Search Documents

By Sadough vanini Ali

The silicon anisotropic wet chemical etching technique is widely employed for fabricating various microelectromechanical system (MEMS) structures for advantages such as simple etching equipment and its capability to fabricate special microstructures. In this paper, we consider a complete theoretical derivation of the analytical solution based on geometrical and kinetic aspects of step flow on any surface and with a mathematical method we derive new equation for calculating the microscopic etch rates of surface atoms for a new range of concentrations and temperatures. Furthermore, a novel equation is presented for the calculation of the microscopic activation energies for some typical surface atoms and a new comparison of activation energies between some atoms is made that divides atoms into three categories. The results demonstrate agreement with the experimental results.

Oct 1, 2011

By J. Larose, E. Irissou

The aerospace business has always been driven by innovation. A significant portion of the overall business technology development strategies is still based today on improved materials and coatings. In this highly regulatory business environment, large amounts of funding are required to increase the maturity level of novel technologies, but the evolution process still remains a delicate endeavor. The technical risks involved during technology development obviously need to be managed and mitigated throughout the development cycle, but other hurdles almost inevitably get encountered, such as budget limitations, transition from lab scale to production scale, loss of focus, intellectual property negotiations and supply chain integrity. This presentation will cover some of the issues raised when a great idea is slowly morphed into an aerospace production part.

Jan 1, 2010

By M. L. F. Gameiro

The aim of this study was to check the feasibility of non-dispersive solvent extraction to recover copper from ammoniacal solutions using hollow fibres as contactors. Data of mass transfer using the B3-diketone LIX 54 as extractant was obtained. The influence of tube and shell hydrodynamics on the extraction rate of copper was studied. The overall mass transfer coefficient of copper was calculated from the experimental data by performing steady state material balance. Simultaneous extraction and stripping experiments were carried out using different volume ratios of feed phase to stripping phase. The results obtained showed that practically all the copper content was removed from the ammoniacal feed solutions. The recovery of copper reached nearly 100% in several extraction-stripping experiments.

Jan 1, 2007

By T. Watanabe, M. Nakagawa, K. Kimapong

Lap joint of A5083 aluminum alloy and SS400 steel was produced by Friction Stir Welding (FSW) Process. The effect of welding parameters such as rotational speed, traverse speed and tool dimensions on the mechanical properties and the interface microstructures of the joints were investigated. FSW process could successfully produce the lap joint between A5083 aluminum alloy and SS400 steel. The variations of rotational speed, traverse speed and pin depth of a rotating tool gave rise to various characteristic interfaces of the lap joint and had conspicous influences on the joint properties. The increase in hard and brittle intermetallic phase and defects formed at the interface of the joint decreased the mechanical properties such as the shear load of the joint.

Jan 1, 2004

By A. Chaisantikulwat

Most solid-oxide fuel cell (SOFC) modeling emphasizes steady state cell operation. However, understanding the dynamic behavior is essential to predict the performance and limitations of SOFC power systems. In this work, we demonstrate a dynamic model of a SOFC, and we simulate a feedback control scheme that can maintain output voltage despite load changes. Dynamic response is determined as the solution of coupled partial differential equations derived from conservation laws for energy, mass and electric charge. From such a model, the step responses to system input variables can be determined. Low order dynamic models that are sufficient for feedback control design can be derived from the step responses. The development of the partial differential equation model is outlined, and the limitations of the control system are discussed.

Jan 1, 2005

By I. Colquhoun

Current practice tends towards "integrity as an afterthought". That is, integrity is treated as an isolated aspect of operations and maintenance. In fact, this works quite well. But it would work so much better and with less uncertainty if integrity management measures were introduced at the design phase and addressed the entire life-cycle of the pipeline asset. The talk will address the measures and metrics that can be implemented on a new pipeline during design to optimize integrity and deliver a comprehensive operating manual and integrity management program for the pipeline system. This deliverable should describe the risks to be assessed and monitored, and the actions to be taken to control these risk adequately. Properly executed, integrity by design will provide a good working estimate of the life-cycle integrity management costs and maximize system reliability.

Jan 1, 2005

By B. Farabi Khoshmehr

In the present study the effect of Silicate Sodium oxidation agent concentration and Plasma Electrolytic Oxidation (PEO) treatment time were investigated on properties of oxide layer on Aluminum alloy. The phase composition and surface morphology of PEO films were evaluated through x-ray diffraction (XRD) and scanning electron microscopy (SEM). Pin on Plate abrasive machine were used to investigate of were resistance of coating. The results showed that oxide layer which formed on Aluminum surface consist of high temperature a- Al?O? and ?- Al?O? phases. The diffraction peak intensity and percentage of these phases were increased by increasing silicate sodium concentration. Microscopic studies revealed a porous surface for PEO coating. This was affected by silicate sodium concentration and oxidation time. The wear test results showed that the weight loss of PEO coating was reduced due to improvement of their wear resistance.

Oct 1, 2011

By A. Morales

Flue dusts from a copper smelting furnace (continuous furnace), have been extensively characterized. The main phases detected have been cuprospinel, anhydrous copper sulfate (chalcocyanite), lead sulfate (anglesite) and arsenic oxides (claudetite and arsenolite). As minor phases, zinc sulfate (zincosite) and several copper or copper/iron sulfides were detected (digenite, anilite, bornite, cubanite), and also a copper oxide (tenorite). The suspension of this material in water leads to the partial dissolution of copper and zinc (chalcocyanite and zincosite) and arsenic oxides. The hydrocyclone classification of the residue makes it possible to obtain two fractions: a copper-rich coarse fraction and an arsenic-rich fine fraction. The coarse fraction can be recycled to the smelting furnace and the fine fraction can be mixed with wastewater sludge from a paper factory, to make both residues inert before disposing them to landfill.

Jan 1, 2007

By M. Reza Bateni, M. Zandrahimi, J. A. Szpunar

Titanium aluminides and nickel aluminides offer the potentials, as coating materials, for high temperature and aerospace applications. In this research, attempt has been made to develop Al-Ti and Ni-Al intermetallic compound coatings on the surface of Inconel 738. The coatings applied through pack cementation and simultaneous diffusion annealing processes. Scanning-electron microscopy (SEM), energy-dispersive X-ray spectrometry (EDAX) and grazing angle X-ray diffraction were used for evaluating of coating structure. It was demonstrated that the pack cementation technique could be used to develop TiAl3 and AlNi intermetallic compounds coating on Inconel 738 substrate. When pack cementation technique is based on a halide-activated pack with aluminum and titanium powders, the coating consists of TiAl3 intermetallic compound phase. Whereas, by pack aluminization of Inconel 738, the coating consists of AlNi intermetallic compound phase.

Jan 1, 2004

By J. Schmidt

Cold drawing of copper wire rod is usually combined with an in-line annealing process to adjust the ductile microstructure of the wire again. One important key factor for successful annealing is the quality of the copper itself. Rod producers can check the recrystallization behaviour of the rod by different methods: chemical analysis, Spiral Elongation Test (SEN) as well as the Rapid Elongation Test (AR) are some examples of common testing methods. The comparison of the results of these methods does not always show sufficient correlations. The paper introduces firstly the SEN and AR-Tests and their different approaches to the mentioned task. The second step is to compare some results of the SEN-Test with the results of the AR-Test and identify causes of deviations. Thirdly, the effect of pre-annealing is discussed, which is especially common for wire rod with diameters of more than 8 mm.

Jan 1, 2007

By M. S. Moats

As smelter feeds become more complex, the impurities that ultimately report to electrorefineries are changing. Many of these impurities collect in the electrolyte and must be controlled. As commercial copper electrorefineries look to expand their capacities by increasing their operating current density, the interaction between electrolyte composition and anode passivation can cause operational difficulties. To improve the industry's understanding of the passivation phenomena, the role of electrolyte composition was evaluated using commercial electrorefining anode samples. The electrolyte composition variables examined were copper, acid, nickel, arsenic, chloride, thiourea and glue. Finally, the role of non-commercially utilized additives, such as bromide and polyethylene glycol were studied. From this investigation, electrolyte parameters that inhibit copper dissolution through copper sulfate precipitation, copper oxide stabilization and/or absorbed species lead to accelerated passivation. Species that prevent passivation have the ability to complex cuprous ions. Possible mechanisms for the role of each.

Jan 1, 2007

By M. Huang

Electrodeless conductivity was employed to investigate the feasibility of continuous on-line monitoring of the free acidity of sulphate and/or chloride solutions of Cu and other base metals from various hydrometallurgical processes. These solutions were measured with both commercial and experimental electrodeless conductivity sensors from 15 to 250°C. It was confirmed that hydrogen ion has the greatest impact on conductivity by carrying the bulk of the current because it is the most mobile ion. In combination with a solution speciation analysis the conductivity sensor can be calibrated to account for the contribution of Cu electrolytes as well other dissolved salts allowing fast and accurate on-line measurement of free acid. The sensor was tested at both lab and pilot scale with very good performance. The average difference between the measured and the titrated acid concentration was less than 5%, which is excellent for industrial applications.

Jan 1, 2007

By Jerry Danni

In order to remain viable today, corporations must view the environment as a strategic issue, and integrate environmental management throughout the organization. Corporate programs that used to be based primarily on regulatory compliance now must emphasize strategic environmental management systems, and must integrate these environmental systems with basic business functions. The mining industry today is global, and must have an organizational structure that can embrace different cultures, physical settings, and regulatory regimes. Sound environmental management practices are not different from good management principles. An effective environmental management system should be a complementary system to an organization?s overall management framework, integrated and aligned with the existing management structure. Integrating environmental management into core business functions is just good business. An effective environmental management system is a critical component of a company?s commitment to environmental, social and economic accountability. This paper presents the elements of the Kinross Gold Corporation strategic environmental management system and discusses the integration of the environmental management system into the core business functions throughout the Company

May 1, 2003

By G. P. Cooper

A comprehensive computational heap leach model was used to evaluate options for operating a chalcocite-ore heap leach process. The stockpile leach model is based on the computational fluid dynamic software framework PHYSICA+ and incorporates various physical and chemical phenomena to simulate fluid transport, mineral reaction kinetics, bacterial effects, and heat, energy and acid balances for the overall leach process. The leach model is calibrated against small-scale column leach tests, and simulation results are validated against closely controlled column pilot-scale tests. For a given set of ore conditions, the effects of raffinate irrigation rate are examined. Several options for pulse leaching were investigated, and the effects on copper recovery and pregnant leach solution (PLS) grade are described. Model simulations indicated that pulse leaching could be used to control copper grade of the PLS. Finally, an analysis of inventory issues is presented for various lift heights including multi-lift simulations to examine potential operating options. U sing irrigation rate, raffinate copper grade, and lift height as variables in a factorial design of experiments, the simulations showed that raffinate copper grade is the main factor that affects the soluble copper inventory grade.

Jan 1, 2007

By Ian Thomson

OBJECTIVES OF EXPLORATION ? Prove/Disprove presence of potentially economic mineralization ? Keep on budget ? Minimize negative environmental impacts ? Gain a ?Social License to Operate? (SLO) WHAT IS A ?SLO? ? Granted by the local community ? Intangible, informal, non-permanent ? Has to be earned and then maintained ? Defined as ? Ongoing Approval (BSR and AccountAbility) ? Ongoing Approval, broad social Acceptance (Joyce and Thomson) ? Ongoing Acceptance (Nelson, and many others) ?Expression of the quality of a ?relationship?

May 1, 2010

By Martin Irving

Adding Value to Canadian Diamonds - A Changing Diamond Industry - Diamond Mining - Diamond Manufacturing - Diamond Jewellery Markets - NWT Diamonds Changing Diamond Industry - De Beers ? privatization - Oppenheimers (45%), Anglo-American (45%), Botswana (10%) ? going retail - LVMH joint venture - New Players ? jurisdictions - Canada ? companies - BHP-Billiton - Aber Diamonds

May 1, 2002

By Sadough vanini Ali

Hot deformation behavior of functionally graded steel (FGS) was investigated via conducting hot compression tests at different temperatures and strain rates. Functionally graded steels consist of ferrite, austenite, bainite and martensite layers that are made by diffusion of alloy elements during the melting process. The zenerhollomon parameter has been used to describe the flow stress variations as a function of temperatures and strain rates. The parameter values for all the layers via using the boundary conditions was determined based on composite graded behaviors. Furthermore by applying the rule of phase mixtures, the whole strain rate applied on composite would be the sum of layers strain rates considering the layers volume fraction, while the layers have the same stress. Consequently the composite flow stress for each strain rate and temperature was determined.

Oct 1, 2011