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By Richard R. Klimpel, Simon Isherwood

"The industrial processing of ores containing gold and/or platinum minerals is generally mining site specific, e.g. McQuiston and Shoemaker (1985). The variety of various mineral processing techniques employed is extensive and includes size classification, gravity concentration, amalgamation, roasting, cyanidation, chemical leaching, ion ex-change/solvent extraction and froth flotation. Because of the relatively small quantities of Au and Pt that exist in the earth’ s crust, the economical recovery of Pt and Au often requires that the Au and Pt be associated with other industrially important minerals. This association of Au and Pt with other minerals can occur in very complicated mineralogical forms. It is probably safe to say that Au and Pt mineral concentration from natural ores represents some of the most complex metallurgical challenges facing the mining industry.Froth flotation is a technique that is receiving increasing industrial attention for the treatment of finely disseminated and/or associated Au and Pt minerals. The high throughput at relatively low capital cost, the potentially high selectivity, and the existence of a well-established technology for treating more abundant associated minerals such as base metal sulfides makes froth flotation an attractive processing alternative. Broadly speaking, the industrial oriented froth flotation experience with Au and Pt minerals exists in two major categories: 1) the flotation of Au and Pt associated with pyrite (or pyrrhotite) and 2) the flotation of Au and Pt associated with primarily Cu, Zn, or Cu/Pb/Zn containing sulfide ores.In the case of the precious metal association with pyrite (or pyrrhotite), much of the published froth flotation experience comes from South Africa. Typically, such processes are done using an acid side flotation with a collector such as mercaptobenzothiazole. The approach obviously is to float pyrite and hence recover associated gold. Generally the higher the total sulfur recovery the higher the gold recovery. Similar experiences of Pt associated with pyrite are a lot less common mineralogically and hence less well documented industrially. For example, in Canada, Pt is often associated with pyrrhotite but is not really processed as a straight pyrrhotite recovery.For the situation of Au and/or Pt associated with other base metal sulfide minerals, the industrial experience base is quite varied and is well documented from both North and South American operations. The nature of most of these flotation processes is to design, operate, and optimize the installed concentrator to get the Cu, Pb, Zn, Ni, etc. that is the bulk of the valuable sulfide ore and then take whatever precious metal recovery comes. Typically, such flotations are on the basic side using standard thiol collectors such as xanthates, dithiophosphates, thionocarbamates, etc. It is very common with such ores to use mixtures of collectors in order to get ""everything"". Often in such plants, there is an inherent balancing act occuring so as to operate in such a manner to reject pyrite (and pyrrhotite) in order to maintain high base metal mineral concentrate grades and yet recover sufficient precious metals such as Au and Pt minerals which often are associated with the iron sulfides being rejected. Obviously in such an environment, the smelter operation often ends up telling the concentrator what the precious metal recovery actually was in a given production period."

Jan 1, 1994

By G. J. Kipouros, N. Dadvand

"In recent years coatings of alloys have been produced for a wide range of applications including many for wire bonding application. The main characteristic of the baths of electroless plating is the presence of sodium hypophosphite as a reducing agent and also as the supplier of phosphorus. In the electroplating of alloys the Watts bath is predominantly used. This presentation compares the two techniques, electroless plating and electroplating, and discusses the possibilities of cross utilization of sodium hypophosphite in an attempt to formulate baths that eliminate the waste disposal issue related to some components.INTRODUCTIONThe importance of surface characteristics and the linkage of surface coating process to surface characterization has given rise to the evolution of surface engineering. Not only the surface preparation and morphology has become very important to the coating technology but also the knowledge of surface area exposed to the process of coating or corrosion is absolutely essential in ascertaining the behaviour of coatings and their adherence to the substrate. The above concepts are not unknown to researchers involved in the protection of surfaces, particularly metallic, from corrosion and/or erosion corrosion. However, the complexity of the surface defects, roughness, porosity, interconnected porosity and other related factors have contributed to the uncertainty of the true surface area versus the nominal surface area. Therefore critical parameters such as current density and chemical surface intensity although have been studied extensively at the atomistic level by carefully prepared surfaces are very difficult to be determined at the practical scale required during the coating processes.The most pronounced case calling for an understanding the relationship between the surface area and the effective protection is the coating of surfaces of items produced by compression or consolidation of powdery materials. With the advent of nanomaterials and the additive manufacturing through 3D metal printing this issue is becoming more important. Certain experience in this field come from the accumulated knowledge resulted from the attempts to characterize the electrochemical behaviour of powder metallurgy metals and alloys. Powder metallurgy has been a well-established process for half a century on basic metals such as iron, copper and their alloys. Recently the development of powder metallurgy process for aluminum, titanium and attempts to develop powder metallurgy processes for magnesium and its alloys has brought to light another important issue that of the development of coatings on difficult to plate reactive metals such as aluminum and magnesium. Despite of many successes in the development of powder metallurgy alloys the exact characterization of the corrosion behaviour of the coatings and the substrates is difficult to determine because of the unknown morphology of the exposed area i.e. the exact morphology and area of the exposed surface (Samal, 2007)."

Jan 1, 2016

By R. Lepsoe

THE basic products of the Company are lead and zinc. Around 950 tons of these metals are produced each day. In the last decade, the production of by-products has increased to such an extent that they are now nearly as large an operation as that of the base-metals. Of the many by-products, the most objectionable, and up to a few years ago the most useless, was the sulphur. The sulphur comes in the ore from the Sullivan mine. It is in the ore chiefly as lead, zinc, and iron sulphide. By selective flotation, these three sulphides are separated into the lead concentrates, the zinc concentrates, and the mill tailings. These mill tailings contain the bulk of the iron and the sulphur. Of the 6,5CO tons of ore treated per day, about 5,000 tons are wasted to the mill tailings dump, and, while now valueless, will in future years undoubtedly be used as a source of iron and sulphur. There are about 1,500 tons of sulphur and 2,200 tons of iron per day in the tailings, and about 400 tons of sulphur left in the total concentrates. In the recovery of lead and zinc in the pure form, the first step is the roasting operation. Here, most of the sulphur is driven off as sulphur dioxide in the gases. It has always been apparent that this sulphur should be. recovered and utilized if possible. At the same time, this would cure the smoke nuisance. Because, in spite of the low concentration of sulphur dioxide and the fact that it was discharged from stacks at an elevation of 400 feet above the plant, some damage to vegetation close to the plant had been experienced.

Jan 1, 1937

By Jeffrey D. Eisenman

FRP is a proven material for the solvent extraction processes of copper production. There is a history of successful applications of FRP piping and equipment in hydrometallurgical processing. The performance of FRP equipment has not always been consistent, but at no fault of the material. Its non-metal attributes and behavior vary from those of more typical materials of construction, such as steel and alloys. FRP is a mainstay material in many areas of solvent extraction and electrowinning and yet not well understood by all. We will discuss the critical concerns, which are key to reliable performance of FRP systems. This paper will include discussion of key elements, which are fundamental to reliable FRP piping design and considered best practices. Essential design and construction considerations to maximize reliable service life of FRP equipment, such as thickeners and process vessels, used in copper extraction and processing, will be discussed. Additionally, we will expose potential pitfalls and share lessons learned from previous copper processing plant projects, which can aid and impact other copper processing projects to ensure best system performance and reliability. INTRODUCTION The corrosion resistant attributes of fiberglass reinforced plastics (FRP) make it an attractive and cost effective material of construction in corrosive service applications that are found in copper processing. FRP is used all over the processing plant in seawater, brine and sulfuric acid services where the corrosive nature of these services would challenge most ferrous materials and coatings. FRP is a fully customizable material to meet the specific needs of each service and process. FRP piping and equipment can be found throughout the hydrometallurgical process, in the acid plant, desalination, leaching processes, solvent extraction and electrowinning to name a few. Beyond its superior corrosion resistant characteristics, FRP can be made abrasion resistant by introducing particulate additives into the resin, such as silicon carbide and alumina oxide. Because many of these services have combustible organic elements in the flow streams with accompanying safety concerns, the linings can be made conductive with carbon fibers to dissipate static charges that might collect on the surface of the equipment otherwise. Further, FRP can be made flame retardant as well, where flammability may be of concern.

Jan 1, 2019

By G. S. Hume

FOR MANY YEARS Canada lived in the hope of attaining a substantial production of petroleum and natural gas that, to geologists familiar with the sedimentary basins of this country, seemed an entirely reasonable expectation. There have been surges of exploration activity stimulated by oil and gas discoveries and development such as occurred in Turner Valley. However, it was not until the Leduc field in Alberta was found in 1947, and the significance of that discovery was realized, that the search became really intensive and continuons. Expansion now has become a matter-of-fact attitude based on results which would have been considered impossible of achievement a few years ago.

Jan 1, 1957

By A. Brown

"The mining industry is no exception to the general rule that continuing research is essential to good management; in fact, because of the imperfect state of knowledge in regard to many important factors associated with a mineral extraction, mining research assumes a position of unusual importance. On the basis of a recent visit to mining research centres in a number of European countries, the author describes their organization and their role in the mining industries of these countries. Some observations are made on Canadian mining research efforts, with a view to indicating a more systematic basis of procedure."

Jan 1, 1960

By J. W. Matousek

Tonnage oxygen plays a critical role in the primary production of two of the most important industrial metals - copper and iron - and minute quantities of oxygen play equally critical roles in determining the properties of the market products. For refined copper, oxygen in the final metal is balanced between maximizing electrical conductivity, neutralizing the effects of harmful impurities, and ensuring that the metal takes on the desired "set" during casting - the surface texture and physical properties required for subsequent rolling and drawing. For refined iron, oxygen must be removed to minimize reaction with carbon during cooling from the molten state with the generation of CO and CO2 - leading to a loss of carbon and the creation of "blow-holes" in the solid ingots and the potential for defects in rolled and forged products. This paper reviews the thermodynamics of oxygen in molten copper and iron at the levels of primary interest to production metallurgists.

Jan 1, 2014

By A. Farzanegan, D. A. Lowther, A. R. Laplante

"Off-line optimization studies are often necessary to improve the efficiency of grinding circuits. These studies are primarily based on the mathematical modelling of processing units (e.g., ball mills and hydrocyclones) and computer simulations. To complete an optimization task, process engineers must possess skills and knowledge of different subtasks involved in such efforts, e.g., plant audit, laboratory tests, and data analysis. Such know-how can be in part provided by Knowledge-Based Systems (KBSs). One such system, being developed in C Language Integrated Production System (CLIPS), is presented here, with focus on the estimation of ball mill selection functions for the purpose of both diagnostic and simulation, and its use for the optimization of ball size. Some of the interpretation and diagnostic rules will be presented, as well as grinding kinetics and classification data likely to fire them.IntroductionSince the late eighties there has been a growing trend in applying Knowledge-Based Systems (KBSs) to mineral processing [Meech 1990, Bearman and Milne 1992). Table l lists some KBS (often referred to as expert systems) applications that have been used mainly as tools for improving on-line monitoring and control of grinding circuits. However, there has been fewer attempts to add the symbolic processing powers of KBSs to conventional off-line grinding simulators. Figure 1 shows a relatively standard procedure to perform an off-line optimization study [Napier-Munn and Lynch 1992]. In brief, a typical program includes taking representative samples from a number of streams, running laboratory tests on collected samples, estimating model parameters which describe physical processing units (e.g. ball mills and hydrocyclones) validating model predictions and using models for simulation trials. One inevitably needs to be familiar with concepts of process modelling and simulation as well as various computer programs to be able to complete all steps of the study. Much of this ""expertise"" can be captured by KBSs, given their inherent capabilities for symbolic knowledge representation and manipulation."

Jan 1, 1997

By Helge B. Wurst, Michael P. Cipold, Jan F. Bachmann, Claus C. Bachmann

"In washability, the objective is to establish the set of maximum possible separation performance criteria for a given mineral feed. The method of choice for this has been the conventional sink-float analysis. Time, cost and safety aspects of the sink-float method have prompted the search for a new approach for establishing separation performance criteria, especially as performance levels of separator plants can be maximized if reliable information based on an analysis of washability in conjunction with particle size distribution, elemental constituency becomes readily available. The new method to establish washability and associated performance information utilizes at least two measurement technologies concurrently: single energy x-ray transmission and image processing. For porous or very inhomogeneous materials the results can be refined further by using dual energy x-ray transmission and image processing. The value of the collected data increases considerably if the washability data were additionally available in time to be considered in the control of the process plant. The incorporation of an automated washability monitor gives near real-time data that would impinge positively on the profitability of the plant operation. The method was extensively tested with a range of sample with different densities, varying from 1 g/cm³ (coal) to 5 g/cm³ (iron ore).INTRODUCTIONWashability of minerals like coal and iron ore is expressed by a curve or graph showing the results of a series of float-and-sink tests. Several of these curves are drawn to illustrate different conditions or variables, usually on the same axes, thus presenting the information on one sheet of paper. Washability curves are essential not only for the design but also for the operation of preparation plants.In determining the washability analysis, particle density is the underlying feature of all washability curves. Conventionally, the particles are separated into density fractions by immersing them in fluids of a predetermined density followed by skimming of those particles that stay afloat. The particles remaining afloat thus have a density lower than that of the fluid they were subjected to. The particles that remained at the bottom of the fluid container thus had a higher density higher than that of the fluid. By progressively increasing, for example, the density of the fluid and immersing the remaining particles so as to be able to skim the next density fraction, the particles would be fractionated into density groups. The liquids used range from aqueous solutions to organic liquids to suspensions. Unfortunately the liquids used for this separation process are often toxic and expensive. It stands to reason that a new method of determining washability is sought."

Jan 1, 2016

By Bradley Stoughton

The magnetic oxide of iron, F eO4 , contains a theoretically larger amount of iron ( 72.4 per cent.) than any other commercial ore. It is probable that it has originated in many cases by the prolonged exposure of the hydrated oxide, ZF e20 a + 3H20 to heat and pressure which converts it first into hematite, F e20 3, and then into magnetite. It would thus appear as if nature had already done part of the work of removing all the oxygen and that magnetite should be relatively easy to reduce. That it is, in fact, less reducible than either limonite or hematite, is due chiefly to its dense and compact physical structure, which makes it less pervious to the furnace gases, and also to its characteristic action in resisting crushing to a uniform size, with consequent irregularity in reducing conditions within the furnace. The net result is that the magnetic oxide requires more fuel and more time for its reduction in the blast-furnace than any other iron ore of similar iron content and physical condition. There is another very important reason why the smelting of magnetite is more costly than that of hematite, and its treatment viewed with a great deal of adverse prejudice by blast furnace operators, namely, that magnetite decreases the proportion of heat developed by the fuel in the stack of the furnace, and increases the already excessive heat requirements of the heart.

Jan 1, 1924

By Bradford C. Wesstrom

An overview of the challenges encountered at the Freeport McMoRan El Paso Copper Refinery with higher concentrations of antimony electrolyte will be shared. The observations will cover the detrimental effects on copper starting sheets, commercial cathodes and anode slimes. The study will show negative effects on quality and productivity. Experimental work will utilize a test cell to study the effects on electrolytes by different Antimony, Arsenic concentration and anode molar ratio. Best practices will be shared for producing high quality cathodes while effectively managing the detrimental effects of higher antimony electrolyte.

Jan 1, 2014

By Bryan Tisch

Goal of GMGE ??To advance mine reclamation through the beneficial use of organic residuals for the sustainable establishment of bioenergy crops and other productive land uses Objectives ??To advance the current ?standard? of mine reclamation by demonstrating that mining lands can safely become agriculturally ?productive? through the use of organic residuals. ??To generate and compile sound scientific data that can be utilized by stakeholders to better assess the environmental impacts of utilizing these materials. ??To complete a manual of best practices regarding the utilization of organic residuals on mine lands. *Considerable effort to be placed on operations/implementation side of utilizing residuals ?rather than just pure research

May 1, 2011

By H. M. Woodrooffe

This paper deals with the laboratory facilities at the Mines Branch for carrying out research in the industrial minerals field, and also reviews current programs in ceramics and construction materials, in non-metallic minerals and in the milling of industrial minerals. It then discusses the application of these pro-grams to industrial problems.

Jan 1, 1967

By Mark Richards

Highland Valley Copper is a large, open-pit copper mine in the southern interior of British Columbia. Reclamation has been in progress on the site since 1987. Some 6,300 hectares will have been disturbed at the end of the mine?s life, the majority of which will eventually be reclaimed. The establishment of vegetation and the development of a self-sustaining vegetative cover are the central components of the mine?s reclamation plan. The present vegetation-monitoring program for the reclaimed area represents a significant commitment of resources and only addresses a small portion of the site each year. In an effort to expand the area surveyed while improving the efficiency of the monitoring, the use of remote sensing is being investigated. Airborne multispectral imagery was acquired in the summer of 2001, and the results of the multispectral classification were compared to ground observations made during the routine 2000 and 2001 monitoring program. A thematic map with 17 vegetation classes was produced. Within the vegetation classes, there was a strong spectral separation between ? dry grasses? and ?legumes? with further separation according to their density. Green biomass could also be quantified remotely across a wide variety of vegetation types. During summer 2002, further aerial imagery was acquired in combination with a targeted ground-truthing program to determine characteristic vegetation types associated with recognized spectral signatures, which can be used in a supervised classification. It is anticipated that after some fine-tuning, it will be possible to shift the ground-sampling effort from areas where the aerial classification confidence is high to more complex areas.

May 1, 2003

By E. Czech

Hydrogen generated through aluminum-assisted water split reaction is a novel, efficient and environmentally friendly method. It has been found previously that the passivation of aluminum can be prevented in neutral (pH=7) or near neutral pH conditions in water by grinding aluminum with a catalyst, such as A12O3, SiO2 or SiC. Recently, the best results have been obtained by using water-soluble inorganic salts (WIS), ground with aluminum. The massive, rapid corrosion reaction of the Al-WIS system which takes place in regular tap (or marine, or ground) water can be utilized to produce hydrogen by aluminum-assisted water split reaction, in-situ, on-demand. The reaction offers clean, low-cost, environmentally benign and entirely recyclable technology for on-board on-demand hydrogen generation. Besides pure gaseous hydrogen, only pure solid aluminum hydroxides AlOOH or Al(OH)3 are formed as the reaction products. The hydrogen yield and Al-WIS reaction efficiency are high. From 1 g of mechanically alloyed aluminum powder, up to 1.25 liters of hydrogen were generated, i.e. efficiency up to 92% was achieved. The amount of hydrogen and hydrogen generation rate depend on various reaction parameters. The effect of chemistry and concentration of additives, water temperature, powder particle size and milling conditions on the reaction kinetics will be presented and the possible process mechanism will be discussed.

Jan 1, 2005

By M. H. Allan

SASKATCHEWAN POWER CORPORATION is a Provincial Crown Corporation responsible for the production transmission and distribution of electric power and natural gas in the Province of Saskatchewan. Through the electric power responsibility, we became interested in the coal reserves in Saskatchewan, which, although still somewhat of an "orphan fuel" in the early and mid 1950's, gave the promise of providing a low-cost source of energy for electric generation. Coal in Saskatchewan, a lignite with an "as-received" heating value of from 5000 to 6500 Btu's per lb and up to 40% moisture, was first recorded in 1853 . By the end of the 19th century, many small mines were in operation in the Estevan, Coronach and Shaunavon areas supplying local inhabitants with a cheap source of heat. These small mines, some of them prosperous, some of them not, continued operation right up to the late 1940's, when oil replaced coal in the market place. The year 1930, however, saw the introduction of the new technique of strip mining in the Estevan area. This technique revolutionized coal mining. It was now possible to use large machinery to uncover the coal and cast the overburden to one side instead of burrowing through thin seams of coal varying from 2 to 10 feet thick. The overburden cast aside by these large mechanical shovels, or later draglines, created heaps of spoil which at that time, during the depression, were a sure sign of prosperity and the welcome news that people had jobs. By the late 1940's, coal production had dropped off, but the spoil piles remained and were now labelled by some as "scars on the landscape", even though there had been some natural succession of grasses. In addition, some people had planted trees in experimental plots and even some aerial seeding had been done.

Jan 1, 1978

By S. Caron, M. Bourassa, J. Châteauneuf, L. Tardif

"Since many years, the Yvan-Vézina gold plant custom mills and processes different ore types that show different behaviors. Because of this, cyanidation control is more complex than for a typical milling operation. In 1992, a Cyancor™ on-line « free cyanide » analyzer has been installed for monitoring and optimizing cyanidation. This implementation significantly reduced cyanide consumption for the overall cyanidation process. In order to further reduce cyanide costs, an automatic control strategy has been implemented to decrease fluctuations of« free cyanide » from their set points.This paper outlines the major steps of the project: process control audit, control strategy development, implementation and running-in period. Control strategy features include data filtering modules, adaptive PID algorithm and set points management modules are also presented. Finally, the strategy efficiency is illustrated with load-disturbance responses.IntroductionLocated in northwestern Quebec, the Yvan-Vézina plant has an average capacity of 1300 t/d using carbon-in-pulp technology. In 1991, the Yvan-Vézina gold plant was processing three types of ores (Beauchemin, Mouska and Silidor mines) and a pyrite concentrate (Beliveau mine). A cyanide reduction program was then undertaken to reduce « free cyanide» fluctuations <6>. To reach this objective, the optimum cyanide concentration was determined for each ore, a continuous monitoring method with the Cyancor™ on-line analyzer was developed and a tighter control of cyanide addition was applied. These modifications to the leaching practice significantly reduced cyanide consumption.After a while, it was observed that regulation of « free cyanide » concentrations could still be improved by the use of an automatic control strategy. Yvan-Vézina and CRM began collaborating in 1995 to develop and implement such a strategy. Results show that main disturbances of the circuit (e.g. ore mineralogy and pulp feed rate) can be significantly overcome in order to reduce their effects on the leaching operation."

Jan 1, 1998

By H. Wilhelm, W. I. van Drunick

The Anglogold Ashanti (AGA) Navachab single stage SAG mill has provided an excellent setting for incremental optimization. Over the past decades, several interventions have resulted in marked improvements in specific performance; including steel ball scat removal, re-design of the mill lifters, replacement the pebble crusher and cyclone cluster, as well as the use of a vibrating screen in place of a discharge trommel. Recent initiatives now include an operating fine DMS circuit, studies on pre-crushing of the ROM feed and also fine-screening as an alternative to hydrocyclone classification. The current optimized state of the Navachab mill allows it to operate at approximately 20% higher efficiency when compared to mills of similar shell dimensions in gold mining, treating similar ore. This paper describes the systematic improvement of the SAG circuit to its current state.

Jan 1, 2012

By L. Xia, B. Hart, K. Douglas

In the flotation of Rare Earth Element (REE) bearing minerals, oxalic acid is reportedly acting both as a depressant and pH modifier. Testing has established the significance of oxalic acid in the flotation process however its specific role in either the recovery or selectivity of REE over their gangue minerals is not well understood. Pulp pH reduction trials with alternative acids have not shown the same effect on the REE mineral recovery or the depression of gangue phases. This work examines the effect of oxalic acid on the surface of gangue minerals (quartz and carbonates (dolomite and calcite)) in a series of conditioning tests. Gangue surface analyses by TOF-SIMS indicate that oxalic acid inhibits the transfer of secondary ions generated during the conditioning process from one mineral phase to another. In this regard, the oxalate anion acts to fix ions in solution through chelation, limiting their participation in surface adsorption.

Jan 1, 2014

By S. M. Taghavi, M. Halali

This paper investigates the possibility of zinc oxide production from zinc ore concentration residues, and also the effect of temperature, time and depth of bed on waste materials reduction percents. The results obtained show a significant increase of the reduction percent as a function of time and temperature. With increasing in depth of bed, reduction percent will decrease. Maximum zinc oxide percent in products was 93.5%.

Jan 1, 2004