation of the schedule. When calendar dates are applied to the logic network, it becomes a schedule which provides the basis for evaluation of project status, forecasting the occurrence of events and controlling the project. The sequence of activities that requires the longest time to complete determines the overall duration of the schedule. This longest sequence of activities is called the "critical path". The "critical path method" (CPM) is used to describe this particular schedule network methodology. The two common conventions of CPM networks are the "arrow diagram met hod" (ADM) and the "precedence diagram method" (PIM). There are arguments in favor of each of these two methods, and usually the one that is used is a matter of personal preference, project directive or corporate procedure.

Jan 1, 1986

By Ian M. Thomson, Robert W. Greene

To move 7 million tons annually from their new inland coal mines at Camp Breckenridge, Ky., TVA selected a transportation package proposed by American Commercial Barge Line. The land portion includes two cable-driven conveyors covering 12.7 miles; a 260,000-ton storage area on a man-made island with a stacking-reclaiming bucket wheel; and a barge-loading system of 5500-tph capacity. The 183mile river portion will utilize three unit-tows with towboats and barges specially designed to carry the maximum tonnage allowed by locks and channel depth. The system has two noteworthy features. The first is a single-flight cable belt conveyor over nine miles long. The other is a high capacity twin belt conveyor using the principal of two separate belts supported in 60° troughing idlers. This conveyor exhibits a high carrying capacity combined with accurate tracking and lack of spillage. A description is given of the mechanical problems and solutions to the design, construction, and operation of the conveyor system which provides the link between the coal mine and the barge loading dock.

Jan 1, 1974

By Andrew E. Nevin, Sidney A. Williams, James N. Lukanuski

Three porphyry copper districts in southern Arizona are partly overlain by post-ore fanglomerates with certain physical and petrologic characteristics which define a distinct and significant class of rock. These units are the Locomotive fanglomerate at Ajo, the Helmet fanglomerate at Twin Buttes-Mission-Pima, and the Cloudburst formation at San Manuel- Kalamazoo, herein termed “Locomotive-type fanglomerates.” Post-ore units at Poston Butte and Lakeshore, Ariz., and Sar Chesmeh, Iran, also appear to fit this class. Locomotive-type fanglomerates may be genetically related to porphyry copper deposits as subsequent products of differentiation, volcanism, uplift, and sedimentation in short-lived basins of limited areal extent. These units are sufficiently distinct to be utilized as exploration guides for porphyry copper deposits in the Southwestern U.S., northern Mexico, and elsewhere.

Jan 1, 1977

By Ryan CG, Both RA, Mernagh TP, Large RR, Hunns SR, Gemmell JB

The Hellyer and Mt. Chalmers deposits are mound-style volcanic-hosted massive sulphide (VHMS) deposits in Australia. Textural, petrographic and microthermometric investigations of fluid inclusions in the Hellyer stringer system indicate that Type I, primary, liquid-vapour inclusions are 10-15 pm in size, and yield homogenisation temperatures of 170-220¦C in early 2A veins, 165-322¦C in main-stage 2B veins and 190-256¦C in late-stage 2C veins. These data suggest a waxing and waning thermal history. However, the average salinity remained between 8-11 NaCl equiv. wt % in all Stage 2 veins. At Mt. Chalmers, Type I inclusions up to 20 ¦m are found in quartz from the mineralised zone, and these inclusions yielded homogenisation temperatures of 160-268¦C and salinities of 5-8 NaCl equiv. wt %. Laser Raman spectroscopic (LRS) analysis indicates the presence of CO2 (

Jan 1, 1995

By Kukla G. T

A Seam deposit User oriented Mine Planning System (SUMPS) was developed by The Broken Hill Proprietary Company Limited (BHP) at its head office in Melbourne. It is one of the computer mine planning systems developed by the Corporate Data Processing (CDP) section of BHP. To date it has been employed in the feasibility study of four coal prospects for the BHP Group, including Gregory in central Queensland - Ham and Van Hoorn (1978). It was also used in detailed short term mine planning for Gregory. A recent application was in the feasibility study of Saxonvale, a multi seam coal deposit in New South Wales with seams up to 20 m thick. The other two applications of SUMPS were also on thick multi seam coal deposits. Development of programs for the underground sub-section of SUMPS is continuing. SUMPS was developed and implemented on mini computers with graphics and plotting peripherals. The company's philosophy towards computing is one of centralized development and project planning, with transfer of hardware and software to site once the mine becomes Operational.

Jan 1, 1980

By Marius R. Campbell

VArIoUs classes of coals are recognized in this country at the present time. These classes depend largely upon physical characteristics rather than upon chemical composition, and consequently they cannot be accurately defined. The divisions into anthracite, semi-anthracite and semi-bituminons are fairly satisfactory; but the term bituminous embraces so large a variety of coal that it is of little value, and the term lignite is so loosely applied that it has little or no place in a scientific classification.

Jan 1, 1906

By Robert Keeney

THE electric smelting of manganese ore and the production of ferro- manganese did not exist as an industry, in the United States or elsewhere, previous to the outbreak of war in 1914. Ferromanganese had been produced, electrically, during times of high prices by two companies at Niagara Falls and by several European companies, but the production. was spasmodic, and none was electrically produced when ferromanganese sold at from $35 to $40 per ton. Thus the electric smelting of manganese ore must be considered as a development caused by the high prices prevailing during the years 1916, 1917 and 1918, and the necessity of smelting domestic ore in order to fill the ferromanganese requirements of the steel industry of the United States, which increased from 189,088 tons in 1914 to 356,356 tons in 1918. The electric furnace is well adapted to smelting domestic-ore because it can be located in small units near the source of ore supply. In 1918, the ferromanganese production of the United States was 333,027 tons, of which about 7 per cent., or 23,000 tons, was produced in the electric furnace. The electric furnace not only assisted materially in the development of a domestic-ore supply but made a considerable saving of coke, as it requires about 1,4 tons of bituminous or lignite coal per ton of ferromanganese compared with a blast-furnace consumption of 2.9 tons of coke per ton of ferromanganese. Some of the plants in the United States that smelted manganese ore in the electric furnace during the war and in 1920 are listed in Tabled. From early in 1919 to about February, 1920, little ferromanganese was produced in the electric furnace. During this period the price of ferro-manganese (78 to 82 per cent. manganese) was about $100 per ton. During the first half of 1920, several plants resumed operation when the, price of. ferromanganese (76 to 80 per cent. grade) gradually increased to $200 per ton, delivered.

Jan 2, 1921

By T. K. Bundtzen

Placer gold in the Iditarod and Innoko mining camps of western Alaska is derived from a suite of comagmatic, Late Cretaceous to Early Tertiary, alkali-calcic, meta-aluminous. volcanic-plutonic complexes and peralumi-nous rhyolite sills that intrude Mesozoic flysch. Heavy-mineral concentrates from 42 mining operations and streams draining known mineralized areas in the igneous complexes contain placer gold and a variety of ore minerals derived from epithermal to hypothermal conditions of formation. The minerals include cassiterite, ilmenorutile, samarskite, cinnabar, scheelite, chromite, stibnite, silver sulfosalts, monazite, and zircon. Results of the study show that 1) cinnabar. stibnite, and quartz formed with the bulk of the placer gold in an epithermal lode environment, 2) chromite appears to have originated in mafic phases of monzonite plutons and alkalic basalts, and 3) niobium-tin-tungsten-uranium-silver values may have been derived from stockwork accumulations in cupolas of monzonite plutons.

Jan 1, 1987

By Bukovinsky SB

The smelting, refining and hydrometallurgical operations practised in the winning of non-ferrous metals are associated with severe aqueous and high temperature corrosion problems.With the increasing costs of maintenenace and the utilization of computerization to control the processes, the trend in recent years has been to spend more capital on improved and proprietory grades of engineering materials, which offer greater reliability and more cost effective plant performance.The problems which have plagued stainless steel users for many years are the alloys' poor performance in chloride or other halide media where pitting, crevice or chloride induced stress corrosion cracking may occur, have been essentially solved by the new proprietory grades. The controlled additions of minor alloying elements including rare earth metals have led to the development of stainless steels with high mechanical strengths, improved corrosion resistance, and high temperature corrosion resistance and structural stability.

Jan 1, 1985