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By Quinlan M. J, Ratcliffe J. S

Chemical kinetics is a dependent process which usually correlates the rate at which a reaction proceeds with the mechanism descriptive of the manner by which reactive particles interact. Given the latter, the object gen- erally is to find the reaction rate dependency in terms of an intensive property of the system - number of reactive particles present, and of the energetics of the system - usually temperature. Chemical kinetics depend on a dem- onstration that reaction considerations alone control the phenomenological process under study. For these rea- sons, chemical kinetics are usually involved in homogeneous gaseous systems. Even in liquid homogeneous sys- tems earliness or lateness of reactant mixing rather than chemical kinetics may be controlling. Considerations of transport phenomena are involved in heterogeneous systems and often control the observable rate:an additional problem in such systems is to apportion the rate due to mass transfer - usually a linear process - and that due to reaction which may be linear or non-linear. Experimentally, conditions are often chosen so that only one consideration controls but this becomes more difficult where solid phases are involved. Kinetic modelling involves considerations of chemical kinetics, transport phenomena, and factors attributable to the physical environment in which the process takes place. The latter two considerations may be quite different as between experiment and plant. The kinetic model may be a mathematical representation of a conceptual mech- anistic model of the reaction. Alternatively, it may be an empirical relationship resulting from, for example, some curve fitting procedure applied to experimental data. The latter approach may be necessary where the system is particularly complicated.

Jan 1, 1975

The winning and upgrading of mineral raw materials necessarily includes size reduction, which serves the liberation and production of marketable products from highly valuable and bulk materials. For crushing, the following factors can be duly accounted for depending on material type and the selection of the suitable machine: ò producing a particular size distribution, ò producing a particular grain shape, ò selective comminution, ò gentle comminution, and ò producing a size range required by a specific process and/or for a specific product.

Jan 1, 1993

The Abra mineralized body is regarded as a significant new style of mineralization for its environment. It is a blind polymetallic deposit, located in the Bangemall Basin of Western Australia. It was discovered by Geopeko in 1981 by diamond drilling a coincident magnetic gravity target, which revealed a large low grade epithermal Fe-Ba-Pb-Ag-Cu-(AuW) deposit, hosted by chemogenic and clastic sedimentary rocks, overlain by 200-500 m of clastic sedimentary rocks, of Middle Proterozoic age. The mineralization occurs as an upper stratabound phase, and a lower vein "stringer" style phase within a pervasive chlorite alteration envelope.

Jan 1, 1987

There are two mechanisms in the flo- tation process by which particles are transported from the pulp to the con- centrate: bubble-mineral aggregation and entrainment. It is the chemical processes which occur in the pulp which are critical to the success of flotation since they control the floatability of different min- erals and the selectivity which can be obtained. However, these chemical pro- cesses are so complex that metallurgists are still limited in their ability to predict the floatability of particles in industrial circuits by consideration of the minerals present and the chemical environment. The alternative approach to understand- ing flotation is to examine the behaviour of minerals in industrial flotation pro- cesses, to recognise similarities and differences, and to define the "laws" which appear to apply. Using this ap- proach it has been found that minerals float at a rate which is proportional to their concentration in the pulp, and that the rate of flotation of different min- erals is influenced by variables which' affect the pulp or the froth phase. The ultimate application of this approach is the use of models for circuit simulation purposes. It is this alternative approach which is the theme of this paper. One of the most important problems in understanding the technology of flotation has been in defining the characteristics of the particles being floated. Particles entering flotation vary widely in size and mineral composition, and different par- ticle types float at different rates. These rates do not change uniformly as operating variables change. It has been conventional practice to assess flotation performance in terms of the metal contents of total streams because no better method has been available, and this procedure has obscured important effects which occur in

Jan 1, 1984

The relative contents of Au in a series of groundwaters from water bores and exploration drillholes, located near Au mineralisation at Stawell, Ararat, Clunes and Ballarat in central Victoria, were found to be clear indicators of relative proximity to mineralisation in each region. In the same series, waters with anomalous concentrations of As distinguished Au mineralisation in bedrock from secondary palaeochannel or deep lead Au. In some groundwaters, acid pH values, high sulphate relative to other anions and detectable concentrations of reduced Fe reflected sulphide minerals associated with bedrock Au deposits. Close to some ore zones, locally anomalous groundwater concentrations of Mn reflected the Fe carbonates that accompany Au in these zones. In addition, elevated concentrations of other elements provided geochemical signatures for the aquifer lithologies associated with Au mineralisation. Of the lithological indicators Co and Ni, U and F, Rb and Cs, Mo and Li respectively reflected the mafic, felsic, potassic rich and quartz zones, principally in the Stawell mine area and to a lesser extent those at Clunes and Ballarat. Mineral stability diagrams, based on groundwater activities of K', Mgt and H`, demonstrated that a series of ore-zone groundwaters follow a trend that conforms with a biotite to sericite to kaolinite alteration sequence in aquifer mineralogy. This is a good illustration of how present day groundwaters under surface conditions can reflect the underlying mineral sequences that accompany these Au deposits. These observations around mine areas suggested that groundwater chemistry could provide a rapid and cost effective method of assessing prospectivity for An of extensive areas in central Victoria. To test this, regional sampling and analysis of 355 bore waters was carried out in a region where potential An bearing rocks are covered by Mesozoic and Cainozoic sediments and volcanics. Contoured elemental abundances and distribution from this program indicated five zones in which groundwaters had elevated Au and despite the cover, appeared to reflect variations in the underlying Palaeozoic rocks. Three of the Au zones could be in terrain affected by extensions or intersections of faults, a feature in common with the established Au deposits in central Victoria. Reflections of concealed Palaeozoic rocks included a possible zone of concealed Cambrian greenstones that coincides with three of the Au zones. It was concluded that each of the An zones represents a groundwater Au focus that warrants follow-up exploration.

Jan 1, 1997

By F Clark, M Erickson, J Biggam

Unraveling geological complexity and understanding geological risk are critical components of the challenge that face any mining or exploration venture. This understanding is essential to the successful selection of mineralised domains on which grade estimation relies, so knowledge of the geological characteristics of the mineralised domains is vitally important. æNuggetyÆ mineralisation introduces a higher level of risk and geological observation and intuition may be the only option to ensure that opportunities are realised and ore/waste characterisation is undertaken successfully. Mineralisation at the world class Sunrise Dam gold mine contains a significant coarse gold component, which has necessitated the development of a systematic visual approach to decision making that enables geological staff to determine the potential gold grade in the absence of assay results, and in those instances when assay results appear implausible. The development of the Mineralisation (MZ) Code at Sunrise Dam has assisted in reducing the risk of misclassifying ore as waste and enabled geological control to prevail with confidence where complexity and ambiguity existed.

Jan 1, 2009

Australia is the Western world's largest producer of alumina, supplying one third of total needs. Western Australia's South-West has the greatest concentration of alumina production in the world, with a current annual production rate in the region of 6.8 million tonnes per annum, over 20 per cent of the total supplied to market economies. The value of this production in 1989-90 was 2.34 billion dollars, a very significant contribution to the economy of the State (1). This is despite the fact that the bauxite from the Darling Range is the lowest grade that has ever been commercially exploited, and despite the geographical isolation of the region. It is therefore of great importance to the National and State economies that this industry retain its competitive edge, particularly in the current times of economic downturn. One essential ingredient of this competetiveness is technology and innovation, which can be assured by the committment of the industry to an active program of Research and Development, with support from the public sector as Appropriate.

Jan 1, 1991

By I F. Wood

Planning for flooding and assessment of flood impacts are important requirements for mining projects, as they are also for other types of development. With more intense development and concern from the community, supported by government regulatory requirements, assessment of flood concerns and impacts has become of increasing importance. To ensure that flooding issues are fully understood and results presented in an appropriate format, advanced hydraulic analysis procedures have been developed and are beginning to be applied. These procedures must be rigorous in an engineering context but the results must also be readily understood by the community and government agencies. Advanced two-dimensional hydraulic modelling is becoming accepted as an important means of assessing flooding issues for mining projects. With presentation of results from hydraulic models with Geographic Information Systems (GIS), flood impacts can be analysed rigorously and presented clearly. This paper discusses the application of advanced hydraulic modelling in the planning and impact assessment of a major mining project located on a floodplain where there is extensive inundation. The analysis provides for both input to the planning of the project and for detailed assessment of potential impacts. This case study illustrates some important aspects of the application of hydraulic modelling using a two-dimensional modelling to a critical flood design.

Jan 1, 2003

The population and the per capila consumption of mineral resources have both grown dramatically during the century past. It is argued that growth will continue through the century ahead but that the magnitudes of undiscovered resources are probably adequate to meet demands. The challenge that the mineral explorer of the future will face is finding deposits beneath several kilometres of barren rock.It is further argued that the principal challenge that society will face in the century ahead is the amelioration of environmental stress.

Jan 1, 1993

By Dunn J, Nguyen G, Graham J

A pyritic gold concentrate from the Golden Mile, Kalgoorlie, was roasted over a range of temperatures in a pilot scale fluid bed reactor. The calcines were subsequently cyanide leached. Mineralogical studies of the con- centrate, calcines and leached residues were also undertaken. Calcines produced at 500'C gave the poorest gold extractions and high cyanide consumptions. Gold recoveries of approximately 90 per cent were obtained from calcines produced at 550-600'C but higher roasting tempera- tures resulted in an increase in the residual gold content of the leached calcine. There is some evidence of flash smelting of the pyrite at the higher roasting temperatures and encapsulation of gold particles. Mineralogical examination of the calcines shows that the mechanism of oxidation is temperature dependent. At 500'C pyrite is directly oxidized to hematite with a concentric layered texture which appears to inhibit lixiviant access to enclosed gold particles. At higher temperatures the conversion sequence pyrite-pyrrhotite-hematite produces a spongy calcine which al- lows easier penetration by the leaching medium.

Jan 1, 1991

Proceeding from statistical data on the development of waste volume, an endeavour was made to characterise waste materials with regard to the applicability of treatments based on mineral processing. Many types of waste are characterised by a high heterogeneity. The separation processes used for processing raw minerals can also be used for separation of various waste mixtures. For some waste mixtures, differences in properties can be utilised for separation which are mostly less distinctive for raw minerals. State-of-the-art technology is illustrated with selected Examples.

Jan 1, 1993

By B Walker, A Robertson, C Wels, S Fortin

A background characterisation study was carried out in the Sangre de Cristo mountains, New Mexico, to: quantify naturally occurring contaminant loads from mineralised areas; define site-specific background concentrations; and to determine key factors controlling spatial and temporal variations in contaminant concentrations. The study included a comprehensive sampling and testing program (paste pH/EC, ABA, leach extraction tests) of soil/bedrock from mineralised areas (including erosional scars), and a ground water and surface water quality monitoring program in selected mineralised watersheds. Results demonstrate that high concentrations of contaminants occur naturally in ground and surface water draining the mineralised area of the Red River basin. The erosional scars were found to represent the major source of acid rock drainage (ARD) (~66 per cent) in this area due to: high rates of weathering and erosion, which continually exposes sulfide-bearing outcrops; and high rates of run-off as a result of high elevation and lack of vegetation. The scar material is generally very acidic (paste pH ranges from 8.5 to 1.5; average = 3.6) with highly elevated concentrations of sulfate and leachable metals. The composition and concentration of leachable metals vary significantly, not only between scars but also within a given scar. While all streams draining the various scar watersheds are highly acidic, each has a characteristic æfingerprintÆ of sulfate and metal concentrations. Most of the run-off from the scars infiltrates into alluvial debris flow aprons and reaches the Red River via groundwater flow.

Jan 1, 2003

By Black LP, Law SR, Oversby BS, Mackenzie DE, Wyborn D

Three volcanic sequences of different ages occur close together in the Burdekin Falls area, southeast of Charters Towers in northeastern Queensland. The oldest is equated with the Cambro-Ordovician Mt Windsor Volcanics, and consists mostly of strongly deformed, regionally metamorphosed rhyolitic lava and minor feldspathic to quartzose sandstone. This unit is overlain by folded but unmetamorphosed Upper Devonian-Lower Carboniferous volcanics (DCv) of the lowermost Drummond Basin sequence. The primary volcanic facies of (DCv) principally comprises andesitic and rhyolitic lavas, and dacitic ignimbrites. Similar volcanics are widespread in the lowest formations of the Drummond Basin sequence elsewhere, and dominate that sequence east of the Anakie Inlier. The youngest volcanic sequence is Late Carboniferous and composed of lower, more deformed, compositionally diverse ignimbrites, lavas and conglomerates, overlain by generally less deformed rhyolitic ignimbrite sheets. The upper part is equated with the Bulgonunna Volcanics which extend 90km south to the Mt Coolon area. The Burdekin Falls area contains an ignimbrite stratigraphy different from that in the south. However, one of the most voluminous ignimbrites (Locharwood Rhyolite) in the southern stratigraphy is also present in the north, enabling the two to be correlated.Each of the three volcanic sequences reflects proximity to eruptive sources. Both the volcanics at the base of the Drummond Basin sequence and the Late Carboniferous volcanics are largely the products of subaerial eruptions. The former were erupted from several intermediate-composition volcanoes, and the latter from multiple-vent silicic calderas. All three sequences are considered to be prospective for precious and/or base metal mineralisation. Polymetallic massive sulphide deposits occur in the Mt Windsor Volcanics farther west, and many epithermal gold prospects and mines are hosted by the volcanics at the base of the Drummond Basin, especially east of the Anakie Inlier. The Late Carboniferous volcanic sequence is deeply eroded, and co-magmatic high-level plutons are widely exposed; this sequence may therefore be more prospective for deeper-than-epithermal mineral deposits.

Jan 1, 1990

By Muldoon T

Water sprays on mining machines are generally put there to reduce dust; however, research by the Bureau of Mines and others has shown that considerable airflows may also be generated by these sprays. This recognition of water spray-gen- erated air movement led to the "Spray-Fan" - a continuous miner auxiliary ventilation system which was shown to reduce methane peaks by a factor of 15. Recent successes and failures of the Spray Fan are reviewed. More recently, the same principles were used in the design of the "Shearer- Clearer" for reducing dust at longwall shearer operators. The original design was successful; however, a new design is now available which is more practical to install and does a much better job of holding the dust against the face downwind of the shearer. The latest research objective is to eliminate the negative impact of spray- generated air turbulence on continuous miner dust control. Most coal faces in the USA are ventilated in the exhaust mode using "line curtain", and the forward airflow on the side of the heading opposite the curtain is inevitably weak. Air turbulence generated by sprays which are incorrectly located and/or operated at excessive pressures can cause roll back - in which the dust cloud at the face is forced unwind against the ventilation and spreads over the miner cnerator. The general approach to reducing "roll back." is reviewed and art anti-roll back water spray system is presented.

Jan 1, 1983

Level measurement of underground orepasses is important. Orepasses are not only utilised to funnel ore to the shaft skip loading station but also as silos for storing of ore in order to smooth out ore flow in a shaft system. Safety and operational efficiency are also improved as proper orepass level measurement could prevent overfilling of tipping areas. A study was therefore commenced to determine alternative technologies available as well as identifying practical installations across the Anglo American plc Group. From an instrumentation perspective an orepass system is an extremely difficult environment to take measurements in. Factors like dust, vapour, interference, bridging, wear and physical installation have to be taken into account. The study discusses time-of-flight (ultrasonics, radar and laser) measurement techniques followed by other possible solutions. These solutions included strain gauge measurement, the æjumping monkeyÆ technique, radiotomography, fibre optics and very long baseline interferometry (VLBI). Finally, various South African suppliers have been approached in order to determine instrumentation that is available for orepass level measurement in the marketplace. These recommendations were verified, where possible, by visiting the claimed installations.

Jan 1, 2005

Mount Isa Mines' Hilton Mine was brought into large-scale production in 1990/91 at a time of sharply falling metal prices. To ensure the operation's survival and eventual prosperity there was an urgent need to reduce operating costs and increase revenue. A target of a 40 per cent increase in productivity over five years was set. Strategies to obtain the required improvements were developed on the basis of greater involvement and increased contribution from the workforce, major changes to the mining methods and the development and application of new technology. This paper describes the organisational, operational and technological changes that have been implemented at Hilton and presents the results achieved to-date.

Jan 1, 1993

Rifting and transfer faulting in the Late Cretaceous to Early Tertiary resulted in the formation of the Bundaberg Trough and Wallaville Basin and deflected the margin of the Maryborough Basin southwestward between the Kolan and Burnett Rivers. During the Cainozoic, three periods of volcanic activity occurred in the Bundaberg-Gin Gin area. The oldest of these periods, Paleocene to Early Eocene, resulted in the outpouring of tholeiitic lavas. During the Late Miocene to Pliocene, undersaturated alkali basalts generated at depths of from ca. 35 to 55 km were emplaced. These lavas were followed in the Pleistocene by the alkaline Hummock and Berrembea Basalts. The loci of eruption of all of these lavas were controlled by the intersection of the transfer fault system and pre-existing north to northwesterly trending faults in the Bundaberg-Gin Gin area.

Jan 1, 1990

By Hoffmann CF, White NC, Tedder IJ, Wood DG

Since the discovery of Pajingo in 1984, the northern Drummond Basin has emerged as a significant new gold province, and has become the focus of intense exploration for epithermal gold mineralisation. Prospects in the Conway area are hosted by felsic to intermediate lavas and volcaniclastic rocks near the base of the Drummond Basin sequence. These Drummond Basin rocks appear to represent favourable hosts to mineralisation because they are cut by structures which could have focussed and channelled fluids on a regional scale, and because they constitute a possible source of gold and, perhaps more significantly, sulphur for the transport of gold. Prospects in the Conway area are up to 15 km2 in area, and are of the adularia-sericite type. They illustrate many of the classic features (siliceous sinters, alteration mineralogy, and fluid characteristics) recognised in epithermal deposits. K-Ar dating of sericite alteration in three of the prospects has produced a range of ages from 283 to 334 Ma, suggesting that the systems are the product of multiple hydrothermal events.

Jan 1, 1990

By Kurita K, Tanaka T

In order to clarify the gas flow and motion of coke and reaction in the raceway, the mathematical raceway model was developed. This model consists of the equations of momentum and continuity of gas and coke. The simulated results were compared with the results of the cold and hot experimental model. The relationship between the blast volume and the raceway size, the pressure distribution and the velocity distribution of coke are in good agreement with the experimental results. Moreover the equations of reaction and heat conservation were simultaneously calculated with the dynamic equations. Distributions of gas composi- itions and temperature were simulated and found to be in good agreement with the distributions of gas compositions of CO, CO2 on the tuyere level measur- ed in the hot experimental model.

Jan 1, 1981

By Willis I. L, Stevens B. P J, Stroud W. J

The Early Proterozoic metamorphic rocks of the Broken Hill (BH) Block have been recently subdivided into sixteen formations and four groups (Willis et al., 1983b, Stevens et al., 1983). This stratigraphic subdivision has relied upon recognition of distinctive mapped rock units and "associations" of mapped rock units, which characterize particular lithostratigraphic units. The rock units and rock unit associations define local ordered sequences which can be compared and correlated, thereby establishing the stratigraphic succession. In the Clevedale homestead, Thackaringa, BH City, Bores Mine-Freyers mine, Silver King mine, and Brewery Well areas, coherent stratigraphic successions have been interpreted. These areas illustrate the regional variability of the stratigraphic succession and facies changes within individual stratigraphic units. Stratigraphic type sections are located in the Thackaringa, Bores Mine-Freyers mine, Silver King mine, and Brewery Well areas. The principles of stratigraphic interpretation applied in the BH Block can be used in other areas of Willyama Supergroup outcrop such as the Euriowie, Olary and Mount Painter Blocks. The general technique may also have applicability to other highly deformed and metamorphosed terrains.

Jan 1, 1983