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By Michael Drozd

Introduction Flotation is a recovery process that utilizes natural or chemically-introduced hydrophobicity of minerals to separate ore from gangue by attaching the ore particles to bubbles. Flotation has been known since 1906, when it was patented by E. L. Sulman, H. G. K. Pickard and John Ballot. Flotation's first documented plant use was in 1911, when it was used on gravity tailings from a zinc plant. Cyanide leaching was first patented in 1887. Most early precious metals flotation was linked to lead or copper concentrates. Most precious metal flotation is linked to sulfide recovery and utilizes such reagents as xanthates, dithiophosphates and thiocarbanilides. But the involvement of flotation in precious metals recovery does not have to be limited to active flotation of the gold and silver bearing minerals. Flotation can be used to remove interfering minerals, such as carbon, or cyanicides, such as copper, arsenic bearing minerals or other cyanide complexing minerals. Cyanide Leaching The use of cyanide to recover precious metals is the backbone of the industry. The various recovery processes that use cyanide are: 1. Leaching-Counter Current Decantation(CCD) Merrill-Crowe 2. Carbon-in-pulp (CIP) 3. Carbon-in-leach (CIL) 4. Vat leaching 5. Heap leaching These processes are selected depending on ore grade, ore leaching characteristics, reserve size and capital limitations. Ore grade is used as the first criteria to determine the type of cyanide plant required. However, the reserve size can determine whether a ground ore alternative is used. The ore leaching characteristics may indicate that the higher recovery, associated with a process that employs grinding, is the only economic recovery alternative. There are some extremely large leaching plants with grades that would be non-economic for some existing heap leach plants. Many factors, such as strip ratios, metal recovery and reserve size, determine what the ultimate plant design will be. The exact processing scheme that is used, is a multifaceted decision matrix, which gives the process metallurgist some job security. Precious Metal Recovery Using Flotation Flotation recovery can conceivably be used on any ore that has been ground. Many operations utilize gravity separation on the ore to remove native gold from the ore prior to sending it to cyanide leaching. On certain ores, where the gold is in visible nuggets or particles, this processing alternative is advantageous because the native gold cyanide recovery is

Jan 1, 1993

By C. Hendricks

This paper is based upon field studies conducted in a western Canadian open pit coal mine. This work has involved the adaptation of microprocessor-based instrumentation to monitor various operating parameters on-board blasthole drills and mining shovels. A review of instrumentation and monitoring methodology will first be presented. Based upon experience from field-based studies, the paper will subsequently focus on the application of monitoring technology within the framework of an integrated Equipment Monitoring System. Such a system will permit the real-time performance evaluation of key equipment involved in surface mille production.

Jan 1, 1991

By Walter Voglauer, Elisabeth Zechmeister

Five serial photos show the first second of the demolition of a 75 m high, reinforced concrete tower in the 23rd District of Vienna, Austria. The tower demolition with high explosives was necessary because a 175t excavator could not finalize the destruction with mechanical tools. All mechanical works in preparation of the blast, such as the borehole drilling, were done by civil companies under the responsibility of the contracted demolition company PRAJO. The blasting itself was planned and executed by the engineer corps of the Austrian Armed Forces, Sunday, May 26, 2013. Nearly 800 boreholes filled with more than 100 kg of military plastic explosives were initiated with about 1,600 Austin electric delay detonators in exactly 1,000 ms and 30 steps of delay. The 10,000 tons of reinforced concrete tower fell as planned without any damage to the environment. Photo 5. The rest of the detonators initiate the water pools filled with high explosives forming a bizarre white water front to fight the following strong development of dust. The first 1,000 milliseconds are over.

Jan 1, 2015

By C. Wen

In Huoqiu region of Anhui Province, Fe2O3 occurs mainly in the form of specularite. Besides quartz, the gangue minerals include iron-bearing silicates such as chlorite and sericite which account for about 10% of the total gangue. The separation effect of conventional collectors is poor in the flotation of the minerals, that is, the average grade of iron concentrates is only 60-62%. Using the developed amphoteric collector can successfully realize not only the separation of specularite from various gangue minerals with results of iron concentrate grade above 65% and iron recovery of above 80% but also low temperature flotation at 15°C.

Jan 1, 2012

By B. Chalmers, Stefan Wojciechowski

Rotary oscillation of the mold has been used to produce mechanical stirring of the melt during unidirectional solidification. Al-Cu alloys (1 to 4 wt pct Cu) were solidified to study the influence of alloy composition, temperature at which intensive cooling was initiated, and intensity of stirring on the temperature distribution in the sample, the resulting structure, and the copper microsegregation at the columnar to equiaxed transition. The Proposed explanation for the equiaxed solidification in stirred castings consists of the melting off of dendrite fragments, their partial remelting in hotter liquid, and the subsequent growth of the surviving part when the temperature of the melt is lowered. This may result in the formation of a crystal network, which can stop the growth of the columnar crystals and produce the equiaxed zone. It has long been known and many times affirmed that ultrasonic vibrations or relative motion of liquid and solid can significantly reduce the length of the columnar zone and refine the grains in the equiaxed zone in ingots and castings. Because of the technological importance of these phenomena many investigations have been conducted in which ultrasonic energy or mechanical vibration,1-6 electromagnetic stirring,7"10'17 magnetic stirring,"'12 or mechanical stirring13'14 were used to produce the relative liquid-solid motion. More recently, the question of the importance of natural (or thermal) convection has been raised.15-l7 Several possible mechanisms have been suggested.l,8,18-20 They can be divided into two main groups. The first group includes such nucleation hypotheses as nucleation frequency enhancement due to cavitation at the mold wall or other surfaces; cavita-tion in the body of the liquid resulting from the pressure wave, or an agglomeration mechanism, which involves the formation of nuclei by the accretion of subcritical nuclei. The second group considers the grain-refining action to be due to crystal multiplication phenomena such as the removal of the dendrite fragments by viscous forces or by a high-pressure cycle following cavitation or by a melting-off process. Sbme recent investigations give good experimental support to the melting-off proposa1.21-23 The purpose of the present study was to examine the effect of mechanical stirring during the unidirectional solidification on the structure of alloy samples and on the solidification variables. The motion of the liquid was produced by rotary oscillation of the mold around its vertical axis.

Jan 1, 1969

By Dale S. Preece, Lee M. Taylor

Accurate computer prediction of the muck pile produced by a conventional blast requires modeling of the physics that occurs during the rock motion phase of a blast. The ability to predict the motion and the subsequent muck pile can have a significant economic impact on the mining industry.

Jan 1, 1990

By B. Simser, V. Falmagne

"Noranda’s Brunswick mine is a 10 000 t/d producer of lead-zinc-copper-silver ore that has been in operation since 1964. Mining of this multiple lens deposit is primarily by blasthole stoping techniques between 400 m and 1200 m below surface. The combination of a high overall extraction ratio, an overall steeply dipping tabular shape, and high horizontal stresses (twice the vertical) have elevated the induced stress regime to levels comparable to much deeper operations. Improved mine design, and a better understanding of how the rock mass responds to mining in high-stress environments is essential to improve overall recoveries and maintain safety. Seismic monitoring has proven to be an essential tool at Brunswick, for both short-term safety of workers, and long-term strategic planning.Practical case studies illustrate how seismic data, particularly source parameter information, can be used to measure the rockmass response to mining and improve mining layouts in difficult regions. As the global trend continues toward mining in deeper, higher stress environments (e.g., South African Witswatersrand Basin, Sudbury Basin) and as local extraction and thus ground stresses continue to increase in existing deposits, seismic monitoring will play a critical role in mining safely and economically."

Jan 1, 2004

By B. Simser

Noranda?s Brunswick mine is a 10 000 t/d producer of lead-zinc-copper-silver ore that has been in operation since 1964. Mining of this multiple lens deposit is primarily by blasthole stoping techniques between 400 m and 1200 m below surface. The combination of a high overall extraction ratio, an overall steeply dipping tabular shape, and high horizontal stresses (twice the vertical) have elevated the induced stress regime to levels comparable to much deeper operations. Improved mine design, and a better understanding of how the rock mass responds to mining in high-stress environments is essential to improve overall recoveries and maintain safety. Seismic monitoring has proven to be an essential tool at Brunswick, for both short-term safety of workers, and long-term strategic planning. Practical case studies illustrate how seismic data, particularly source parameter information, can be used to measure the rockmass response to mining and improve mining layouts in difficult regions. As the global trend continues toward mining in deeper, higher stress environments (e.g., South African Witswatersrand Basin, Sudbury Basin) and as local extraction and thus ground stresses continue to increase in existing deposits, seismic monitoring will play a critical role in mining safely and economically.

May 1, 2004

By R. J. Teitel

The Pb-U system has been investigated by X-ray, thermal, and microscopic analyses. Two pyrophoric intermetallic compounds were found; UPb3 and UPb. The crystallographic structure of UPb3 is reported. A phase diagram was drawn for the system showing three eutectic and one syntectic reaction. AS a result of the interest in uranium metallurgy, the Pb-U system has been investigated. Practically no quantitative data appears in the literature concerning this system. Chips were machined from bars of high-purity uranium obtained from Ames Laboratory and the lead was 99.9 pct high-purity grade from Bel-mont Smelting & Refining Co. The chips were pickled in a dilute solution of nitric acid, washed in water and then alcohol, and dried prior to use for alloy preparation. The lead was simply sheared from the pig with no chemical treatment. Lead and uranium were placed in graphite crucibles and loaded into an induction furnace. In order to insure good alloy formation, the lead was loaded above the uranium to wash the uranium chips into the melt. After the charge was held at the desired preparation temperature for 15 to 30 min, it was allowed to cool in the crucible. The entire melting operation was accomplished in an atmosphere of helium (double charcoal refined grade with no further treatment). The procedure was to outgas the furnace by first evacuating it to 10-% m Hg, admitting helium to 8 psi gage and sealing the furnace off. An optical pyrometer focused on the charge through a hole in the crucible cover was employed for thermal measurements. Usually a 50° to 70°C correction had to be added to the instrument value. The most suitable alloy preparation temperature range was found between 1220° and 1280°C. The reason for this is explained by the phase diagram, Fig. 7. Above this temperature range two liquids separate preventing alloy formation upon cooling at a reasonable rate. On the other hand, below this range the uranium was coated with a layer of both compounds and the rate of reaction was diminished by diffusion processes. The fastest reaction rate occurred in this narrow range of temperature because only UPb coats the uranium and it evidently does not protect the uranium as well as UPb,. Apparatus and Procedures The development of apparatus and techniques was determined by the peculiar properties of the alloys. All the alloys were pyrophoric, and, consequently, the alloys had to be protected from oxidation by handling them in a dry box or inert atmosphere furnaces. Other operations performed outside of this equipment had to be done as quickly as possible. Thermal analyses were conducted in a furnace and arrangement similar to that described by the author.' Graphite crucibles having a thermocouple well in the bottom were used to contain the prepared alloy, while a helium atmosphere protected the melt from oxidation. The furnace was outgassed by pumping a 10-3 mm Hg vacuum until the furnace had been heated to 400°C. Then helium was admitted and the furnace sealed under 8 psi gage pressure. Chromel-alumel thermocouples were used for thermal analysis and the accuracy of thermal measurements was judged to be k 5°C. At first, an attempt was made to use platinum-platinum-rhodium thermocouples, but evidently lead vapors attack it at high temperatures forming low melting alloys. These lead vapors had direct access to the thermocouple because the graphite crucible was porous. A differential temperature control was used to regulate thermal analyses. The thermal gradient across an alundum tube placed between the windings and the crucible was maintained constant by a controller.

Jan 1, 1953

By G. S. Scott

It is sometimes desirable to know what changes in sizing characteristics would appear in screened coals if screens of different - size openings than those employed had been used . This report is concerned entirely with the application of the Rosin- Rammler law to a solution of this problem .

Dec 1, 1943

Following the Coalbrook Colliery disaster in 1960, Salamon and Munro (1967) established the well known empirical coal pillar strength formula in South Africa. This formula has prevented further violent multiple pillar failures. In 1996, a back analysis of the collapsed and uncollapsed cases in Australia led to the development of the Australian empirical coal pillar strength formulae. The original collapsed and uncollapsed coal pillar database of Salamon and Munro (1967) was updated in 2006. This study introduced various strength formulae for different coalfields and seams in South Africa through back analyses of collapsed and uncollapsed cases. Today, the resultant pillar strength formulae from these previous studies and the behaviour of coal pillars are mostly well understood and applied with confidence. However, it was assumed in the previous studies that the behaviour of pillars is not time dependent; therefore, the formulae established do not provide an associated time to failure of coal pillars. This paper attempts to evaluate the so called 'Geometrical Limits' concept to provide the Australian coal mining industry with a tool to assess the long-term behaviour of bord and pillar workings where the pillars are prone to failure due to spalling of ribs. In order to achieve this outcome, the principles of the safety factor concept and the probability of failure calculated using the coal pillar strength formulae have also been evaluated and practical design examples are presented in this paper.

Nov 25, 2010

By Faruk Oksuz, Phillip L. Covell, Martin Doll

A series of difficult ground conditions causing high groundwater inflows and hazardous gas intrusion abruptly halted the construction of a 6.4-meter (21-foot) finished diameter and 1,890 meters (6,200 feet) long tunnel planned to serve as a 4-millioncubic meters (1-billion gallon) per day capacity river outfall for treated wastewater. Some 808-meters (2,650-feet) section of the constructed tunnel, TBM, and all other tunneling equipment were completely flooded with hydrogen sulfide laden artesian groundwater. The subsequent pumping and tunnel recovery efforts were unsuccessful and the tunnel was abandoned. In the end, the construction contract was terminated and options to redesign and reconstruct the project were re-evaluated to maximize the use of already constructed tunnel facilities such as the construction access and inter-mediate shafts and six outfall diffuser shafts in the river.

Jan 1, 2007

By Desmond Y. M. Lee

This paper presents a procedure to prepare input for the computerized pit design system at Iron Ore Company of Canada. The procedure is simple and requires very little training. Also, it is general enough to accept both bench (horizontal cross section) maps and section (vertical cross section) maps. The output of this procedure is data which represent blocks of ore and waste with dollar values based on mineral content. The ultimate pit design is presented in printer-generated graphs, with numbers indicating the depths of pit bottom walls. Roads are added manually by the engineer with the aid of other computer programs. Section maps and bench maps are also printed as part of the output of the ultimate pit design.

Jan 1, 1978

The first of this three part series examines he history and some of the properties and characteristics of explosives. Use of explosives is discussed for underground and surface coal operations—the largest consumers in the mining industry. Part two of the series will deal with explosives use in surface and underground hardrock operations. Part three will discuss explosives transportation, storage, handling, and destruction.

Jan 7, 1981

By Regis F. Kopac

With the growing dependence on coal as an energy source, finding a means to prevent or reduce the freezing of coal during winter shipment has become increasingly important. Several chemical companies focused on this problem and applied chemical technology to develop suitable solutions. As a result, a number of freeze conditioning agents have been introduced in the past few years, several of which have been highly effective in controlling frozen coal. The efficacy of these chemicals has been well established, however many users have found that only a well defined program will produce acceptable results at a reasonable cost. Positive program results yielding recognizable benefits have caused many power generating and coking plants to consider freeze conditioning agents. A freeze conditioning agent (or FCA) has been defined as a multi-component organic liquid designed to be sprayed on coal particles at bulk shipping points to assure that receiving locations will be able to unload, store and use the treated coal with minimum delay or inconvenience. The chemicals are generally applied at rates of 1 to 2 pints (0.473 to 0.946 liters) per ton and normally function by changing the crystalline structure of water left on the coal during processing. The bond strength of the ice that may subsequently form is markedly reduced. Instead of freezing into solid, unmanageable masses, the coal can be easily unloaded by rotary dumping or the opening of hopper car doors.

Jan 1, 1980

By Carlos Rebolledo, Nelson Parra

Arsenic is an unresolved problem in the mining industry considering the fact that most of the new copper deposits have high arsenic contents; stricter environmental restrictions for handling, transporting and processing complex materials are expected and stable abatement of arsenic is not extensively applied. In 2018 Chile produced 24.5% of the total copper from concentrates and in the future copper production in Chile is expected to increase, mainly associated with production of concentrates that will also contain more arsenic. China has set an import benchmark of maximum 0.5% for arsenic content in copper concentrates and this value is expected to be more restrictive in the future. On the first day of 2018 China banned the importation of scrap. Blending practice has been a business option, but it is not sustainable in the future, as “normal” copper concentrates become less and less clean. By the end of 2018, Chile formulated new regulations, increasing the capture of SO2 and arsenic to 95%. In order to comply with these regulations Chilean smelters had to make large invest large amounts of money. Disposing of arsenic as a stable residue is a pending issue. EcoMetales is a 100% subsidiary of Codelco and provides the mining industry with environmental solutions. It has a plant near Calama in Chile that treats flue dust from smelters, refinery effluents and acid solutions from acid plants. EcoMetales is fully committed to contributing to the solution to the arsenic problem. Currently we are developing four main projects: 1) Concentrates treatment. A PLCC project considering the treatment of 200 ktpy of copper concentrates with arsenic from the northern district of Codelco; 2) EPAS DET project considering the treatment of 700 m3/d of weak acid solution with arsenic from the of El Teniente devision of the Codelco acid plant; 3) Borras project, considering the recovery of valuable metals (Cu, Ag, Ge, Pb) from the flue dust leaching plant; 4) Tailings project, considering the recovery of metal values from tailings. The purpose of this work is to present the trends and treatment processes for arsenic handling in the copper mining industry with a focus on the scorodite process. INTRODUCTION Between 2000 and 2015 the global copper concentrates production has grown from approximately eleven to fifteen million metric tons per year. Chile produced 26.5% of the total copper from concentrates and in the future copper production in Chile is expected to increase, mainly as a result of the production of concentrates (Figure 1)

Jan 1, 2019

By W. J. Miles

Many years ago, a relationship was established between dust inhalation and pneumoconiosis. Since then, various government agencies have regulated crystalline and amorphous forms of silica material in the workplace. In 1987, the International Agency for Research on Cancer (IARC) classified crystalline silica as a probable carcinogen. With this listing, crystalline silica became a regulated substance under the Hazard Communication Standard. The minerals and chemicals industries have responded in various ways. They have: • developed worker and user training programs and literature; • labeled products with appropriate warnings; • continued to implement dust reduction programs; and • developed meaningful epidemiological studies of workers. • begun development of reliable analytical methods for measuring crystalline silica at the 0.1 % threshold level; Background Silicosis historically has been the major health hazard resulting from exposure to crystalline silica. Silicosis is the scarring of the lung from excessive exposure to crystalline silica. It has been recognized as an occupational disease for more than 2000 years, since early Greek physicians noted the respiratory problems of miners, stonecutters, and quarrymen who were exposed to excessive quantities of mineral dust. During the industrial revolution, the incidence of the disease was greatly increased by the use of machinery that increased dust levels. Subsequently, the need for dust control was recognized and measures were instituted. Silicosis is characterized by progressive breathlessness on exertion and develops over the course of years. Xray images of the lungs show

Jan 1, 1990

By Celine Y. Zhang, Chloe J. Feng, Charles Q. Jia, Donald W. Kirk

Oil sands petroleum coke (OSPC) is a by-product of coking - a high-temperature process that converts the mined bitumen to the synthetic crude oil (SCO). For every barrel of the SCO produced, about 20 kg of OSPC are generated. Over 70 million metric tons of OSPC have been produced and stockpiled as a result of the development of oil sands industry in the past few decades. Unlike conventional petroleum coke, OSPC has uniquely high impurity contents, particularly sulphur (~ 7 wt%) and metals (e.g. vanadium at ~0.15 wt%), which has hindered its large-scale applications as a solid fuel. Vanadium is a valuable metal that is widely used as an alloy for strengthening steels. The stockpiled OSPC contains about 100,000 tons of vanadium, while the world’s production in 2013 was only 75,600 tons. At the current price of $25US/kg, the OSPC-bound vanadium represents a total value of $2.5 billion US dollars. In this work, we investigate the technical feasibility of extracting vanadium from OSPC. The work focuses on the characterization of vanadium in OSPC and the conditions for effective extraction of vanadium from the OSPC.

Jan 1, 2015

By James J. Dowd

The investigation to evaluate the reserves of coking coal in the United States suitable for the manufacture of metallurgical coke is being made by the Bureau of Mines in three parts: (1) To estimate known measured and indicated recoverable reserves of all coking coal; (2) to upgrade marginal coals through effective preparation; and (3) to study the carbonizing properties of coals and coal blends not now widely used for metallurgical coke making. This is the eighth of a series of reports giving the results of studies by counties under part (1) of the investigation. (See appendix.) This report covers Jefferson County, Pa., which comprises parts of Marienville, Hallton, Ridgway, Brookville, DuBois, Penfield, Smicksburg, and Punxsutawney quadrangles. (See fig. 1.) A short resume of the chemical and carbonizing properties of the coals is included. Data on the coal beds in the county were obtained from mining companies, land companies, individual landowners, and other sources of authentic information. A base map for each bed in each quadrangle was made to the scale 1 inch equals 1,200 feet. Maps of mines, locations of drill holes, bed and total coal thicknesses, and the outcrop of the bed were plotted on the maps. With all available data plotted, isopach lines were drawn to limit areas of known unmined reserves in beds 0 to 14 inches thick, 14 to 28 inches thick, 28 to 42 inches thick, and over 42 inches thick, These areas of coal reserves also were divided into "measured" and "indicated" categories. All areas in each thickness range and in each category, mined-out areas, areas excluded from the estimate, and areas outside of the outcrop were measured by planimeter on the base maps. Estimates of total reserves 14 inches and more thick and maps for individual beds were prepared from these data.

Jan 1, 1952

By P. M. Budge, William L. Fink, Kent R. Van Horn

The investigation of the phase relations of high-purity aluminum-base alloys is a part of the fundamental research program of the laboratories of the Aluminum Company of America. The results of a number of binary and ternary systems have previously been published in the Transactions of this society. The aluminum end of the binary aluminum-titanium system has been studied. This system has received relatively little attention. To the authors' knowledge, there are two previous papers on this subject. E. van Erckelensl determined the constitutional diagram reproduced in Fig. 1. According to this diagram, the liquidus represents the separation of TiA14, (Ti = 30.7 per cent.). He concluded that this is the composition of the compound, because in his work the eutectic horizontal terminated at 30.7 per cent. titanium and the metallographic examinalion of a sample of this composition revealed only one phase. According to the constitutional diagram developed by W. Manchot and A. Leber,² reproduced in Fig. 2 from data given in their article, the liquidus represents the separation of the compound TiA13 (Ti = 37.2 per cent. ). The composition of the compound was derived in a manner similar to that utilized by van Erckelens. Moreover, Manchot and Leber confirmed the composition of the compound by analysis of the constituent left as a residue after dissolving the alloys in weak sodium hydroxide solution. Although these are the only publications describing the constitution of the system, other investigators have studied the composition of the titanium compound. L. WÖhler3 says that there is a compound TiA13 which was later confirmed by W. Manchot and P. Richter4 and by

Jan 1, 1931