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By F. J. J. van Loo, J. K. Kivilahti, M. Paulasto

"Activation mechanism and interfacial reactions in brazing of ShN4 with different AgCuTi filler alloys has been investigated thermodynamically and experimentally. During brazing the AgCuTi filler alloy is divided into two liquids Ll and L2, where the (Cu,Ti)-rich liquid L2 gathers at the ShN4 interface and reacts with it. The concentration of Ti in L2 is high, but due to the strong attractive interaction between Cu and Ti, the activity of Ti in L2 is considerably low. In reaction between ShN4 and Cu-containing brazes a Ti-Cu-Si-N compound is typically formed at the interface. In absence of Cu, in joints brazed with AgTi based filler alloys, extremely Ti-rich solution reacts with ShN4 and as reaction products TiN and TisSh[N] are formed. IntroductionAdvanced ceramics like silicon nitride are increasingly used as structural components in demanding applications as well as in electronics industry. Complex, multicomponent structures for engineering applications generally require interconnections and therefore joinability of ceramics largely determines the possibilities of metal-ceramic structures to enable demanding functions. Brazing with active filler metals, most of which are based on the Ag-Cu-Ti system, has been commonly employed for joining of ShN4 to other ceramics and metals. The interfacial microstructures formed when ShN4 is brazed with Ag-Cu-Ti braze alloys have been discussed in several recent studies [1-7]. However, some inconsistencies exist in the reported results. The formation of layers of TiN and titanium silicides, possibly TisSh, next to the ShN4 has been reported in several studies [1-5], while in another investigation, a layer of an orthorhombic TiSi- Cu-N phase was found beyond the TiN layer [6]. In few investigations the thermodynamics of the ShN4-Ti system has been considered, but no detailed thermodynamic analysis of the chemical interactions between the braze and ShN4 has been provided. In order to resolve which chemical reactions are possible under various joining conditions and thereby to be able to control the brazing of ShN4 the reactions in brazing has to be studied using both microstructural and thermodynamic analysis."

Jan 1, 1996

By Rudolf E. Greuer

Every mine contains inflammable materials, either in form of the minerals mined or in the form of brought-in supplies. Although great efforts are made to make mines as far as possible fireproof and to prevent ignition sources, the possibility of mine fires, like that of other accidents, will always continue to exist. Detailed statistics are available for coal mines. They show (65,112) that the number of major mine fires in the USA over the last 20 years has remained more or less constant with approximately 50 per year. The same number is reported (26) for the British coal mines. Other countries (147) report about 1 major fire for every 10 million tons of coal production. Conflicting data are published on the number of fatalities caused by fires, presumably because frequently deviating opinions on the cause of death exist. On the average (82,99) 4 miners are killed per year in the US and in the British coal mines. Although this number is much smaller than that for several other causes of fatalities, one must keep in mind that almost every small fire can develop into a large disaster.

Jan 1, 1973

By Ed Billington, Mike Shields

The trail blaster is faced with a wide range of workrelated challenges, not the least being the work setting itself. It is usually remote, being anywhere from 5 to 30 or more miles (8 to 50 km) from any road. It may be in mountains, high rock desert, or coastal rain forest, and can range from sea level to over 12,000 feet (3700 m) in elevation. The blaster may be part of a 2-person clearing crew, a 4-person maintenance crew, or a 10-person construction crew. The crew will usually be mobile, moving and working up to 10 miles (16 km) or more per day, relying mostly on their own backpacks to move camp, tools and supplies from site to site. Periodic resupply may be by helicopter, aird rop, or even “sherpa” groups, but most often will be by packstrings of horses and mules. The crew goes into the backcountry a n y w h e re from two weeks to three months at a time, and while there, its members “live the job” 24 hours a day, enjoying baking heat, torrential rain or mid-July s n o w s t o rms along with the truly glorious weather that c o m p e n s a t e s . So who is this blaster? Well, “he” may be she, since some of the top trail blasters are women. He/she will also be more than a blaster: Crews are small, so experienced members must be capable of handling the full range of trail work. Thus this blaster is also a driller, and usually also a bucker, snag faller, rigger, dry-stone mason, log and timber carpenter, bridge builder, mule p a c k e r, small-engine mechanic and, not least, camp cook capable of putting out a hot meal from a campfire , in a downpour, in the dark. Being in remote locations, often without reliable communication to the outside world, trail crews enjoy a remarkable degree of independence from “supervision.” With that comes the responsibility to make sound decisions which expedite the work, while promoting crew safety and welfare .

Jan 1, 2004

By N. Kumar Kittusamy

A field study was conducted to evaluate seat designs on shuttle cars. Eight operators participated in evaluating seat designs on the basis of perceived levels of vehicle jarring/jolting and discomfort. Researchers also measured the levels of vehicle jarring/jolting. Four basic seat designs were compared on low and mid-coal seam shuttle cars during production operations at two underground coal mines. Two seats were currently used on the shuttle cars and another two were NIOSH designs. Objective data were collected using accelerometers with pre-amplifiers and filters connected to a data recorder; whereas subjective data were gathered with a visual analog scale (VAS) and a questionnaire. Results from measured levels of jarring/jolting showed that the NIOSH Seat L2A smoothed out bumps better than any other seats. Using the VAS, mid-seam and low-seam shuttle car operators rated the levels of jarring/jolting and discomfort lower with the NIOSH seat than the other seats. Questionnaire responses indicated that operators rated NIOSH seat designs as more comfortable. This research will provide the industry with better seat designs for isolating jarring/jolting in vehicles. Furthermore, researchers plan to improve the NIOSH seats using information gathered in this study.

Jan 1, 2003

Analysis for pillar extraction potential (A-PEP) is an intelligent tool, which could be used as a preliminary output indicator when considering the secondary extraction of regional support pillars in the Witbank and Highveld coalfields of South Africa. The safe and economic extraction of underground coal pillars is of paramount significance and importance to the South African coalmining industry to ensure continuity of supply of this fossil fuel. Pillar extraction practices in South Africa have been responsible a significant proportion of safety and fatality statistics in relation to its relative output (less than 5 per cent of total South African coal production) and, as a result, research was undertaken in local pillar extraction operations and extended to similar operations in New South Wales, Australia to assess a way forward for pillar extraction in South Africa. It was found that, although little in the way of new technologies has emerged in this field in the recent past, significant contributions could be made in the field of risk analysis to obtain a generic design methodology for pillar extraction in South Africa. The resultant A-PEP tool to assess pillar extraction potential is based on certain physical, risk and economic factors, which combine to indicate operational success in terms of economic, health and safety attributes. At the time of A-PEP?s development there was alack of operating underground coal pillar extraction operations, which made it difficult to validate its applicability. Since then, however, A-PEP has been successfully tested and validated against two unique underground coal pillar operations, which is the discussion of this paper. One operation is situated in the Witbank coalfield and is extracting pillars, which are 20 years old and at a depth of 80 metres below surface, while the other operation is situated in the Highveld coalfield-which is extracting 6 month-old-pillars underneath a massive dolerite sill at a depth of 220 metres. A-PEP has shown that its predictive nature is consistent the workings at both operations, irrespective of their unique conditions, and as such it can be successfully used as a mine planning tool. The A-PEP mine planning tool thus represents a positive step toward an integrated approach to underground coal pillar extraction when considering legal and operational aspects, which could form the basis for legislative guidelines when considering the future of pillar extraction in South Africa.

Jan 1, 2005

By André Desbiens, Jocelyn Bouchard, René del Villar

"The metallurgical performance of the column flotation process is determined by the concentrate grade and recovery. Although the former can be continuously measured using an on-stream analyzer, the latter must be estimated by a material balance calculation based on seldom verified steady-state assumptions. Consequently, the automatic control and optimization of flotation columns should be performed using secondary variables having a strong influence on the metallurgical performance, such as froth depth, gas hold-up or bubble surface area flux and bias. The aim of this paper is to present a model-based automatic control strategy using froth depth and bias measurements obtained from virtual sensors developed at Laval University. Preliminary pilot plant results on two-phase (water– air) and three-phase system (water – minerals – air) will be presented and eventual industrial implementation of such a strategy as well as the possibility of achieving effective real-time optimization from bias and froth depth measurements will also be discussed.INTRODUCTIONFlotation columns have been widely studied and used in mineral processing for about twenty years. Although a great deal of work has been accomplished to understand the influence of different variables such as froth depth (H), bubble surface area flux (Sb) and bias (Jb) on the metallurgical performance, the measurement of some of these variables is still difficult to be performed – except at the laboratory level – because in most cases, no commercial device yet exists.As a result of this, it is almost impossible to achieve neither efficient control nor optimization of the process at the industrial level, even in open-loop operation. This paper aims at presenting a simple control strategy of froth depth and bias. Description of the sensors used to achieved measurements, preliminary pilot plant results for froth depth control, eventual industrial applications and possibilities for process optimization are also treated."

Jan 1, 2003

By James J. Graham

Uravan, Ambrosia Lake, Gas Hills and South Texas are all historic names in US uranium. These mining areas supplied the uranium that brought the United States into the nuclear age during the 1960s, and fueled the birth of nuclear energy for peaceful uses — a promise of nearly limitless, clean energy for the world’s future. That promise still exists today, but it is hard to hear over the rhetoric of environmental activists and politicians. Nuclear power offers dependable electricity with limited environmental impact at stable prices. Nuclear power releases no greenhouse gases or particulate matter into the atmosphere. High level nuclear waste (HLW), although long lived, is readily controlled and compact. In the United States, generating 1 billion kWh of electricity with coal produces 47 kt (52,000 st) of solid waste (ash and sludge), compared to 3.6 t (4 st) of HLW produced by nuclear.

Jan 1, 2002

By David O. DeGagné

While mine backfill plants are becoming increasingly more automated and instrumented, especially with paste fill operations, underground backfill distribution systems have hardly changed over the years. While fill properties are appropriately measured in the preparation plants, as backfill enters the mine borehole, the technology for control, data gathering and reporting is somewhat lacking. Mines typically experience problems with borehole and pipeline plugging, pipeline bursting, bulkhead failure and exposed fill sloughing. With adequate instrumentation of the backfill system it is possible to obtain a complete, continuous and detailed picture of the entire filling operation from preparation to post-pour. Good data will, over time, provide the basis for needed improvements of backfill systems and will be essential to safer, more efficient and less costly fill practices. This paper will review the areas of the filling operations where monitoring would prove critical to eliminate failures such as pipelines, bulkheads, fill exposures, stope walls, etc. The types of monitoring systems currently available will be reviewed and potential areas for development will be highlighted.

May 1, 2001

The whole of the iron ore required by the Broken Hill Proprietary Company Limited at the Newcastle Steel Works, and Australian Iron and Steel Limited, at Hoskins' Kembla Works, is drawn from the Iron Knob, Iron Monarch, Iron Prince and Iron Baron deposits situated in the northern part of Eyre's Peninsula, South Australia.The Iron Knob and Iron Monarch deposits are near the township of Iron Knob, approximately 42 miles W.S.W. of Port Augusta, whilst the Iron Prince and Iron Baron deposits are some 18 miles due south from Iron Knob, in another group of leases, the adjacent township being known as Iron Baron.The ore mined at Iron Knob, Iron Monarch, Iron Prince and Iron Baron is conveyed on the Company's 3ft. 6-in. gauge tramway to Whyalla, on the western side of Spencer's Gulf, approximately 45 miles south by west of Port Augusta whence it is shipped to Newcastle and Port Kembla.SHORT HISTORY.The establishment in South Australia of the lead smelting industry at Port Pirie, Dry Creek and Port Adelaide in the...

Jan 1, 1937

By T. H. Chuang, Y. Y. Shiue

"Rapid whisker growth was significantly alleviated in a Sn-58Bi alloy doped with 0.5 wt.% La. Experimental results showed that many thin, plate-form intermetallic phases appeared in the solder matrix. The absence of tin whiskers was correlated to the shape effect of RE-containing intermetallic plates. After reflowing, Cu6Sn5 intermetallic compounds appeared at the solder/pad interfaces of Sn-58Bi and Sn-58Bi- 0.5La packages with OSP pads, which grow linearly during the aging at 75 and 100? for various times ranging from 100 to 1000 h. In addition, the interfacial intermetallics layers in Sn-58Bi-0.5La solder joints were also observed thinner than those in undoped Sn-58Bi joints. However, RE-containing interfacial intermetallic compounds in Sn-58Bi-0.5La solder joints led to lower bonding strengths in both ball shear tests (0.4 mm/s) and high speed ball shear tests (2000 mm/s). All the reflowed and aged solder joints of both packages were ruptured through the solder balls indicating brittle characteristic INTRODUCTIONIt has been widely reported that solder alloys doped with rare earth (RE) elements reveal many beneficial effects, such as higher strength, lower melting point, improved wettability, and longer creep life (Wu et al., 2004; Ma et al., 2002; Chen et al., 2002). In addition, Dudek et al. reported that the alloying with 0.5 wt.% La in Sn-3.8Ag-0.7Cu solders resulted in an increase of rupture strain, up to 150% over undoped solders (Dudek et al., 2006). However, Chuang and Yen observed that a large amount of long, fiber-shaped tin whiskers were extruded out of the oxidized CeSn3 intermetallic clusters in the matrix of a Sn-3Ag-0.5Cu-0.5Ce solder air-stored at room temperature for several days (Chuang & Yen, 2006). Furthermore, many coarse hillocks appeared around the CeSn3 clusters in the RE-doped alloy after storage in an air furnace at 150? for several minutes. Chuang proposed a mechanism for the phenomenon of rapid whisker growth, which the predominate oxidation of CeSn3 intermetallics in Sn-3Ag-0.5Cu-0.5Ce solders induced compressive stress and extruded the tin atoms out of the specimen in the form of tin whiskers (Chuang, 2007). However, further investigation showed that Sn-9Zn-0.5Ce solders, after long term exposure at room temperature and 150?, were immune to the whisker growth; the immunity was attributed to the refining of the CeSn3 intermetallic phase in the alloy (Chuang & Lin, 2008). The inhibition of tin whiskers through the refining of rare earth containing intermetallics was further observed in Sn-3Ag- 0.5Cu-0.5Ce solders doped with 0.5 wt. Zn (Chuang & Lin, 2009). In addition to the size effect, the thin plate shape of intermetallic compounds was also shown in this study to inhibit the whisker growth on the surface of Sn-58Bi-0.5La solders."

Jan 1, 2012

Adhesion of Escherichia coli onto Oxide Minerals - Extended DLVO Theory and Flotation Behaviour

Sep 13, 2010

By U. N. Bhrany, N. Arbiter

Over the last one hundred years the problem of assessing the efficiency of energy consumption in producing rock breakage has been studied by many investigators from a variety of viewpoints. Their contributions fall into three main categories: (1) those characterized by a priori assumptions of a relation between the energy required for fracture and the degree of fragmentation produced (e.g. Rittinged(l), Kick(2) Bond(3)); (2) those studying simple systems with controlled energy applications (Gross(4)?(5) ); (3) those treating operating data to develop practical relative measures of efficiency (Coghill(6), Taggart(7)). Closely involved in the efficiency problem is the characterization of size distributions produced by comminution. Unless an experimental size distribution can be approximated by a distribution function and its constants, it becomes difficult if not impossible to develop quantitative energy-particle size relationships. While many such functions have been proposed, none are both completely adequate and convenient. The simpler fonns usually describe only a part of the sizing data, while those which apply to a greater extent are cumbersome(8). The thesis underlying the study here reported can be stated as follows: Size reduction in a tumbling mill subjects ore particles to a relatively constant fracture-producing environment. The intensity of the forces is determined by such factors as the mass of the breaking bodies (rods, balls, rock), and the speed and dimensions of the shell. For a particular ore the extent of size reduction will depend both on the intensity and on the duration of exposure. The latter is the residence time in a batch mill, or is determined by the effective volume and the flow rate in a continuous mill. Size reduction can thus be regarded as a rate process in which the weight of material in size intervals varies as a function of grinding time. Although both the rates of disappearance of coarser sizes and

Jan 1, 1961

By Chris Sammon

The Block 75 portion of the City Creek redevelopment project in Salt Lake City required multiple shoring walls surrounding the 6 acre site constructed to depths ranging from sixty-five to ninety feet below original street grade. Shoring for the project was challenging due to site soils consisting of cobbles, sands and gravels, interlayered lakebed silty clay and fine sandy silt with incised stream deposits of silty/clayey sand and gravels combined with a high groundwater table. Moreover, several abutting structures each with a unique foundation system would be directly or indirectly supported by the shoring system. Three sections of interest are the shoring walls constructed at Main Street, Deseret Trust Building and Eagle Gate Tower. Main Street shoring extended to as much as sixty-five feet below street grade and utilized existing basement walls anchored in place in the upper zones with soil nail walls with pre-installed vertical elements for face stabilization below. Data are presented which illustrates the effect dewatering had on the settlement of the Main Street Shoring. The Deseret Trust Tower shoring supported a 12 story, historical masonry building. Site conditions dictated a separate design for the east side and the north side of the building allowing comparison of relative performance between these walls. Settlements of this structure were controlled by installing micropiles through the 90 year old structures spread footings. Shoring for the Eagle Gate Tower was to be constructed immediately adjacent to a mat supported 22 story high rise structure. This shoring system combined secant piles, ground anchors and incorporated existing abandoned-in-place pipe piles with infilling high pressure jet grouting to create a cutoff wall and eliminate the adverse impacts of dewatering below this sensitive foundation.

Jan 1, 2010

Threshold blasting involves the use of small amounts of high explosive to break and fragment hard rock without having to evacuate mining personnel. The method is easily assimilated and effective in rockbreaking, but requires rigid control on drilling, charging and timing. Current underground trials are aimed at fine-tuning the amount of explosive energy and blast hole geometry to allow the firing of multiple sets of shot holes in a continuous manner. Through correct procedures, the after-blast fumes, dust and fly rock can be contained so as to provide a safe working environment. Threshold blasting hugely reduces the volumes of explosives used in mining and brings to maturity the potential of the process begun by Alfred Nobel when he introduced nitroglycerine, and later dynamite, to mining. Its key contribution is its enabling of continuous mining operations with well understood and relatively low cost technologies. The use of batch blasting, employing large burdens holds the greatest potential for delivering high flow rates of ore at minimal cost. There is good potential for rapid evolution of the concept.

Jan 1, 2002

By Carlos León

El presente trabajo señala el proceso de optimización en la recuperación del cobre y molibdeno en la concentradora de Toquepala. La implementación y desarrollo de la remolienda del flujo de concentrado desarrollan un mayor grado de liberación, y por ende, una mayor recuperación del cobre y molibdeno en el circuito. Asimismo, el descarte de relave OK-50 ha permitido normalizar las recuperaciones de cobre y molibdeno en ciertas secciones de la flotación rougher de la planta, incrementando en la recuperación del cobre de 0.8% y 1.8% en molibdeno. Por ello, es factible mejorar las condiciones de operación de la planta a través del desarrollo de pruebas metalúrgicas llevadas adelante como un esfuerzo conjunto entre todos los integrantes del equipo Concentradora Toquepala.

Sep 13, 2001

By D. I. Smith

Constructing tunnels in congested urban areas requires tunnels to be placed closer together and with less cover than was previously necessary. Contract CQ031 of New York?s East Side Access project will construct four six-meter diameter bored tunnels in a three-up one-down ?T? configuration, with less than three meters of soil between the tunnels. Mixed-face rock and glacial till conditions with a high ground water table will be encountered under active railroad yards. The tunnels will also pass beneath the busiest railroad interlocking in North America with cover as shallow as three meters. This paper discusses the challenges of designing segmentally lined tunnels for these conditions.

Jan 1, 2008

By Hon-Yim Ko

1972 constituted the second year of the projected five-year study on constitutive relations of coal. The schedule adhered closely to the five-year outline which is summarized in Table 1. This chapter is intended to serve as introduction and concise synopsis of the year's activities and results, which are presented in greater detail in the following chapters, which have been contributed by the individual researchers in charge of the various aspects of the project under study. Coal Sources, Material Procurement, and Sample Preparation Most of the studies performed during 1972 were done on coal from two sources: the Old Ben Mine #22 in Illinois, and the Bruceton Mine in the Pittsburgh seam of Pennsylvania, which may be considered typical of coal sources of economic importance in the Midwestern and Eastern part of the U.S. These two mines have proven to be reliable suppliers of coal material for our research. We have been able to establish good working relations with their personnel and feel that we can continue to count on their cooperation and help.

Jan 1, 1972

By Kenneth H. Johnston

This report describes in detail three waterflooding projects and a pressure-maintenance project in Butler and Cowley Counties, Kans., that will be visited on the 1963 annual spring tour of the Kansas-Oklahoma Waterflood Association. Among the unique features of the projects are the flooding of five oil-producing horizons separately with injection water furnished by two water-treating plants. Discussion of the individual projects includes information on their early history, the source and treatment of the injection fluids, oil production decline curves, and the results of water injection on oil production.

Jan 1, 1963

By R. A. Leveille, M. D. Doggett

"Economic returns for the copper industry have been assessed by building cash flow models for each of the 100 new mines brought into production over the past 20 years. Ninety-one of the 100 new mines returned the assumed 8% cost of capital and generated a positive net present value (NPV) at the development decision point. Economic criteria for individual mines are highly variable with NPV ranging from -$111 million (-$111M) to +$3850M (all money values are presented in United States dollars) and internal rate of return (IRR) ranging from -8% to +95%. The copper industry collectively would generate approximately $39 billion dollars in NPV through the development of the 100 new mines.The returns to exploration ($174M per deposit) were measured by deducting the cost of exploration per deposit ($221M) from the returns to development per deposit ($395M). Overall, the copper business has provided positive returns to exploration. However, the variability in returns across deposits means that only 41 of the 100 new mines can carry the average cost of exploration. The long lead times and high costs associated with exploration result in only those deposits with large amounts of contained copper being able to cover the average finding cost of the industry.The returns to development and exploration are shown to be highly sensitive to the cost of capital and metal price assumptions. With respect to deposit type, porphyry deposits are both larger (NPV) and exhibit lower profitability (IRR) than the nonporphyry deposits. On a geographic basis, returns to development and exploration are higher in Chile than elsewhere, reflecting the larger average deposit size and lower average exploration cost per deposit."

Jan 1, 2009

By E. Farrokh

Estimation of the cutter life and cost is a part of evaluating performance for a hard rock TBM in any project. Various approaches has been proposed for calculation of disc cutter life in various rock types based on machine specifications and rock strength and abrasivity. Cutter change time is a parameter that is used in some of the estimates and is defined as the average time required for changing a cutter on the cutter head and cutter life is the number of cubic meters of excavated rock per each disc cutter. Analysis of cutter life information of several tunnel projects from around the world has revealed that the published models for estimation of cutter consumption require some revisions to offer a more accurate prediction. The preliminary analysis of data shows that the average cutter change time is approximately 66 minutes for different cutter sizes and there is a minimal difference between corresponding cutter change times of the large (e.g. 19 or 20 in) versus smaller cutters (e.g. 15.5 to 17 in). This paper reviews the available and published cutter life data from various projects. It also introduces new models for estimation of cutter life and cutter change time as part of TBM down time and utilization analysis.

Feb 27, 2013