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By Gopala N. Krishnan

The most promising candidate for the recovery of alumina from non-bauxitic sources is the leaching of clay by HCL acid followed by crystallization of aluminum chloride hexahydrate (ACH) by hydrogen chloride sparging. Hydrothermal precipitation of boehmite ( ?-A100H) from aluminum chloride solution will simplify the process, will reduce energy consumption and will eliminate corrosion problems involved in calcination of ACH to obtain alumina. This report summarizes the results of Phase I of a program to study the precipitation of boehmite from AlC13 solutions. The amount of boehmite precipitation from dilute A1C13 solutions (5 wt%) is . negligible below 200°C. Above 200°C the precipitation increases with increasing temperature approaching 40% at 300°C. Addition of HCl acid to the dilute A1C13 solution even in small quantities drastically reduces boehmite precipitation. Solution impurities such as Fe, Ca, Mg, or Na substantially promote the precipitation of boehmite. No precipitation is observed from concentrated A1C13 solution (30wt%) representing the leach liquor.

Jan 1, 1980

By R. C. Kadyk, C. J. Bise

High-voltage cable couplers are convenient and widely used accessories in modern coal-mine power distribution systems to help extend and retract power-feeder cables throughout a mine. Coupler design has tried to keep pace with the industry's desire to move to higher distribution levels, but the increase in recorded failures of 15-kV class couplers, which serve the 12.47-kV and above distribution levels, has inhibited this transition. Problems associated with the effects of partial discharge on high-voltage cable couplers are analyzed. The phenomenon of partial discharge is discussed, a testing standard is developed, and various coupler designs are subjected to its requirements. An analysis of test results and results based on field applications are provided.

Jan 1, 1985

By Jeff Starchuck, Harald Kullmann

"In 2005, an inspection showed that the Deception Bay Wharf in the Canadian Arctic was at the end of its service life. Although Deception Bay is closed with landfast ice up to 5 ft thick, shipping operations continue year-round, with additional voyages in the summer open-water season to supplement mine supplies. The rehabilitation scheme that allowed minimal interruptions to shipping involved concrete caissons cast on barges and an ingenious placing system.WorleyParsons Westmar of Vancouver, B.C., performed the inspection under contract to the owner, Xstrata Nickel, Montreal, Quebec. The wharf, on the coast of the Nunavik region of Quebec, was originally constructed in 1971 for an asbestos mine, and is now used to support Xstrata’s Raglan nickel mine, importing fuel for p o w e r g e n e r a t i o n a n d general mine supplies, and exporting nickel concentrate to smelters in the south. Emergency repairs were essential to allow operations to continue at the site, while the parties considered permanent rehabilitation options and secured funding. The repairs were done in the openwater seasons, and included reinforcing the failed interlocks above water level with steel patch plates and injection grouting of the cell fill below the port crane in 2005. In 2006, workers installed a circumferential belting system below water level.Westmar held critical planning sessions with the mine operation personnel to find ways to stretch the limits of the mine supplies and nickel storage facilities. In the end, the parties agreed to shut down construction activities four times during the ice-free season to allow access to the dock site.Westmar developed a plan that allowed mine operations to continue during construction, and Xstrata approved the plan and budget in September 2006, for execution in 2007. Rapid construction was essential. To accommodate the short construction season and maintain minimum levels of service for the mine, the work was radically different from conventional Arctic deep-sea port construction. Like the original Deception Bay Wharf, construction practice was to use steel sheet pile circular cells with the consequential heavy support services for the labour force. Construction duration was typically two seasons. The plan for Deception Bay was executable in one season based on a concrete caisson structure. Only a modest amount of schedule float was needed."

Jan 1, 2009

By Shengli Wu, Jinming Zhu, Wei Huang, Xinliang Liu

The sinter of high basicity would interact with lump ores or acid pellets in the cohesive zone of blast furnace due to the difference of chemical composition and micro structures. The results of this work showed that the softening-melting properties of lump ores and acid pellet would be obviously improved by the high temperature interaction. However, the high temperature interaction index (INI) would be influenced by many factors, such as chemical composition, porosity, interaction interface and so on. The INI between sinter and porous limonite lump ore (L-2) was much higher than that of dense hematite lump ore (L-1) and acid pellet (P-1). In addition, though the softening and melting properties of L-2 were poorest in respective iron ores, the softening and melting properties of integrated burden B (consist of sinter and L-2) were not worse than other integrated burdens due to the strong high temperature interaction.

Jan 1, 2015

By E. C. Harder

CERTAIN typical characteristics of bauxites, ores of aluminum permit their classification into a number of categories, each of which has special features that enable grouping within it deposits from widely scattered bauxite fields. There may be local variations in conditions that have introduced differences of lesser importance between similar deposits in different fields, resulting perhaps from the influence of factors other than those that have produced the distinguishing features of each of the different groups, but in general the similarity between the deposits in each group is sufficiently striking to make the grouping indicated of interest. Several factors and conditions enter into the decomposition process that results in the development of bauxites and laterites and affects their character. The principal conditions favoring optimum bauxitization are: (1) pres- ence of rocks with easily soluble minerals yielding residues rich in alumina; (2) effective rock porosity, enabling easy access and free circulation of water; (3) normal to abundant rainfall alternating with dry periods; (4) vegetation, including bacteria, advantageously distributed; (5) available sources of appropriate solution and precipitation agencies; (6) a tropical or at least a warm climate; (7) low to moderate topographic relief, allowing free movement of the water table but a minimum of erosion; and (8) long quiet periods in earth history. Assuming that all of these factors are operating to a greater or less degree, it seems that the one that affects most the physical character of the resulting bauxite or laterite deposits is the chemical and mineralogical composition of the rocks that by their decay yield the bauxite deposits. This factor is used in the classification followed in this paper. In the process of weathering of ordinary silicate and carbonate rocks of the earth's crust, whether of igneous or sedimentary origin, it is the minerals of the alkalies that yield most readily to attack. The alkaline earth compounds also offer no great resistance, particularly the carbonates. Thus, among the rock-forming elements, those producing the most insoluble compounds are aluminum, iron, and silicon, together with certain ones of less importance, such as titanium, manganese, and phosphorus. In normal weathering processes such as prevail in temperate regions, the common minerals of rock decay are

Jan 1, 1952

The paper describes the 209 in. single stage axial flow mine ventilating fan which commenced operation at The Zinc Corporation Limited, Broken'Hill, N.S.W., in January, 1954.This fan is used to ,ventilate the underground workings of The Zinc Corporation Limited and New Broken Hill Consolidated Limited and, at the time of installation it was the largest fan of its type in the world. It has amaximum capacity of 900,000 c.f.m. at 4·2 in. watergauge and is equipped with adjustable pitch blades and a novel form of variable speed drive.The considerations which lead to the adoption of this particular design are outlined, and a full description of the contruction and installation of the fan and auxiliaries is given.Comprehensive acceptance tests were carried out on the completed installation and, the testing procedure is described in detail. The results of sound level measurements are also included. A brief report on the performance during the 12 month period from 1st July, 1954, to 30th June, 1955, is then given.SELECTION AND DESIGN OF FANGeneral ConsiderationsBecause of the economic advantages of joint ventilation of the underground workings of The Zinc Corporation Limited and New Broken Hill Consolidated Limited, it was decided, after a full review of the future ventilating requirements of both mines, to sink a 20 ft. diameter circular upcast airway on the common boundary of the two properties, to handle a maximum quantity of 900,000 c.f.m.The anticipated air requirements were at this stage estimated to be:(a) initially 700,000 c.f.m. through a mine equivalent orifice of 160 to 2'40 sq. ft. (equivalent total pressures being 2·70 in. w.g. and 1·20 in. w.g.) ;

Jan 1, 1956

By J. W. Stevenson

The need for a separate ventilation department within the management team was recognized by the management of U. S. Pipe and Foundry before the company was purchased by Jim Walter Corporation in January, 1970. Because the coal beds of the deep underground coal properties owned by Jim Walter Resources lay 1300 to 2200 feet below the surface, efficient mine ventilation practices are essential through shaft openings varying from 16 to 22 feet in diameter. The extremely high methane gas quantity indicated to be in the coal bed because of the depth of cover and documented by various U. S. Bureau of Mines tests and demonstrated by early mining proved the need to implement this early management decision. At U. S. Pipe and Foundry mine ventilation was a function of the Mining Engineering Department with ventilation personnel assigned to the mine receiving their day to day work assignments from the mine manager or mine foreman. At Jim Walter Resources, the General Manager - Ventilation reports to the Senior Vice President, Mining Engineering, who reports directly to the President, Mining Division, Figure 1 (Company Organization Chart). Position descriptions are static; however positions are dynamic and consequently the degree of emphasis of specific duties and responsibilities change depending not only upon the aptitude of the individual performing the job but also upon his ability to meet the needs of his supervisors; and ultimately upon his ability to react to the economic forces directing our society. The following describes the duties and responsibilities of the General Manager - Ventilation, Figure 2.

Jan 1, 1980

By G. F. Jr. Butterworth

THE metallographic structures most frequently encountered in rifle barrels, and which are illustrated by the accompanying photomicrographs, fall naturally into two groups, distinguished by the method used to produce in the stock a physical condition having the requisite properties. The first group consists 'of "rolled" barrels; that is, barrels subjected to hot working by rolling in or near the critical range. In the second group, the stock, which is smaller in diameter than the first, is upset to form the butt end and is then heat-treated by giving it a quench and a draw. These barrels will be referred to as "heat-treated" barrels. The structure of the rolled barrels resembles closely that of the same steel after annealing. There is the same network of excess ferrite outlining the grain boundaries, but the grains themselves are composed of sorbite rather than pearlite. The grain size is closely related to the rolling temperature. The critical-point curves of this grade of steel, which is approximately 0.50 to 0.60 per cent. of carbon and 1.00 to 1.30 per cent. of manganese, show a single very pronounced point between 1300° and 1350° F. (704° and 732° C.). Barrels rolled within this temperature range give an exceedingly fine grain, shown in Fig. 1. In fact, the grains may be so fine that, at a low magnification, they may be confused with the heat-treated structure discussed below, Fig. 6. A magnification of 500 diameters, however, will always resolve a rolled barrel into the characteristic structure, shown in Fig. 2. As the temperature is increased, the grains are found to be larger. If, on the other hand, the rolling temperature is below the critical range, the structure previous to rolling will not be obliterated, the only effect of rolling being to elongate the coarse sorbite grains in the direction of rolling, Fig. 3. This distortion is greatest at the muzzle. Heat-treated barrels are quenched in oil from above the critical range, which should give a martensitic structure, Fig. 4, but the presence of some troostite in the martensite is frequently noted when the quench has not been sufficiently drastic, Fig. 5. The structure brought about by the subsequent draw is not so striking, though quite as typical. It is sorbitic or sorbito-pearlitic, and under- a low magnification appears

Jan 7, 1919

By R. J. Blackwell, J. R. Rayne, W. M. Terry

This paper presents results of an experimental investigation of factors that control the efficiency with which oil is displaced from porous media by a miscible fluid. The study was made to elucidate the relevant processes both on microscopic level (within individual or between neighboring pore spaces) and on macroscopic level (within a large sand body). Mixing of miscible fluids on the microscopic level was studied in sand-packed tubes. It was found that molecular diffusion is the dominant dispersion mechanism for reservoir conditions of rate, length and pore sizes. Macroscopic channeling was studied for various mobility ratios in reservoir mode1s scaled to relate viscous, gravitational, and diffusional forces. The formation of channels was due to viscous firzgering, gravity segregation and variations in permeability. With adverse mobility ratios, it was found for reservoirs of realistic widths that diffusion will not be effective in preventing the formation and growth of fingers, even in homogeneous sands. At sufficiently low rates channeling was eliminated by gravity segregation in tilted reservoirs. The dependence of recovery on mobility ratio, length-to-width ratio, flow rate and angle of dip is presented. INTRODUCTION Oil recovery by solvent flooding is finding increasing application in the field. While the process promises high recoveries from the region swept by solvent, under adverse conditions only a small fraction of the reservoir volume may be swept at the time solvent breaks through to the producing well. Further, the high cost of the solvent encourages its use only as a bank whose size must be kept at a minimum. Thus, two important questions arise: (1) what fraction of the reservoir can be swept, practically, by solvent? and (2) what is the minimum size solvent bank that can be used to carry out the displacement? The answers to these questions require knowledge of both macroscopic channeling processes and microscopic mixing processes. The studies described here were carried out to gain this knowledge. Microscopic mechanisms which cause mixing will be discussed first, because an understanding of these mechanisms is necessary for proper interpretation of the experimental work on channeling described later. INVESTIGATION OF MICROSCOPIC DISPLACEMENT PHENOMENA FOR MISCIBLE FLUIDS The questions to be resolved concerning microscopic displacement behavior are: (1) how much mixing occurs between oil and solvent in the direction of flow? and (2) does the solvent completely flush the oil from the pore spaces in the region invaded by solvent? The classic work of Sir Geoffrey Taylor' and its extension by Aris2 have shown that it is possible from theory to describe the amount of mixing in single straight capillaries when solvent displaces a fluid of equal viscosity and equal density. Aris showed that the lengths of the mixing zones, 81, corresponding to the 10 per cent and 90 per cent concentration levels of the solvent can be calculated from the formula, 81 = 3.62 \/Kt, .........(1) where 8l is the length of the mixing zone, cm; t is the time, sec; and K is the effective dispersion coefficient, cm2/sec, given by K/D = 1 + (1/48) (au/D)2......(2) where a is the radius of the capillary, cm; D is the molecular diffusivity, cm2/sec; u is the average velocity

By Gaston Gingras

"IntroductionL'entretien de l'equipement minier dans les mines à ciel ouvert est une activité qui est aussi vieille que I'existence des mines et qui a progressé au cours des années pour suivre l'évolution des techniques d'exploitation. Lors de la mise en usage de s premières pelles à la va peur, celles-ci étaient généralement entretenues par I ‘équipe de quatre hommes qui était responsable de son opération. Pour les travaux plus compliqués ils utilisaient les services de machinistes qui eux savaient comment réparer Ie moteur à vapeur et couler des coussinets de ""babbit"". Les premières pelles diesel étaient entretenues de la même façon mais pour les réparations au moteur, on devait recourir au représentant du manufacturier qui était Ie seul à avoir les compétences nécessaires.Ce n'est vraiment qu ‘après la deuxième guerre mondiale que I ‘usage de l'équipement mobile s'est répandu dans les mines à ciel ouvert pour débuter les extractions selon les méthodes que I'on connaît aujourd'hui.L'entretien de l'équipement minier de façon organisée à débute avec I ‘usage de ces machines dans nos mines. Ces machines étaient un peu primitives, petites et pas très dispendieuses a I'achat. Même si la disponibilité était basse, elles fournissaient quand même un rendement qui en ces temps était acceptable. L’organisation de I ‘entretien de cet équipèrent était assez primitif et n'occupait qu'une place secondaire aux yeux de la direction de la mine."

Jan 1, 1988

By K. S. Eric Forssberg, T. V. Subrahmanyam

The present paper deals with the important technological developments in gold processing and where possible, the data is presented in the form of tables. Gold processing methods have evolved to such an extent that low grade and complex ores once considered uneconomic are now becoming viable. Constant efforts are underway to innovate technologies in order to improve the efficiencies and cut down the capital and operating costs. The methods are discussed.

Jan 1, 1988

By Frank Haas

Many articles on the physical properties of fire damp have appeared in the Transactions and elsewhere but practically nothing has been written in regard to its occurrence or fluctuation in quantity in an ordinary mine. After the Monongah explosion in 1907, with the loss of 361 lives, the Consolidation Coal Co. sought a method by which such catastrophes could be prevented. While the cause of this particular explosion was attributed to coal dust, some of those acquainted with the mine thought that fire damp was involved, if it was not the initial cause. So the literature on the subject was studied and mines where similar conditions prevailed in this country and Europe, were visited, with the view of establishing some system by which gas could be more easily detected and controlled. The results of this study were disappointing for no method was found other than the time-honored fire boss with his safety lamp, with some variations in the rules and regulations governing his inspections and reports. Duties of the Fire Boss Pending the development of a better method, it was decided to standardize and perfect the duties of the fire boss and the reports based on his observations. Those who were then in service were closely examined, various lamps were experimented with and the lamps and individuals tested under known conditions. It was found that a fire boss could tell whether gas was present but his estimate of quantity was not even an approximation; therefore, while the services of fire bosses were indispen-sible there was need of additional information by which the quantity of gas could be estimated with some precision in order to determine its variation from time to time. Chemical Process for Determination of Methane After considering all methods known at that time a chemical process was adopted. The principles involved in the process are that in an enclosed receptacle, in the presence of excess air, methane will be completely burned by means of a hot platinum wire to carbon dioxide and

Jan 1, 1927

In the course of an investigation of the influence of bismuth on copper carried out some years ago, (1) the author found that phosphorus exerted a beneficial effect on bismuth-copper alloys of low bismuth and oxygen content by neutralizing the embrittling effect of the bismuth. In the intervening years, a further examination of bismuth-phosphorus-copper alloys has been canied out and the influence of other elements and combinations of elements on copper containing bismuth has been studied.The results recorded in the present paper are part of this investigation.MATERIALSAll the alloys were made from high-grade copper (KS.A. wire-bar) of the following composition: copper 99·95%, oxygen 0,040'%, iron 0·0015%, sulphur less than 0-001%, bismuth less than (j>'OOl%, other elements each less than O· 0010/<-. The bar was hot rolled and cold drawn to strip which was cut into short lengths and cleaned in nitric acid ready for melting.A piece of this 'strip was drawn to wire 0·08 in. diam., annealed at 5000 C, and measured for electrical conductivity as a check on purity. The result was 101·5% of the I.E'.C. standard.In making the alloys, phosphorus was added as 14% phosphor-copper, bismuth as 17% bismuth-copper, and the other constituents either as copper alloys or as elements of a high degree of purity.PREPARATIQN OF STRIPSThe charges were melted in plumbago crucibles (Morgan salamander brand) in an oil-fired furnace, Le;, in the manner commonly adopted in industrial practice. The copper was first melted under charcoal, well stirred with a chaned stick, and the necessary alloying elements added and stirred in with the stick. The weight of a charge varied according to requirements but generally was about 4 lb. The charges were poured into slightly tapered brass moulds heated to about 1000 C and dressed with a mixture of mineral oil and tallow. They were not only poured under charcoal through the burning mould dressing but also- through a ring of flame produced by burning kerosene on asbestos cord wrapped round the top of the mould. Experiments carried out with plain copper proved that by this means oxygen could be excluded from the stream of metal. The billets were 7·5 in. long x O·83 in. diam. x 1·3 lb. weight.The billets were cropped about 1 in. from the top, cleaned in nitric acid, and measured for density by the usual method of weighing in air and -in water. As these measurements were required only as a check on casting, technique a high degree of accuracy was not essential (accuracy = -+ 0·2%).

Jan 1, 1942

Discussion Of the paper Of GEORGE K. BURGESS, J. J. CROWE, H. S. RAWDON, and R. G. WALTENBERG, presented at the Pittsburgh meeting, October, 1914, and printed in Bulletin NO. 93, September, 1914, pp. 2433 to 2437. ALBERT SAUVEUR, Cambridge, Mass.-The Bureau of Standards has once more rendered a public service. Manufacturers and consumers of steel rails alike should welcome the important results now laid before them by Dr. Burgess and his co-workers. Personally I welcome these results all the more that in the past, as some of the members may remember, I have never failed, when occasion arose, to call the attention of rail manufacturers to the importance of controlling the finishing temperature of their rails. The pioneer metallographic work conducted at the South Works of the Illinois Steel Co. in the early '90s clearly brought out the close relations existing between the manufacture, properties, and finishing temperature of steel rails and I think I may say without fear of being contradicted that the results of this early investigation had considerable influence in drawing the attention of manufacturers to the importance of finishing temperature and of heat treatment in general. The results now before us should be, it seems to me, of great value to rail manufacturers in their efforts to produce a better and, above all, a safer rail. It seems to be demonstrated in this paper that there is no difficulty in installing in rail mills pyrometric outfits, making it possible to record, without interfering in the mill operations, the temperature of the rails as they leave the finishing rolls, or of the ingots as they are withdrawn from the soaking pits, or at any intermediate point in the process of manufacture. The inference necessarily follows that manufacturers should see to it that such pyrometric installations are made, in order that they may actually know, instead of guessing at, the temperature of their rails;, and, for obvious reasons, rail consumers should insist upon such installations. In the rolling of heavy sections especially should care be taken to lower their finishing temperature, seeing that the present tendency is to finish them at higher temperature, whereas, owing to the slower cooling of their central portions, which makes for coarseness of grain, they should, if anything, be finished at a lower temperature than lighter rails.

Jan 4, 1915

By Benjamin Talbot

The problem of segregation and cavities in steel ingots is a subject which has given and is still giving metallurgists, engineers, and operators matter for serious consideration. This question has come more into prominence lately in the United States, due largely to the desire of railroad engineers to secure a better rail than they have obtained ill the past, as the service they demand is increasing in severity; and no doubt manufacturers will be able to meet what is required of them. The rails here are as good as those made in other countries, but the conditions of service and the extremes of climate are more Revere and consequently more breakages occur. Various reasons have been advanced to explain why rails may not be as good in quality to-day as in the past. Some engineers consider that modern methods of manufacturing, designed chiefly to obtain large output, tend to reduce the standard of excellence of more deliberate methods. Others think that 4-ton ingots are worse than those of 2 tons. Again, it is stated that the 100-ton heat in one ladle is too large, and is a step in the wrong direction in casting. My experience upon the question of the size of the ingot is that in rolling rails of from 85-to 100-lb. sections, the range of ingot is only practically such that the difference in the size does not help in the question of segregation, cavities, or blow-holes. I call attention to two ingots from work done at Pencoyd, Pa., 16 years ago. These ingots were bottom-poured, cast at the same time from the same center-runner, the one being 20 by 24 in. and the other 13 by 16 in. in size. The steel was acid open-hearth, and contained C, 0.43; P, 0.062; S, 0.069 per cent. At the same place in each ingot where seg-

Jan 1, 1914

By V. Vallyathan, Xianglin Shi, N. S. Dalai

While Cr(VI) is a known carcinogen, the underlying biochemical mechanism is still not fully understood (1). In a pioneering study Jennette (2) utilized electron spin resonance (ESR) spectroscopy to demonstrate that a long-lived Cr(V) species is generated during the reduction of Cr(VI) by microsomes in the presence of NADPH. Later Wetterhahn and co-workers (3, 4) showed that incubation of chromate with isolated rat liver mitochondria causes the reduction of Cr(VI), as well as the formation of a Cr(V) species. Analogous Cr(V) species have also been detected in the reduction of Cr(VI) by other cellular systems such as Hanserulla polymorphared (5) and blood cells (6, 7). All these as well as other studies (8-12) have suggested that this Cr(V) species plays a significant role in the mechanism of Cr(VI) toxicity. Thus far, however, the chemical structure of this dominant Cr(V) species formed in cellular systems has not been identified, and this observation provided an impetus for the present investigation. Another reason for undertaking this study was that some recent reports (10-16) suggest that hydroxyl ('OH) radicals may also play an important role in the mechanism of Cr(VI) toxicity. In particular, it has been shown that OH radicals are formed in reactions between Cr(V) species and H2O2 (13-16), and that the radical yield depends on the chemical structure of the Cr(V) species (15). For example, while Cr(V)-diol complexes efficiently generate OH radicals, another Cr(V) species, the tetraperoxochromate (CrO3/8) ion, does not (15). Thus in the present study, we focused our attention on the following: (a) structural identification of the Cr(V) species generated in the reduction of Cr(VI) by subcellular as well as cellular systems, using microsomes, mitochondria, and Escherichia coli; (b) possible detection of OH radical in the same systems since there is no earlier report of chromium-mediated generation of 'OH radicals in a cellular system; (c) possible involvement of molecular oxygen in chromium-related OH radical generation since a recent report (17) indicated that Cr(VI) mutagenesis is strongly oxygen dependent; and (d) elucidation of the mechanism of OH radical formation in these systems.

Mar 1, 1992

By J. Weijdema, D. N. Dietz

In the conventional underground combustion process (dry combustion) much heat is left behind in the swept formation and goes to rva.rte. Econonmy can be improved by heat recuperation through water injection. This is most advantageous if done at the earliest opportunity before much heat is dissiputed to cap and base rock. Water injected simultaneously with the air will flash to superheated steam, which passes through the combustion front together with the nitrogen from the air. A condensation front traveling up to three times as fast as the combustion front drives out the oil. In this type of wet combustion, the water evaporates before it reaches the combustion zone. The evaporation front travels more slowly than the combustion zone. If so much water is injected that the evaporation front overrun the combustion front, combustion in that spot will be quenched and some unburned fuel will be left behind. Air reacts with the oil farther down-stream where steam temperatures occur; at steam temperature, the air reacts rapidly with the oil. Velocity of the combustion front is increased thereby and is governed essentially by the water-injection rate. In the extreme case of high water-injection rate, a short heat wave of constant length is driven through the formation by water injection. Once this wave has been established, no more heat need be generated than that required to make up the heat losses from the short heat wave; a relatively low rate of air injection will suffice. The feasibility of partially quenched combustion has been confirmed in tube experiments. A heat wave at steam temperature is observed. Chemical analyses of flue gas indicate preferential burning of hydrogen while a carbonaceous residue is left in the formation. Introduction A disadvantage of so-called dry in situ combustion is that air-compression costs are rather high. An air consumption of about 400 std cu m/cu m (400 scf/cu ft) of formation swept is an accepted figure. This high consumption is mostly wasted since much heat is left behind in the depleted oil sand. Methods were investigated for recuperating as much as possible of the heat left behind. This paper deals only with basic principles and is confined mainly to one-dimen- sional flow without lateral heat losses; experiments were conducted in relatively narrow, well insulated tubes. If some water is injected with the air, it will turn to superheated steam in an evaporation front, which should travel behind the combustion front. The steam having passed the combustion front causes a steam drive by a condensation front that can travel faster than the combustion front. The latter needs to travel only part of the distance covered by the oil-displacing condensation front, and thus consumes less air. The water-air ratio would seem limited to that at which cold water overruns the combustion. This limitation was deliberately exceeded considerably in theory and experiments. It was found that combustion is then indeed quenched, but only locally. Farther downstream, the oxygen finds residual oil at steam temperature, which is suficiently high to ensure rapid oxidation. Thus, the combustion front uses only part of the available fuel because it is chased through the formation faster than its normal velocity. No heat is left behind. This new process is called "partially quenched combustion". At the upper limit of the water-air ratio, a small heat slug is moved through the formation by the flow of water and steam. Only a small flow of air is needed since it has only to generate sufficient heat to make up for the lateral heat losses of the short heat slug. Theory Although many factors complicate underground combustion, the processes will be presented in their simplest form. For this reason, one-dimensional flow without lateral heat losses is assumed. Heat conduction in the direction of flow also is disregarded. Under these conditions, dry combustion causes very high temperatures. The heat-carrying capacity of the gas stream is small. Heat generated by oxidation of a residual oil saturation is retained in the sand. The available fuel determines the air requirement and the temperature obtained. Accepting the often-mentioned air consumption of 400 std cu m/cu m (400 scf/cu ft) formation, we calculate a temperature of the swept sand of 1,200C (2,192F) (Fig, I). If water is injected at a modest rate with the air, it will flash to superheated steam upon contact with the heated sand. One cu m (35.31 cu ft) of hot formation will evaporate about 0.5 cu m (17.66 cu ft) of water, and thereafter will accommodate (at an estimated 0.80 saturation and an assumed 0.40 porosity) another 0.3 cu m (10.59 cu ft) of water in cold condition. As long as less than 0.5 + 0.3 = 0.8 cu m (28.25 cu ft) of water is injected for every 400 std cu m (14,125 scf) of air (water-

Jan 1, 1969

By J. P. Ferro, W. H. Stewart

Wet ground and dry muscovite mica continued to be the most commercially significant types of mica in the US. Canada's phlogopite mica and some US deposits of sericite mica have also contributed to the overall application of mica in a variety of industries. Mica's major end uses are paint, rubber, and construction material. Its value was about $30 million last year. The southern Appalachian Mountains weathered granitic bodies and pegmatites continued to be the primary US muscovite mica source. North Carolina production of mica as a coproduct of feldspar, kaolin, and lithium processing accounted for more than 60% of the total output. New Mexico, South Carolina, South Dakota, Georgia, and Connecticut accounted for the rest. Flake mica was also produced from mica schists in North Carolina and South Dakota. It is also being investigated in Ontario, Canada. Wet ground mica Wet ground mica was produced by four companies: KMG Minerals, Franklin Mineral Products, J.M. Huber Corp., and Concord Mica. KMG and Franklin Mineral Products accounted for more than 80% of the production. Wet ground mica is a highly delaminated platey powder used to reinforce solvent and aqueous system paints for increased weatherability, durability, and greater resistance to moisture and corrosive atmospheres. In plastics, it is an excellent filler and reinforcing agent, providing better dielectric properties, heat resistance, and added tensile and flexural strength. In the rubber industry, wet ground mica is used as a mold lubricant to manufacture molded rubber products, such as tires. It also acts as an inert filler that reduces gas permeability. Miscellaneous uses include additives to caulking compounds, foundry applications, lubricants, greases, silicone release agents, and dry powder fire extinguishers. Wet ground mica prices range from $353 to $496/t ($320 to $450 per st) fob plant. Specialty products may be higher, depending on customer requirements. Dry ground muscovite mica Dry ground mica was produced by nine companies: KMG Minerals, Unimin, US Gypsum, Mineral Industrial Commodities of America, Spartan Minerals Corp., Asheville Mica Corp., Deneen Mica Co., Pacer Corp., and J.M. Huber Corp. Dry ground mica's primary market is wallboard joint compound. Here, it is a functional extender that improves the physical properties and finishing characteristics of the mud. It is also used in various grades as a filler in asphalt products, enamels, mastics, cements, plastics, adhesives, texture paints, and plaster. Dry ground mica became popular as an additive in oil well drilling fluids, where the mica flakes platey nature helps seal the well bore, preventing circulating fluid loss. But oil's dramatic price drop and consequent curtailing of well drilling brought this once booming market to a virtual halt. Forecasters predict that this business will gradually pick up during the next few years and most current dry ground mica producers will again produce the oil well drilling material. Dry ground mica prices range from $110 to $420/t ($100 to $380 per st) fob plant. High quality sericite mica, sometimes referred to as an altered muscovite, was mainly produced by two US companies. Mineral Industrial Commodities of America and Mineral Mining Corp. have equivalent capacities of about 27 kt/a (30,000 stpy). The majority of the material produced was consumed by the joint compound industry. Minor uses are in paint and oil well drilling. The lack of ground sericite penetration into the traditional ground muscovite markets is attributed to high silica content, typically in excess of 20%, and a bulk density. Prices range from $88 to $187/t ($80 to $170 per st) fob plant. Phlogopite mica is a dark colored, magnesium bearing mica rarely found in the US. Suzorite Mica Corp., a division of Lacana Petroleum, mines a deposit in Quebec that is 80% to 90% phlogopite. The dark color has prevented the material's entry into the traditional paint markets. But the physical properties and high purity make it useful as a low-cost reinforcing filler in many plastics and several asphalt applications. Phlogopite mica is ground to several grades and may be treated with various surface coatings for use in plastics or coated with nickel for EMI/RFI shielding applications. Prices for phlogopite products range from $144 to $580/t ($104 to $580 per st) fob plant. As in recent years, production of domestic muscovite sheet - block, film, and splittings - remained insignificant. These resources are limited and uneconomic due to the high cost of hand labor required to process sheet mica in the US. Imports from India and Brazil were the primary sources of the estimated 1 kt (2.4 million lbs) valued at $2.5 million consumed by US electronic and electrical equipment manufacturers in 1986. Reserves As a feldspar, kaolin, and lithium industry coproduct, flake mica will continue to provide a large percentage of mica re- This summary of 1986 mica activity was received too late to be used in the June issue.

Jan 7, 1987

By Harry Verakis, Thomas Lobb

This paper is a summary and an update of the underground mine blasting accident investigations and studies previously conducted by the Mine Safety and Health Administration (MSHA) and the former US. Bureau of Mines. Blasting accidents are usually a small percentage of the total number of mining accidents. However, blasting accidents continue to occur and the severity of these accidents is disproportionately high with respect to other types of mining accidents. In 2000, about 5.7 billion pounds of explosives were produced in the USA. The mining industry consumed the greatest portion of explosives manufactured for blasting with about 67 percent used for coal mining. Metal and nonmetal mining operations account for about 23 percent of the use of explosives. The use of permissible explosives in underground coal mines continues to decline (3,373,069 pounds for 2000).

Jan 1, 2002

By B. K. Gorain

"The Air-Metabisulfite (AMBS) process has been developed to treat complex copper, molybdenum and precious metals (gold, silver) bearing ores using brackish and sea water. This process was able to produce significantly better copper concentrate grades and higher recovery than possible using conventional lime and/or cyanide based processes for certain complex ores with high sulphide gangue minerals. The AMBS technology in now used commercially following a rigorous evaluation process emanating from laboratory curiosity to plant applications. In addition, many projects have embraced this technology at a feasibility level involving various complex ore bodies.This paper presents a summary of the findings from testing the AMBS technology on various ores types. Experiences gained from this successful development from bench to piloting and then to plant applications are also presented in this paper.INTRODUCTIONProcessing of sulphide copper, molybdenum and precious metal ores typically involves flotation of copper bearing minerals while depressing non-sulphide and other non-copper sulphide minerals such as pyrite, pyrrhotite and sometimes arsenopyrite. Though in many precious metal ores, the values are in these sulphide minerals as well. The conventional method employed in the industry to produce a saleable copper concentrate requires depression of these non-copper sulphide minerals using an alkaline pH above 9.5, though 10.5 to 11.5 is more common. Alkalinity is controlled by the addition of a pH modifier. Lime is normally employed as a pH modifier due to its relatively low cost; however, the costs associated with adding lime can be significant and the effectiveness of lime as a depressant could be drastically reduced when the process water supplied to the flotation circuit contains high level of dissolved salts. In some cases, a small amount of cyanide is used along with lime to depress non-copper sulphide minerals especially when its proportion to copper sulphide minerals in the ore is higher than three."

Jan 1, 2016