Search Documents

By E. J. MCOAUSTLAND

THE behavior of steel after overstrain and at moderate temperatures is fairly well known. It has been made the subject of much investigation, and our knowledge is clear and definite on many points. The ultimate raising of the elastic limit, after moderate overstrain, and the consequent lowering of the ductility, seem to be well established. It is also well understood that the immediate effect of overstrain is to lower the elastic limit, possibly to zero, but that if not interfered with, this limit will subsequently rise higher than before. The "tests after moderate temperature," reported in this paper, were undertaken to verify the above statements for the particular steel under investigation, and also to determine, if possible, the total time required for complete recovery from this state of overstrain. The behavior of overstrained steel at temperatures at or below 32° F. is not so well known. Tests made by Prof E. G. Coker, at McGill University,' show that steel, overstrained and subjected to cold, will remain in a state of overstrain for an indefinite period. I am not aware of any other published results of tests along this particular line. The effect of time and temperature on the recovery of steel from overstrain was made in 1902-3 the subject of sortie investigation in the laboratories of the College of Civil Engineering of Cornell University. A general plan was outlined in connection with the regular courses of instruction in testing of materials; but the press of routine work and the demands of the schedules on the time of the students were so great as to presage long delay in the completion of the work. Not much had been accomplished up to 1904-05, when Messrs. E. C.

May 1, 1906

By R. R. Goddard

By use of the frequency response method with a radioactive tracer, it was possible to determine fluid dispersion and distribution in a natural consolidated and an unconsolidated medium. Measurements were made in a linear flow system at oleic saturations of 69 per cent in the consolidated medium, and 100 per cent in both media. Dispersion and distribution were obtained by measuring the amplitude attenuation and the phase velocity of sinusoidal waves with a dual monitor apparatus. The gamma ray emissions permitted in situ measurements at any distance along the porous samples. One result of importance was that the effective diffusivity increased as the wave length increased. As a consequence, a dispersion coefficient appropriate for the injection of large slugs might exceed the value measured by use of small slugs. Since flow models based solely on fluid velocity and an effective diffusivity coefficient imply that the diffusivity should be independent of frequency, such representations were not adequate for the data of this study. A comparison was made with a capacitance model of porous media with deadend PVs, but even this model was not completely adequate. By using attenuation and phase velocity data, fluid dispersion can be predicted without postulating a differential equation satisfied by the tracer concentration, thereby eliminating the need of a complicated model to represent dispersion. INTRODUCTION The flow of similar miscible fluids through a porous medium can be fairly adequately described by two parameters: the average fluid velocity and the effective diffusivity.1-3 It has been pointed out recently, however, that significant discrepancies exist between this representation and the experimental data.4-7 An improved agreement can be obtained by introducing additional parameters based on the concept of dead-end pores. The purpose of the present investigation was to find out whether the frequency response method could be used to measure the relevant parameters. The method was used in the following form. A stream of fluid was flowed at a constant rate through a sample of porous material and the concentration of a radioactive tracer in the fluid was varied sinusoidally at a fixed frequency. The effects of flow through a porous medium are a decrease in the amplitude of the concentration wave and an increase in the velocity of the peaks of the waves above the average velocity. Attenuation and phase veIocity of the waves were measured as a function of frequency and fluid velocity. The simple two-parameter model implies that the diffusivity should be independent of frequency. Data reported in this paper show that the diffusivity decreases as the frequency increases. Hence, as shown also by many others, the two-parameter model is not completely adequate. Coats and Smith 5 used two additional parameters in their model: the volume of the dead-end pores and the rate of mass transfer between dead-end pores and the flowing stream. Their capacitance model of a porous medium containing some stagnant fluid, to which transfer occurs by molecular diffusion, did not explain the dispersion results of either the present study or of theirs. Instead, the capacitance effect can be better described as the result of extreme velocity variations within the pores of the medium, with transfer between the velocity zones by convection. EXPERIMENTAL PREPARATION OF POROUS MEDIA Data reported here were obtained with a natural Berea sandstone, and with two packings of 20/25 mesh sand. Pertinent information about these media is listed in Table 1. The sandstone core was first sealed with a non-

Jan 1, 1967

By H. H. Campbell

The following pages discuss some problems connected with the manufacture of steel by the open-hearth process. The methods employed necessarily enter into the domain of what is called theory; but the results are eminently practical. The determination of the various losses of thermal power and the investigation into the chemical reactions in the bath, are important to every manufacturer. It will be understood that definite figures concerning one furnace and one system, will not apply to all other furnaces and systems; but it is hoped that methods are developed, which are capable of general application and which will shorten the labors of others. The gas-calculations contain nothing entirely novel; but certain methods appeared to be very convenient and they are here elaborated in order that others may have a model to follow. The determination of the loss of iron by weighing the slag and finding the percentage of iron therein, is probably unusual. If so, the fact is to be regretted, since this is the only way that an accurate result can be obtained. The common method of estimating the loss in open-hearth work, is to subtract the weight of metallic products from that of the materials charged. Nothing could be more unsatisfactory, inaccurate and meaningless. Pig-iron, steel, wrought-iron and ore are charged into the furnace; complicated chemical reactions occur; the sand of the pig-iron, the slag from the wrought-iron, the gangue of the ore, all rise to the top ; the silicon, manganese and carbon burn and leave the metal; some of the iron oxidizes and goes into the slag; some of the ore is reduced and gives up metallic iron ; the recarbonizer is added, the mission of which is to waste itself; in the pouring of the steel, pit-scrap is made in the ladles, around the moulds and under the spout; the errors in weighing the products join hands to make accuracy impossible; and then the " loss" is determined by diffrence !

Jan 1, 1891

By Charles Janin

The first successful bucket-elevator dredge to operate in California was put in comnlisvion wt Oroville in March, 1898. There had been numerous previous attempts at dredging, but noue of the earlier boats proved a success. The gold-miners in California earl3 conceived the idea of a machine to dig gravel from the beds and bars of auriferous streams that were inaccessible by the methods then employed, and it was only a few months after the discovery of gold in California that such a machine was Shipped around Cape Horn from New York to San Francisco. Thij was, however, but the forerunner of many failures in gold-dredging, and was soon at the bottoni of the Sacramento river. During succeeding years many other unsuccessful attempts mere made, and it was not until 1897 that a dredge of the single-lift bucket-elevator type mas floated on the Yuba river. This dredge was built by the Risdon Iron Works for 12. H. Postlethwaite, and would probably have been a success if it had been operated on some of the rich Ororille ground

Jan 1, 1912

By Richard McCaffery

WHEN we began the study of blast furnace slags we limited our work at first to a study of those slags containing only lime, alumina and silica. On our paper1 on some of the results of this first work, the solubility of sulfur in slags containing no magnesia was reported and the question of sulfur solubility and slag viscosity discussed. There has been, for a long time, a very great difference of opinion among metallurgists as to he effect of magnesia in blast furnace slags, and the literature is full if expressions of the most contrary opinions on the subject. As a result, our next publication' developed the constitution of slags considered as a four-component system, silica-alumina-lime-magnesia, and advanced an explanation of slag structure which accorded with the facts and with scientific theory. The present paper continues our study of the general subject of slags. As blast furnace slags are included in the silica-alumina-lime-magnesia system, which is a particular case of four-component solutions, we have determined that there are 22 components Table 1), which may enter into the silica-alumina-lime-magnesia system and that 10 or 12 of these components may be present in blast furnace slags which are within the ordinary ranges of composition. To cave a very definite conception of the behavior of these components in a slag, we have developed the theory of the cooling of a four-component solution from the liquid state to the solid and the conclusions that we obtained have been made use of in this paper. On account of the importance of the four oxides and 18 compounds which enter into the silica-alumina-lime-magnesia system, some method of calculating the percentages of the various compounds that are present in the slag when the percentages of the oxides are given, seemed very desirable and we develop L method later herein for doing this, and finally we give illustrations of the composition of a wide series of blast furnace slags and show some applications of these composition data.

Jan 1, 1927

By B. Ball, D. W. Fuerstenau, P. C. Kapur

A two-phase distributed-parameter model of the flotation process has been extended to allow consideration of the important process parameter, concentrate grade. A simple expression is presented for the grade of concentrate in terms of the zeroth and first moments of the concentrate distribution. An example is given for a binary ore containing two pure minerals each having nondistributed rate constants. For extend-ing the model to the distributed rate constant case, a cubic polynomial zoas utilized to simulate the feed distribution. One particular example is considered and grade-recovery curves are generated to show the dependence of such curves on the initial feed distribution. Operating flotation plant engineers have traditionally evaluated plant performance in terms of the recovery of valuable mineral and the grade of the concentrate. In both operation and research, grade-recovery relationships have been used as a guide for selecting flotation conditions. Weissl illustrated the use of grade-recovery curves in plant operation and considered the grade-recovery relationship to be a metallurgical one. The extensive experimental work of Chi" using standard batch flotation tests on iron ores shows that, even with extensive statistical correlation of data, little insight can be gained into the basic fundamentals of these relations. Such relations must depend on the kinetic behavior of the various mineral species in the flotation circuit. In his flotation text book, Gaudin3 considered the relationship of recovery and of product grade to flotation kinetic indices, but he did not extend his calculations to yield grade-recovery relations. Although Gaudin used a simplistic model for his analysis, he did recognize that variations in flotation rates must result from variations in locking, surface heterogeneity, particle size and shape, among other things. In a recent paper,' we presented a model of the flotation process that could be readily analyzed with an analog computer. This model combines the concept of a distributed set of rate constants"" with that of the two-phase flotation model,8" resulting in a model more powerful and flexible than previous ones. The purpose of the present paper is to show how this model can be used to generate grade-recovery curves and to determine the dependence of such curves on the various kinetic parameters. In this paper, the model will be limited to the semi-batch case, but extension to the continuous case is a straightforward step.

Jan 1, 1971

By George W. Bain

Methods of mining building stone of any sort are planned to produce as few fractures as possible, and present a strong contrast to methods of mining metallic ores, which must be crushed eventually and have fractures produced in as great profusion as possible. Shocks transmitted to a stone invariably make it more porous and more permeable and reduce its effective life, therefore methods of mining building stone involve as This building illustrates the fine detail of workmanship, unprotected sharp corners and thin edges, and tall narrow columns characteristic of marble structures. These features require exceedingly coherent stone, and preservation of these features for decades or centuries demands many special quarrying precautions to keep absorption to 0.14 per cent or less, a detail not essential to stone for coarser architectural types. few shocks as possible. This is singularly true for marble because marble structures are intended to have long life, greater delicacy of line, more gracefulness and fineness of sculpture than those made from any other structural material (Fig. 1). So that delicate lines may remain in almost perfect preservation for decades, or even centuries, it is important

Jan 1, 1938

By George W. Bain

Methods of mining building stone of any sort are planned to produce as few fractures as possible, and present a strong contrast to methods of mining metallic ores, which must be crushed eventually and have fractures produced in as great profusion as possible. Shocks transmitted to a stone invariably make it more porous and more permeable and reduce its effective life, therefore methods of mining building stone involve as This building illustrates the fine detail of workmanship, unprotected sharp corners and thin edges, and tall narrow columns characteristic of marble structures. These features require exceedingly coherent stone, and preservation of these features for decades or centuries demands many special quarrying precautions to keep absorption to 0.14 per cent or less, a detail not essential to stone for coarser architectural types. few shocks as possible. This is singularly true for marble because marble structures are intended to have long life, greater delicacy of line, more gracefulness and fineness of sculpture than those made from any other structural material (Fig. 1). So that delicate lines may remain in almost perfect preservation for decades, or even centuries, it is important

Jan 1, 1938

By Dan Crackel, G. G. Ramos, Mark Heisel

INTRODUCTION Feasibility studies indicated that a cratering type stoping method was best suited to the character of the first ore block at Carr Fork. This method known as vertical crater retreat (VCR) has since been modified to a combination cratering and deck blasting using VCR drop raises for initial undercut development . The modified form retains many of the advantages of VCR while allowing high tonnage production blasts which have offset many of the disadvantages. FIRST CONCEPTS AND PREMISES Geologic Considerations The Steep Highland Boy (SHB) skarn orebody, the first of several blocks being developed, is a steeply dipping 70° to 90° limb of a syncline, with a width averaging 25 m (82 ft). The bed has a consistent east-west strike length of over 400 m (1300 ft) and extends from the surface to depths of over 1000 m (3300 ft). The footwall is highly fractured quartzite and the hanging wall grades from garneti te to limes tone and hornfe 1s. Because of the limestone in the hanging wall, the hanging wall appears more competent than the footwall. The ore is garnetite with lenses of massive sulphide and magnetite. The quartzite footwall is highly fractured not only because of the bedding but also due to the folding and intrusion of the quartz monzonite. This irregular footwall outline of some stopes in- creases the likelihood of excessive dilution. The principal ore mineral is chalcopyrite with some bornite. The garnetite ore is quite variable in terms of compressive strength and drillability. In addition to the sulphide and magnetite lenses, it is transected by clay- altered dikes and major and minor north-east faults. TABLE (1) gives the range and mean strengths of the rocks. Investigating Mining Methods Initial consideration of a suitable mining method centered around maximum safety and efficiency with minimum potential dilution. The following major methods were considered and investigated. Cut and fill mining was eliminated because of low productivity, the cost and problems associated with providing fill, and the relatively unsafe nature of the method. Sublevel caving was rejected due to the unpredictable cavability of the waste and the geometry of the ore body. Conventional sublevel or blasthole methods require excessive development, as fan and ring drills are limited to efficient drilling in the 18 to 25 m range (60 to 80 ft). Mining downdip with equipment drilling small diameter holes would have required eight separate extraction/drill horizons with crosscuts and associated excavation in the main ore block. The use of down the hole (DTH) machines cap- able of drilling 165 m (6g in) diameter holes

Jan 1, 1981

By C. R. Kuzell

INTRODUCTION KNOWLEDGE of the thermal capacity of gases is of great importance in making metallurgical calculations. The metallurgist is, frequently called upon to investigate and determine furnace efficiencies in which the heat carried into or out of the furnace by gases is a large item in the heat balance. Not only do such problems present themselves in the determination of furnace efficiency, but also in the study of the application of heat is accessory apparatus, such as stoves, regenerators, waste-heat boilers, driers,.etc. The thermal effect of the use of excess air in the combustion of fuel, the theoretical temperatures of combustion, the quantity of heat in hot blast at various temperatures, the effect of hot blast on furnace temperatures, are a few more examples of frequently occurring calorific problems involving gases. So many are the applications of the data on the heat capacity of gases that the subject merits careful study. The heat in a gas maybe due to its heat of combustion, if it is a combustible gas, and to its temperature. The latter is called its sensible heat and is the heat absorbed or evolved by a gas as its temperature is raised or lowered. The heat of combustion of gases is well established and is commonly known. The values can be found in almost any mcdern treatise on metallurgy. The sensible heat of gases has not been so well established because it is in most cases a function of the temperature, and the values of specific heats of gases over a wide range of temperatures have only recently been determined. It is the purpose of this paper to deal with the sensible heat of gases.

Jan 8, 1914

By L. O. Bieber, L. H. Martin

DIFFERENT MELTS OF THE same type of nickel and high-nickel alloys, while having almost identical mechanical properties at room temperature, may have widely varying hot malleability. Either the upper limit or burning temperature may vary or a variation in malleability may occur within the temperature limits normally encountered during hot working. Melts which have reduced hot malleability of the latter type, are said to have a "hot short" range. Examination of melting records and chemical analysis of these heats fails in most cases to show the reasons for these variations. In May, 1930, an investigation was started to determine if a quick and accurate method of hot-malleability testing could be developed which would predict the ability of the metal to withstand hot forging and hot rolling by standard mill practices. The results obtained were so satisfactory that from that time on, all melts of nickel and high-nickel alloys produced in the International Nickel Company's Huntington, W. Va. Works have been tested when hot malleabilty was an important factor. To date, over 63,000 commercial melts of Monelt † nickel, Inconel† and other high-nickel alloys have been tested and the test data compared with processing results. As the result of experience gained in over sixteen years, two standard methods of hot malleability testing have been adopted.

Jan 1, 1948

By H. M. Howe

PART I. INTRODUCTORY. § 24. INTRODUCTION.-This paper discusses the chief existing data as to the temperature, in iron-carbon alloys, of Ae.3, the upper limit of the transformation range when in equilibrium, as distinguished from Ac3, the temperature at which the end of the transformation is noted in heating up, and from Ar3, that at which its beginning is noted in cooling down. The former is in fact carried above Ae3 and the latter below Ae3 by lag. I touch incidentally on the influence of manganese on Ae3 (§ 29, p. 1102). The sections, tables, and illustrations, are numbered consecutively with those in the accompanying papers by Howe and Levy on Determination of, the Position of Ae3 in Carbon-Iron Alloys, and by Burgess, Crowe, and Rawdon on Thermal and Microscopical Examination of Professor Howe's Standard Commercial Steels, to which the present paper forms a sequel. § 25. The contradictoriness of our present evidence is shown by grouping it together in Fig. 14. For instance, both Goerens and Meyer (Series 2) and Meuthen (Series 12) used practically stationary temperature, and thus reduced the influence of lag very greatly; yet Ae3 for 0.32 carbon steel according to the former investigators is 894°, but according to Meuthen it is at or below 770°, a discrepancy of 124° or more. In view of our ability to measure these high temperatures within a few degrees, the existence of such a discrepancy is as unwelcome as it seems needless. I attack the thankless task of bringing some order out of this chaos.

Jan 6, 1913

By John Wulff, Richard P. Seelig

The importance of the pressing operation in the forming of articles by powder metallurgy depends to a great extent on the type of product to be made. While in some few cases the pressing is merely a means of compacting loose powder particles into a solid mass preliminary to a sintering treatment, in most applications it constitutes a molding operation with the purpose of shaping the raw material in powder form into a certain predetermined, accurately defined part not altered in shape by subsequent sintering. In still other cases, no pressing at all but sintering in molds gives useful articles. A limited number of products are made by the simultaneous application of pressure and heat. The factors that control the product of the pressing operation are raw material, lubricant, type, size and shape of die and compact, magnitude and time of application of pressure, as well as temperature of pressing. All such factors need to be controlled; yet, depending on the function of the pressing operation, greater emphasis may be placed on processing factors other than the pressing operation. In any complete discussion of pressing, subsequent sintering cannot be disregarded. For the sake of brevity, the present paper has been limited to the mechanics of pressing and only occasionally refers to sintering. For the same reason, hot-pressing has been omitted as beyond the scope of this paper In any survey of the literature on the pressing of metal powders, the 1938 paper of Balshinl on the theory of the process of pressing deserves mention. The first attempts at an interpretation of pressing phenomena were made by Balshin' and RakovskL2 The experimental results of both are of great interest. Since the experimental results are not described, the work was repeated, using our own interpretation of the possible techniques, and is reported in the following pages. The basic theory of Balshin,' based on a hydro-dynamic analogy, however, leads to hut another way of plotting density and pres- , sure against height of a pressed compact. Since it does not give any new insight into the phenomena, nor account for the influence of side-wall friction, a discussion of the theory has been omitted from this paper. Density Gradients in Compacts The process of pressing metal powders in a die (disregarding for this consideration the powder filling and ejection operations) may be divided into three phases: (I) packing, (2) elastic and plastic deformation, (3) cold-working with or without fragmentation. It must be emphasized that these three steps do not follow each other in sequence; on the contrary, in practice

Jan 1, 1946

By John Wulff, Richard P. Seelig

The importance of the pressing operation in the forming of articles by powder metallurgy depends to a great extent on the type of product to be made. While in some few cases the pressing is merely a means of compacting loose powder particles into a solid mass preliminary to a sintering treatment, in most applications it constitutes a molding operation with the purpose of shaping the raw material in powder form into a certain predetermined, accurately defined part not altered in shape by subsequent sintering. In still other cases, no pressing at all but sintering in molds gives useful articles. A limited number of products are made by the simultaneous application of pressure and heat. The factors that control the product of the pressing operation are raw material, lubricant, type, size and shape of die and compact, magnitude and time of application of pressure, as well as temperature of pressing. All such factors need to be controlled; yet, depending on the function of the pressing operation, greater emphasis may be placed on processing factors other than the pressing operation. In any complete discussion of pressing, subsequent sintering cannot be disregarded. For the sake of brevity, the present paper has been limited to the mechanics of pressing and only occasionally refers to sintering. For the same reason, hot-pressing has been omitted as beyond the scope of this paper In any survey of the literature on the pressing of metal powders, the 1938 paper of Balshinl on the theory of the process of pressing deserves mention. The first attempts at an interpretation of pressing phenomena were made by Balshin' and RakovskL2 The experimental results of both are of great interest. Since the experimental results are not described, the work was repeated, using our own interpretation of the possible techniques, and is reported in the following pages. The basic theory of Balshin,' based on a hydro-dynamic analogy, however, leads to hut another way of plotting density and pres- , sure against height of a pressed compact. Since it does not give any new insight into the phenomena, nor account for the influence of side-wall friction, a discussion of the theory has been omitted from this paper. Density Gradients in Compacts The process of pressing metal powders in a die (disregarding for this consideration the powder filling and ejection operations) may be divided into three phases: (I) packing, (2) elastic and plastic deformation, (3) cold-working with or without fragmentation. It must be emphasized that these three steps do not follow each other in sequence; on the contrary, in practice

Jan 1, 1946

By W. V. Swarzenski

In its effort to combat waterlogging and soil salinity, the Water and Soils Investigation Division of WAPDA (West Pakistan's Water and Power Development Authority) has carried out an extensive program of test drilling andwater sampling since 1954. Data collected during the past ten years have permitted the delineation of fresh and saline groundwater zones in the Punjab Plain. Fresh groundwater containing generally less than 500 ppm of total dissolved solids is found in wide belts paralleling the major rivers and in other areas of fresh-water recharge. Locally, fresh groundwater extends to depths of 1500 ft and more. Saline groundwater occurs down gradient from sources of recharge, particularly in the lower central parts of the interfluvial areas, and presumably underlies most of the Punjab Plain. The groundwaters of the Punjab are characterized by their evolution from calcium, magnesium bicarbonate waters near sources of recharge to waters containing a dominant proportion of sodium. The highly mineralized waters of the Punjab are generally of the sodium chloride type, whereas in the Dera Ismail Khan District, sodium sulfate waters predominate. The pattern of distribution of saline groundwater zones and the observed gradual increase in mineral content, down gradient from sources of recharge, can be explained best by a hypothesis stressing the process of evaporation from the water table and solution of minerals within the alluvial aquifer. In 1954, detailed groundwater surveys in the Punjab Plain were initiated by WASID, the Water and Soils Investigation Division of West Pakistan's Water and Power Development Authority. The investigations, undertaken under a cooperative agreement between the governments of Pakistan and the United States, were aimed at the formulation of reclamation measures to improve waterlogged and saline soils, and to assess the groundwater potential of the Punjab and other areas of West Pakistan. The nature and urgency of WASID's primary task limited the exploration of the alluvial aquifer generally to its uppermost part. About 1030 test holes drilled in 47,000 sq miles of the Punjab defined the nature of the alluvium to depths of about 600 ft and yielded data on water quality to 400 or 500 ft. A report on the hydrology of the Punjab, based on the results of these investigations was published by WASID in 1963.' The present report incorporates data obtained by WASID since 1962 in a program of deep test drilling in the Punjab and the adjacent areas of Bahawalpur and Dera Ismail Khan District, permitting the definition of fresh and saline groundwater zones to depths of 1500 ft in some areas. Groundwater in the Punjab Plain is contained in alluvial deposits, predominantly sand and silt, which extend almost everywhere to depths of 1000 ft and more. The alluvium has been deposited by the Indus River and its tributaries since late Tertiary time and is contiguous with similar deposits in India. The Indo-Gangetic Plain extends from the foothills of the Himalayas to the ancient rocks of the Peninsular Shield in central India and to the ocean. Gradients are generally very low and range from about 1% ft per mile in the upper part of the plain to less than 1 ft per mile in the south and southwest. The monotony of the alluvial plain is broken by scattered bedrock outcrops in two of the interfluvial areas, Chaj Doab and Rechna Doab. The bedrock hills are projections of the northwest-trending Delhi-Shahpur Ridge that is largely buried by alluvium. The rocks of the buried ridge, presumably of Precambrian age, are essentially impermeable and define the lower limit of the alluvial aquifer in parts of Chaj, Rechna, and Bari doabs. Elsewhere in the Punjab, there are no outcrops of other consolidated rocks and their presence below the alluvium is conjectural. The principal areas of bedrock outcrops, near Kirana and Sangla, are shown diagrammatically in Fig. 1. The movement of groundwater through the alluvial aquifer of the Punjab has been described by Green-man and others.' In most of the area, the pre-irriga-tion water table sloped from the rivers downstream and toward the central axes of the doabs, indicating that the rivers were sources of groundwater recharge. As a result of seepage from irrigation canals, water levels have risen as much as 90 ft. In 1960 they were within 5 to 15 ft of the land surface and above the

Jan 1, 1970

By W. O. Philbrook, H. W. Hosking, N. B. Melcher

A simple and inexpensive mercury-tracer method has been develohed to study rates and Patterns of gas flow in blast furnaces. A Pulse of mercury is injected into the hot blast, and its arrival at the sampling Point is recorded by an electronic circuit that measures resonant absorbtion of ultraviolet light by mercury vapor in the gas aspirated .through the detecting. cell. A rapidly developing interest in blast-furnace technology in recent years has created a strong demand for precise knowledge of the rates and patterns of gas movement through the stock column. Classical fluid-flow theory cannot supply the desired information because the complexity of the blast-furnace situation precludes the accurate determination of many of the parameters required for solution of the equations. In fact some of the terms employed in fluid-flow treatments become almost meaningless under blast-furnace conditions. The void fraction of the stock column, for example, varies widely from place to place and is affected by the segregation of charge materials, attrition of lumps during descent, and channeling. Gas density varies with changes in local pressure, temperature, and composition, while viscosity varies with temperature and composition. Even if mean values for these functions were acceptable, they would be either impossible or extremely difficult to determine with a high degree of accuracy since the value of the mean for all gas properties would depend upon the flow distribution itself. Attempts to study gas movement by the pitot-tube determination of kinetic pressures have met with little acceptance. Reproducibility of results is extremely difficult to achieve in a situation where alignment of the tube orifice with respect to the flow direction in tortuous channels cannot be guaranteed. Because of these difficulties it would appear that progress can be achieved only with a direct method of measuring gas velocities and determining the shape of flow paths through the stock. The establishment of such a method is described in this paper. SELECTION OF METHOD Direct measurement suggests the use of a tracer by means of which the progress of a "parcel" of gas can be followed through the furnace. Several requirements must be met before any selected material can be considered a suitable tracer. First of all, it must be a substance not normally present in blastfurnace gas or dust; otherwise its presence in a gas sample will have little significance. It should be volatile at temperatures normally existing within the furnace, to ensure that it will travel with the gas, as a gas. It should possess special properties enabling its presence in the gas to be detected readily, and it should not undergo exchange reactions with any material normally present within the furnace, including refractories and coke as well as all components of the metal and slag. Radioactive materials naturally are considered because their radioactivity renders them susceptible to detection. However, of the many radioactive materials available, almost all are eliminated from final consideration by their unsuitability in terms of other properties. Radioactive silicon, carbon, calcium, phosphorus, and many others have been considered and discarded, either because they are not volatile over the whole range of significant temperatures, or because they could be expected to undergo exchange reactions with burden or refractory materials. Others which might be suitable in terms of these properties are eliminated because of a low activity, short half life, or the necessity for fragile counting apparatus. Of the many elements available in radioactive form, perhaps radon is the only one suitable for blast-furnace gas-flow studies. This has been used in several investigations1-4 with considerable success. The use of radiotracers has certain inherent disadvantages. One is the cost. An appreciable sum must be allowed for materials each time a test is made. Also, special methods of handling must be employed, and very often the progress of an investigation must be governed by the availability of isotopes and the delivery arrangements that can be made for them. An advantage is immediately gained if the tracer material can be a substance which can

Jan 1, 1960

By Wendell S. Williams

Single crystals of TIC doped with boron at high temperat~ires develop second-phase inclusions. The inclusions are in the form of lamellae lying parallel to {l 11 } planes of the Tic matrix and can be vevealed by etching [100] cleavage faces of the boron-doped Tic crystals. measurements of the critical resolved shear stress. t, of TIC crystals containing such inclusions showed that the ropid drop in t wilh increasing temperatu.ve found for pure Tic was greatly reduced. At 1600°C, the inclusion containing crystals had a value of t five limes that of pure Tic. The hardening effect also was found to inhibit hot pressing of TiC powders containing boron impurity. Thermochemical and crys-tallographic arguments suggest that the inclusions are TiB2. The boron content of the hardened carbide is a few tenths of 1 pct. TITANIUM carbide is noted for its high room-temperature hardness. However, measurements of the critical resolved shear stress, T, of single crystals of Tic at high temperatures have shown that t decreases exponentially with increasing temperature.' This temperature dependence of t is attributed to thermally activated dislocation mobility limited by a large Peierls stress.' In turn, this large Peierls stress is believed to be a consequence of strong co-valent and ionic binding in Tic. The rapid drop in 7 with increasing temperature, characteristic of pure Tic, is lessened by the introduction of second-phase inclusions. Exposure of Tic to boron at high temperatures produces such inclusions. A report of the influence of boron on t in Tic is presented, followed by a discussion of the nature and formation of boron-containing inclusions in Tic which are believed to be responsible for the hardening effect. I) CRITICAL RESOLVED SHEAR STRESS OF BORON-DOPED Tic CRYSTALS Tic single crystal boules grown by Union Carbide Corp., Linde Division, were doped with boron by placing them in a carbon crucible packed with boron powder and heating in a vacuum furnace to 2000°C for 1 hr. Samples 1 by 1 by 3 mm were cleaved from these doped boules. High-temperature compression tests' were made on these samples to determine the critical resolved shear stress as a function of temperature . The rapid drop in critical resolved shear stress found for pure Tic crystals' did not occur: tests indicated that the boron-doped crystals at 1600°C had values of T equal to those of pure Tic crystals heated to only 1100°C, Fig. 1. No difference in the shape of the individual stress-strain curves was produced by the boron doping, but the stress scale was multiplied by a large factor. The hardening effect of boron in Tic probably extends to temperatures lower than those used in the present work (1100°C minimum). At room temperature, however, the influence of boron is difficult to determine because the stress required for gross plastic flow in pure Tic is SO high that in practice fracture cccurs first. Microhardness is the only test that can give an indication of the yield stress in Tic at room temperature. such measurements were made5 on boron-doped Tic; the matrix had a hardness value

Jan 1, 1967

By Alexander L. Field

The Bureau of Mines is investigating the problem of slag viscosity, its variation with the temperature and with the composition of the slag, and its effect upon the distribution of the sulphur between molten iron and slag, as introductory to a series of contributions to the theory of the metallurgical processes. The method of measurement, viscosity apparatus, furnace and other accessories mentioned in this paper have been described fully in s Bureau of Mines report.1 The Literature on Slag Viscosity The viscosity of blast-furnace slag had not been measured previous to the investigation described in this report. A number of investigators have determined the "fusibility," or softening temperature, of slags by means of the cone method .or other deformation method, but these methods supply only limited information regarding the temperature-viscosity relations of the slag in question. Any deformation method that may be employed indicates only the temperature at which the slag attains a more or less definite viscosity., the magnitude of the value obtained depending on the method used. For details of the various methods used by different investigators, see the Bureau of Mines paper already referred to. An isolated measurement by Doelter on a single mixture at 1,300" C. represents the highest temperature reached in the various viscosity investigations previous to those described in this report, in which results have been referred to absolute units. Arbitrary deformation tests have of course been made at much higher temperatures.

Jan 1, 1917

By D. L. Archer, W. W. Owens

Conventional waterflooding often is uneconomic in highly fractured reservoirs because of the gross bypassing of the reservoir oil by injected water. Imbibition and pressure pulse flooding have been used in at least one fractured reservoir in an attempt to achieve better oil recovery performance. This paper presents the results of laboratory flow tests conducted on large cores to evaluate the possible applicability of these methods (particularly pressure pulse flooding) to different types of reservoir systems. Test data were obtained on both water-wet and oil-wet systems, and on systems having two widely different levels of compressibility and flow capacity. Results indicate that pressure pulse recoveries from fractured reservoirs will likely not exceed 5 to 10 per cent pore space with maximum response achieved during the first pulse cycle. Improved recovery by this method is possible from both oil-wet and water-wet reservoirs. Comparable saturation distributions during imbibition and pressure pulse production suggest that an initial pressure pulse cycle to speed production response would not interfere with subsequent imbibition flooding in water-wet reservoirs. INTRODUCTION There is a steady increase in the number of fluid injection projects being initiated each year to improve oil and gas recovery over that obtained by primary production mechanisms. Experience gained in different geographical areas and with different recovery methods is teaching that reservoir anatomy is one of the more important factors controlling the success or failure of such projects. Fractured formations appear to be the rule rather than the exception, especially in carbonate reservoirs. Conventional methods of fluid injection, whether it is waterflooding, gas injection or miscible flooding, have limited applicability to highly fractured reservoirs because of the severe bypassing of reservoir fluids. The result is early breakthrough of the injected fluid and rapidly increasing ratios of injected to in-place fluid with an undesirable effect on return on investment. Thus, innovations to conventional methods must be developed if recovery from fractured reservoirs is to be optimized. One new method proposed for application to highly fractured reservoirs is pressure pulse waterflooding. Although pressure pulsing with gas has been suggested' and rested in at least one reservoir; the Sohio Oil Co. is generally credited with the development and testing of pressure pulsing in conjunction with waterflooding. Publications" of Sohio's waterflood operations in the Spra-berry Trend indicate that the idea for pressure pulse flooding evolved from a critical analysis of the disappointing early performance of their flood initiated in a portion of the trend in April, 1961. This flood was planned to take advtantage of imbibiltion and high pressure gradients across the reservoir matrix blocks (unfractured Mocks of the reservoir rock which are visualized to be generally surrounded 'by the fracture system) evaluated in pilot tests by the Atlantic Richfield Co.5 and Humble Oil & Refining Co.' However, the early recovery and pressure performance of this flood indicalted that high pressure gradients induced between the fracture system and the centers of the matrix blocks were forcing water into the periphery of the blocks and temporarily interfering with the counter-current flow of oil due to imbibition. Fill-up in the blocks was occurring with re-solution of the free gas phase as pressures climbed above the original reservoir bubble point. It appeared that cessation of water injection to permit the capillary forces to become dominant and that expansion of the rock and its contained fluids during pressure reduction might aid in expulsion of oil from the rock matrix into the fractures. Subsequent production performance. aflter cessation of injection, proved this hypotheslis correct. Thus, pressure pulse waterflooding was born. Pressure pulse flooding appears to have several advan'tages over imbibition type flooding in highly fractured reservoirs. First, all wells may be used for water injection which should hasten fill-up and achieve a more rapid increase in reservoir pressure. Second, because of increased injection pressures and rates, flooding gradients will force water into the reservoir matrix more rapidly than would be achieved by imbibition alone. Third, during the pressure depletion cycle of the flood, the compressibility of the system, which has been increased by resolution of the free gas phase, provides energy for the displacement of oil at a rate greater than would correspond to countercurrent flow during imbibition. Fourth, during depletion all wells may be put on production, thus contributing to higher oil withdrawal rates on a reservoir-wide basis. One possible disadvantage of pressure pulse flooding as compared to imbibition floodling, however, is that the outer periphery of each matrix block is flooded to a residual or near residual oil saturation during the Water lnjection stage. This zone of reduced permeability to oil m'ay offer greater restriction to the production of

Jan 1, 1967

By Jose Luis de Valle Alonso

Although present electrolytic zinc manufacturing processes are aimed at the direct wet process recovery of the metal, and, with this end in view, several industrial scale patents have been applied for during the last few years, the object of this paper is to enhance the possible metallurgical interest in the conventional recovery of zinc and other metals from leaching residues. Therefore, its main end is the description and discussion of the recovery process of zinc, lead and cadmium from leaching residues. Fundamentally, the process consists of the following: Flotation processing to recover the non-roasted blende still contained in the residues. Pyrometallurgical processing of flotation tails in low-shaft furnaces (kilns) and open-flame rotating furnaces and the ensuing recovery of zinc, lead and cadmium as a mixture of their oxides through volatilization.

Jan 1, 1970