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By C. Basilio

Thermodynamic calculations based on a rigorous mass balance technique have been carried out for the chalcocite-potassium ethyl xanthate (KEX) system. The results of the calculations are used to: i) construct Eh-pH diagrams for KEX additions ranging from 0 to 10-4 M, ii) determine the amounts of cupric ions and copper xanthate formed at different Eh and pH values to make three-dimensional diagrams, and iii) determine the minimum KEX addition required to form CuX and CuX2.. This allows prediction of the optimum conditions for flotation and comparison of this with microflotation test data. In addition, voltammetry experiments have been conducted on chalcocite electrodes at pH 9.2 and pH 6.8 in order to gain information on the role of metastable species in flotation. On the basis of these experiments, possible reaction mechanisms are discussed and comparisons are made with what is expected on the basis of thermodynamics.

Jan 1, 1985

By R. Ajalloian, L. Karimzadeh

This paper describes the engineering properties of Givi dam foundation. Givi dam will be built across the Givi River on the andesitic rocks (Karaj formation) in Ardabil province (northeast of Iran). Geotechnical investigations including drilling, pumping tests, sampling for laboratory testing and discontinuity survey. Physical and mechanical properties of andesitic rocks such as density, water absorption, porosity, uniaxial compressive strength, triaxial compressive strength, durability and direct shear tests are evaluated in this paper. Discontinuity data are process for the determination of dominant sets and for the rock mass characterization in terms of classification systems ( RMR, Q and RSR ). Correlations between these three classifications are discussed. Le barrage doit être construit sur la rivi_re givi qui cou_e sur les andesites (formation de Karaj)dans la province d_ Ardebile situee_ a Nord- Ouest de l_ _Iran. Les études géophsique commesondage, Pompage. Et échantillonnage afin de verifier les discontinutés out éte_ effectuées. Lesproprietés physique et méchanique des roches andesifique ont éte_ verifieés. Les informations concernaüt aux discontinuitiés afin de montrer leur principale direction ont éte_ verifieés, les proprietés des roches dans leurs ensemble ont éte_ etudieés. Les divers classifications(RMR,Q,RSR ) ont éte_ comparés et analyseés. Dieses Schreiben ist zur Erklaerung der Ingenieureigenschaften ueber Baugrund des Givi Deiches.Dieser Deich soll im Givi fluss auf Andesitgesteine (Karaj formation) gebaut werden. Der platzdes Deiches legit im Ardebil Provinz nordwestlich von Iran. Geotechnische Untersuchungen Sind:Bohrungen, pumpen Versuche, Probenentnahme fuer Laborversuche, BrechbarkeitBestimmungen, physikalische und mechanische Eigenschaften der Andesitgesteine wurde hierausgewertet, wie Z.B.: Wasserleitfahigkeit, Porositaet, Scherfestigketswiderstand, Informationenueber Brechbarkeiten der Gesteine wurde gesamelt, und die meisten Brechbarkeiten bestimdamitman die Gesteine besser klassifizieren kann. In Endefekt wrid die Resultate verschiedeneKlassifizierung wie RMR, Q, und RSR besser geachtet und zusammen vergliechen.

Jan 1, 2003

By Hector M. Henao

To provide thermodynamic data for converting nickel matte to liquid nickel at high temperature, an experimental study was conducted on the phase equilibrium between the Ni-S alloy and the FeOX-SiO2, FeOx-CaO, and CaO-A12O3 base slag in a magnesia crucible and the CaO-Al2O3-MgO slag in an alumina crucible. All experiments were carried out at 1773 K under controlled pso2 of 0.1 atm and po2 in a range between 5x10- and 10-5 atm by using CO-CO2-SO2 gas mixtures. The dissolution of nickel in the slag was found to be minimum for the CaO-Al203¬-MgO slag with a molar ratio of NCaO/NA1203=1.7. The solubility of nickel in this slag at p02 of 6x10 atm (just before the precipitation of solid NiO) was 4 mass%. This result suggests that a CaO-A12O3 base slag could be used in converting Ni-S melt to nickel while minimizing nickel losses to the slag.

Jan 1, 2002

By Jie Li, Shu Yang, Zhongliang Tian, Xun Hu, Yanqing Lai, Shaolong Ye

The electrolyte with high solubility for Sc2O3 is very important to realize the preparation of Al-Sc master alloy by the molten salt electrolysis. The solubility of Sc2O3 in K3AlF6- Na3AlF6-AlF3 melts is determined with an isothermal saturation method. The effects of KR (ratio of K3AlF6 to K3AlF6+Na3AlF6), the concentration of Al2O3 and the temperature on the solubility of Sc2O3 are also investigated. The results indicate that the solubility of Sc2O3 in K3AlF6-Na3AlF6-AlF3 melts increases and then decreases with KR increasing. The solubility of Sc2O3 is 8.698 wt.% in (K3AlF6-Na3AlF6)(KR25%)-18 wt.%AlF3 melts at 940℃. The effect of temperature on the solubility is little, and the values are 8.575 wt.% and 8.762 wt.% respectively when the temperatures are 930℃ and 960℃. The solubility decreases from 8.809 wt.% to 7.058 wt.% as the concentration of Al2O3 increases from 1.5 wt.% to 5.0 wt.% at 950℃.

Jan 1, 2015

By Jaffrey Y. Foley

Placer gold and platinum-group metals (PGM) In the Slate Creek area, northern Chistochina Mining District, are derived from silicified and carbonate-altered, Cretaceous-Tertiary (?) dikes and related mafic and ultramafic rocks. Gold In the placer deposits is also derived from Tertiary conglomerate and altered Jurassic-Cretaceous argilllte. The argilllte and Igneous bedrock sources show a unique Ag-Au-Cu-Hg-PGM association that Is attributed to a combination of magmatic, hydrothermal, and supergene processes. The bedrock and placer deposits contain a variety of gold silver-lead-copper and PGM alloys. The observed geochemical, mineralogic, and alteration features are consistent with current geological models for turbidite-hosted gold deposits. No economic gold or PGM lodes were Identified, but several areas warranting more detailed investigation were Identified. Conventional geochemical sampling and analysis of small sample splits weighing between 10 and 30 grams were shown to be unreliable as a consistent means of identifying gold- and PGM-bearing bedrock. Pan concentration of pulverized rock samples was shown to be a more effective, but still Imperfect means of Identifying gold and PGM source rocks. Geochemical data and mineralogic examination indicate that gold and PGM in potential lode sources are very finely and erratically disseminated, are chemically combined with other elements, and may not be entirely free-milling or amenable to simple gravity concentration.

Jan 1, 1990

By Julian Boldy

"A review of lI5 significant volcanogenic massive sulphide discoveries in the Canadian Precambrian during the past 65 years reveals that only 7% resulted from surface exploration methods aimed at depths below the effective reach of current geotechnical systems. This has been due to the relative ease of shallow discovery, resulting in the harvesting of ore deposits within 100 m of surface. This surficial layer has been more or less effectively supersaturated by routine exploration. In view of the fact that a mining district's metal content is not likely to be confined to a surficial layer, the time has come to explore the vertical dimension, prospecting for ore at depths in excess of 150 m in productive districts.Essential to this task is an understanding of the Precambrian volcanogenic ore deposit model. The deposits generally have .a tendency to be associated with the terminal phases of felsic volcanism, and to be located along certain time-stratigraphic horizons, marked by the products of volcanic exhalation. The significant massive sulphide deposits are discrete entities, ranging from the top 5% of deposits greater than 45 million tonnes in size, with a surface area of 0.30 km2, to median-sized deposits greater than 1.2 million tonnes in size with a surface area of 0.02 km2. These significant economic ore deposits range in value from $5.5 billion for the top 5% of deposits to $125 million for median-sized deposits. In terms of their frequency of occurrence, the former group has a 4% distribution and the median-sized deposits have a 15% distribution.An historical review of many of the principal Precambrian mining districts, such as Noranda and Flin Flon, shows that major tonnages are usually discovered during the initial phase of application of each new geotechnical search system, until carried to its ultimate limit of effective depth penetration. With the exception of the Noranda district, the mean depth of ore discovery in the other districts is still generally confined to within 50 m of surface.Targeting deep ore is difficult. One effective prospecting method is the detection of fracture-controlled mercury leakage haloes in outcrop (or core) above and peripheral to blind deposits. This technique has proved to be a useful pathfinder, and focuses attention on deposits buried at depths in excess of 700 m in some instances. Down-hole EM systems also promise to be effective in locating deposits previously bypassed by drilling. In addition, trend surface analysis programs of trace element geochemistry should be used as an aid to targeting ore by directing exploratory drilling along the plane of ore-hosting stratigraphy.By definition, mining districts have a proven ""favourability"" for the occurrence of ore. Discovery probabilities in these districts will be considerably enhanced if future search efforts are concentrated below a depth of 150 m, and more use is made of ""deep"" ore search systems coupled with sound geological reasoning. Deep drilling programs to a depth of800 m should initially be designed to search for the top 25% of deposits greater than 3.3 million tonnes in size, with a surface area of0.05 kmt. :a value of$310 million and a 12% frequency of occurrence; This can be accomplished for an over-all cost approximating $40,000 per drill hole. If the search depth is limited to 400 m, the over-all cost of each drill hole is $20,000, equivalent to expenditures routinely allocated to grassroots exploration drilling in the remote greenstone belts of the Precambrian. Depending on a company's objective, prospecting for deep ore offers a stimulating challange - though risky, it has its rewards."

Jan 1, 1981

By E. F. Loiseau

IN a paper on the manufacture of artificial fuel, read at the Philadelphia meeting of February, 1878, I enumerated the difficulties which I had to overcome before succeeding in the mixing of coal-dust and clay, the compressing of the same mixture, and the water-proofing of the lumps. The drying of the lumps, after leaving the press, was the remaining difficulty, and it was expected that a plan devised by Dr. Charles M. Cresson, of Philadelphia, would enable us to dry the fuel as rapidly as it was moulded, and that a continuous production could in that way be obtained. The company was reorganized. The works were purchased by the new company at an assignee's sale, and the oven was modified, according to Dr. Cresson's plan. Anticipating a possible failure, I had prepared a plan by which I expected to be able to demonstrate that anthracite coal dust mixed with pitch, could be manufactured with our present machinery slightly modified ; so that after all, if we were compelled to give up the attempt to make fuel for domestic use, there was a possibility of succeeding in the manufacture of a good steam-fuel. The plan suggested by Dr. Cresson for drying the pressed lumps of coal-dust cemented with clay, did not work as well as we expected. It enabled us to dry more fuel than we did before, but it could not be made to dry more than one-half of the lumps produced by the press. The plan was abandoned, and I was authorized to experiment with coal-dust and coal-tar pitch. The cement which is used in Europe to conglomerate coal-dust is ,usually dry pitch, which is prepared by separating from the tar, at a temperature of 572° Fahrenheit, the volatile matters which it contains. Some manufacturers, however, employ crude tar, others, a rich tar, which has been cleared of 25 per cent. of its volatile substances, by heating it to 392° Fahrenheit. But with common tar very weak fuels are obtained, which do not burn well, and give out a strong smell and a great deal of smoke ; it is also necessary to subject them to a baking process, in order to solidify them, and to eliminate the more volatile of the materials contained. This operation of course requires a special plant, the cost of which increases sensibly the price of manufacture, without counting the products

Jan 1, 1880

By James P. Morris, William H. Hansmire

The U. S. Department of Energy's (DOE) Yucca Mountain Project (YMP) is a scientific endeavor to determine the suitability of Yucca Mountain for the first long term, high level nuclear waste repository in the United States. The status of this long-term project from the construction perspective is described. A key element is construction of the Exploratory Studies Facility (ESF), which is being excavated with a 7.6 m (25 ft) diameter tunnel boring machine (TBM). Development of the ESF may include the excavation of over 15 km (9.3 mi) of tunnel varying in size from 3 to 7.6 m (10 to 25 ft). Prior to construction, extensive constructibility reviews were an interactive part of the final design. The intent was to establish a constructible design that met the long-term stability requirements for radiological safety of a future repository while maintaining flexibility for the scientific investigations and acceptable tunneling productivity.

Jan 1, 1995

By Frank Firmstone

In a paper read at the meeting in Cleveland, Ohio, in 1875,* I showed that as a result of changing from open-topped to close-topped furnaces at the Glendon Iron Works, there had been a decided falling off in regularity of working, which we attributed to the very different distribution of the materials in the new method of filling. Subsequent experience has, on the whole, confirmed the opinions then expressed, and in 1881 we decided to try the modification of the Langen charger, shown on the accompanying drawings, thinking by its use to approximate to the distribution obtained by dumping the barrows at six equidistant points in the circumference of the open-topped furnaces. The top of the furnace is closed by a ring-shaped " bell," as we still call it, the outside of which is cylindrical and rests by the turned lower edge on the bored seat of a " loose ring," supported by the lower part of the hopper. The inside of the bell is an inverted frustrum of a cone, the central opening in which is closed by a cylindrical plug, which is prolonged into a pipe to carry off the gas.? This center-plug is connected by rods and chains to sectors on the ends of a forked lever, to the other end of which is attached, by a wire rope, the piston-rod of the blast-cylinder used in opening the top. The rods connected to the center-plug pass loosely through the apexes of triangular frames, to the other angles of which the bell is attached; it thus being suspended by four points when the top is open. When the materials are dumped out of the barrows into the hopper, a part is thrown over the crest of the bell into the space between it

Jan 1, 1885

By S. V. Ketov, V. P. Menushenkov, V. S. Shubakov

"The glass samples were obtained by melting of the oxides mixture SrO-Fe2O3-B2O3(Al2O3) at 1200-1250°C with subsequent quenching of the melt on quickly rotating steel roller. Submicronsized Sr(Fe,Al)12O19 particles were formed in glass-ceramic matrix during the crystallization aging of glass. The aging temperature Tag varied in the range 650-950°C. The submicron-sized hexaferrite powder was obtained by removing of the matrix phases using etching. The samples were characterized by X-ray diffraction, scamiing electron microscopy and magnetization measurements. The glass-ceramic material exhibits very high coercivity value up to 10 kOe. The samples of magnets were obtained by pressing of the hexaferrite powder at RT and subsequent aging in the range 900-1200°C. The aged samples exhibit coercivity value up to 8 kOe.IntroductionStrontium M-type hexaferrites have been widely used in technology and industry mainly for production of permanent magnets owing to their appropriate magnetic properties, chemical stability and low cost [1,2]. The SrFe12019-based compounds are characterized by high magnetocrystalline anisotropy and single easy magnetization axis. The highest coercivity is received for monodomain, defect-free single crystal particles with size D - 100 mn. Finely grained strontium hexaferrite prepared by chemical methods such as sol-gel pyrolysis and oxide glass crystallization exhibits high coercivity up to 6-8 kOe [3-5]. Owing to the partial substitution of Al for Fe in the strontium hexaferrite leading to the increase in the magnetic anisotropy field Ha=2Ki/M,, the increase in the coercivity may be received [6]. The notable results were achieved using the SrO-Fe2O3-AlzO3-B2O3 glass crystallization and formation of perfect submicron crystals of alumina-doped hexaferrite [ 6, 7]. The coercive force of glassceramics reached values of up to 10 kOe. Hexaferrite particles are well faceted and have the shape ofhexagonal bipyramids with truncated vertexes [7].In the present paper, we report results of our investigation into the SrO-Fe2O3-B2O3(Al2O3) glass crystallization, hexaferrite powders and permanent magnets, which were prepared by pressing submicron-sized hexaferrite powders at RT and subsequent sintering at 900-1200°C."

Jan 1, 2012

By E. Watkins, J. C. LeRoy, A. Vivyurka

"TAILINGS REVEGETATIONWelcome to the Revegetation Session. My instructions are to introduce the Speakers and to provide a general introduction.I do the latter with humility not only because of a lack of personal experience or because tailings revegation is not well established technology, but because any general statement on a country or industry as diverse as the Canadian Mining Industry is bound to be wrong somewhere.Laying aside normal standards of accuracy I proceed as follows:In considering the question of tailings revegetation, one asks two basic questions:1. What ought to be done?2. What can be done?The first question can be broken down into three kinds of criteria or objectives:a) Legislativeb) Technicalc) AestheticThe first I leave to the politicians and the last I will avoid. Aesthetics is the philosphy of taste. It is concerned with the appreciation of things rather than what they really are. It is much easier to get into an argument on aesthetics than to get out of it feeling you have said something of consequence.Technical criteria can be divided into the following sub-objectives: 1. To isolate the tailings basin so surrounding land is not degraded. The first step here is stabilization of the surface to prevent wind and water erosion."

Jan 1, 1975

By C. Heckman, M. S. Moats, A. Luyima, W. Cui

"Cyclic voltammetry, electrochemical impedance spectroscopy (EIS), and galvanodynamic and chronopotentiometric techniques were used to characterize the effects of DXG-F7®, a commercial smoothing agent, on copper electrodeposition onto 316L stainless steel from a synthetic electrolyte containing 40 g/L copper (Cu2+), 160 g/L sulfuric acid (H2SO4) and 20 mg/L chloride (Cl-) at 40oC. The findings were compared against results using HydroStar® 4208, a modified polysaccharide. The nucleation overpotential and plating potential observed in cyclic voltammetry and galvanodynamic testing showed that neither DXG-F7 nor HydroStar significantly polarized acidic copper electrodeposition. Subtle differences between the additives were found during EIS testing and modeling, but more research will be needed to fully understand these differences. Surface-roughness measurements of two-hour deposits indicate that DXG-F7 and HydroStar produced smoother deposits as their concentrations in the electrolyte increased. No difference in the surface roughness of deposits was detected between the additives. Based on the experimental evidence resulting from the laboratory testing, no significant difference was found between DXG-F7 and HydroStar at 20 mg/L Cl- concentration, with the exception that DXG-F7 dissolves more easily in water than HydroStar. Introduction Cathode deposits obtained from acidified copper sulfate electrolyte(s) without organic additives are often soft, coarsely crystalline and nodular (Sun and O’Keefe, 1992). Therefore, small amounts of organic additives are added to the electrolyte to produce level and dense cathodes during copper electrowinning. The action of organic additives is thought to be due to their adsorption on the surfaces of the newly formed copper grains. Hence, any copper grain that grows excessively fast adsorbs a layer of organic additive, which inhibits growth. The result is a smoother and harder deposit of suitable purity (Sun and O’Keefe, 1992). In part I of our four-part series on the examining of copper electrowinning smoothing agents, a review of previously published work on organic additives used during copper electrowinning was presented (Moats, Luyima and Cui, 2016). In the review, it was noted that many tankhouses had switched from guar to other saccharide-based products such as HydroStar and DXG-F7."

Jan 1, 2016

By Nikolaos Petropoulos, Ulf Nyberg, Daniel Johansson

A series of signature boreholes were blasted to observe any difference between confined and free face blasts. Four geophones were used to capture the compressive wave. The conventional approach, i.e. the calculation of vectorized peak particle velocity (vPPV) did not show any difference. Also a wavelet transform was tested.

Feb 1, 2020

By R. Koen, H. Visser, A. Roodt

"SynopsisThe tetraethylammonium salt of the mono-anionic coordination compound mer-oxidotrichlorido(thenoyltrifluoroacetylacetonato- K2O,O’)niobate(V) (NEt4)[NbOCl3](ttfa)], has been prepared under aerobic conditions and characterized by single-crystal X-ray diffraction. (NEt4)[NbOCl3](ttfa)] crystallized in the monoclinic P21/c space group, with a = 11.483 (5), b = 12.563 (5), c = 17.110(5) Å, and ß = 100.838 (5)o. The complex structure exists in a 50.0% (NbA) : 50.0% (NbB) positional disorder ratio.IntroductionComplexes containing organometallic type ß- diketone ligands with O,O and O,N donor atoms are used widely in coordination chemistry and have applications in catalysis, radiopharmaceuticals, etc. (Schutte et al., 2011; Roodt, Visser and Brink, 2011; Brink et al., 2010; Otto et al., 1998). These ligand systems are very useful because of their highly coordinative nature, high solubility, and also due to their ability to be functionalized with various substituents on the carbonyl carbon atoms (Schutte et al., 2011).Only a small number of ß-diketonate ligands have successfully been coordinated to a Nb(V) metal centre, with only a select few being characterized by X-ray crystallography (Viljoen, 2009; Bullen, Mason and Pauling, 1965; Preuss, Lamding and Mueller-Becker, 1994; Funk, 1934; Davies, Leedlam and Jones, 1999; Allen, 2002. The synthesis and crystal structure determination at room temperature of mer-oxidotrichlorido (thenoyltrifluoroacetylacetonato- k2O,O’)niobate(V) {(NEt4)[NbOCl3(ttfa)]} was first reported by Daran et al. in 1979. Accordingly, for this current investigation, (NEt4)[NbOCl3(ttfa)] was re-evaluated at 100 K to determine if the structural features might change with temperature."

Jan 1, 2015

By John Hanna

The Mineral Resources Institute (MRI) has developed a unique process for selective fatty acid flotation of phosphate minerals from siliceous ores. The process takes advantage of preferential adsorption and high reactivity of fatty acid collectors towards apatite over silica surfaces under slightly acidic conditions of pH 5-6.5. The process was successful in upgrading various phosphate samples from Florida and North Carolina containing 7.7-15.3% P205 and 62.3- 77.2% Insol to concentrates assaying 28.1-33.1 % P205 and 4.1-9.9% Insol with high P2O5 recovery of 81.8-92.2%. Depending on the type of silica impurities present one or more cleaning steps, with or without sodium silicate, would be required to improve the grade of the rougher phosphate concentrate.

Jan 1, 1992

By R. Stickler, A. Vinckier

An optical and electron microscope study was made on a commercial 302 stainless steel heat treated for massive carbide precipitation. Convincirg evidence was obtained that the grain boundary precipitate does not grow away from the grain boundary into the matrix, but grows as a network of large thin dendrites in between the grains. IN austenitic stainless steels the carbon in supersaturated solution precipitates when the steel is heated in the temperature range 450" to 1000°C. During such heat treatments the chromium-rich carbide occurs primarily at the grain boundaries and has adverse effects on the corrosion resistance and low-temperature ductility of the material. It has been shown that the morphology of the precipitated particles differs widely depending on the time and temperature of the heat treatment, the nature of the boundary, the misfit between the grains, and so forth.1"5 It was assumed by Mahla et al.,' Streicher,' and Mc Nutt' that the carbide particles which nucleate in the grain boundary grow in various geometric or dendritic forms away from the boundary into the matrix. However, Kinzel,' Hatwell et a, and Plateau et aL4 found that the particles nucleate in the grain boundary and grow as a network of thin dendrites in the grain boundary interface. We have made a comprehensive studyg of the precipitation occurring in a commercial 302 austenitic stainless steel heat treated for times ranging from 0.15 to 1500 hr at various temperatures from 480" to 1065"~. This study was made to elucidate the influence of heat treatments on both the mechanical and the corrosion properties of this steel. Part of this investigation which is pertinent to the morphology of the grain boundary carbides referred to above is separately reported here. We found that the particles which nucleated in the boundaries grew in the interface of these boundaries, thus supporting the viewpoints of Kinzel,' Hatwell et al.,3 and Plateau et al.4 Furthermore, when carbide particles nucleated in the matrix very close to the boundaries, they possessed a morphology distinctively different from the particles growing in the grain boundaries. MATERIAL A study of metallographic samples and of fracture surfaces of a 302 stainless steel is reported in this paper. The composition and heat treatments are listed in Table I. Polished and etched samples were examined und813r the optical microscope, and carbon extraction replicas of etched micrographic samples and various fracture surfaces3'8'9 were examined under the electron microscope. RESULTS AND DISCUSSION A representative optical micrograph of the 302 steel, condition A, is shown in Fig. l(a). Particles can be seen on the grain boundaries but no traces can be found of particles which grow from the grain boundaries into the matrix. A carbon extraction replica of this sample shows numerous large thin dendrites, Fig. l(b). The lateral dimension of such carbide particles vary up to 100 p, and their thickness estimated from the amoun! of electron penetration i:; between 500 and 1000A. Such large dendrites are extracted from almost all grain boundaries and, if they had grown into the grains, they would definitely be revealed by etching traces in the matrix, Fig. l(a). The reason why these large dendrites on the extraction replica appear to be grown into the grain is due to the mechanism of the extraction replica process. Thus, these dendrites are supported by the carbon replica film only at the edges originally along the grain boundary trace A-A, Fig. l(b), in the polished metal section and have subsequently fallen over onto the carbon replica film during handling. Although such dendrites generally fall only to one particular side of the grain boundary trace, one finds occasionally that parts of a dendrite have fallen to both sides, as shown in Fig. l(b). Further evidence for the growth of carbide in the grain boundary can be obtained from the appearance of fracture surfaces. A small impact specimen of the 302 steel, condition A, was broken at liquid nitrogen temperature. The fracture path follows the

Jan 1, 1962

By C. M. Harrer

The location, features, qualities, and extent of iron occurrences and the associated resources--limestone and dolomite, bentonite, coal-lignite, petroleum and natural gas, power, and water--are evaluated. The results of pioneer beneficiation tests on South Dakota taconite are discussed. In addition, pertinent features of taconite development, cost factors, the Western and Central United States trade area and markets are reported. The State's production of iron ores until 1963 has been small and for purposes other than the manufacture of iron. This investigation disclosed the probability of large resources of taconite in Pennington and Lawrence Counties. The average iron content is 29 percent, and a 65-percent or better iron concentrate might be produced. Ample resources are available for mining and processing taconite. An investment of at least $26 million would be required for a plant capable of turning out 1 million tons of agglomerated iron concentrate per year. The feasibility of such an enterprise is indicated, but intensive investigation and research must be completed to justify such an investment,

Jan 1, 1966

By R. S. Dean

This is the fourth of a series; of annual report of the Metallurgical Division to be released in this form and cover the fiscal year July 1, 1937, to rune 30, 1938. This report is not merely a recitation or brief of the year's work; it contains technical information in usable form, although a some of this has appeared or will he issued in greater detail in separate reports. The table of contents that follows fists the principal investigations accomplished and those that are being continued. Other projects are being begun and contemplated for the next year.

Jan 1, 1938

By Edmund S. Leaver, R. S. Dean, T. L. Joseph

The metallurgy of manganese has developed along the lines of iron metal¬ lurgy. Enough high-grade ore has Been available so that by reduction with carbon it could be turned into an iron-ma.nga.nese alloy and a slag containing some 9 to 15 percent manganese. More siliceous ores have been smelted in the blast furnace to form iron-silicon-manganese alloys called spiegel. When lower-grade ores came in for serious consideration, which lias only been since l°l4, two types of processes received the most consideration — hydrometallurgical processes to produce a concentrate which could be smelted like the higher-grade ore and processes involving concentration of the manga¬ nese from manganiferous iron ores by preferential reduction of the iron (184)1. Special chapters in this bulletin are devoted to the production of ferro¬ manganese from ore, the hydrometallurgy cf manganese, and the Bureau of Mines modification of the preferential reduction process. Other methods of producing manganese alloys from low-grade or refractory ores have been suggested and may find future application. Manganese has a very high affinity for sulphur and is particularly adaptable to concentration by matte smelting. According to Betts (26), manganese silicate may be smelted with pyrite to give manganese sulphide and iron silicate. This method would be applicable to concentration of either the silicate or carbonate ores. The sulphide, once obtained, could be roasted to oxide and reduced in the usual way. Another possibility for the production of manganese from silicate ores involves their reduction by silicon or manganese silicides. Swedish Patent 52290, February 25, 1925. covers the reduction of a slag rich in manganese by silicon-manganese alloy containing more than 10 percent silicon, Joseph H. Brennan (38.) describes the concentration of manganese iron ores by partial reduction with silicon. Beckett (7,4,19) describes the reduction of manganese dioxide with a manganese silicide for the production of standard ferromanganese. Beckett gives as a typical alloy, manganese 64.4, silicon 24.6, and as a typi¬ cal ore, 5S.5O manganese as MnO^. The product of the reaction between these two is 80.11 percent manganese and 1.22 percent silicon.

May 1, 1934

By Joseph T. Coe, Alireza Kordjazi, Michael Afanasiev

Cross-hole sonic logging (CSL) is a common quality assurance measure for the evaluation of the structural integrity of drilled shafts. The results of CSL can be supplemented by a set of tomographic images generated by cross-hole tomography (CT). Although the same access tubes, sources and receivers are used in both methods, CT has the advantage of providing a higher quality image of the possible anomalies in drilled shafts. Nevertheless, it has been reported in literature that the CSL and CT miss anomalies with sizes of smaller than 10 percent of the cross sectional area of the drilled shaft. This implies poor resolution despite the high-frequency of the stress waves utilized in these methods. This issue with resolution can be at least partially attributable to the fact that CT relies entirely on the inversion of the first time of arrival and ignores the information embedded in the rest of the recorded traces. This study examines the application of full waveform inversion (FWI) to generate a higher resolution image of the possible defects in drilled shafts from the same data used for cross-hole tomography. FWI is a wave-field method that aims to directly match the recorded traces with traces obtained from a numerical model of the domain. This has the benefit of avoiding the selection of the first time of arrival, along with increasing the resolution of the final image due to extracting more information out of the traces. Through a series of numerical simulations, synthetic traces were generated from a drilled shaft with defects of known mechanical properties, dimensions, and location. These traces were then inverted to evaluate the performance of FWI for structural integrity testing of the drilled shafts. INTRODUCTION The presence of construction defects can compromise the structural integrity of drilled shafts and negatively affect their performance (O’Neil 1991; Sarhan et al. 2002; O’Neil et al. 2003; Poulos 2005). Several non- destructive testing (NDT) methods exist that are currently used for the evaluation of the structural integrity of drilled shafts. Cross-hole sonic logging (CSL), cross-hole sonic tomography (CT), and thermal integrity profiling (TIP) are well-established and documented in the industry and practical manuals (Brown et al. 2010). NDT methods prevent the need for coring and excavation and are relatively fast and cost effective. Successful implementation of these techniques has also been reported in the literature (Branagan et al. 2000; Iskander et al. 2001; Mullin 2010; Johnson 2016).

Jan 1, 2019