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By W. R. Hibbard

THE classical work on the electrical conductivity of alloys was carried out by Matthiessen and his coworkers1 in the early 1860's. He attempted to correlate the electrical conductivity of alloys with their constitution diagrams, but the information regarding the latter was too meager for success. Guertler2 reworked Matthiessen's and other conductivity data in 1906 on the basis of volume composition (an application of Le Chatelier's principle with implications as to temperature and pressure effects), and obtained the following relationships between specific conductivity and phase diagrams (plotted as volume compositions) : 1—For two-phase regions, electrical conductivity can be considered as a linear function of volume composition, following the law of mixtures. 2—For solid solutions, except intermetallic compounds, the electrical conductivity is lowered by solute additions first very extensively and later more gradually, such that a minimum occurs in systems with complete solid solubility. This minimum forms from a catenary type of curve. Intermetallic compound formation with variable compound composition results in a maximum conductivity at the stoi-chiometric composition. Landauer" has recently considered the resistivity of binary metallic two-phase mixtures on the basis of randomly distributed spherical-shaped regions of two phases having different conductivities. His derivation predicts deviations from the law of mixtures which fit measurements on alloys of 6 systems out of 13 considered. Volency (Ionic Charge) Perhaps the first comprehensive discussion of the electrical resistivity of dilute solid-solution alloys was presented by Norbury' in 1921. He collected sufficient data to show that the change in resistance caused by 1 atomic pct binary solute additions is periodic* in character. The difference between the period and/or the group of the solvent and solute elements could be correlated with the increase in resistance. Linde5-7 determined the electrical resistivity (p) of solid solutions containing up to about 4 atomic pct of various solutes in copper, silver, and gold at several temperatures. He reported that the extrapolated"" increase in resistance per atomic percent addition is a function of the square of the difference in group number of the solute and solvent as follows: ?p= a + K(N-Ng)2 where a and K are empirical constants and N and Ng are group numbers of the constituents. This empirical relation was subsequently rationalized theoretically by Mott,8 who showed that the scattering of conduction electrons is proportional to the square of the scattering charge at lattice sites. Thus, the change in resistance of dilute alloys is propor-t,ional to the square of the difference between the ionic charge (or valence) of the solvent and solute when other factors are neglected. Mott's difficulty in evaluating the volume of the lattice near each atom site where the valency electrons tend to segre-gate: limited his calculations to proportionality relations. Recently, Robinson and Dorn" reconfirmed this relationship for dilute aluminum solid-solution alloys at 20°C, using an effective charge of 2.5 for aluminum. In terms of valence, Linde's equation becomes ?P= {K2 + K1 (Z8 -Za)2} A where K1 and K2 are coefficients, A is atomic percent solute, Z, is valence of solvent, and Zß, is valence of solute. Plots of these data for copper, silver, gold, and aluminum alloys are shown in Fig. 1. The values of K1 and K2 are constant for a given chemical period (P), but vary from period to period. The value of K, increases irregularly with increasing difference between the period of the solvent and solute element (AP), being zero when AP is zero. The value of K, appears to have no obvious periodic relationship. All factors other than valence that affect resistivity are gathered in these coefficients. Because of the nature of the coefficients, Eq. 1 is of limited use in estimating the effects of solute additions on resistivity unless a large amount of experimental data are already available on the systems involved. It is the purpose of the first part of this report to investigate the factors that may be included in the coefficients of Linde's equation. On this basis, it is hoped that the relative effects of solute additions on resistivity can be better estimated from basic data, leading to a more convenient alloy design procedure. It is well 10,11 that phenomena that decrease the perfection of the periodic field in an atomic lattice, such as the introduction of a solute atom or strain due to deformation, will also increase the electrical resistivity. Thus, in an effort to relate changes in electrical resistivity to alloy composition, it appears appropriate to consider the atomic characteristics related to solution and strain hardening

Jan 1, 1955

By Timm Schoening, Greinert. Jens, Iason –. Zois Gazis

"Ferromanganese nodules are again of interest because of their high concentrations of Ni, Co, Cu as well as REE. With regards to an operational underwater mining industry, one of the main questions and important requests is to finding a method that can predict the abundance of nodules with high accuracy within reasonable time spans, without many requirements for ground truth data; and all these on an operational scale and ideally automated. In this regard, we present results of a study based on the combination of highresolution multibeam and optical data acquired by an AUV using specific machine learning techniques to reveal a detailed distribution of the Mn-nodules in correlation to the seafloor terrain. The accuracy of the method employed and results gained were validated and approved through comprehensive statistical analysis and by comparison to box-core data.Study AreaOur study area (AUV survey block G77) is located in the Clarion-Clipperton Zone (CCZ) (Eastern Central Pacific Ocean), an area that has been receiving international research and industrial attention for many years already (e.g. McKelvey et al., 1979; Bernhard and Blissenbach, 1988, von Stackelberg and Beiersdorf, 1991, Jeong et al. 1996). Block G77 covers an area of 9.5km2 in a depth between -4478m and -4536m. The area is characterised by gentle slopes 0-5° (0-3° in most of the area and only in the outer parts of the Block slopes can exceed 5°). The seafloor is characterised by moderate to low rugosity, the only exception being a small area in the eastern part, where sub-recent smallscale volcanic activity created 15 cone-shaped morphological features of up to 55m height and 150m width that are clustered in an area of 700 x 380m (Figure 1)."

Jan 1, 2017

By William C. Cooley

Data on equipment and components which have been used in hydraulic mining experiments, tests, and operations were collected from the literature. Also data were obtained from U.S. manufacturers and suppliers of equipment which is potentially applicable and available in the U.S. for hydraulic mining. The data have been divided into 24 main categories (see the following page) and have been assembled on two-page data sheets which follow. Wherever possible, drawings or photographs are included immediately after each data sheet.

Jan 1, 1975

By M. S. Seltzer

High temperature steady-state creep rates have been determined jor lead sulfide single crystals whose defect concentrations were fixed by equilibration under controlled sulfur pressure. The activation energy of creep, Qc , for undoped lead sulfide, is a function 01 composilion, decreasing from 2.9 to 2.2 ev as the carrier concentration increases from 9 x 1016 to 8 1018 electrons cm-3 for lead excess crystals, and increasing from 1.7 to 2.3 ev as the concentration of holes increases from 4 x 1017 to 1 x 1018 cm-3 in sulfur excess material. For five different composilions, Qc for undoped and bismuth-doped crystals has been found to be equal to Qpb + Qs, the self-diffusion activation energies for lead and sulfur in PbS. It is well-established1 that high-temperature steady-state creep of pure metals is a diffusion-controlled process, where the activation energy of creep is equal, within experimental error, to the activation energy of self-diffusion. The relationship between the activation energy for steady-state creep and those for self-diffusion in binary compounds is more complicated, however, because two different diffusing species must be considered, and becayse the activation energies may be influenced by compositional variations and by foreign atom additions.2-4 In some cases experimentally determined creep activation energies are correlated with those for self-diffusion of the slower-moving species, but such agreement is by no means universal. Interpretation of experimental results is difficult because few investigations include measurements of creep rates and self-diffusion coefficients of both diffusing species on single crystals of similar composition and foreign atom concentration. The objective of this investigation, therefore, is to determine the influence of stoichiometric defects and foreign atoms on steady-state creep and self-diffusion for a well-characterized binary compound. Lead sulfide, a compound semiconductor which crystallizes in the NaC1-type structure, and whose homogeneity range includes compositions on either side of the 1:l atom ratio, was chosen for study in this investigation. The pressure-temperature-composition relations for PbS are available,5,3 and deviations from stoichiometry may be monitored by electrical measurements.7 Single-crystal specimens are available to allow observation of effects due to bulk phenomena without interference from grain-boundary effects. These crystals have been employed to determine steady-state creep rates under compressive stress for "pure" and bismuth-doped PbS as a function of sulfur pressure and temperature as well as crystal orientation and applied stress in order to establish the relationships between defect concentrations and creep rates. EXPERIMENTAL PROCEDURES Crystal Growth. Lead sulfide crystals, prepared by the Bridgman method, are grown in evacuated quartz crucibles, filled with almost equal atomic proportions of high-purity (99.999 pct) lead and sulfur, and heated to a temperature above the melting point of PbS (about 1127°C) so that the lead and sulfur react to form molten PbS. The crucible and melt are dropped through the hot zone of the crystal-growing furnace at the rate of 1 cm per hr. The maximum melting point of PbS is slightly on the lead-rich side of the 50:50 composition; hence crystals grown from a near stoichiometric melt are usually n-type semiconductors containing excess lead atoms. Typically the lead excess concentration in solid solution with the PbS is 3 x 1018 atoms cm-3. Crystals containing either 1/20 or 1/2 mole pct Bi2S3 were prepared by addition of the foreign atoms prior to crystal synthesis. Preparation of Specimens of Controlled Stoichiom-etry. Since it is difficult to grow crystals of desired composition, the process of crystal growth and control of stoichiometry are separated into two distinct operations. Equilibration of as-grown PbS to a desired composition is most easily accomplished by first annealing the n-type crystals under high sulfur pressure (about 1 atm) at temperatures above 700°C. This process serves to put excess lead precipitates into solution, yielding 0 -type crystals upon quenching to room temperature. Inter diffusion occurs readily in crystals so treated, and the methods described by Bloem may then be employed to obtain crystals of controlled stoi-chiometry. For the creep measurements made in this study, this involves heating crystals in mixtures of H2 and H2S The equilibrium constant for H2S is given by: Thus the sulfur partial pressure is obtained from knowledge of the H2/H2S ratio and Kh2S for the temperature in question. Fig. 1 shows the p-T-x diagram for PbS. It can be seen that, within the stability limits for single-phase lead sulfide, desired compositions may be obtained by equilibrating under a specified sulfur pressure and temperature. Characterization of Crystals. The principal methods for evaluating PbS crystals include measurement of electrical properties and mass-spectrographic analysis. The measured electrical parameters include Hall coefficient, conductivity type, and electrical resistivity Bloem7 has shown that there is a 1:l relation between the defect concentration and carrier concentration obtained. Hence, if the contribution to the carrier con-

Jan 1, 1968

By A. Haines, O. Varaud, I. Baidoo

Abosso Goldfields Limited (AGL) is in the process of developing an expansion of their Damang Open Pit gold mine in Ghana. AGL acquired the Damang mine in January 2002, with SRK participating in the geotechnical investigation and design for the project since 2001. A deep resource drilling program, completed during 2004, intersected an extension of the orebody below the then planned final pit floor. A feasibility study has been completed to determine the economic extraction of this deep ore with an expanded pit shell. The Damang mine is in a stockwork sulphide deposit at the culmination of the Damang anticline. The deposit occurs as hydrothermal mineralisation associated with dominantly east dipping thrusts and sub-horizontal quartz veins. Primary gold mineralisation also occurs in the conglomerates of the Tarkwaian Formation. The geological units consist of steep easterly dipping dolerite, sandstone, siltstone and phyllite beds, with the weathering profile comprising saprolites overlying a relatively thin joint oxidized horizon. It is planned to deepen the current open pit to a final depth of up to 270 m, primarily by the development of a push-back of the eastern and western walls. The edge of the Eastern Tailings Storage Facility (ETSF) is currently located within 80 to 100 m of the crest of the existing pit. The geotechnical design focused on the optimization of the bench face angle and finally recommended a ?Steep Slope Strategy?, involving 24m high near vertical benches. Limiting bench stack heights of 96m at a maximum of 66° were derived from the influence of major structures and the variation in rock mass conditions. The overall slope angles in each pit sector were developed around the requirement for haulage ramps. One of the main design challenges was to optimise the standoff distance between the final pit crest and the ETSF. This process had to consider maximum access to the resource without undue influence on or from the nearby tailings dam. A planned increase to the height of the dam wall was an additional factor in the design. Dewatering of the pit walls was also a major consideration in this tropical environment.

Jan 1, 2006

By Zhaohui Qiu, Yaguan Ji, Hong Zhong, Qingxia Liu, Yada Liu

"Water is a necessary process medium in mineral processing. For the operations where fresh water is not available, sea water could be used as an alternative processing medium to replace the fresh water if we would have built a solid understanding of the interfacial science and flotation chemistry of sulfide minerals in sea water. In this research, micro flotation of chalcopyrite and pyrite in deionized water and sea water were investigated. For chalcopyrite, the recovery starts to drop from pH 10 in deionized water and from pH 9 in sea water, and the flotation recovery close to 100% before it drops. We can found from the results that chalcopyrite flotation is depressed much at pH 11 in sea water when much white precipitate is found. For pyrite, the flotaion recovery changs a lot in deionized water with 1*10-5 M potasium amyl xanthate (PAX) as collector. It’s relatively high at pH 8~10 compared with that at pH<8 and pH>10. While in sea water, the trend is almost the same as that of chalcopyrite. Zeta potential measurements and chemical equilibrium calculation were used to find out that magnesium hydroxide species coats on the surfaces at high pH in sea water are the main reason for depressing the chalcopyrite and pyrite flotation. Through understanding the interfacial science and the solution chemistry of sea water and its impact on processing efficiency, this research will not only helps reduce the use of fresh water to minimize the disposal of spent water for environment protection, but also enhance the recovery of valuable minerals in froth flotation."

Jan 1, 2014

By R. L. Howell, L. C. Atkinson

Typical sedimentary sequences overlying coal seams consist of interbedded sandstones, siltstones, shales, and rider coal seams. In many surface coalmine settings, these sediments are saturated; and prior dewatering of them is necessary for effective and economic mining, including the stacking of saturated spoils. Such sedimentary sections usually have a very low vertical hydraulic conductivity that does not allow them to drain in a timely manner prior to their being stripped. One potential solution is installation of drainwells. Drainwells are small diameter wells that can collect water laterally from the various more permeable layers in the overburden and then gravity drain it to a lower layer – often the coal seam being mined – where it can be removed by pumping wells or sumps located in the bottom of the pit. A ground-water flow model utilizing the 3-dimensional finite element code MINEDW has been used to evaluate the effectiveness of usingdrainwells in a hydrogeologic setting that is typical of the Powder River Basin. A series of numerical simulations were completed using various combinations and spacings of drainwells and pumping wells to dewater the overburden and coal seams. The numerical simulations suggest that drainwells can be a very effective method of overburden dewatering.

Jan 1, 2000

By A. C. T. Bigg, Y. Kocak, N. K. Bodur

The Gumuskoy silver mine, owned by the Etibank, in the province of Kutahya, Turkey, has been operating since 1987 with primary, secondary and tertiary crushers, and two parallel single stage ball mill circuits. Continuing problems with crushing and feeding of the ore to the ball mills, because of the moisture retaining and sticky nature of the ore, prompted an investigation into the possibility of converting the grinding circuit to an autogenous or semiautogenous grinding circuit. This would remove the bottleneck associated with the secondary and tertiary crushing. At the same time the target feedrate is to be raised from 140 t/h to 175 t/h. This paper demonstrates the response of five ore types, and blends of ore types in an onsite pilot plant test program, and also suggests how the variations can be handled in a SAG mill/ball mill circuit incorporating just one of the present ball mills.

Jan 1, 2000

By M. Guney, A. R. Bell

In Mindola mine on the Zambian Copperbelt, there is a plan to extend the current production level of 1.2-1.5 km (3,900-4,900 ft) with five additional production levels. Research work indicated that the present total heat output of 38.6 MW will inevitably increase to 63.2 MW in 25 years. Estimated WB and DB temperatures, representing the total heat generation in stope faces and development headings during these same periods are predicted to increase to 33.8/40.2°C (93/104°F) and 35.3142.10C (95/108°F) respectively. It is assessed that the nominal refrigeration capacity needs to be progressively increased to 9, 000 MW.

Jan 3, 1984

By Adam Gerondale, David Hemstreet, Lisheng Shao, Kenji Yamasaki

"Foundation soils of a proposed single-span bridge over a busy railroad in Anchorage, Alaska included a layer of sensitive, non-plastic to low-plasticity silt. Slope stability analyses showed that, without ground improvement, the proposed abutments would not be stable immediately following the design earthquake due to the liquefaction of the sensitive silt. Wet soil mixing was selected to mitigate the liquefiable soils and assure abutment stability because: (i) it is a non-vibratory method and can be used for areas adjacent to the railroad tracks and underground utilities, as well as in areas not sensitive to vibration; and (ii) preand post-ground improvement testing, such as SPT or CPT, is not required. Eliminating the liquefaction hazard at the site also allowed for the abutments to be economically supported on shallow spread footings. A total of 511 soil-cement columns were constructed at the two abutments, each with a diameter of 8 feet (2.4 m) and an average length of 20 feet (6.1 m), extending from about 30 to 10 feet (9.1 to 3.0 m) below finished ground elevation. The columns were laid out in a shear wall pattern (in the longitudinal direction of the bridge) to increase stability under the loading by approach embankments.INTRODUCTIONAlaska Department of Transportation and Public Facilities (Alaska DOT&PF) is currently constructing West Dowling Road Overcrossing in Anchorage Alaska. It will be a single-span, steel box girder bridge approximately 200 feet (61 m) long and 100 feet (30 m) wide. It will have approach embankments, about 40 feet (12 m) high, on both sides. It will carry the new extension of West Dowling Road over double tracks of Alaska Railroad and Arctic Blvd. Foundation soils of the abutments consist of surficial fill and peat layer underlain by soft silt which is likely to liquefy and lose strength under shaking by a design earthquake. Both deep and shallow foundations were considered to support the bridge abutments. The design team pursued the option of improving the foundation soils and using shallow footings. Several ground improvement methods were evaluated, out of which wet soil mixing was selected as the best option.In situ wet soil mixing (hereinafter simply soil mixing) is mechanical mixing of soil in its location with cement slurry and produces soil-cement (soilcrete) columns that are stronger, less permeable, and less compressible than the original soil. Soil mixing is used for various applications including reinforcement of soft soils, excavation support, liquefaction mitigation, cutoff walls, etc. This paper presents a case history of soil mixing successfully used to improve foundation soils of bridge abutments to allow the use of spread footings."

Jan 1, 2015

By Oxenford R. J

An important rutile-ilmenite-zircon bearing sand deposit was discovered by local farmers at Eneabba, 300 km by road north of Perth in 1970. These heavy minerals occur in a series of ancient strandlines and associated dunal deposits at elevations from 85 m to 170 m above the present sea level and are situated,30 km inland. The strandlines were deposited on wave- cut platforms in an ancient bay bounded by Mesozoic sediments during a series of regress- ions from a high sea level, probably during late Tertiary or early Pleistocene times. The immediate source of the heavy minerals in the Eneabba deposit is a widespread low content of those minerals in the nearby Mesozoic sedi- ments. The high-grade southern portion of the Eneabba deposit has been closely drilled and is now being prepared for production by Allied Eneabba.Pty. Ltd., a subsidiary of Allied Minerals N.L. This part of the deposit is 11 km long and up to 2.5 km wide. It is characterised by little or no overburden and the average depth of mineralisation, bounded by a 2.5 per cent heavy mineral cut-off, is 12 m. The water-laid strandline deposits at the base of the mineralisation are generally high grade, ranging from 20 to 60 per cent

Jan 1, 1973

By Richard C. Moore

The U.S. Bureau of Mines contracted a study to review the air and water monitoring requirements of five Federal environmental acts (the Federal Water Pollution Control Act, the Safe Drinking Water Act, the Clean Air Act, the Surface Mining Control and Reclamation Act, and the Resource Conservation and Recovery Act) and to compile information on the currently available monitoring instruments. A literature review of the acts and their associated regulations was conducted to determine applicability to the mining industry as well as any air and water monitoring requirements. In addition, an industry search and literature review was performed to assess the instrumentation available to comply with the monitoring regulations. Based on this research, the instruments are classified by general applicability to air, surface water, or ground water monitoring, then catalogued by monitoring parameters. A discussion is provided on recommended and innovative monitoring techniques.

Jan 1, 1981

By Charles R. Fettke

The permeability of an oil or gas sand is its capacity for transmitting fluids, either liquids or gases, under pressure. The permeability of a sand depends upon the size and shape of the openings in it and the extent to which these communicate with one another, as well as upon the ratio of their volume to the total volume of the sand. The apparatus employed and the method of procedure used by the authors in conducting the permeability tests have been described in a previous pub1ication.l For the tests described here 1/2-in. cubes were used. They were set in the lower end of a 1-in. union, inserted in a square hole cut in a hard rubber stopper which fitted into the lower end of the union. In the tests with air, volumes were measured with a wet American gas meter of 100 cu. ft. capacity. In those with water, distilled water at room temperature was employed, unless otherwise noted. DescRiption of Sands Tested The tests described in this paper were performed upon 18 samples representing typical oil and gas sands from 7 localities in northwestern Pennsylvania. For purposes of identification, the cores from which the samples came have been designated by capital letters, the sequence of the samples in the cores by numerals, and the individual cubes by small letters. All cubes from the same samples came from adjacent portions parallel to the bedding. Core A of the Bradford sand came from the north central part of the Bradford field, from an area where water-flooding operations have proved highly successful. Core B of the same sand was obtained from the southern part of the field. This core contained a so-called "loose streak," 7.5 ft. thick, in the middle portion of which B2 is a representative sample. The "loose streak" has given trouble in water-flooding but responded favorably to an air-drive, using a pressure of 300 lb. The natural production was increased approximately five times over a period of three years in which the air-drive was in operation. Core C, also of the Brad-

Jan 1, 1931

By J. D. Shenk

The White Cliffs diatomite deposit occurs in a lacustrine facies of the Quiburis Formation, an Upper Miocene to Pliocene basin-fill sediment of the lower San Pedro Valley. On-going geo-logic mapping has defined an 2.5-3.0 m (8-10 ft) thick ore zone near the mill site, several marker beds, a NNW-trending high-angle normal fault, and a NW-trending syncline. The diatomite has an average loose-weight dry bulk density of 130 kg/m3 (8 lbs/ft3) and is presently marketed outside Arizona for asphalt filler. Current development is projected to yield 3500 mt (4000 st) of finished product, with an estimated 91,000 mt (100,000 st) of finished product obtain-able from several other nearby sites.

Jan 1, 1988

Often plant performance suffers as a result of poor control. Poor control leads to low mill throughputs, poor classification and less than satisfactory concentrate grades and overall recoveries. By using the appropriate control tools, substantial gains in plant performance can be made. Mintek?s MillStar and FloatStar controllers have been implemented at various sites across the world. The MillStar controller incorporates leading technology that controls process units from the mill feed through to the flotation feed. Typical results show that milling circuit throughput is increased by 6-10 % and the final product grind size is tightly controlled, thereby enhancing flotation performance. The FloatStar controller is aimed at stabilising and optimising flotation circuits. Through improved level control alone, recovery improvements of up to 1 % have been achieved. Furthermore, by using on-line grade analysers, the controller stabilises final concentrate grades, whilst maximising flotation recovery.

Jan 1, 2005

By Aaron L. Sacks, David R. Good, Srinivas Yennamanda, Joseph K. Carey

Construction of Parcels 6 and 7, the second phase of The Wharf, began in 2019 and geotechnical construction was completed by December 2020. The overall project consisted of horizontal site, parks, and office buildings. The Wharf’s Phase 2 development includes approximately 1.2 million ft2 (110,000 m2) of above-grade construction including five multi-story, mixed-use buildings constructed over up to three levels of underground parking. The site is located between the WMATA Green Line Tunnels to the north and the Washington Channel to the south; it is bisected by a 108-in. (2740-mm) diameter DC Water outfall pipe. This arrangement, along with very difficult ground conditions, created challenges in the geotechnical design and construction. The support of excavation for this complex project required several different methodologies, including sheet piles, soldier piles, displacement piles, tiebacks, deep foundation anchors, jet grouting, and internal bracing with multi-tier rakers. Ground improvement was also required for support of spread footings in soft soils over the garage footprint. Underpinning of the active 108-in. (2740-mm) diameter DC Water outfall pipe running on a north/south alignment through the center of the site between the two garage structures was also performed. Since portions of the support of excavation are below the groundwater table, an extensive pre-excavation dewatering program was necessary and was separate from the foundation package. On the north side of the project, support of excavation (SOE) was required on a curved alignment, offset approximately 10 ft (3 m) from the outbound Green Line tunnel. Due to the proximity of the tunnel, a stiff, near-zero displacement wall was required. A portion of the buildings extend over the tunnels, imparting load to the tunnels to approximately restore original overburden loads excavated for the basement space. The building foundation is a 3 to 4-ft (0.9 to 1.2-m) thick mat slab anchored into the Potomac clay formation. Continuous movement monitoring of the tunnels was performed by an automated system. This paper describes the design and construction of the SOE and foundations for this high-profile project, which required collaboration between the Owner, Engineer, Construction Manager, and Specialty Geotechnical Contractor to solve many challenges.

Oct 1, 2022

By J. M. McCormack, R. K. Saxer, J. R. Myers

ThE Knudsen effusion technique was used to determine the chemical activities of copper and platinum in binary Cu-Pt alloys in the temperature range 1542" to 1673°K. Wiebke and Matthes1 previously obtained chemical activities of copper and platinum in this system at 673° and 923°K by the electromotive-force measurement method. They reported that the copper activities exhibited negative deviation from Raoult&apos;s law at all compositions. The chemical activities of platinum were found to change from a positive to a negative deviation at 923°K. Myles2 recently studied this system in the temperature range 1265° to 1356°K by means of the torsional-effusion technique. His results indicated that both copper and platinum exhibited negative deviation from ideality at all compositions. The use of the Knudsen effusion technique to obtain the vapor pressure of metals and alloys is well-known.3 In this work, Knudsen cells were fabricated from seamless tantalum tubing of 1-in. OD and 0.020-in. wall thickness; cell bases and covers were cut from 0.010-in.-thick tantalum sheet and welded to the cells in an argon atmosphere. Orifices were drilled and reamed to approximate a knife-edge of 30-deg included angle. Calculation based on Balson&apos;s4 derivation showed the orifice to be nearly ideal. All temperature measurements were made with a Leeds and Northrup disappearing-filament-type optical pyrometer at the orifice of the cell, which closely approximated black-body conditions and eliminated the need for emissivity corrections. Details of the experimental techniques used, and the necessary correction factors required during this investigation are essentially those previously described.5,6 Before investigating the Cu-Pt alloys, vapor-pressure measurements were obtained over specimens of pure (OFHC) copper. The pure-copper data5 served to assure the accuracy of the experimental apparatus and technique.

Jan 1, 1967

By Michael D. Balen

The U.S. Bureau of Mines (Bureau) is currently conducting a four-year study to assess the mineral resources and the mineral development potential of the 5.7 million acre Valdez Creek Mining District (VCMD) located in southcentral Alaska. The VCMD study is part of the Bureau&apos;s ongoing statewide mining district evaluation program. This report is a summary of the 1988 field work. The field work involved collection of reconnaissance placer and rock samples, and also involved sampling and examination of the mines, prospects, and mineral occurrences which were identified by literature research of the geology, exploration history, and mining history of the district. During the 1988 field season, Bureau personnel spent a total of 11 weeks in the field, collected 1,006 rock and placer samples, and located, mapped, and sampled 106 of the known mineral occurrences. The Bureau has visited 243 of the 250 known mineral occurrences during the course of the VCMD project. Reconnaissance sampling for placer occurrences resulted in the identification of 4 previously unreported gold placer occurrences, and identification of 5 occurrences that contain detectable levels of platinum or palladium. Reconnaissance sampling for lode sources of base and precious metals resulted in the identification of 5 new Lode gold-silver occurrences, identification of 2 occurrences that contain elevated quantities of chromium, cobalt, nickel, palladium, and platinum, and identification of one occurrence that contains elevated quantities of copper, molybdenum, anti zinc.

Jan 1, 2011

By R. T. Swinderman

"Virtually every article you read on safety has a statement to the effect: “It’s obvious that safety pays”. If it is so obvious, why is it so hard to answer these questions? • How does the Maintenance or Operations Manager convince the Plant Manager to spend money from the annual budget for safety improvements? • How does the Plant Manager influence Corporate to prioritize safety improvements? • How does an engineering firm persuade the owner to spend more on design and equipment up front to reduce risk? There are many cultural and structural reasons why it is so difficult to prove the obvious. In my opinion the main culprits are: the almost universally used ‘Low Bid’ process, variations in reporting incident statistics between industries and countries, and, the Generally Accepted Accounting procedures (GAAP) [or International Financial Reporting Standards (IFRS)]. Conventional wisdom is it’s smart not to spend more than you need to meet the minimum regulations and maximize production. But buying on price alone often harms people, degrades the environment, and reduces the company’s bottom line. How can this be? You met the minimum safety requirements and saved money by buying on price. Don’t those savings go right to the bottom line? When you buy on price you get minimum quality, minimum compliance and are often backed corner with no reasonable options to rectify the problems that arise from buying on price instead of buying on long term life cycle cost. Culturally few companies actually ‘walk the talk’. It is trendy to have giant billboards at plant entrances proclaiming world class compliance with quality and safety standards. Annual reports are embellished with safety slogans and sustainability statements. Behind the front gates and the glossy annual reports the message is clear: produce or be replaced. Only a few companies go beyond the window dressing and actually endorse, from the top down, continuously improving their safety culture. Those that do embrace safety, show significant performance advantages over their competition that are reflected in their safety, productivity and environmental records and, ultimately their financial statements and share price. Current accounting (and reward) systems make it unlikely financial managers will accept non-conventional approaches to justifying expenditures on safety because they are driven to report “hard” numbers that can be documented and are within the “GAAP or IFRS Rules.” But in reality, accountants quantify soft or intangible costs all the time in their financial statements. Justifying safety investments is greatly enhanced by quantifying what most financial managers would call intangible costs. Government agencies have no problem assigning intangible costs to justify regulations to improve safety. How many times have you heard that the regulation is justified because the cost to industry is X while the benefit to the society is 2 or 3X? How can they say that without including intangible costs? We find it hard to believe these government claims of benefits to society because we have been trained to think about saving hard direct costs to justify investments."

Jan 1, 2017

By P. Soros

To accommodate the immediate and long term growth of the Hunter Valley, one of Australia&apos;s major coal producing regions, a third coal terminal was required in the Port of Newcastle, N.S.W. The initial capacity required was 15 million tons per annum, made up of 40 different blends, to be expanded to 50 million tons of 100 different blends, made up from 70 grades. Coal arrives in 3,200 ton unit trains, a total of 16,000 trains in a year.

Jan 1, 1986