Search Documents

By K Belanger, J. Mclachlan, F. Stober, G. Norval, B. Snider, A. Munsch, T. Koehler, E. Piantino, J. Carlos Queiroz

The project to rebuild the smelting furnaces at the Anglo American - Barro Alto ferronickel smelter, located in Goias, Brasil, was initiated in September 2013. To optimize the capital cost, while maximizing furnace integrity and robustness, a design basis giving flexibility to ore composition variation was developed in order to ensure sustained nameplate production. The resulting capital efficient, fasttracked project execution was accomplished through the creation of an integrated project team of Anglo American and Hatch through FEL 3 and FEL 4 phases of the project. The integrated team addressed the project challenges through a cooperative and versatile approach, created by access to knowledge, experience and systems in both Anglo American and Hatch. The team could operate at an optimized speed of execution, as demonstrated in the FEL 3 and FEL 4 completion durations, as well as efficiently mitigating any risks of increasing cost or delaying schedule by utilizing lessons learned and team knowledge from Anglo American on the original green-field project and Platinum smelters and Hatch on similar reference ferronickel furnace rebuilds. Other critical drivers of project cost minimization and revenue loss/generation (considering production revenue of each furnace) are scheduled durations for construction, commissioning and ramp-up. The integrated team commenced construction, commission and ramp-up planning almost one year in advance of the shutdown and this paper will discuss the strategies developed to reduce risks and optimize the construction schedule to mitigate revenue loss and optimize ramp-up time to sustained operation at nameplate capacity.

Jan 1, 2015

By Ji-He Wei

The ESR of Cu-Cr-Zr alloy has been experimentally investigated. The remelting experiments have been carried out with different slag fluxes in the Cal, + Nal, CaF2 + ZrO2 and CaF2 + NaF + ZrO2 systems on an ESR furnace of 25kg capacity; using a water-cooled copper mould of 96.5 mm diameter, with the forged square bar electrodes of 50x50 mm2. The slag amount was taken to be 1.5 kg. The remelting current and voltage used were 1600-1800A and !5-25K, respectively. The influence of the slag composition on the stability of the remelting process and the losses of alloying elements (2r and Cr) has been considered and examined. The technologies of hot working and heat treatment of the ES ingot have been described and discussed. Some physical properties of the slag in a CuF2 + NaF + ZrO2 system and the remelted Cu-Cr-Zr alloy have been determined. The results indicated that with the slag flux of CaF2 + NaF + l0 mass % ZrO2 and the other operation parameters employed, a high quality ingot of Cu-Cr-Zr alloy may be obtained at the considerably high yields of Zr and Cr by means of ESR. For the remelted Cu-Cr-Zr alloy with a specified composition of 0.5 mass % Cr and 0.1 mass % Zr, the appropriate electrical conductivity, hardness and softening temperature are as high as 45-46S/m, HRB 82-84 and 550°C. respectively. The properties of the Cu-Cr-Zr alloy products are in accordance with and superior to the requirements and specifications of ISO5l82-l99l(E).

Jan 1, 2000

(Members are urged to send in for this. column any notes of interest concerning themselves or their fellow-members.) Members and guests who called at the Institute headquarters during the period Sept. 10, 1916 to Oct. 10, 1916. Arthur K. Adams, Chanaral, Chile. C. F. Moore, Salt Lake City, Utah. Hiram W. Belnap, Washington, D. C. L. D. Moore, Providence, R. I. E. A. Bridgman, Seattle, Wash. George A. Morrison, Chicago, Ill. D. W. Buckly, Wallace, Idaho. Pablo Ortega, Havana, Cuba. G. L. Carlisle, Jr., New York, N. Y. L. W. Paige, New York, N. Y. Ernest H. A. Cohen, Johannesburg, So. Africa. Charles Petzel, New York N. Y. A. Faison Dixon, Camp Rio de Oro, Venezuela. C. A. Pierce, Patagonia, Arizona. Charles E. Dutton, Goldfield, Nev. W. E. Pomeroy, El Paso, Texas. D.-F. Hewitt, Washington, D. C. George S. Rice, Washington, D. C. . James E. Howard, Washington, D. C. G. J. Schofield, Seattle, Wash. A. 0. Ihlseng, Joplin, Mo. Warren D. Thompson, New York, N. Y. I. Ishikawa, Niagara Falls, N. Y. M. M. Valerius, Tulsa; Okla. Montrose L. Lee, New York, N. Y. G. B. Waterhouse, Buffalo, N. Y. V. H. McNutt, Billings, Mont. Joel H. Watkins Washington, D. C. Benjamin L. Miller, So. Bethlehem, Pa. H. P. Wherry, Chicago, Ill. Arthur K. Adams has left for Chile, where he will act as geologist for the Andes Copper Co., a subsidiary of the Anaconda copper company.

Jan 10, 1916

By F. Habashi

The changes that took place in China between 1984 and 2004 are remarkable. Visits were made to universities, research institutes, metallurgical industry, and many cultural centers within five trips during this twenty years period. The impressions of these visits are outlined.

Jan 1, 2007

The southern portion of the Swan Coastal Plain, a geomorphological element formed since late Tertiary times, contains commercially exploitable accumulations of ilmenite, zircon, rutile and monazite associated with a series of raised shorelines. The location of the deposits is controlled by a locally outcropping Archaen granite/ granulite complex and a sea current pattern determined by local geography and a prevailing wind direction. A progression from medium to high titanium ilmenite is evident parallelled by progressive leucoxenisation as the age of the deposits increases. Variations in trace element content accompany this process. Circulating groundwater has caused vertical mineralogical variations within individual deposits and by precipitation of iron has formed layers of hardpan.The Geographe Bay deposits are of important economic significance.INTRODUCTIONObservations made during the course of a brief survey of the southern portion of the Swan Coastal Plain provide an outline of the geology and mineralogy of the mineral sand deposits of the area. This preliminary study will require considerable modification in the light of more detailed work in the future.REGIONAL GEOLOGYThe Geographe Bay area is situated in the south-west corner of Western Australia between longitudes 115° O'W. and 116° O'W. and latitudes 33° 15'S. and 33° 45'S.The general geology of the area is shown in Fig. 1 where the control of the physiography exercised by the Cape Leeuwin-Cape Naturaliste basement ridge is readily apparent. Between this ridge and the Precambrian east of the Darling fault lies the southern part of the Perth basin which contains outcropping Jurassic to Recent sediments and lavas (McWhae, et al., 1958).The Leeuwin-Naturaliste ridge is the exposed portion of L Assistant Production Managcr. Laporte Titanium (Aust.) Ltd.

Jan 1, 1964

By Fabien Miller

Automation technologies are increasingly envisaged to improve underground mining productivity. However, the technologies need to be used and adopted gradually in order to get the best benefits. This paper presents the technical and operational aspects of autoguided production vehicles at Brunswick Mine. During 2001 Noranda?s Brunswick Mine has successfully commissioned an automated haulage zone where two optically guided trucks transport ore from a remotely operated chute to two orepasses. Operational advantages include increased system capacity and enhanced safety and comfort for the operator. The data obtained up to now indicate that the system can operate reliably in mine production

May 1, 2002

By B. Larsen, S. Z. Nascimento, K. Fidje, J. P. M. Amaro, H. Gran

Safe and good operation of Søderberg electrodes is dependent upon high quality electrode paste coupled with correct electrode operating procedures. Good electrode performance depends further on proper melting and densification of the electrode paste. The melted paste should form a dense and viscous layer that prevents gasses from the baking process to move upwards. Both paste cylinders/blocks and briquettes can be used, but the procedures may differ between the various types of paste products. For briquette columns the formation of the important viscous layer is obtained through melting and densification of the briquettes. By basic rheological studies of electrode paste and by laboratory tests of briquette beds at isothermal conditions we have achieved a better understanding of the melting process. The effects of temperature gradients, pressure and friction between the briquettes and the electrode casing have also been evaluated qualitatively in pilot scale experiment and in industrial scale tests. The paper shows that melting and densification starts at a considerable lower temperature than the pitch softening temperature. It is concluded that the formation of a briquette electrode column depends on parameters as temperature, briquette column pressure and the friction. Operating conditions influencing the above parameters should be defined and established for each specific furnace operation. Such factors are e.g., charging and slipping procedures, column heating and electrical conditions.

Jan 1, 2004

By Michael Cianchetti, Nadir Ansari, Matthew Janes

"PROJECT DESCRIPTIONThe R C Harris Filtration Plant underwent an expansion to install an underground sludge treatment capability consisting of a series of underground tanks within stepped excavations 12m (39 ft) and 10m (33 ft) deep into compact, wet sands over stiff clays and clayey silts.Concerns regarding the original structure influenced designers to set the lateral deflection limit for the proximal front footing at 4mm (1/6 in), (0.03% excavation depth). The design-build team indicated at the time of tender that the movement criteria was unattainable using the tender design. Through extensive Fast Lagrangian Analysis on Continua (FLAC) and a novel construction geometry the design-build team crafted an alternative that produced significant savings over the original concept and met deflection concerns.GEOTECHNIQUEThe hillside site drops 14.5m (47.6 ft) over a distance of 53m (174 ft) between the existing Filter Building on the north and the Services Building on the south. The soils adjacent to the Filter Building consist of 6m (20 ft) of sandy fills, to the footing elevation, over compact sands and layered dense sands and silts to a depth of 10m (33 ft) below existing footing. Beneath the silts lies a 10m (33 ft) thick stiff clayey silt, 2m (6.6 ft) of sandy silt till (containing cobbles and boulders) and an artesian gravelly sand at a total depth of 30m (98.5 ft).The tender information was deemed inadequate to accurately determine soil parameters for a finite element analysis. As a result, the design-build team performed pre-tender Cone Penetrometer Testing (CPT), including dynamic analysis. The CPT data indicated stratigraphy consistent with the conventional bore hole exploration (SPT results) however, the CPT data provided consistently superior soil strengths. The CPT data indicated the sands and silts were dense to very dense throughout their full thickness. The clayey silts below the sands were found to have shear strengths in the 100 to 200 kPa (14.5 to 29 psi) range with an Over-Consolidation Ratio (OCR) ratio of 1.5 to 2. The dynamic analysis, while low strain, indicated very competent behavior with Young’s Modulus values in the 200 to 350 MPa (29,000 psi to 51,000 psi) range. The CPT derived shear moduli and OCR values were vital in determining the soil engineering parameters used for the FLAC analyses."

Jan 1, 2007

By John B. Wright

This paper describes laboratory techniques and subsequent results of Bureau of Mines research to produce chlorination-grade feedstock from an abundant, low-grade, domestic, rock ilmenite ore. The research is part of the Bureau-effort to devise technology that may help decrease U.S. dependence on imported raw materials. A rock ilmenite containing about 46 wt pct Ti02 was smelted in an electric arc furnace with coke, woodchips, and Na2C03 to separate most of the iron as pig iron and to form a low-iron, titanium-enriched slag. The slag was ground, pelletized, oxidized, and then sulfated with mixtures of SO2 and air in a continuous 4.5- to 9.1- kg/h apparatus at 1023 to 1223 K. The sulfated slag, containing 60 to 65 pct TiO2, was reground and leached in water at ambient temperature to decrease the combined levels of the troublesome Ca, Mg, and Mn impurities from 7.0 to 1.7 wt pct. At levels of more than 3 wt pct, these impurities contribute to operating and disposal problems, The final product was upgraded to about 84 wt pct TiO2. This material potentially is suitable for chlorination in a fluidized-bed reactor. The most favorable results were achieved with leached slag sulfated at a feedrate of 4.5 kg/h and at temperatures of 1073 to 1123 K.

Jan 1, 1984

By Akira Tsune, Shingo Sugimoto, Tadayuki Ishiyama, Nadao Saito, Masatsugu Okazaki

"The Deep Ocean Resources Development Co. Ltd. (DORD) of Japan signed a 15-years contract with the International Seabed Authority for exploration of polymetallic nodule in a 75,000 km2 area, consisting of West and East Areas in the Clarion and Clipperton Fracture Zone in 2001. The exploration work is now concentrated in resource estimation of the first generation of mining area, the High Abundance Area.A detail survey of the Model Area, set in the High Abundance Area, was conducted using AUV (Autonomous Underwater Vehicle) equipped with MBES (Multi-Beam Echo Sounder), SSS (Side Scan Sonar), Sub-Bottom Profiler (SBP) and still camera. The seafloor topographic map based on 1 m grid data was produced in an area of approximately 80 km2 (Figure 1). Photographs, continuously covering the seafloor taken by AUV along two west-east trending traverse lines, together with detail seafloor topographic map produced from MBES give an excellent opportunity to observe distribution manner of pollymetalic nodule related to topographic features. This helps to understand more accurate resources estimation of a whole area of the High abundance Area. Furthermore, information of micro-topography gives ideas for conducting ore collecting operation and designing ore collector."

Sep 1, 2014

By Ted Klemetti

Roof deterioration in weak moisture-sensitive rock leads to roof falls in coal mines. An observation site was set up in intake air at an underground coal mine in central Ohio to evaluate the time-dependent deterioration of moisture-sensitive roof rock. By periodically collecting and weighing the rock falling from the roof, the National Institute for Occupational Safety and Health (NIOSH) was able to quantify the deterioration of the moisture-sensitive shale roof. The measurements showed that more roof rock is falling in the dry winter months. Movements in an intersection were monitored in order to determine if deformation correlated with seasonal changes in temperature and humidity. The rate of intersection roof-to-floor convergence was found to be cyclical and related to seasonal changes, with more convergence during the months of April through September. At the study site intersection, the roof beam did not show deflection indicating movement most likely due to mine floor deformation. The bolt load also increased in the warmer months before shedding load, possibly due to rock failure. Temperature and relative humidity sensors, placed in holes in the roof show that mine air does not mix with the air in the holes. Consistent saturation levels of relative humidity were measured in the holes and it appears that high levels of moisture may have migrated into the bolt holes from roof shales. A roof sealant applied to a portion of the test roof appears to be preserving the roof and reducing the amount of rock fall into the entry, while the screened area virtually eliminated rock falling from the roof.

Jan 1, 2009

By B. C. Allen

Grain-boundary gvoocing was studied irz chronziu?n. molybdenum, tungsten, and the solid-solution alloys, Cr-35Re. Mo-33Re, and W-25Re at 0.6 to 0.9 of the absolute liquidus temperature under an inevt atmosphere , foveign nzetal zlapor, and liquid metal. The controlling mechanism of matter transport was deduced frolr groove size and shape. kinetics of growth, and cotnparisoz with theoretical relatiotzships derived by Mullins. Grooves in chowzizon formed prittzarily by volume diffusion tkrongk kelium or argon at 1 atm pressure and by e1)apovation-condensatiotz in a static vacuum. Groozles in the other nzetals and alloys forrned priniarily by sirface diffusion, the coefficients of which were calculated. Carbon was found to decrease the acti7:ation energy for surface diffusion on molybdenun. Sitrface diffusizities weve sinzilav for iWo-0.0ZC and Mo-33Re. The presence of about 1 -?nm pressure of silver or tin vapor did not affect the neckanis)n of grooz;e formation. In liquid titz or silz:er, pain bolindary gvooves formed by zolume diffusion in the liquid. BASED on theories of ullins," the mechanisms of grain-boundary grooving have been determined for low-melting metals such as copper in an inert atmospheres or in liquid lead.4 The purpose of this investigation was to study grain-boundary grooving in the refractory Group VI-A metals, chromium, molybdenum, and tungsten, and the bcc solid-solution alloys, r-35e, 0-33e,= and -25e,' at 0.6 to 0.9 of included to see whether Mullins' theories were applicable to them as well. EXPERIMENTAL WORK The materials chromium, molybdenum, tungsten, Cr-35Re, Mo-33Re, and W-25Re were in the form of 0.050-cm-thick sheet assaying 99.98 pct or better. The nominal carbon level was generally 30 ppm. The oxygen + nitrogen + hydrogen content was -50 ppm. Mo-33Re and W-25Re were prepared by powder-metallurgy methods and supplied by Chase Brass and Copper Co. The remaining materials were arc-cast. Chromium and Cr-35Re were prepared at Battelle by arc melting, extruding, swaging, and rolling. Mo-0.003C was supplied by Climax Molybdenum Co., and Mo-0.02C and tungsten by Universal Cyclops Corp. As a source of liquid metals, tin and silver granules assaying 99.98 pct were used. Spectrographic analyses indicated the presence of -100 ppm each of iron and silicon. Vacuum melting reduced the combined gas content to c5 ppm (2.60,, 0.9N2, 0.4H2 in tin and l.602, 0.7N2, and c0.04H2 in silver). Specimens were prepared for grain-boundary grooving. Coupons 0.5 by 1.5 cm with a small hole in one end, or substrates 1.5 by 1.5 cm, were cut from sheet. The specimens were annealed in containers of the same material to provide a vapor-solid equilibrium as well as to protect them from gaseous impurities. Outgassing was done at 2 x 10"5 mm for 15 to 30 min at 1150°C for chromium and Cr-35Re, 1750°C for molybdenum and Mo-33Re, and 2600°C for tungsten and W-25Re. Then recrystallization to a stable grain size of about 0.5 mm was accomplished by annealing at least 1 hr at 1600°C for chromium, 1800°C for Cr-35Re, 2350°C for molybdenum, and 2300°C for Mo-33Re in a rhenium-element resistance furnace under 1 atm of static argon or helium. The atmosphere was gettered by tantalum radiation shielding. Tungsten and

Jan 1, 1967

By S. S. Todd

[The purpose of this investigation was to obtain, heat-of-formation values a four Common titanates and, to conjunction with other requisite data, to derive free-energy-of-formation values In tem peratures in the range of 1,600°-1,800° K. T ht four titanites are tricalcium ?ditanite !['a¬spheremr?raritanar( rint-tir.rniurn rill( 1 This rc rr,rt sul,rlc?nu?nIs :r },r; vinu~ hul,lrc.irse,n3i n wlti h eht-rmnnIN-ti i n c {ar.a ai?rc? pu -,csseeri (or, 11 in(c-rnxiLIic co mrc+unrls conraininL~ rir:,niurrl. 'f Lac? !1~:)mc? c?xpcrirnc'ntnl n-ut rhod w,i. rna~loycul. lic?.ats of for rn:ltion of rlre comi?c,unr4~ it 29S.N. ut re mca,urc?,l by tioItl[ion e':iIorrr)utrv, using a ctrneaR }ryrlrc,fllanric-hY rir~chlorie- ,aci l mixttrrt .is rhr c-zle~rinrrrric- fluid and rc.actic~n rtu,liura}.]

Jan 1, 1956

By Laurens de Jonge, Wiebe Boomsma, Rodney Norman, Stanislav Verichev

"Earth provides natural resources, such as fossil fuels and minerals that are vital for human life. As the global demand grows, especially for strategic minerals, commodity prices rapidly rise. Thus there is an identifiable risk of increasing supply shortage for minerals. Hence a major element in a long-term economic strategy must be, to ensure security of supply for these strategic minerals. In this rapidly changing global economic landscape, deep sea mining has gone from a distant possibility to a likely reality within just a decade.Although deep sea minerals extraction was investigated in the 1970’s, it was abandoned because of changing commodity economics, advances in on-land exploration techniques, growing concern on environmental impact, and political and legal aspects with regard to ownership issues. The developmental data from those days, if still available, are not adequate to allow engineering and building of an integral system for extraction of deep sea minerals without additional R&D work. Thus, deep sea mining is yet to attain a Technology Readiness Level (TRL) sufficient to successfully undertake deep sea mining operations, from resource discovery to resource assessment and to resource exploitation [Blue Mining, 2014]."

Sep 1, 2014

By Robert B. Hopler

Explosives, originally used only in fireworks and warfare, became legitimate contributors to human progress when miners in Eastern Europe began using them to break rock in the early 1600%. Since that time these powerful materials have had a dual role in the world: as agents of destruction in war, and as irreplaceable tools necessary to advance civilization. In the latter role, they serve as agents to enable mankind to produce metals, build roads, and drive tunnels. In other words, to provide those materials, services, and infrastructure without which the modern world could not exist.

Jan 1, 1997

By Y. Özçelik

Rocks show a variety of engineering and physical properties that affect typical quarry operation such as diamond wire cutting in the marble quarry. The physical and mechanical properties of rocks depend on their mineralogical and petrographical characteristics. The purpose of this study is to investigate the effects of mineralogical and petrographical properties of a rock, such as grain size and mineral content, and how these affect the wearing of diamond bead and cutting rate in a diamond wire cutting operation in a marble quarry. Statistical analysis is used to carry out the study. Three different rock types were examined, namely, hard rock (andesite) and softer rocks like limestone and marble. The study revealed that the mineralogical and petrographical properties of the rocks, such as percentage of quartz, biotite, plagioclase, matrix minerals, and opaque minerals, are important. In addition, the grain size of quartz and plagioclase in andesitic rocks and calcite grain size for carbonate rocks significantly influenced the wear rate and cutting rate in diamond wire cutting operations.

Jan 1, 2005

MONDAY, FEB. 17 9.00 A.M. to 9.00 P.M. Registration at Institute Headquarters. 9.00 A.M. Meeting of Committee on Development of the Activities of the Institute, Room 905, 9th Floor. 10.00 A.M. Simultaneous Sessions of Institute of Metals Division, Room 2, 5th floor. Industrial Organization, Room 1, 5th Floor. 12.30 P.M. Luncheon at Headquarters, 5th Floor. 2.00 P.M. to 4.25 P.M. Simultaneous Sessions of Institute of Metals Division, Room 2, 5th Floor. Industrial Organization, Room 1, 5th Floor. Petroleum and Gas, Room 905, .9th Floor. 2.30 P.M. Sightseeing trip by automobile for the ladies. Among the points visited will be: The American Museum of Natural History. The Episcopal Cathedral of St. John the Devine. The Spanish Museum. The American Geographical Society. The American Numismatic Society. The visits will be followed by Tea. 4.30 P.M. Memorial Service to Dr. Rossiter W. Raymond, Auditorium. 8.30 P.M. Smoker, 5th.floor.

Jan 2, 1919

Fig. 4 and 5 of the paper 'The analysis of ventilation and cooling requirements for mines' by J. van der WaIt, E. M. de Kock, and L. K. Smith are positioned incorrectly in the February issue (J.B. Afr. Inst. Min. Metal., vol. 83, no. 2, Feb. 1983). Extractive metallurgy of zinc At a professional development seminar to be held in Montreal (Canada) from 18th to 22nd April, 1983, specialists from industry and university will discuss the extractive metallurgy of zinc from ore to finished metal with special emphasis on the theory and practice of modern technology.

Jan 1, 1983

By Joachim Klein, Frank Reimann

Nodular-graphite cast iron (GGG) is a material similar to steel, and one which exhibits excellent properties, in particular for components exposed to pressure. GGG cast iron has been used in many cases when sinking mine shafts with conventional tubbing. With linings made of cast iron tubbings (the backfill concrete is not integrated into the calculations, and merely serves as bedding) the properties of the cast iron can be made full use of, provided the tubbing is made to the appropriate cross-section. Calculations have shown that better static values can be arrived at when using cross-sections other than those of tubbings made to conventional German standard. The cross-sectional design of the new types of shaft lining made from GGG is to be developed on these lines irrespective of the cast iron structure being only stressed component or its restistance function being combined with the one of concrete. GGG 50 is used for the first time to make the reinforcing inner liner of a main shaft currently sunk in Germany. The physical properties of nodular-graphite cast iron, strength and deformability, suggest that, in the future, its application will not be restricted to shaft support but also in tunneling. New moulding techniques with better three-dimensional modelling resulted in new tubbing designs as installed e.g. for the Hannover underground at present. Shield-driven tunnels have to withstand earth and water pressure, apart from axial machine loads. In this field time is money as well. Therefore easy handling and quick installation are necessary for successful, use. Last but not least, safety is of first-order importance for work in shaft sinking and tunneling. Cast iron lining systems, accordingly, are adequate systems, in particular for excavations underneath water for transport systems and for goods and passengers.

Jan 1, 1987

By Y. De Gao, C. Gang Zhong, X. Yang Qiu, Li Wan

The chelating reagents are used as effective collectors in wolframite flotation, and certain metal cations need to be added using chelating collectors so as to activate valuable minerals and obtain good flotation indexes. Different metal cations will result in different reactivity with collectors, in order to select the effective activator in BHA flotation of wolframite, the activation effectiveness of different metal cations on wolframite ((Fe,Mn)WO4) flotation were studied using pure minerals. The results showed that the wolframite activation by Pb2+was the best among the selected cations. The maximum flotation recovery of wolframite was found to be 95.58 % under conditions of 100mg/LBHA and 1×10-4mol/L of Pb2+at pH 9. The dosage of Pb2+needs to be controlled in an optimum range. Also, the activation mechanism of Pb2+ on BHA flotation of wolframite was investigated by measurements of contact angle, zeta potential, adsorption capacity and IR spectroscopy. It was found that Pb2+ could chemically adsorb onto the wolframite surface improving the flotability of wolframite and enhancing the adsorption of BHA on wolframite. When the dosages of BHA and Pb2+ were 100 mg/L and 1×10-4 mol/L, the adsorption quantity of BHA on wolframite sharply increased up to 0.30 mg/L at pH 9 compared with wolframite treated with only BHA.

Jan 1, 2014