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By H. C. de Wet

The predevelopment and preparation of a total infrastructure in a deep level mining environment, prior to the shaft system being commissioned has major advantages. This paper intends to indicate these advantages and outline an understanding of the disadvantages. These benefits can be classified in three basic groups: the financial and timing advantages, a knowledge of the ore body and the development of required technology to meet the design parameters. The required technology in many aspects was still to be developed prior to successful application. Stemming from the technological evolution are some secondary advantages which will be described in each of the groups. Safety and health considerations and some practicalities made some of the new technology redundant prior to the actual application. In each case the actual achievements and the anticipated benefits will be indicated to allow the reader to distinguish clearly between planned and actual achieved advantages.

Jan 1, 1997

By K. Hanna

This U.S. Bureau of Mines report describes a rock mechanics instrumentation program conducted in a shallow underground coal mine in central Illinois. This research program was designed to provide a basic understanding of the structural behavior of entry intersections. A wide variety of instruments and measurement techniques including hydraulic borehole pressure cells, multiple-point borehole extensometers, roof bolt compression pads, and overcoring were employed to monitor roof stresses, pillar loading, strata movement, floor heave, and bolt loading before, during, and after intersection development. A summary of intersection design theories, failure modes, and support techniques is included and instrumentation installation procedures and analysis methods are presented. The study identified two critical parameters that affect intersection stability: in situ horizontal stresses and geological discontinuities. Important design parameters for improving intersection stability are roof span and intersection geometry.

Jan 1, 1991

By T. Bajpayee, J. Ellenberger

Microseismic monitoring and evaluation is one aspect of the National Institute for Occupational Safety and Health (NIOSH) research program. Roof falls are often preceded by a period of elevated microseismic activity, but not all periods of elevated activity result in a roof fall, nor do all roof falls occur after some amount of elevated activity. The objective of this study is to review periods of elevated microseismic activity and determine whether fracture activity rate can be used to anticipate the initiation of roof falls. The study was carried out at an underground limestone mine where major roof falls are associated with excessive horizontal stress. The progression of roof falls was detected by the microseismic signature produced by the rock falling from the mine roof onto the mine floor, which is termed a roof fall impact event. A total of nine elevated fracture activity periods that resulted in seven major roof falls were examined. It was observed that elevated fracture activity preceded the initial roof fall impact event in three out of four major roof falls. The initial impact event was not identified for the remaining three roof falls. Fracture event rates were analyzed and a roof fall alarm trigger of five fracture events in a ten minute time period was established for this test case. The fall alarm trigger was tested against six of the elevated activity periods. Four roof falls occurred in the six periods of elevated activity, and two would have triggered the alarm before the roof fall occurred, while two false alarms were generated. The results show that limited success would have been achieved by the microseismic system as a roof fall alarm trigger. However, the trigger would have been successful at warning of the onset of elevated activity, allowing mine employees to respond appropriately. The study highlighted some issues with implementing such a system in an operating mine, including the need for real time identification of fracture related microseismic signals among mining induced signals, and accurate location and identification of fracture clustering.

Minerals are fundamental to the U.S. economy, contributing to the real gross domestic product (GDP) at several levels?mining, processing and manufacturing finished products. The estimated growth rate for the real GDP of the United States was 2.1 percent and the nominal GDP was about $13.8 trillion in 2007 (Table 1). The prime interest rate decreased to 7.25 percent in December from 8.25 percent at the beginning of 2007, reflecting actions taken by the Federal Reserve Board to counter financial difficulties surrounding subprime mort-gages. Delinquencies on subprime mortgages increased throughout the year, affecting not only the delinquent home owners but also financial instruments invested in mortgage-backed securities. The average contract mortgage rate for the purchase of previously occupied homes in the United States was 6.35 percent in November; a slight decrease from 6.37 percent in January but still greater than 5.34 percent reported in July 2003, the lowest rate in the past five years. With the tightening of credit, the seasonally adjusted annualized rate for new privately owned housing starts declined 27 percent from December 2006 to November 2007. The loss in the residential market was balanced by a 9-percent increase in nonresidential construction between January and August 2007, during which slight increases occurred in nearly all

Jan 1, 2008

By B. Zeytuncu, O. Yucel, O. H. Celik, M. H. Morcali

"The Taguchi method was used as the experimental design to determine the optimum conditions of cementation behavior of the ruthenium chloride solution. Cementation was carried out using metallic zinc powder. The experimental conditions were studied in the range of 25-45°C for reaction temperature (A), 30--60 min for reaction time (B), 0.5-1.5 for pH of solution (C), and 30--50 mg for zinc powder (D). Experimental parameters and their levels were determined in the light of preliminary tests. Orthogonal array (OA) L9(34) consisting of four parameters each with three levels, was chosen. The optimal conditions found for ruthenium, such as a reaction temperature, reaction time, pH of the solution and mass of zinc, are respectively: 45°C, 45 min, 1.5 and 50 mg. Under these conditions, the ruthenium cementation efficiency obtained by theoretically and experimentally was in good agreement, which were 99.8% and 99.7% respectively."

Jan 1, 2013

By T. Wang

A new generated NaNO3 ? NaNO2 ? KNO3 ternary thermal energy storage system which has low melting point as 124°C and high specific heat capacity was studied for the short and long?term thermal stability by using the Thermogravimetric Analyzer (TGA). Based on the actual working condition of molten salt in solar two, the simulated cyclic thermal stability measurement was also conducted. The ternary system demonstrates excellent short ? term thermal stability and thermal reliability after cyclic heating and cooling processes. However, in the long ? term as well as the simulated cyclic stability measurement, large amount of weight loss was observed. Moreover, the stepwise long ? term isothermal study reveals that below 440°C the weight change is minimal and this temperature is viewed as the upper limit temperature of thermal stability for this ternary system. To determine the lost phases at high temperature above the upper thermal stability limit, techniques such as XRD and SEM are used to compare the condition of the salt mixture before and after the long ? term thermal stability study. On the basis of the comparison, it can be concluded that the major weight loss was due to the decomposition of sodium nitrite.

Jan 1, 2012

By R. S. Dean

As set forth in the decision of the Trail Smelter Arbitral Tribunal, dated April 16, 1938 This Tribunal is constituted under and its powers are derived from and limited by the convention between the United States of America and the Dominion of Canada signed at Ottawa, April 15, 1935, duly ratified by the two parties and ratification exchanged at Ottawa, August 3, 1935 (hereinafter termed "the Convention") . . . The duty imposed upon the Tribunal by the Convention was to "finally decide" the following questions: (1) Whether damage caused by the Trail Smelter in the State of Washington has occurred since the first day of January 1932, and, if so, what indemnity should be paid therefor? (2) In the event of the answer to the first part of the preceding Question being in the affirmative, whether the Trail Smelter should be required to refrain from causing damage in the State of Washington in the future and, if so, to what extent? (3) In the light of the answer to the preceding Question, what measures or regime, if any, should be adopted or maintained by the Trail Smelter? (4) What indemnity or compensation, if any, should be paid on account of any decision or decisions rendered by the Tribunal pursuant to the next two preceding Questions? In this decision reported to the Government of the United States of America and to the Government of the Dominion of Canada, the Tribunal answered the first question in its entirety and reserved decision on the other three questions in accordance with the following extract from their decision

Jan 1, 1944

By J. H. Brophy, S. J. Michalik

A constitution diagram for the system Mo-Ir has been determined. The maximum solubility of iridium in molybdenum is 16 at. pct at 2110ºC and decreases to less than 5 at. pct at 1500°C. The solubility of molybdenum in iridium is 22 at. pct. Three intermediate phases appear in the system: 8 MoJr, having the p-tungsten structure; a phase, a cornplex tetragonal structure; and the hcp ? phase. Metallography, melting point determinations, X-ray diffraction and fluorescence, and electron micro-probe unalyses were employed in establishing the diagram. PREVIOUS to the present investigation, the intermediate phases in the Mo-Ir system were identified, but no detailed account of the phase diagram has been reported in the literature. Raub1 investigated alloys of Mo-Ir over an extensive range of composition between the temperatures of 800º and 1600°C. The in-termetallic compound MosIr was found to exist with nearly pure molybdenum, as the solubility of iridium in molybdenum was not detectable parametrically in this temperature range. MO3Ir was found to be iso-morphic with a ß-tungsten type structure, having a parameter of 4.959Å. An intermediate hcp phase, designated as the ? phase, ranged in composition from 52 to 78.5 at. pct at 800ºC, and from 41 to 78.5 at. pct Ir at 1200°C. Parameters noted for the ? phase were as follows: at 42.7 at. pct Ir, a = 2.771i0, c = 4.4366, c/a = 1.601; at 78.5 at. pct Ir, a = 2.736A, c = 4.378A, c/a = 1.600. Molybdenum was found to be soluble in iridium up to 16.5 at. pct Mo (83.5 at. pct Irj, with the parameter of iridium increasing to 3.845A at the solubility limit. Knapton,2 who investigated alloys between 15 and 85 at. pct Ir, essentially agreed with Raub's data, but, in addition, found a a phase in as-melted alloys near 25 at. pcto Ir. The oaphase lattice parameters were a = 9.64Å, c = 4.96Å, c/a = 0.515. The a phase was replaced by the 8 -tungsten phase on annealing at 1600°C. Knapton concluded that the a was stable only at elevated temperatures, and placed the composition of the a phase at approximately 30 at. pct Ir. The intermetallic compound Mo3Ir, with a lattice parameter of 4.965A, was included among the 8-tungsten structures reported by ~eller.' Matthias and Corenzwit,4 and Bucke15 studied the superconducting nature of MosIr, and reported a superconducting transition temperature of 8.$K. The present investigation describes the phase relationships in the Mo-Ir alloy system determined by melting point measurements, X-ray diffraction and fluorescence, and metallography. EXPERIMENTAL PROCEDURES Alloys for the determination of the phase diagram were prepared from powders. Commercial 99.9 pct Mo from Fansteel Metallurgical Corp. and 99.9 pct Ir powder from J. Bishop and Co. Platinum Works were used. The powders were weighed to nominal compositions, mixed, and then pressed, without binder, into compacts weighing 4 to 6 g. These were presintered in uacuo between 1200' and 1400°C for 1 hr, to reduce the degree of spattering during subsequent arc-melting. The compacts were arc-melted in a nonconsumable tungsten electrode furnace six times on alternate sides on a water-cooled copper hearth in an atmosphere of zirconium-getter ed argon at 500 mm of mercury pressure. In almost all cases, this procedure yielded buttons of satisfactory homogeneity. The composition of all melted buttons were confirmed by X-ray fluorescent analysis using the experimentally determined ratio of the iridium La1 line intensity to that of the molybdenum Ka1 line as a function of composition. In this determination four alloys analyzed by wet chemical methods were used as standards. An uncertainty range of ±1 at. pct has been attributed to all indicated compositions. All heat treatments and solidus measurements were carried out in tantalum resistance heating elements in vacuum conditions of 10-4 to 10-5 mm of mercury. A detailed account of this procedure has been reported by Schwarzkopf and Brophy.8 In the heat treatment and solidus measurements of iridium-rich alloys (50 at. pct Ir or greater), a tungsten lining was inserted into the tantalum resistance heating element because of a eutectic reaction which occurs between iridium and tantalum at 1948ºc.7 Heat treatments and solidus measurements carried out at compositions less than 40 at. pct Ir both with and without tungsten linings within the resistance

Jan 1, 1963

By Y. Boissonnas

INTRODUCTION, The transalpine rail routes in Switzerland are well over one hundred years old. As the established routes no longer meet the demands of the continually increasing volumes of rail traffic between north and south, two new routes through the Alps were planed. The old Gotthard rail line is in fact a mountain railway. The northern and the southern access ramps?with a maximum speed of 80 km/h and a maximum slope of 2.2%?reach the old Gotthard rail tunnel at an elevation of approximately 1,100 m above sea level. This is approximately 900 m higher than the city of Milan. In 1992, the Swiss electorate people voted with an overwhelming majority in favor of the project to build the new base routes through the Alps. The Swiss voted again in 1998 in favor of the financing proposal for the new infrastructure. Swiss Federal Railways together with the BLS Lötschbergbahn were commissioned for the realization and management of the Gotthard and Lötschberg routes. AlpTransit Gotthard Ltd., founded by Swiss Federal Railways, was given the task of managing the design and realization of the Gotthard route until the start of regular service. In the meantime the shorter Lötschberg Base Tunnel was open to traffic in 2007

By Percy Chávez

Dado el avance de la globalización, las empresas mineras latinas se encuentran expuestas ante el poder de las empresas transnacionales -en tanto estas utilizan información estructurada, verificada y centralizada para tomar las decisiones más acertadas y tener el control de las condiciones operativas. En este sentido, el presente texto señala la experiencia realizada en la Cía. Minera Atacocha aplicando la información centralizada para el desarrollo de proyectos de infraestructura en sus operaciones mineras.

Aug 25, 2002

By M. C. Ruiz, M. E. Godoy, J. B. Rivarola, M. W. Ojeda

The amount of Pd recovered from an exhausted olefin hydrogenation catalyst was found to depend on mixing technique, particle size, carbon percentage, chlorine flow, reaction time and temperature. Pd extraction was total when a sample in the 125-175 micrometre particle size range was chlorinated for 60 min at 723 K with 20 cm3 Cl2/min, for 60 min at 748 K with 30 cm3 Cl2/min and for 30 min at 773 K with 30 cm3 Cl2/min. No C addition was needed; the initial C content of the catalyst was sufficient for total recovery. Pd extraction was also affected by heat treatment in different atmospheres before chlorination. Treatment with O2, N2 and N2 with traces of O2 led to different degrees of oxidation of C and permitted the formation of oxidised Pd species. Thermal pretreatment in N2 with traces of O2 was most conducive to Pd extraction

Jun 21, 1905

By R. W. Parsons

The over-all apparent single-phase permeability of fracture-rock systems was studied using two different two-dimensional models. In a strict sense the results are applicable only to these models, yet may give some insight into real reseruoir behavior. The regular fracture-matrix model can have any number of regular fracture sets. All fractures within each set have the same orientation, width and spacing. The gross behavior is amlytically equivalent to that of an anisotropic permeable medium. In the heterogeneous fracture systems, individual fracture conductivities vary within a two-dinensioml network pattern. A computer program calculates the overall permeability after the conductivities are randomly placed in the network. The calculated permeability depends upon the distribution of these conductivities and the particular fracture pattern into which they are placed. Although detailed information on actual reseruoir fracture systems is not available, this study shows how some of the possible variables may affect obserued gross reservoir characteristics. INTRODUCTION Characteristics of reservoir rocks are determined by direct (core analysis) or indirect (logging and production tests) examination. Both methods, singly and together, are widely used in reservoir evaluations. For fractured reservoirs a problem exists in relating characteristics of cores to the in situ reservoir properties. Knowing fracture characteristics can be of value in determining production mechanisms. Because of the limitations of observation, the intimate details of a fractured rock system will never be known. One approach in analyzing fractures is to study the behavior of some conceptually simple models. The two models analyzed contain features which may be realistic, yet are mathematically tractable. Flow is considered in two dimensions only, with the plane of interest at right angles with the fractures. This concept represents the horizontal flow in a reservoir system with the fractures oriented vertically. Only single-phase, laminar flow is considered. The regular fracture-rock system permeability is calculable from a simple analytical expression. The heterogeneous system requires a computer program for calculating overall permeability.

Jan 1, 1967

By Robert Bachus, Jamey B. Rosen

"Abstract Large scale In Situ Barrier Wall Construction projects, specifically those related to earth dams, dikes, and levees, frequently require stringent quality control measures to ensure the success of the wall. This presentation discusses the applications of Geographic Information Systems (GIS) technology to capture information from multiple data streams and provide geotechnical feedback, quality control, and project control feedback. Techniques used to geospatially analyze verticality data from secant piles and panels will be demonstrated. Examples will be presented from barrier wall installations at two sites owned by the U.S. Army Corps of Engineers (USACE): the Wolf Creek Dam in Kentucky, and Center Hill Dam in Tennessee.IntroductionDeep foundation installations require contractors to collect a substantial amount of information over the course of a project, both for internal quality control of construction progress and for demonstrating compliance with customer or owner specifications. Methods of collecting information are constantly improving, bringing with it the need for a systemic approach to managing the increasing amounts and types of data. Handling these diverse types of data presents challenges with both budget and schedule demands. This paper discusses some techniques for adding or increasing quality control in barrier wall constructions by consolidating, visualizing and analyzing data using relational database and Geographic Information Systems (GIS) technology, collectively referred to as Information Management System (IMS) development. The IMS concept is designed to facilitate the collection, transfer and processing of data and provide an easy way to remotely access and visualize construction progress.The remainder of this paper presents the needs and objectives of an IMS applied to quality control in barrier wall construction, the components and data flows involved, the capabilities and user interfaces of the systems and the benefits for the end users. Examples are presented throughout from case study projects including: a pile barrier wall applied in the rehabilitation at the Wolf Creek Dam in Kentucky (under contract to the Treviicos-Soletanche Joint Venture), and a secant pile barrier wall currently under construction in the rehabilitation of the Center Hill Dam in Tennessee (under contract to Bauer Foundations Corporation) (both owned by the Nashville District of the USACE)."

Jan 1, 2014

By Prescott Greene

AVAILABLE MACHINES Machines discussed in this section include only rubber tire mounted kerf cutting machines of a self¬propelled electrically powered design. Such machines handle bars up to 4.6 m (15 ft) in length, cutting kerfs of from 115 to 191 mm (4.5 to 7.5 in.). The basic design concept of all machines currently in production is very similar. The chassis features dual driving wheels on the cutter-bar end, fixed directly to the main frame. The steering wheels on the outby end of the frame are articulated in some manner to keep all four wheels on the floor over uneven bottom. Machine power for tramming, and all other functions except powering the cutting chain, is furnished from a pump motor that drives the specific pump or pumps required by a given machine. The cutter chain is driven through a mechanical drive train from a separate electric motor having no duty other than driving the chain. The general arrangement of a cutting machine is shown in Fig. 1; two types of machines, with their specifications are shown in Figs. 2 through 5. A hydraulically powered cable normally is included to eliminate the need for manual cable handling and make this a one-man machine. A bug duster, though optional, is needed for most applications. The bug duster is an hydraulically driven scroll conveyor located directly behind the cutter chain drive sprocket. Its function is to move the cuttings away from the sprocket to prevent them from packing up in this area and consuming a lot of machine power to further pulverize them. Available machines vary from models 610 mm (24 in.) high that can cut horizontally only from 203 mm (8 in.) below ground line to 229 mm (9 in.) above, to machines 1143 mm (45 in.) high that can cut in any plane from 178 mm (7 in.) below the ground line to 3.7 m (12 ft) above it. Most currently manufactured machines fall in the 17 200 to 20 400 kg (38,000 to 45,000 lb) weight range, but can be dis¬assembled for underground installation where weight and size are a problem. Maximum teardown results in all pieces having a weight of 5400 kg (12,000 lb) or less and a size allowing passage through a 1.2 x 2.1-m (4x7-ft) opening. Further reduction in either size or weight of the parts becomes a serious problem. Machines currently being manufactured are avail¬able for use with power supplies of 250 v dc; 500 v dc; 440, 550, or 950 v ac (60 Hz). Also available are machines for use on 415, 500, and 950 v 50 Hz. De¬signs to allow operation on other voltages of either 50 or 60 Hz can be made available without any serious problems. As of September 1977, a typical medium-seam ma¬chine without the extra options needed for unusual conditions, but fully equipped to operate, was selling for about $185,000. CAPABILITIES Materials That Can Be Cut The problem of deciding before a machine is put on the job whether it can work effectively is an old one that has never been completely solved and probably

Jan 1, 1982

By A. S. Macfarlane

This paper describes how knowledge of the orebody morphology and ore morphology can be used to optimize the planning, mining, and metallurgical output from an open pit copper mining operation, such as to significantly increase the stability of the whole value chain process, and increase the reliability and value of the process outputs. In the case under consideration, the orebody contains both copper and cobalt. This in itself provides a challenge, in that the two metals do not occur in consistent ratios across the orebody as a whole. Furthermore, mineralogical differences within the orebody have a significant impact on plant performance in terms of throughput rates, acid consumption, and recoveries. In order to stabilize and optimize the plant performance, it is necessary to firstly have a complete understanding of the geometallurgical factors that affect performance, and then to have a sound knowledge of how these are distributed within the orebody. These models then inform the mine planning strategy that optimizes cash flow and NPV, and also allow the development of a stockpiling strategy that not only stabilizes the plant, but also allows variations in the plant feed according to ore type and grade in volatile price scenarios. Integral to the realization of these opportunities is the establishment of an appropriate measuring, control, and reconciliation system, customized to the optimization objectives. The paper describes how all of these factors and strategies can be integrated to produce optimal value from the orebody through to final dispatched product. It also shows the significant value that can be released through such an approach.

Jan 1, 2014

By John Popovich

The MICON RokLok binder system including component and consolidation processes and safety and its first aide are described. The implementation procedures and selection of injection parameters are discussed. Finally a case example of recovering a 30-ft. long roof fall in mainline haulage entry is used to illustrate the economic potential of preventive measures by RokLok injection.

Jan 1, 2001

By M. I. Mthenjane

"BackgroundThe paper discusses post-mining land use however, the essence of the topic is the emotional motivation behind the decisions related to mining investment and development. Therefore this is not a typical SAIMM technical paper about the science and techniques of post-mining land use. There are already numerous papers written and conferences held on this aspect of post-mine land use; the science is well understood, but the evidence of the practical application of the (environmental, social, and economic) science is sparse. At a recent conference held in November 2017 on the theme of ‘Science, Business, Society Dialogue – linking science, society, business and policy for the sustainable use of abandoned mines in the SADC region’, it was demonstrated through the delivery of several papers on the possible viable options of post-mine land use. The conference was structured in nine sessions, covering the following relevant topics:? Sessions 1 and 2: Nature and magnitude of the problem: raising awareness? Sessions 3 and 4: International experiences in remediation: case studies? Sessions 5, 6 and, 7: Technological solutions: converting liabilities into assets? Session 8: Implementing solutions: social and legal aspects? Session 9: Wrap up, lessons learned: conference resolution.Summaries of the key outcomes of the sessions are available for reference.The aim of this paper, accompanied by the video speech, is to provide a visualization of the possibilities of post-mine land use. Mining contributes approximately 7% to South Africa’s GDP - this is the lowest it has ever been and is attributable to both a diversifying economy and to poor mining and investment policy which has resulted in reduced investment in the sector. The objective of the paper is to highlight the opportunities, for succeeding and diversifying economic activity following mining and mineral extraction which can continue to sustain the livelihoods and wellbeing of communities and societies beyond mining.During mining, very few alternative and local economies develop. Dependence on mining and its value chain prevails until mining ceases. This idea is conveyed in Figures 1a and b."

Jul 1, 2019

By Keith A. Heasley, Timotlly M. Barton

Historically, the surface subsidence over underground coal mines has been predicted using empirical profile or influence functions which have little or no connection to the actual mechanics of the subsidence- Without a mechanistic basis, establishing the exact site-specific parameters to use in these empirical methods has been problematic. A practical subsidence predictive method based on mechanics has the appealing capability of allowing the determination of site-specific parameters from fundamental properties of the overburden with minimal field calibration work. This paper presents a case study where a mechanics-based, boundary-element program is used to calculate the surface subsidence associated with several panels of a Northern Appalachian longwall coal mine. The program used in this case study is called LAMODEL, and it incorporates a frictionless, laminated overburden into a general purpose displacement-discontinuity code primarily designed for calculating the stresses and displacements in coal mines or other thin seam or vein type deposits. In this paper. the program is used to calculate both the underground convergence and the resulting surface subsidence at three longwalls. The subsidence results from the model are compared with field measurements and analyzed The results from the case study in this paper demonstrate that the laminated model with calibrated properties can easily provide fairly accurate subsidence predictions and is fairly flexible for fitting measured subsidence. However, additional subsidence predictive case studies are recommended in order to ultimately evaluate the potential of the laminated overburden model for practical subsidence prediction

By T. Hidayat, D. Shishin, S. Sineva, M. Shevchenko

The effects of the slagging components Al2O3, CaO and MgO on the thermodynamics and phase equilibria of the gas/slag/matte system with major elements “Cu2O”-“FeO”-SiO2-S are characterised using an integrated experimental and thermodynamic modelling approach. The experimental technique included high-temperature equilibration experiments using a spinel substrate in controlled gas atmosphere (CO/CO2/SO2/Ar), quenching of the sample and subsequent measurement of the compositions of equilibrium phases with Electron Probe X-ray Microanalysis (EPMA). Thermodynamic modelling is undertaken using the computer system FactSage. In previous experimental studies on this system, the separate effects of Al2O3, CaO and MgO were determined. In the present investigation, the combined effects of these additional components are investigated at 1200oC and P(SO2) = 0.25 atm and a range of P(O2)’s. Special attention is paid to ensuring chemical equilibrium is achieved in each case, for this reason possible kinetic factors are systematically analysed. The results obtained are presented in the form of graphs showing the compositions of matte and slag phases as functions of copper concentration (matte grade). The new experimental data are used for the improvement of the thermodynamic database for multicomponent copper-containing systems. The effects of the slagging elements on this multicomponent system will be presented in the paper. INTRODUCTION Whilst Fe-O-Si form the principal components of copper smelting and refining slags, additional impurities are present in industrial practice typically at 2–5 wt.% Al2O3, 1–4 wt.% CaO and 1–2 wt.% MgO levels (Davenport, King, Schlesinger, & Biswas, 2002). These elements are introduced into the slag as impurities in concentrates and other feedstocks, in fluxes added to the process and in refractory materials. Understanding, and accurate description, of the changes that take place in the smelting process in the presence of these additional elements is of major importance to the optimization of industrial operations. Although experimental data are available on slag/copper matte equilibria, further work is needed to accurately characterise the influence of Al2O3, CaO and MgO on phase equilibria and elemental distributions of elements in gas/slag/matte systems. The individual effects of the Al2O3, CaO and MgO slagging components on equilibrium phase assemblages under selected conditions have been quantified in a recent series of studies on the Cu–Fe–O–S–Si-(Al, Ca, Mg) gas-slag-matte-metal system (Fallah- Mehrjardi, Hayes, & Jak, 2018; Fallah-Mehrjardi, Hidayat, Hayes, & Jak, 2017a, 2017b; Hidayat, Fallah-Mehrjardi, Hayes, & Jak, 2018a, 2018b; Jak et al., 2016; D. Shishin, Decterov, & Jak, 2018; Denis Shishin, Hayes, & Jak, 2018). Since, thermodynamically, the condensed phases do not behave ideally, it is to be expected that the effects of individual elements may not be additive, and the additional interactions between the Al2O3, CaO and MgO slagging components will also have to be taken into account. These additional effects are expected to be smaller than those of the individual components, so higher accuracy is needed. The present paper describes analysis of the precision and accuracy of the experimental technique on multi-component, multi-phase equilibria in these systems to enable the combined effects of Al2O3 + CaO + MgO on slag/matte/spinel equilibria, i.e. for high Fe/SiO2, to be accurately measured. The effects of Al2O3, CaO and MgO on the gas - slag - matte are analysed using a thermodynamic modelling approach with the computer package FactSage.

Jan 1, 2019

By Tripathy A. K, Satapathy B. K, Nayak B, Mohanty J. N, Dey D. N

The paper deals with the metallographic tudy of heat treated chromite and chromite-coke composite briquettes. The briquettes, prepared from chromite concentrate of Orissa Mines using molasses-lime, dextrinelime and tamarind seed as binders, were subjected to different temperatures and examined metallographically. The change of phase with temperature was analysed by X-ray diffraction.

Jan 1, 1987