Search Documents

By J Garritsen, P F. Wells, M Xu

IncoÆs Clarabelle mill currently processes ores from eight mines in the Sudbury basin area in Ontario, Canada. The ore from the Garson mine contains a much higher concentration of arsenic than the other ores. Adding this ore into the feed to the mill has resulted in an increase in arsenic content of the Cu-Ni bulk concentrate to a level that significantly affects the smelter operation, and more importantly the efficiency of Cu-Ni separation in the Matte separation plant. The arsenic occurs mainly as gersdorffite (NiAsS), with a small amount being in the form of cobaltite (CoAsS). Extensive laboratory tests on depressing arsenic in Garson ore flotation have been conducted and two reagent suites have been identified as effective arsenic depressants. One is the so called MAA depressant which is a mixture of magnesium chloride, ammonium chloride, and ammonium hydroxide. This reagent combination was reported to depress other arsenide minerals such as arsenopyrite (FeAsS) and enargite (Cu3AsS4). However, in this study for the first time it has been shown to have a depressing effect on gersdorffite. The other reagent suite, a mixture of triethylenetetramine (TETA) and sodium sulfite, that has been reported as an effective pyrrhotite (Fe1-xS) depressant in pentlandite ((NiFe)9S8) flotation, has not been reported as gersdorffite depressant before. The effectiveness of both reagent suites is more pronounced when the arsenic minerals are oxidised through pulp aeration or the addition of hydrogen peroxide. With a flow sheet consisting of a magnetic separation, rougher- scavenger flotation, followed by regrinding and cleaning of combined magnetic and scavenger concentrate, the arsenic recovery to the final Cu-Ni bulk concentrate was reduced from 73 per cent in baseline test to less than 30 per cent with either reagent suite at no decrease in nickel recovery. The TETA/sulfite reagent combination has the advantage over the MAA suite in that pyrrhotite is also depressed, rather than being activated, and the copper and nickel concentrate grades are therefore increased.

Jan 1, 2005

By A Whaanga, W Vigor-Brown

IGO Ltd’s (IGO’s) Nova-Bollinger Deposit (Nova-Bollinger) is a magmatic nickel-copper-cobalt (NiCu-Co) sulfide deposit found 160 km east-north-east of the town of Norseman in Western Australia (WA). The deposit is hosted by the Mesoproterozoic rocks of the Fraser Zone, which is part of the Albany Fraser Orogen (AFO). Since mining commenced in 2016, IGO’s Nova Operation (Nova) has mined and processed to 31 December 2020, 5.63 Mt of ore grading 2.04 per cent Ni, 0.86 per cent Cu and 0.07 per cent Co. Nova’s mine geology team (MGT) has used commercially available implicit modelling (IM) and general-purpose resource modelling (RM) industry software systems, to prepare the 31 December 2020 (CY20) update of Nova-Bollinger’s JORC Code reportable Mineral Resource estimate (MRE). This CY20 MRE update was predominantly based on ~386 km of diamond core drilling, with the drill holes having a nominal grid spacing of 12.5 by 12.5 m throughout the mineralised zones of the deposit. Using IM tools, Nova’s MGT interpreted and modelled 22 separate domains from the drill hole logging, assaying results, and the MGT’s underground mapping. These IM closed volumes were then used to control the estimation of MRE variables into conventional industry digital block models using RM and other ancillary software systems. During 2021, a commercial machine learning (ML) software was trialled by Nova’s MGT for preparing block models of Nova-Bollinger’s MRE domains. The motivation for the trial was that the ML process could expedite modelling through the direct creation of a domain coded block model from the drill hole logging. Compared to the industry standard approaches of wireframing or IM, where the modeller usually makes many subjective choices to produce the domain model, ML offers a more objective ‘hands-off’ process for determining the connectivity of domains defined in drill holes. Additionally, the ML process provides a quantitative confidence metric associated with its output that may have utility in mine production and resource classification. In this paper, the results of the Nova-Bollinger ML modelling trial are compared to the MGT’s current workflow for MRE work. The MGT’s conclusions as to the advantages and disadvantages of the IM and ML methods for preparation of MRE domains are discussed. The ML software was also tested as a method of rapidly interpreting geology outside the principal zones of MRE interest. These testing results are also presented in this paper.

Mar 22, 2022

By Motyka J, Adamczyk AF, Witczak S

A case study of migration of a paper factory fluid wastes, on the distance of 5 km from an underground disposal site to an ore mine is presented. The ore mine in question, situated in SW Poland is pumping 3.5 m3/s (ca 300 000 m3/day) of groundwater, producing a cone of depression about 150 m deep and several kilometers wide. The migration of wastes (pollutant) occurs within the carbonate karstic aquifer of Triassic age. The aquifer is about 100m thick and is characterized by the coefficient of hydraulic conductivity equal to 8 m/day on the average. The results of systematic measurements carried out for 13 years enabled to estimate the mean breakthrough curve of the pollutant. On this basis and taking into account the coefficient of hydraulic conductivity as well as the mean hydraulic gradient between the disposal site and the ore mine, the migration parameters of the polluting material, i.e. the real flow velocity, the effective porosity and the longitudinal disper- sivity have been calculated. As the measurements considered a long migration distance of the pollutant, the obtained hydrodynamic dispersion constant (dispersivity), in the authors opinion, is reliable enough to be applied for regional groundwater calculations, regardless of the "scale effect".

Jan 1, 1988

By Budd B

this paper outlines the operating advantages gained through applying a mine processor (MISA), to various underground and surface operations. On the surface, MISA monitors and/or controls ventilation fans, crushers, fill plant and stockpiles. Underground, MISA monitors and/or controls dewatering pumps, fill reticulation and high voltage electrical distribution on most levels.

Jan 1, 1988

By L Torckler, J Hobbins

Favona is a blind low-sulfidation epithermal vein deposit in the Waihi Vein System approximately two kilometres east of the world class Martha Hill deposit that has produced nearly 6.8 M oz Au to date. The Favona epithermal system has surface expression in variously altered and mineralised hydrothermal eruption breccias forming a series of low hills that are windows through post mineral dacites and ignimbrites. The tip line of the Favona vein is about 50 û 100 m below surface with a steeply east dipping principal vein structure carrying numerous hanging wall splays in the upper flatter section and thickening down dip where the vein steepens. Host rocks comprise feldspar phyric andesite flows with minor pyroclastics. Although Favona has a strike length in excess of 1000 m and vein widths up to 25 m over a vertical range in excess of 400 m it was only recently discovered after nearly thirty years of exploration by various companies involved in the Martha Hill joint venture that operates the Martha Mine. Since discovery in 2001 a feasibility study based on 27.5 km of diamond drilling in 83 holes has been completed reporting a reserve of 1 Mt @ 10 g/t Au against a resource of 1.8 Mt @ 10.3 g/t Au. Exploration is continuing with a further 20.5km of diamond drilling completed to date on nearby prospects.

Jan 1, 2004

The detailed work done by Stillwell and Edwards on the occurrence of cobaltite and safilorite-Iollingite at the South Mine, followed by its presentation as a paper to the Institute, calls for, a few notes on its occurrence elsewhere in the Broken Hill field. No massive cobaltite similar to that in the South Mine veinlet is known except from the Consols Mine (as mentioned in the paper). Fine grained cobaltite has, however, been found in low-grade ore from the North Mine. Microscopic grains occur in a mineralized green feldspar pegmatite. The feldspar has been replaced in part by graphite, and the cobaltite occurs in association with the graphite. In its hardness, pinkish-white colour, and resistance to the standard etchingqeagents it is similar to the South Mine cobaltite; it is etched by acid permanganate solution. An interesting feature of this occurrence is the way in- which some of the minerals (notably galena) have forced apart the graphite lamellae in crystallizing, forming lenses enclosed by the curved cleavage surlaces 0;[ the graphite.StillwelI and Edwards cite a note by G. Smitht for the statement that "cobaltite has been recorded from the Australian Broken Hill Consols Lode in the vicinity of the rich silver deposits, though not in contact with them."Smith, however, is here referring to the oxidized zone. Elsewhere in the same article he states "... a deposit of cobaltite in a very much altered condition was found. This was impregnated with silver, and assayed as high as 3,000 ounces," Of the cobaltite in the unoxidized zone, Smith simply states that it became rarer with depth.Cobaltite has also been recognized by Mr. H. F. Whitworth, M.SC., Curator of the Mining Museum, Sydney, in specimens from Burt's Copper Mine eight miles south of Broken Hill.

Jan 1, 1944

By Roden S

This paper illustrates that sampling problems and difficulties are as common in an R&D environment as they are in an operating plant. Researchers need to be aware of the potential influence of poor sampling practices and when feasible determine the sampling and analytical precision at the start of any experimentation. Specific problems that have been encountered are discussed and the procedures implemented to overcome these difficulties are described. Examples from projects include the cyanidation of a Au/Ag ore, column leaching of refractory gold and oxide ores, the bioremediation of contaminated sites and the flotation of ore containing native copper.

Jan 1, 1976

By Mould GR

Gas drainage has been practiced for many years mainly for safety reasons in various countries in Europe, in the U.S.A., the U.K. and Japan. Legislation has been developed to control the production, transport- ation and utilisation of methane and associated gases. Gas drainage is now being carried out at some Australian Collieries, but as this is a new venture little specific legislation is available. This paper briefly describes the drainage methods and legislation applied overseas, gives a brief history of gas drainage in N.S.W. and indicates the deficiencies of the present legislation. It outlines the approach to new legislation which will deal comprehensively with gas drainage operations and utilisation in New South Wales.

Jan 1, 1982

By P Hatherly, H Gurgenci

With the depletion of the mineral reserves that can be mined by surface mining, demand for highly productive and safe underground mines will increase. Underground drill and blast techniques continue to be refined but true æmass productionÆ is difficult to achieve. As is evidenced by the longwall mining of coal, alternative mining methods based on mechanised mining can meet the expectations but the issues of how to effectively cut strong rocks, how to define the orebody and how the mechanised miners can be automated and maintained all need to be addressed. CMTE is working in all of these areas. We believe that the oscillating disc cutter may provide the long sought-after breakthrough in mechanised rock cutting. Disc cutters are one of the most robust designs of cutting tool and the cutters attack the rock in a manner which effects direct tensile breakage. The internal cutter drive and the inertial damping mean that the already low cutter forces are not all transmitted back to the machine, making it possible to design lightweight, flexible mining systems. For orebody delineation drill monitoring, drillhole logging and geophysical imaging are key procedures being developed at CMTE. To automate mining machines, work is progressing well in the development of systems for autonomous vehicle navigation and mining robotics. A strategic contribution to maintenance issues is being made through the development of procedures for automatic analysis of used oils, monitoring the strength of mechanical structures, and operating point optimisation.

Jan 1, 1998

By A G. L Pratt

Operational readiness is a commonly used term in mining and many other industry settings. However, translating this term into a coherent scope of work that is practical and meaningful is a challenge faced by many mining projects. This inhibits the allocation of resources to the work and its completion. The problem is with understanding how the terminology applies to establishing a mining operation. Resolving this problem requires clarity around what operational readiness means for a mining project’s transition to operations and who owns the tasks of completing operational readiness. The motivation for resolution of this problem is in appreciating the consequences arising from any lack of clarity in definition of this task, the timing of the work, and ownership for its completion. In broad terms, these consequences amount to an erosion of value at a critical time for both the new mine and the company and shareholders. This situation often arises where operational readiness is not adequately addressed in project’s study phases. As a result, neither time, resources nor money are adequately provided to complete the work required. In other cases, operational readiness is sometimes assimilated with the delivery of the project’s physical assets by the project’s construction team, rather than aligned with the establishment of the operating team to deliver the desired operational outputs. This paper argues that operational readiness starts in a project’s study phases and flows through into the start of operations. The definition of operational readiness is discussed as a task, and a model for its planning and completion is presented. This discussion includes assigning ownership for operational readiness planning and delivery to the General Manager of a new operation and the operations leadership team, who are central to the success of this work. After all, the reputations of this leadership team depend on the performance of the operation in its first few years. The author’s work over the last 20 years, leading operational readiness programs and the preparation of feasibility studies for mining projects, has provided the insights and evolution of ideas that are central to this paper. Operational readiness is fundamentally directed at ensuring a new mining operation gets away to a successful start and builds a solid foundation for the future of the mine/operation/province. It requires clarity of purpose, ownership and coordination by people in the operating team, and their preparation of the requisite process definition and establishment of the significant relationships required for operations. Without its successful completion, it is unlikely the new operation will meet and sustain its start-up targets. This paper discusses a practical approach to operational readiness for mining projects.

Mar 29, 2023

By M Flis

The Razorback Iron Ore Project is a high tonnage, low-grade magnetite deposit that defines a new iron ore district in South Australia. Known since the 1960s, the deposit has come into its own as the iron hungry world demands not only larger tonnages, but higher grade and cleaner magnetite concentrate ores that counterbalance the increasingly dirty haematite ores that are coming into production.Razorback is hosted by the Neoproterozoic Braemar Iron Formation, a tillitic unit that is part of the Adelaidean Geosyncline sedimentary sequence. At Razorback, this formation forms the southern limb of the Pualco Syncline, dipping at 42° to the north and outcropping along a prominent ridge. The formation consists of a series of alternating bedded tillitic and interbedded magnetite units that represent cycles of glacial advances and retreats. Seven cycles, resulting in seven stratigraphic members, are recognised. Members B, D, and G are the thickest, at 30 - 70 m each, and are the target of current investigations. While the bedded magnetite has the highest iron content, typically 35 per cent Fe, the tillitic unit, at typically 26 per cent Fe, has similar iron content in the ground mass but is diluted by the inclusion of iron-poor granite and metasedimentary dropstones. The mineralisation forms a simple dipping tabular body with only minor faulting, folding and intrusives. Grades, thickness, dip, and outcropping geometry remain very consistent over kilometres of strike, presenting an excellent mining proposition.Razorback differentiates itself from other Australian magnetite projects in a number of important ways. It is not a banded iron formation (BIF); it will have low crushing and grinding costs; and it is located in an infrastructure-rich area close to open-access, high capacity rail, to a selection of ports and to gas, electricity, labour and engineering services. Royal Resources has announced an Inferred resource of 277 Mt @ 25.9 per cent Fe. The company is targeting a resource of 500 - 1000 Mt to support a 10 Mt per year concentrate production. Davis Tube Recovery work shows that the ore is capable of producing a concentrate of over 68 per cent Fe with very low deleterious elements. Metallurgical testing confi rms the ore is soft, and with near-zero initial stripping ratio the project will have a low opex. With access to existing critical infrastructure, capex will also be low, ensuring Razorback will be a highly competitive iron producer in this emergent mining district.

Jul 11, 2011

By C McGuire

As mobile equipment electrification in underground mining continues to gain popularity, control ofheat and humidity in the workplace is becoming a key driver in sizing of ventilation and mine aircooling systems. For design and sizing of ventilation and cooling systems to be accurate, and for themine mobile equipment fleet to be sized appropriately to meet production goals, vehicle productivitymetrics, heat modelling, and energy balances for electrified fleets need to consider operation througha realistic duty cycle that is reflective of various tasks performed during a shift.The authors conducted a real-world comparison of two 8 cubic yard (14 metric tonne) class Load-Haul-Dump (LHD) machines – one diesel and one battery-electric vehicle (BEV) – performingidentical muck-haul-dump operations on consecutive days at an underground nickel/copper hardrock mine in Ontario, Canada.The battery-electric LHD averaged 8.9 per cent faster cycle time than the diesel vehicle (gross,without accounting for charging time), and was able to transport 25 per cent more material per cycledue to a larger bucket capacity. When including the charging time, average net cycle times wereequivalent for the two vehicles over the 200 cycles. The BEV carried more payload over the eighthour period due to the increased capacity per cycle.The testing identified an approximately five-fold reduction in heat output from the BEV in comparisonto the diesel LHD on a basis of heat output per tonne of rated bucket capacity. Heat output from thefast charger was found to be approximately 4 per cent of the charging rate, with negligibletemperature change observed in the main drift. External noise levels in the mine were found to be14 dB lower for the BEV during transit and 11 dB lower during bucket loading. Fuel/energy costs forBEV electricity input were approximately four times lower per operating hour than diesel fuel costbased on typical 2021 electrical and diesel unit rates for a grid-connected mine in Ontario, Canada.

Oct 12, 2022

By S J. Tear, L D. Queen

"An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation. The Frieda River Project is located in the north-west of Papua New Guinea. The target commodities for a bulk mining operation are copper and gold associated with a large felsic porphyry system. The project comprises a series of deposits, with the Horse-Ivaal-Trukai (HIT) being the largest. It also includes the adjacent smaller Koki and Ekwai deposits.Previous resource estimates for the HIT were made using 14 separate mineralised domains based on structure, copper grades, lithology and alteration. H&S Consultants (H&SC) has revisited the deposit and concluded that a simpler methodology could be used for resource estimation without using wireframes as hard domain boundaries. This conclusion is based on reviewing all the available geological data combined with geological and resource experience of porphyry deposits.It is generally acknowledged that porphyry deposits form by diffusion of mineralising fluids through the host lithologies, meaning that sharp boundaries are unlikely unless these fluids encounter specific physical or chemical boundaries. It is important to prepare a comprehensive geological model prior to attempting resource estimation as it forms the framework for the estimates; however, not all geological features may be relevant to the distribution of mineralisation and there can be a tendency to overcomplicate the estimation process by using too many domains. Unless a hard boundary can be identified consistently and unequivocally, it is generally better not to use a boundary in that location.H&SC completed unconstrained models with no top-cutting using both a simple flat search ellipse and a steep search ellipse to generate global resource estimates reported within a predetermined pit shell at a 0.2 per cent copper cut-off. Both outcomes are within 10 per cent for the tonnes, contained copper tonnes and gold ounces compared to the constrained resource estimate. The slight differences are most likely due to the different search strategies, but also indicate the robustness of the unconstrained modelling approach.CITATION:Queen, L D and Tear, S J, 2015. The Frieda kiss – keeping it simple , in Proceedings PACRIM 2015 Congress, pp 361–368 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Mar 18, 2015

By Q Shu, T Deng, B Yan, B Song, D Wang

In view of the lack of phase equilibria data of vanadium-bearing oxide system and the desirability of them for design or optimisation of vanadium extraction process, the phase equilibria relationships of V2O3-FeO-SiO2-CaO(15 mass per cent) system were determined experimentally and then an isothermal section phase diagram of this system was constructed. Totally, 81 samples of different composition were equilibrated at 1623 K for 48 hours in iron crucible under Ar atmosphere. The equilibrated samples were quenched quickly in cold water, and then the phase constituents of all the samples were identified by X-ray diffraction (XRD) combined with electron probe microanalysis (EPMA) measurements.

Aug 21, 2024

By J Maxlow, M J. Woods, M P. Sandy

The Newcrest Mining Limited Telfer operation comprises both open pit and underground operations producing gold and copper. The underground operation is made up of three production areas, the sublevel cave (SLC), M Reefs narrow vein open stoping and Western longhole open stoping areas. With stoping situated on the abutments of a mature and active sublevel cave, the interaction between mining areas is often complex. This is particularly evident in the M Reefs orebodies with high levels of extraction in all four reefs, and reliance on pillars to maintain local and global stability. A key concern was the potential for a cascading pillar failure to develop and rapidly progress through the M Reefs stoping area. The monitoring plan needed to capture any change in overall stability and identify if deformation was caused by pillar failure within the M Reefs and hanging wall closure, or shear on the reefs caused by SLC influence.

Nov 29, 2022

By Beattie T

For many years explosive sensitized explosives were assessed using the ballistic mortar. The standard test used lOg of explo- sive initiated with a detonator. Over the past 30 years many non- explosive sensitized explosives and blasting agents have been developed. Most of these new explosives and blasting agents cannot be tested in the ballistic mortar as they are not initiated by a detonator. It is also known that all explosives have a criti- cal diameter. When the cartridge diameter is less than the criti- cal diameter a stable detonation cannot be produced and the explosive fails to propagate. For many blasting agents the criti- cal diameters are greater than 50mm and such large diameters cannot be tested in the ballistic mortar. The underwater test allows explosives to be tested in diameters greater than the critical diameter and to be adequately initiated with suitable boosters. The effects of the explosive on the water are easy to measure and the test provides a safe, convenient and reproducible means of assessing explosive performance. The reaction products are allowed to expand to a low final pressure. The underwater test can therefore be used to give a measure of the total expansion work of explosives. The detonation of an explosive induces a shock wave in the surrounding water. The profile of the shock wave can be meas- ured 3-6m from the charge and the energy in the shock wave cal- culated. Measurements over a range of distances show that the shock wave is attenuated as it travels through the water and the attenuation is different for each explosive. This makes it difficult to estimate the energy dissipated in the water between the charge and a single gauge. The reaction products continue to expand and displace water. The bubble continues to expand until the kinetic energy of the water is zero. The gas pressure in the bubble is now lower than the hydrostatic pressure and the bubble radius is a maximum. The higher external hyrdostatic pressure causes the bubble to implode. The bubble energy is the work done displacing the maxi- mum bubble volume against the hydrostatic pressure and can befound from the bubble period. It is not always easy to find a large enough pond for the bubble to expand undisturbed by the water surface and the containing boundaries. This makes it difficult to determine the bubble energy accurately in shallow Ponds.

Jan 1, 1988

By Collier D

The topaz resource at Torrington in northern N.S.W is currently the subject of a joint research and development programme managed by Pacific Copper Ltd, This programme has culminated in a pilot topaz calcination plant, located at Parramatta, which, through its operation, will establish the commercial viability of developing this mineral as an industrial raw material for both the refractory and fluoride chemical industries.

Jan 1, 1989

Coeur d'Alene Mines is a precious metals producer which is dedi- cated to growth through it's exploration and acquisitions efforts. We foster and support these activities by providing our staff with long-term financial support, the encouragement to proceed with their projects and ideas, and a firm belief that we will be successful. Coeur's corporate headquarters are located in beautiful, historic Coeur d'Alene, Idaho. Our main mining operations are Rochester, locate near Lovelock, Nevada, Coeur Mine,located near Wallace, Idaho, and Thunder Mountain, located in central Idaho. Our Ken- sington Gold project is located about 45 miles north of Juneau in southeast Alaska. We have exploration offices located in Reno, Nevada, and Santiago, Chile. At this time, Coeurd'Alene Mines produces precious metals from mines located in the United States. Our Rochester open-pit opera- tion, which is 100 per cent owned and operated, is located in Nevada. Presently, this operation produces 5.5 to 6 million ounces of silver per year and 60-70,000 ounces of gold. We move 65,000 to 70,000 tons of rock per day of which about 23,000 tons is ore. The ore is crushed, stacked on permanent heaps and leached. The recovery is by Merrill-Crowe. Although the average grade is rela- tively low, 1.4 ounces per ton silver and 0.012 ounces per ton Au, the operation is very low cost. Our cost of production is less than $4.00 per silver equivalent ounce. Rochester is anunusual operation in that the crushed rock stacks without much compaction and the ores are easily leached. The final height on our heaps will be about 220', and overall recovery will be about 55 per cent of the silver and about 85 per cent of the gold. Reserves at Rochester are expanding and are now adequate for at least fifteen years of opera- Tion.

Jan 1, 1991

This presentation opens with a definition of technology and how it is implemented. The expenditure and progress on R&D in the mining industry is then investigated and found to be difficult to quantify. The needs and interests of that industry including contribution to this Congress are examined and it is concluded that short-term rather than long-term goals seem to be prevalent. The presentation concludes with the opinion that the answer to the question in the title is both affirmative and negative but overall there is a need for the mining industry to become more innovative.

Jan 1, 1990

By Z U Bajwah

During the Palaeoproterozoic, a large number of granitic intrusions were emplaced in the various parts of the Pine Creek Geosyncline (PCG). In the central region, the granitic magmatism is represented either by the coalesced mass, eg the Cullen Batholith, or individual plutons such as the Mount Bundey Granite which together with the Mount Goyder Syenite intrude the metasedimentary strata, causing wide spread contact aureoles. Some of these granitic intrusions are temporally and genetically related to gold (and less commonly base-metals) mineralisation present in the adjacent metasediments. These plutons are characterised by the presence of biotite and homblende which appear late in the paragenetic sequence. Electron microprobe analyses of biotite and homblende show that these minerals are poorly to moderately zoned. Biotites are characterised by a decrease in Fe/(Fe + Mg) ratios when plotted against AIVI. Similarly a modest decrease in Ti from centre to the margins of the biotite crystals has also been observed. Furthermore, an increase in Mg/(Mg + EFe) ratios from centre to the margins as well as in mafic to felsic rocks is also apparent. On the other hand, homblendes from the granitic bodies display less well marked trends and are poorly zoned. However, they show systematic increases in Mg/(Mg + EFe) ratios, and decreases in Fe, Al"' and Fe/(Fe + Mg) ratios, when plotted against Si. Magnetic susceptibility measurements on powdered samples of the plutons give results characterised by high values ranging from 0.8 x 10-4 to 2.0 x 10-3 emu/g which place the granites in magnetite- series field. This indicates that the oxidation state of the magma was high during crystallisation. The range of chemical compositions of the mafic phases indicates a rise in the oxidation state of the magma as it progressively became saturated in H20-volatiles and other metals, not partitioned into the earlier crystallised phases in the final stages of magma consolidation. These variations in chemical compositions also indicate that initially fOz was high and became progressively higher during fractional crystallisation of magmas; this subsequently led to the emanation of hydrothermal fluids responsible for the mineralisation in the adjacent metasediments.

Jan 1, 1994