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By E. Sehner, G. Van Weert

Metal chloride pyrohydrolysis is a fifty year old technology, operating satisfactory in many plants around the world, mainly on ferrous chloride, The capabilities and costs of its two equipment options (spray roaster and fluid bed pyrohydrolysis) are well known. Why is the technology not more widely used in mineral processing, beyond the production of MgO and upgraded TiO2slag? After briefly reviewing chloride vs. sulphate process characteristics and existing plant operations, this paper will discuss pyrohydrolysis options for the mine developer using the processing of ilmenite, siliceous zinc oxides and oxidic nickel / cobalt ores as examples.

Jan 1, 2003

By G. E. Erdman

The total attitude of the industrial minerals producing company is a most important factor in how they regard quality control, technical support for their customers, and procedures used in mining their minerals products. This philosophy of the producing organization directs their action along certain courses. For instance, one producer might see itself as a mining company with its major goal mining efficiency to make it exceedingly price competitive in the market place. Another producer might see itself as a wide spectrum multi-mineral producer that furnishes a reputation for a complete line of products. Another producer might see itself as a specialist in one specific industrial mineral and bet its whole bankroll on providing the very best of quality with the goal of becoming the largest producer of the mineral commodity. Each perception can have a different impact upon the producer's operations and its regard for quality control. Minerals Being Produced The specific markets being served will have their own influence on how mineral product quality is regarded. Ceramic raw materials, for instance, have a very low tolerance for iron which is the cause of low fired color. Thus, industrial minerals for use in glass and ceramic markets must be won from deposits with a very low iron content. A high iron silica sand might be sold to a manufacturer of good old beer bottles. That is a solution to one particular quality facet, but eliminates selling to a significant market in clear glass, porcelain enamel, ceramics whiteware bodies and hobby glazes. Thus, there is a need for sound research in the industries expected to be served before the product is brought to market.

Jan 1, 1987

By J. A. Barrera-Godinez

Traditional batch flotation tests produce a limited number of data points from which to evaluate the kinetics of the process. In this research, continuous weighing of froth, from a modified circular flotation cell, using a computer/data acquisition system., has been coupled with chemical analyses from intermittent froth sampling. This combination has permitted the experimental data to be smoothed such that the flotation kinetic parameters could be determined with enhanced confidence. To demonstrate the procedure, a galena ore was floated to permit flotation kinetics to be investigated as a function of cell parameters. It was shown that the kinetic data of this lead flotation most closely correlated with the Huber-Panu three parameter model. In addition the results illustrated the effect of froth thickness, froth scraper rate and air flow rate on the cell performance, in terms of mass flow, grade and recovery.

Jan 1, 1990

By Robert S. Foote

The U.S. Energy Research and Development Administration (ERDA) is currently conducting a national program to survey for uranium the conterminous United States and Alaska by 1980 using airborne and surface techniques. This paper discusses the techniques used and some of the results of airborne surveys conducted to date by Geodata International, Inc. Airborne gamma radiation and the earth's magnetic field data are measured to provide data leading to regions potentially more favorable for the exploration and discovery of uranium ore. High-sensitivity radiometric and magnetic field data have been gathered from an aircraft with an average surface altitude of 400 feet (Figure 1). Under most conditions, data are usable up to an aircraft surface elevation of about 1250 feet where limitations will be discussed. Results of data analysis under GJO-1632, GJ0-1644, GJO-1654 and GJO-1663 will be discussed.

Jan 1, 1976

By Scott A. Crozier

Environmental regulation of the United States copper industry has evolved significantly over the past three decades and the pace of that evolution is expected to escalate dramatically during the 1990's. The paper examines, from a corporate perspective, current environmental regulation and expected trends including the development of Subtitle D regulations for mineral extraction, beneficiation and processing activities under the Resource Conservation and Recovery Act. The paper concludes by exploring existing and potential impacts on copper companies in complying with the changing environmental regulatory scheme and responsible and progressive precautionary measures companies should consider to address these issues while simultaneously addressing often competing socioeconomic demands.

Jan 1, 1992

By W. W. Wen

Approximately 3 percent of the raw coal processed in U. S. Steel coal-preparation plants ultimately reports to slurry- tailing disposal. The usual disposal method is to pump the refuse slurry containing the minus-48 mesh (300 µm) refuse into dams or impoundments that are constructed of the coarse refuse. The failure of an impoundment at Buffalo Creek, Saunders, West Virginia and the sliding failure of a coarse refuse pile at Aberfan, Wales, England, resulted in an evaluation of refuse disposal methods by various regulatory agencies as well as coal producers. The result of this evaluation was the promulgation of Federal regulations dealing with the construction, operation, and final abandonment of coal refuse disposal areas. As a consequence of these regulations the use of the landfill/impoundment method of disposal became in some cases economically urlfeasible or technically impossible. U, S. Steel has studied a number of alternative methods of refuse disposal. During an investigation of mechanical dewatering with a pressure filter, Portland cement was added to the slurry to solidify the filter cake. Because of the success of the cement addition it was decided to study the stabilization of fine-coal-refuse slurry through use of cement-type additives.

Jan 1, 1979

By J. C. C. C. Menezes, R. A. S. Silva, A. V. Colling, I. A. H. Scheneider

"Coagulants rich in ferric sulfate can be obtained from pyrite-containing coal tailings using a biohydrometallurgical process. The aim of this study is to evaluate the relationship between quantity of pyrite and rate of oxidation, with regard to the consequent production of ferric sulfate for potential use as a coagulant for water and wastewater treatment. Leaching experiments were carried out on the laboratory scale on four coal tailings with different concentrations of pyrite. Characterization of the coal tailings was conducted for the following parameters: total sulfur, pyritic sulfur, sulfate sulfur, organic sulfur, and elemental analysis of CHN (carbon, hydrogen, nitrogen). The samples were also subjected to X-ray diffraction analysis to assess their mineral compositions. The leaching experiments were accomplished using a laboratory column constructed as a packed bed reactor with a sprinkling system in a closed circuit. After four weeks of leaching, the liquor was filtered and evaporated to an iron concentration of about 12 percent w/w, which is typical of the ferric sulfate coagulants commercialized in Brazil. IntroductionCoagulants used for the treatment of water and wastewater are predominantly inorganic salts of ferric iron and aluminum. Aluminum salts, including aluminum sulfate and aluminum chloride, and prehydrolyzed metal-ion reagents, such as polyaluminum sulfate (PAS) and polyaluminum chloride (PAC), are the coagulants most widely used for water treatment (Bratby, 1980; Tchobanoglous et al., 2003; Buzin et al., 2014).However, the presence of residual amounts of aluminum in drinking water has been controversially implicated in neurological diseases (Association of California Water Agencies, 2000; Becaria et al., 2006; Campbell, Hamai and Bondy, 2001; Rondeau et al., 2000; Walton, 2006). A possible alternative is to use iron-based coagulants, such as ferric chloride, ferric sulfate or polyferric sulfate, instead of the aluminum salts (Jiang, Graham and Harward, 1996; Jiang and Graham, 1998). Iron-based coagulants are commonly produced by the acid dissolution of iron scraps or iron ore (Tchobanoglous et al., 2003).Recent studies have shown that it is possible to produce ferric sulfate coagulants from the pyrite present in coal tailings through a biohydrometallurgical process (Colling et al., 2011). The main advantage of this process is that it does not require acid addition, which can be favorable in terms of production costs. Acidophilic bacteria, such as Acidithiobacillus ferrooxidans, can increase the rate of pyrite oxidation and dissolution by several times (Kontopoulos, 1998; Brett and Jillian, 2003; Johnson and Hallberg 2003). They can be highly significant in the bioprocessing of coal tailings for the production of ferric coagulants, as their action favors the acidification of the medium and iron leach (Colling et al., 2011)"

Jan 1, 2016

By Pierre Mousset-Jones, Felipe Calizaya, Malcolm J. McPherson

The objective of this study is to provide potential users of booster fans in coal mines with the necessary information on monitoring and control of fans and environmental factors. The guide-lines listed in this paper were formulated based on the current practice of mine monitoring, the U.S. Code of Federal Regulations on environmental monitoring, and the United Kingdom's National Coal Board recommendations on the use of booster fans. The principles involved in the design of booster fans as well as the provisions needed to guarantee a safe operation of these units, are illustrated by means of an example problem. The example includes a summary of costs for two ventilation systems: a conventional surface fan system and a fully automated booster fan alternative. A comparison of these costs showed that significant gains may be attained by selecting a combined surface-booster fan strategy over a conventional surface fan alternative.

Jan 1, 1989

By C. E. Jordan

Direct digestion of phosphate ores by the acid-alcohol method offers improved leaching selectivity for the exclusion of iron and aluminum in the product acid. The leaching kinetics of this process will have a major role in the eventual application of this technology. The Bureau of Mines investigated apatite dissolution to determine the reaction rate and mechanisms of the leaching kinetics. The dissolution kinetics were monitored on various sized fractions of pure apatite. The "shrinking-core" kinetics model was applied to the data to determine the rate controlling mechanisms. For each size fraction, the initial reaction rate was controlled by the dissolution reaction. After an hour the dissolution rate slowed indicating a diffusion controlled reaction caused by the formation of calcium sulfate hemi-hydrate coating on each particle. For complete dissolution of the apatite, the phosphate rock should be ground to near 10 µ m size.

Jan 1, 1993

By R. A. Burns

Kaolin clay has a broad range of applications with the paper market representing the largest end-use. Calcined kaolin finds application in paper, paint and plastics primarily for its high brightness and light scattering ability. It is well known as an extender for TiO2. Meta-kaolin possesses a unique set of physical and chemical characteristics finding use in both traditional kaolin/calcined kaolin markets as well as other unique applications. This paper discusses the intricacies of manufacture and the key physical and chemical properties of meta-kaolin. Specific applications and the relationship of the physical/chemical properties to end-use performance are discussed.

Jan 1, 2002

By Yuanyuan Wang, XUEWEN WANG, Jinzhi Wei, Ligang Wen, Muxin Jia, Zhengyao Li

The abstract discusses the use of disodium carboxymethyl trithiocarbonate (D8) as an effective depressant in the flotation separation of stibnite and pyrite. The study investigates the mechanism behind D8's selective inhibition of pyrite, utilizing techniques like micro-flotation experiments, contact angle measurements, infrared spectroscopy, adsorption capacity analysis, and zeta potential measurements. The findings reveal that D8 physically adsorbs onto both pyrite and stibnite, but its adsorption capacity on pyrite is significantly higher. This adsorption enhances the hydrophilicity of the pyrite surface, hindering the adsorption of the collector and effectively depressing pyrite flotation, while having minimal impact on stibnite floatability.

Mar 14, 2022

By Richard F. Roethe

Surface coal mining productivity in the U.S. and Illinois has shown a general declining trend since 1969. The U.S. Department of Energy conducted an analysis in 1980 of the causes of declining productivity in different states. This paper presents a detailed analysis of changes in overall productivity and productivity in different functions such as overburden preparation, overburden stripping, reclamation, coal handling, etc. during the period 1970-1982. Statistical analysys techniques including multiple regression were utilized in the study.

Jan 1, 1983

By James K. Kindig

Solvent extraction as a method of purifying and concentrating metal values from solution has become a standard hydrometallurgical operation for recovery of both uranium and vanadium, and within the past two years it has been put into operation in a commercial plant for recovery of copper from leach solutions. In this first full scale solvent extraction plant for recovery of copper operated by Ranchers Exploration and Development Corporation near Miami, Arizona, a kerosene solution of an organic compound, LIX-64® is used to selectively extract the copper from the dilute acidic copper sulfate leach liquor obtained from heap leach operations. The copper is back extracted from the solvent into a stripping solution which is fed to an electrolysis circuit producing cathode copper for sale.

Jan 1, 1970

By Gary R. Krieger

Baseline Risk Assessment: - Data Collection and Evaluation - Exposure Assessment - Toxicity Assessment - Risk Characterization Lead - Problems and Pitfalls: - Sources - Pathways - Receptors - Toxic Endpoints - Modeling Options - Health Based Clean-Up Options

Jan 1, 1990

By L. M. Gochioco

The U.S. coal industry is under-going dramatic changes to meet the challenges of the keenly competitive fuels market. The application of innovative technologies is needed to improve safety and to increase productivity in order to make coal more competitive as a fuel. As more coal companies shift into capital intensive longwall mining, there is a clear need to invest more in exploration before mine plans are made. Coal seam anomalies may create adverse mining conditions. The early detection of these anomalies could make the longwall mining safer and more productive through improved planning. A standard exploratory drilling program can provide only limited geologic information. The seismic reflection technique can be used to detect coal seam anomalies and is effective in reconnaissance surveying. Recent advances in the quality of coal seismic data have increased the success rate of seismic surveying. Therefore, surface seismic surveys, coupled with selective drilling, will come to play an integral role in coal exploration in the 1990s.

Jan 1, 1990

By J. C. Watts

Ball mill grinding circuit control has received increasing emphasis in the past few years due to such factors as declining ore grades, increasing production costs, and advances in analytical devices and minicomputer technology. Since ball mill circuits have been a traditional bottleneck in mineral processing plant throughput, control systems often improve through- put without requiring additional processing equipment. In addition, much of the variability of the grinding product size and consistency is often removed, allowing better process operation downstream. Among the problems which arise in designing and implementing a process control strategy for ball mill circuits are circuit constraints imposed by processing equipment and local management, proper instrument selection, installation and maintenance, and use of calculated or inferred variables for process measurements. This paper discusses these problems and attempts to identify valid approaches to their solution.

Jan 1, 1979

By D. A. Knight

The property is located in the Porgera Valley 600 Km North West of Port Moresby. The remote location is 2500 m above sea level. The mine area has 3,600 mm of annual rainfall and a temperate climate with temperatures ranging from 10" C to 22° C throughout the year. Alluvial gold was reported in the Porgera area in 1938 and has been an important source of revenue for the area for many years. Intermittent exploration was carried out until the 1960's when Placer (PNG) Pty. Ltd. with Mt. Isa Mines commenced an extensive exploration program. The property was brought to production in 1990 by the Porgera Joint Venture group consisting of Mount Isa Mines Ltd, Rennison Goldfield Consolidated Ltd. and Placer Dome Inc, each with a 30% ownership and the Government of Papua New Guinea with a 10% share. Placer Dome Inc. is the manager of the property with construction under the direction of the Placer Dome Technical Services group.

Jan 1, 1992

By J. Herbst, H. W. Kropholler, L. A. Cramer, E. T. Woodburn, J. C. A. Greene, G. Poling

A generalized mathematical structure is proposed whereby internal species mass flows within a flotation network are defined uniquely by a matrix of enhancement factors. An element of the enhancement factor matrix is defined as the ratio of the mass flow of that species leaving a given cell in the concentrate to the species mass flow leaving the same cell in the tailings. To predict the enhancement factors, knowledge of flotation kinetics effects is required. Recently experimental data has become available relating to the performance of industrial flotation circuits which indicate that the discrete or discrete-distributed kinetic schemes are capable of reasonably effective simulations. These simulations show the importance of including froth effects. The prediction of performance of networks from small-scale batch tests on flotation streams shows that the model for the froth phase used in the simulations does not scale-up well and that aeration effects are also difficult to predict. The network analysis should be useful in differential flotation of complex ores and it is disappointing in this context that little information on the kinetics of activation and depression is available.

Jan 1, 1976

By K. Pietruszka

The article presents the concept of the application of the Finite Element Method (FEM) and ABAQUS software in the global monitoring of changes in the rock mass and on the surface of the area, as a result of backfilling the workings. Waste materials applied for stabilizing old mining workings can have a strong influence on the rock mass and surface. According to the regulations, this process should be carefully monitored, especially in terms of the safety of surface structures and rock mass stability. The article presents the concept of an analytic and graphic presentation of the results of the measurements of old workings, applying the Finite Element Method and ABAQUS software in model studies. The main purpose of such interpretation of the geodetic observations results is the application of methods providing wide possibilities to present the geometry of workings, their changes and the influence of the rock mass and surface.

Jan 1, 2008

By M. C. Williams

The solution of the dynamic population balance model (PBM) of a closed grinding network consisting of a mill, sump, and cyclone is problematic. The fact that the dynamic PBM model equation solution to the Inverse Problem for grinding systems is degenerate or underspecified is demonstrated. Two numerical solution approaches to the Inverse Problem are used. These are: 1) providing additional constraints on breakage selection functions or 2) performing the Arbiter-Bhrany (or other) normalization of the selection functions. Actual experimental anthracite batch grinding data is used to demonstrate the non-unique functionality of the batch dynamic mill selection and breakage functions for a real physical system. The Levenberg-Marquardt algorithm for systems of constrained non-linear equations is used to solve the batch dynamic PBM grinding equations to obtain the grinding selection and breakage rate functions. Different solutions to the same PBM transport equations are provided. The mill, sump and hydrocyclone were modeled as a CSTR operating at various retention times. Batch dynamic PBM data was used to provide the mill kinetic and breakage selection function data. Two different solutions were obtained depending on the numerical solution approach. The severity of the non-uniqueness problem for dynamic grinding is demonstrated. Each solution approach to a dynamic PBM with transport, while giving the same prediction for a single batch grinding time, gives different solutions or predictions for mill composition for other grinding times. This fact makes dynamic nodal analysis and control problematic. The fact that the constraint solution approach gives a solution may suggest that normalization for closed networks is not necessary. Differences in solutions to the PBM cannot be excused away by inaccuracies in the data used to model the grinding phenomenon.

Jan 1, 1995