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By B. McFadzean, K. Moller

"The mechanism whereby thiol collectors adsorb onto a mineral surface has been widely studied. Most of these studies examine the mineral surface at equilibrium state and, often, well above monolayer coverage. However, the formation of species at the mineral surface is a complex process that is both kinetically and thermodynamically controlled. In a typical industrial application, the dosage of collector will be around monolayer level. This study uses isothermal titration microcalorimetry to measure the heat evolved during the reaction of sodium ethyl xanthate (SEX) and sodium isobutyl dithiocarbamate (SIBDTC) and their mixtures with galena and chalcopyrite. The sensitivity of the instrument allows heats of reaction of sub-monolayer quantities of thiol collector to be measured.The study found that both the magnitude and kinetics of the reaction between a collector and a mineral surface was dependent on the type of mineral and the type of collector. Proposals are made for the reactions based on literature and the evidence from this investigation. It was found that when collectors were reacted with mixtures of galena and chalcopyrite, that the magnitude of the reaction was lower compared to that measured for the pure minerals alone. This may be due to galvanic interactions between the minerals, resulting in a passivating effect on one or both of the minerals."

Jan 1, 2014

By Dilip Kumar Mohanty

In today?s world, Sustainability is the key issue before the mankind. With the ever-increasing population & unimaginable boost in industrial growth to cope up with a steady increase in demand and fast change in life style of a human being, the natural resources are exploited to such an extent that the very existence of living beings in this earth planet is threatened. In such devastating situation, the concept of Sustainability emerges out as a great savior. This concept focuses on minimum/ judicious use of natural resources, thereby preserving the resources for future generation while meeting the bare minimum requirement of the present generation. For an emerging economy like India, Mining and Mineral based industries form the back bone of our economic development. Thus, sustainability of mining and mineral processing industry has a far reaching impact on sustainable economic development of our nation. While at a macro-economic level, we have to strike a balance between economic development vis-à-vis socio-economic & environmental impacts, Industries have to ensure judicious and frugal use of natural resources by making use of energy efficient plants & machineries and adopting befitting technology for reduction & recycling of waste. In the context of the above, it would be interesting to look into the sustainability measures taken up by National Aluminium company (Nalco) at its Crushing & conveying plant at Panchpatmali Bauxite Mine, which is incidentally Asia?s largest Bauxite Mine. In the backdrop of the above stated facts, in this paper the authors make an attempt to bring out the sustainability issues in areas of energy conservation, environmental impact/pollution vis-a-vis mitigation measures adopted in crusher & conveyor plant of Panchpatmali Bauxite Mine & CSR / peripheral developmental activities undertaken by Nalco to mitigate the socio- economic impacts. Keywords: sustainability, energy efficiency, recycle, csr, peripheral development

Sep 1, 2012

By Z. Pokrajcic

The traditional comminution circuit is a major consumer of energy ? both as electrical energy and through consumption of media and wear resistant liners. Up to 40% of electrical energy con-sumed at a mine site is attributed to comminution however only a few percent of this energy is used in the generation of new surfaces from size reduction. This paper describes the evaluation of modifications using simulation models based on two operating comminution circuits. The aim of these modifications is to decrease both the amount of electrical energy consumed in the size reduction process, known as direct energy, as well as to decrease the consumption of grinding consumables such as steel grinding media and mill liners, designated as indirect energy. The approach is two-fold: ??Employ, where possible, autogenous grinding techniques to eliminate the need for grinding media and reduce mill liner wear. ??Optimise the use of the grinding energy distribution in the comminution circuit by using more energy efficient grinding devices to target typically problematic features of a comminution circuit such as critical size material from the primary mill and overgrinding in the secondary mill. The investigations show that significant total energy savings, as high as 50% in some cases, can be achieved by employing the techniques described while maintaining circuit throughput and product size. Investigations also show potential benefits in downstream flotation processes as the product size distribution generated from the eco-efficient circuit is generally ?narrower? in shape for improved flotation performance and containing less material in the coarse fraction for overall better liberation.

Jan 1, 2014

By T. Niedoba

The ash contents in coal particles were examined in the paper dependably on particle size and its density. So, the two-dimensional regressive function Z=Z(?, D) was the searched object, where Z is random variable describing ash contents, ? - density and D ? particle diameter. This dependence is determined basing on experimental data concerning the coal of type 31. For this coal, the method of ordinary kriging is applied to calculate the values of a random variable Z. This method requires the proper selection of so-called variogram function, which 4 forms are considered in this paper in purpose to select the best solution. The given results were then evaluated by the residual deviation value and so compared with empirical data.

Sep 1, 2012

By W. Q. Zhao

In order to raise the utilization rate of phosphate resource of Al-Jalamid Mine in Saudi Arabia, a flotation experiment for its phosphate rock was carried out by using WF-01collector that have been produced by Wengfu Phosphate Mine. The results showed that WF-01 collector had extensive adaptability for Al-Jalamid phosphate rock, and the grade of phosphate concentrate could be up to 33% P2O5 mixing the upper, middle and lower beds rock as well as its 80% more recovery.

Jan 1, 2014

By Andrey V. Yevdokimov

The results of the test work on gold leaching using high strength of cyanide solution in the presence of activators are presented. The major physical and chemical relationships of gold leaching were determined. Intensive cyanidation results of gravity concentrates with various material compositions using an activator are given. Process design criteria for intensive cyanidation unit were developed on the base of pilot plant test results. Keywords: gold, activators, intensive cyanidation, gravity concentrates

Sep 1, 2012

By J. Jávor

The response of the air/water interfaces to deformation in presence of surfactants is affected by the adsorption/desorption rate, re-orientation and exchange rate of surfactant. These surface properties can be observed using equilibrium and dynamic surface tension and surface elasticity measurements. However, the effect of these parameters on bubble size in dynamic conditions has not been studied due to the difficulty in capturing freshly formed bubbles in dynamic conditions. The paper presents a new experimental set-up designed and built at the Aalto University, called Shear Force Observation Chamber(SOC). The setupallows the monitoring and analysisof freshly formed air/liquid interfaces in dynamic conditions and facilitates the study of the effect of dynamic surface tension and surface elasticityon freshly formed air bubblesin presence of surfactants. The method helps to establish correlation between bubble size and dynamic interfacial properties and bubble-bubble interaction in turbulent flow. Dowfroth 200, Nasfroth 240 and Dowfroth 250 commercial flotation frothers were tested in this study. The results show a marked difference between results obtained in dynamic conditions compared to the static conditions. The results are presented and the reasons and implication to flotation modelling are discussed in the paper. Keywords: shear force observation chamber, flotation frothers, flotation bubbles, critical coalescence concentration

Sep 1, 2012

By T. Damyanov

Spherical grinding media (balls) are the most widely used media for comminution of ores by grinding. A modelling simulation study of the behavior of two grinding media in the grinding process was conducted to determine the possible advantages of the new shape milling bodies called tetraballpebs. Tetraballpebs are in the shape of tetrahedrons with spherical convex walls. A three dimensional CAD model of the mill drum with a diameter of 1200 mm was used. A continuous operating mode was simulated in terms of the 3D contact elements of the model (milling bodies and mill drum). Simulation tests were carried out in a typical grinding mode and at a typical rotational speed of the drum mill (75 per cent of the critical speed in cataracting mode). Studies carried out with both grinding media include equal number of milling bodies with the same weight and volume. Having thus ensured a uniform mass of the grinding media and same number of milling bodies, and constant other conditions and process parameters, conclusions can be drawn about the influence of the shape of the milling bodies on the grinding process. A kinematic analysis of the system using CAE (computer-aided engineering) model parameterization was conducted. The controlled parameters are: ? Power draw; ? Kinetic energy of each milling body; ? Motion of milling bodies inside the drum Keywords: grinding, grinding simulation, balls, tetraballpebs, DEM, CAD-CAE

Sep 1, 2012

By Y. C. Liu

Ningxiang-type iron deposit is a most important sedimentary oolitic hematite deposit in China. Its? detected ore reserves are 3.72 billion tons, which is 73.5% of all detected reserves, and there are about 10 billion tons of prognostic resources. It is considered as the ?poor mine? for a long time be-cause of its difficult prooerty. But based on the ore characteristics of different deposits, the technological characteristics of ore are different with great diversity in ore baring horizon, distribution range, deposit scale, ore petrology, ore mineral assemblage and iron content. Through the study of deposit features and technological mineralogy of different Ningxiang-type of iron deposits in China, and based on industrial types and natural types of ore deposits, we divide different technological types according the technological features of the ore such as mineral composition, particle size, dissemination, occurrence of useful elements and harmful elements, the main physical and chemical properties of mineral and geological conditions of deposits, etc, moreover, propose the different utilization, mineral processing technologies and product schemes for the different types of ore.

Jan 1, 2014

By Ritva Tuunila, Antti Häkkinen

"Wet stirred milling is one of the most effective grinding methods in producing very fine powders in large scale production, but it is a very energy-intensive process, especially when pigments or even nanosize particles are produced. Therefore, optimization of the process parameters is important. The specific energy consumption is a function of stress energy, which describes the effect of tip speed and media characteristics on grinding, and is related to the number of stress events during milling. In effective grinding, a large number of stress events are necessary. The stirrer configuration influences the number of stress events and their intensity, because the motion of the media and the suspension are caused by a rotating stirrer. The effect of three different stirrer types: a pin, disc and blade stirrer, on the grinding rate, i.e. product fineness and specific energy were investigated in this study with a batch laboratory stirred mill with two tip speeds. The material used in the experiments was calcium carbonate. The results obtained with the smaller tip speed showed approximately similar grinding rates and energy consumption for all stirrer types. When looking in closer detail, the blade stirrer seemed to give the finest product with all grinding times compared to the pin and disc stirrers, which both produced almost the same product fineness with the same grinding times. The specific energy consumption was the smallest with the disc stirrer, but not very big differences were obtained. With a higher tip speed, greater differences occurred both in grinding rates and specific energy consumption. The blade stirrer was the most effective in grinding, and the pin stirrer the next. The net energy consumption for the blade and pin stirrers was almost the same, but it was slightly higher for the disc stirrer."

Jan 1, 2014

By Tatyana A. Ivanova, Tamara N. Matveyeva, Anatoliy A. Fedorov, Tatyana V. Nedosekina, Valentin A. Chanturiya

"As native gold resources are depleted, gold-sulfide ores consisting essentially of pyrite, arsenopyrite, chalcopyrite and pyrrhotite become one of the major precious metal sources, being presently estimated to account for more than 40 % of total world gold reserves.The prime objective of flotation of gold-bearing sulfide minerals is to increase precious metal recovery and to reduce the product cost through achieving maximum selectivity of the separation process. Separation of Fe and As sulfides in selective flotation of gold-bearing ore products helps reduce the amount of ore mass being sent to hydrometallurgical processing, and permits of recovering gold from As-free gold-containing pyrite concentrate by using a lower-cost pyrometallurgical procedure.An ingenious methodology purposively developed by the authors for comprehensive assessment of flotation properties, electrophysical characteristics and crystal chemistry features of natural gold-bearing sulfide minerals of different origin has been used in this study.Comparison of the elemental composition, non-stoichiometry and flotation activity of different monomineralic pyrite varieties revealed that samples with negligible impurity content are nearly stoichiometric, and show similar flotation properties. Samples with high Cu, As and Au contents are highly non-stoichiometric and readily floatable, even in a highly alkaline environment. Samples with high surface sulfur content and the most defective crystal lattices, with iron atoms substituting for sulfide vacancies, are most sensitive to depressive action of the alkali.A correlation between the type of conductivity, impurity content and amount of xanthate compounds on the surface and in the liquid phase of monomineralic pyrite and arsenopyrite suspensions detected by the extractive spectrophotometric analysis has been identified and analyzed. Experiments showed that the proportion of cuprous xanthate in sorptive collector layers on sample surfaces increases with increasing Cu content of the samples. In general, pH for pH, overall xanthate sorption on pyrite is greater than on arsenopyrite, with the difference increasing in passing from an acid environment to an alkaline one. A significant decrease in xanthate sorption on arsenopyrite is observed at pH greater than 9, whereas sorption on pyrite markedly decreases at pH greater than 11."

Jan 1, 2003

By E. Guerrini, M. Maccagni, J. Nielsen

"Lead is the most important material able to meet the current demand for energy storage. The lead acid battery is reliable, efficient and inexpensive. Continuous developments in battery construction are providing improvements in all aspects of the batteries’ performance. The lead acid battery is both the main lead product and the main raw material for lead production. More than half of the lead produced is from secondary smelters where batteries are the most important feed material. The environmental pressure on lead production has been increasing for many years, and continues to become stronger and stronger. The lead production processes and technologies themselves will require updating to meet the new regulations. Although they are very strict now, they will become even more so and current technologies may not be sufficient. Because recyclability is a strong point for the lead acid battery, the secondary smelters need to reduce the environmental impact as much as possible. In recent years, the secondary smelters underwent impressive changes in this direction, but some more improvements are possible. Electrochemistry can offer a step change improvement in making secondary lead production more environmentally friendly. Engitec has developed an electrochemical process base on a very high current density (high productivity) cell using an inexpensive electrolyte and at a relatively low cost. In this paper, the latest update on the technology is provided. INTRODUCTION The lead acid battery is considered the “walking dead” by some new technologies trying to replace it. It has played and will continue to play a very important role in our lives because it is inexpensive, fully recyclable and the existing lead and the mine reserves guaranty enough material for the extended future. According to the life cycle, the lead acid battery is the cheapest and the most effective system to store energy. Lead is practically a close loop where lead battery production consumes more than 80 % of the produced lead but contemporarily it is the most important raw material for the production of metallic lead. In fact, nowadays, the secondary production has overcome primary production and this trend is expected to continue. Primary lead is the make-up material for the existing battery production and the source of lead for the construction of the new ones."

Jan 1, 2018

By Braulio Fernández, Gonzalo Montes-Atenas

The mechanisms taking place during the leaching of chalcopyrite when it is in contact with other sulphide minerals, particularly pyrite, is still a matter not fully solved. The GalvanoxTM process has been suggested as a technical solution to extract copper from chalcopyrite at commercial level inhibiting passivation phenomena widely reported in the field of hydrometallurgy. Although there are some rules of thumb to implement the process in fully flooded stirred conditions such as the optimum pyrite/chalcopyrite mass ratio should range between 2 and 4, among others; not many research studies have been focused on studying the effect of the surface contact area between chalcopyrite and pyrite to reach best copper extraction conditions. The aim of this research work is to determine the effect of the mass and surface area ratio between the minerals and the surface area of each of the mineral species effectively exposed to the leaching solution. Different particle size distributions of pure pyrite and chalcopyrite were contacted in a small column and subjected to leach tests using sulphuric acid in concentrations close those used in industrial leaching processes. The mass and surface area ratios which optimize the extraction of copper were obtained. It was found the best leaching conditions were attained when reducing the particle size distribution of pyrite regardless the particle size distribution of chalcopyrite. Further analysis concerning the impact of this conclusions on large scale operations is presented and discussed.

Jan 1, 2014

By K. H. Luo, J. Y. Liu

An experimental study on interparticle breakage of three iron ores was carried out by compressive stressing of particle-bed in a piston-die device. The feeds to the particle-bed stressing were five narrow size fractions in the size range of 0.2~3.2 mm respectively and a wide size fraction of 0/4.0 mm. The pressures applied were in the range between 30 and 360 MPa. The results show that the energy absorption of the particle bed increases linearly with the pressure; the increase of the product fineness with the pressure declines as the pressure goes up; and the product size distributions resulting from interparticle breakage of different narrow size fractions have no self-similarity. Using data obtained from the piston-die compressive stressing test, the suitability of a previously-developed material-characterization model for interparticle breakage was verified for these ores. It is shown that the particle-bed compression test conducted with piston-die device in lab-scale may provide a cost-effective way of studying and modelling size-reduction of ore materials by interparticle breakage.

Jan 1, 2014

By V. Tsyplakov

This article reviews factors of preg-robbing effect, occurring in the course of pressure oxidation of ore and concentrates, containing chloride compounds and so-called 'organic carbon'. The article also summarizes the main results of the studies and testwork conducted to overcome this effect. The following efficient preg-robbing mitigation methods have been noted: higher temperature of pressure oxidation process, preliminary removal of natural carbonaceous material from concentrate, chloride removal prior to concentrate pressure oxidation, and addition of water-soluble organic blanking agents, which suppress the adsorption activity of the native ore adsorbents. Keywords: preg-robbing, double-refractory gold concentrates, pyrite, arsenopyrite, blanking agents, pressure oxidation, autoclave leaching

Sep 1, 2012

By Kevin Davey, Liza Forbes, Leanne Smith

Given the global scarcity and value of potable water, interest in the use of water of lower quality in mineral processing has grown significantly in recent years. Previous laboratory batch flotation tests conducted at CSIRO have shown that chalcopyrite floats strongly without collector in distilled water and that the collectorless flotability of chalcopyrite is unaffected by the use of brackish water, sea water or hypersaline water. In contrast, bornite is moderately flotable without collector in distilled water but all three lower-quality waters have a detrimental effect on the recovery of bornite. The depressant effect is so strong that the little recovery achieved in these waters was only slightly above what might have been expected from entrainment alone. This work has now been extended to another important copper sulfide mineral, chalcocite. In contrast to chalcopyrite and bornite, chalcocite does not exhibit collectorless flotability so the chalcocite tests in this study were performed in the presence of a standard collector (potassium ethyl xanthate). The results reveal that chalcocite is flotable with xanthate in distilled water but the lower-quality waters have a detrimental effect on the recovery of chalcocite. This effect is partly reversed by increase collector additions. Further tests were completed in order to investigate the effect of the different ions present in the saline waters on chalcocite flotation. Possible reasons for the observed differences are discussed in terms of the pulp chemistry of the system.

Jan 1, 2014

By M. Ito

Cobalt-rich ferromanganese crust and nodule ores from seamount areas contain volcanic and sedimentary rocks as substrate or nuclei and these ores require mineral processing to remove the substrate/nuclei rock before smelting. This paper reviews the results of jig separation and air table treatment for the coarse fraction and flotation and hybrid jigging for the fine fraction. Using these techniques substrate/nuclei rock was removed from the cobalt-rich ferromanganese oxide components. The mineralogical properties and metallurgical treatment methods including hydrometallurgical treatment of low grade ore is also reviewed.

Sep 1, 2012

By R. L. Pascual, W. J. Whiten

"The froth flotation process is not well understood. Both flotation models, and the parameters used to describe the stream flows are not well defined. They in fact vary considerably in different applications. This creates difficulties is designing a simulation program suitable for use by plant personnel, consultants, and researchers. In addition to simulation, an effective simulation program can be expected to provide a range of other services.This paper shows how a process circuit simulator can be designed with sufficient flexibility to satisfy these needs, and discusses some of the additional services."

Jan 1, 2003

By Jan Svoboda, Toyohisa Fujita

"The current status and history of innovation in magnetic methods of material treatment are reviewed. The milestones and key drivers of innovation are identified, advantages of magnetic separation in comparison to other physical methods of material manipulation are discussed and reasons for failure to live up to its potential and expectations are identified. The future focus in such diverse areas as mineral processing, waste treatment, recycling and biosciences is discussed and the research and development needs are outlined.Our walk through the innovation landscape in magnetic separation illustrates the enormous effort that has been expended over the years to convert a wealth of novel idea into workable techniques. Remarkable progress has been achieved and numerous successful innovations have been introduced into material treatment operations. On the other hand these techniques have experienced their fair share of failures. The reasons for these cover a wide spectrum of risks that accompany any effort to implement new technology."

Jan 1, 2003

By H. R. Manouchehri

Large variations in flotation characteristics of minerals have been observed in winter and summer in plant practices as a result of changes in pulp temperature. Variations in temperature may affect the quality for pulp and related process water through changes in dissociation of different chemical species within the pulp, as well as changing in gas and metal hydroxide solubility, reagent adsorption and its stability on mineral surfaces, water/pulp viscosity, etc. All of these affect the flotation characteristics of specific mineral to some degree or another. It has been observed in Cu-Pb-Zn and/or Pb-Zn sulfides flotation that sphalerite (ZnS) flotation is strongly affected by changes in pulp temperature. Plant practices have shown that at the both low, e.g., T <10-12°C, and high, e.g., T > 60°C, the recovery for copper activated sphalerite is dramatically dropped. Within this paper the effect of pulp temperature on flotation characteristics of sphalerite is brought into considerations and laboratory flotation tests were conducted in conjunction with surface and solution chemistry analysis to understand the effect of temperature on sphalerite recovery. The effect of temperature seems to be complex since the temperature affects both the physical (hydrodynamics) and chemical phenomena in the flotation cell. In fact all sub-processes in flotation, i.e., collision, attachment and detachment, are affected by changing in temperature. Experimental results indicating that at alkaline pH values, e.g., 8.5 to 10.5, the recovery for copper-activated sphalerite is dramatically reduced when temperature is below 10-12°C, which is in agreement with plant practice at Boliden?s Garpenberg plant in Sweden. However, results from other studies indicated that the zinc recovery is also considerably decreased at high pulp temperatures, i.e., 62°C and above.

Sep 1, 2012