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By R. Abel

During the last eight years, the Ventanas electrolytic refinery has been improving its results by applying a series of new operational practices, such as the reduction of electrode spacing from 115 mm to 105 mm., raising the current density to 305 A/m2, modification in the operators shifts to about 70% of the workers, reducing the pulling cycles by two hours, and the erection of a new anode preparation machine. These improvements allowed an increase in the refinery capacity from 323,000 to 382,000 metric tons of electrolytic copper per year. In the same period it has obtained certification under the ISO 9001:2000 and ISO 14001:2004 standards. All of these developments have been achieved using conventional technology with copper starting sheets. The continuous improvement that is covered in this paper has allowed Ventanas to optimize its production, costs, and operational results. For the next years, it is planned to follow the same tendency, bringing the productivity of the plant to higher levels.

Jan 1, 2007

By A. Elsayed

Lightweight metals such as magnesium show potential in replacing aluminum alloy castings for engine cradles, cylinder heads and transmission cases. Unfortunately, magnesium alloys are susceptible to entrapping oxides and other impurities during casting that hinder strength and ductility. The current study examined various filter sizes and configurations with the aim of improving the mechanical properties of permanent mould cast AZ91E. The unfiltered casting had a yield strength, tensile strength and ductility of 93.3 MPa, 153.3 MPa and 2.2 % respectively and increased to 96.5 MPa, 167.0 MPa and 3.1 % with the use of a fine mesh filter within the well of the mould. The increased strength and ductility was likely due to the filtered castings containing fewer inclusions on their fracture surfaces as compared to the unfiltered castings.

Jan 1, 2011

By P. Coursol

The Noranda Reactor Process (NRP) has been in operation now for more than 30 years and this mature process has attained a high level of performance. The NRP at the Home Smelter of Xstrata Copper treats a wide range of feed materials and a thorough knowledge of both process control and smelting physico-chemistry has been beneficial to help meet the required plant flexibility. In this regard, some level of predictive knowledge related to slag chemistry, in particular, the liquid and solid phases such as spinels or olivines, has been found to be beneficial. In the last decade or so, the availability of commercial thermodynamic modeling packages, such as Factsage1m have been utilized with advantage to help the plant optimize slag chemistry and minimize problems from difficult slags, for example, those the could arise from undue feed variability. This paper illustrates the application of this software in examining a range of operating parameters such as: %Fe in product matte, the %Fe/%Si02 ratio in the slag, the levels of minor slag components including CaO, Ah03, ZnO, and MgO, and the level of oxygen enrichment on the operating conditions of the NRP. The slag composition boundaries at the conditions affecting magnetite control and solid magnetite/other precipitated solid phases, as well the conditions influencing the slag liquidus ranges of NRP slags are also discussed with respect to the overall process chemistry.

Jan 1, 2007

By M. Pelser, H. Gous, J. H. W. M. Brits, K. Voogt

The effect of impurities; iron and selenium, on current efficiency and deposit quality in copper electrowinning was investigated using an at-line cell at the Rustenburg Base Metals Refiners’ Copper Tankhouse. The tankhouse is a direct leach, starter sheet electrowinning operation with a unique electrolyte composition. The effect of iron on the current efficiency in the at-line cell was found to be less severe than reported in literature. However, the distinction between the chemical impact of iron on current efficiency and the physical impact of iron on a starter sheet operation needs to be realised. The effect of selenium on current efficiency and deposit quality is also reported. INTRODUCTION Anglo American Platinum’s Rustenburg Base Metals Refiners’ (RBMR) Copper Tankhouse serves a unique function in the refinery flowsheet in that its primary functions are the removal of copper and production of acid for the leach circuit. This function needs to be performed to specification in order to keep the leach circuit operating optimally. Current efficiency is seen as an indicator of tankhouse performance and efficient energy use. The tankhouse plates starter sheets onto titanium blanks which, after stripping and preparation, return into the production cells for further plating. Approximately 78% of tankhouses surveyed (Robinson et al., 2013) use permanent cathode technology whereas older, smaller operations still use starter sheet technology. Drawbacks of the starter sheet technology are that the starters are thin and bend easily leading to increased shorts, they need to be removed after two days of plating to be manually straightened and are then returned to the cells. In addition, the electrolyte levels in the cells need to be adjusted during the plating cycle to improve loop adhesion to the cathode and reduce loop corrosion. The starter sheet technology is therefore very labour intensive and the final quality of the product is dependent on the quality of the starter sheets produced. In comparison, permanent cathode or direct plating technology lends itself to automation, allows for higher current densities and better cathode quality due to more robust geometric stability in the cell. The present barrier to implementation of permanent cathode plating at the RBMR Copper Tankhouse is the capital cost required to convert the tankhouse, i.e. blanks and stripping machine. At present, alternatives to titanium blanks, such as LDX 2101, are being investigated for the unique electrolyte composition of this tankhouse.

Jan 1, 2019

By Elisabeth Kolar, Rik Catthoor, Frederik H. Kriel, Rossen Sedev, Gareth Hatch, Army Research Laboratory, Craig Priest, Scott Middlemas

"This paper reports solvent extraction of rare earth elements (REEs) carried out using a microfluidic device and considers the REE loading limit of the organic phase under laminar flow. The microfluidic device contacts aqueous and organic phase streams for a precisely defined contact time (subsecond resolution) and then separates them for offline analysis. Experiments are reported examining the effect of contact time on extraction. We focus on three REEs: one ‘light’ (Nd), one ‘mid’ (Dy), and one ‘heavy’ (Yb) REE, which are extracted using Cyanex® 572. It appears that loading limits may be locally exceeded in the organic phase near to the liquid-liquid interface, where third phase deposits are observed. Third phase formation was also observed close to the liquid-liquid interface in two-dimensional confinement, showing similar third phase adsorption on glass plates. It is also shown that, under microfluidic flow, a typical first ‘split’ between heavy REEs and light REEs can be carried out without exceeding loading limits.INTRODUCTIONMicrofluidic solvent extraction has emerged as a useful tool for studying extraction of metals in a mineral processing context (Ciceri, Mason, Harvie, Perera, & Stevens, 2013; Ciceri, Perera, & Stevens, 2011; Kriel et al., 2015; Mason, Ciceri, Harvie, Perera, & Stevens, 2013; Priest, Zhou, Klink, Sedev, & Ralston, 2012; Priest et al., 2011). The main advantages are the extremely well-defined and tunable flow behaviour, large surface-to-volume ratios, short contact times, and minimisation of sample and reagent amounts. Two main flow configurations have been studied to date: droplet-based and co-flowing streambased extraction. In the former, droplets are formed at a microchannel junction (usually a T-junction or flow-focusing junction) and flow downstream as plugs or ‘free’ droplets. In our case, stream-based extraction, the chip is a plate (often glass) with embedded microchannels (i.e. with cross-sections of tens of micrometres) that carry the aqueous and organic phases in contact without forming droplets. Thus, these chips play the role of a mixer in a conventional mixer-settler and phase separation takes place by branching the streams or collection in a vessel at the chip outlet. Stream-based extraction requires stable streams that are usually supported by a particular channel geometry (e.g. guide structure or small ‘pillars’) or surface chemistry, and flow parallel bounded by the liquid-liquid interface(Aota, Nonaka, Hibara, & Kitamori, 2006; Hibara et al., 2005; Hibara et al., 2002). Phases are disengaged downstream at a Y-junction, which is a qualitative difference between microfluidic and bulk extractions."

Jan 1, 2016

By P. Mottahed, J. Ran

Mining practice and research have shown that the jointed roof in stratified rock behaves like a voussoir beam structure with strength greater than that determined by the continuous beam theory. Previous studies have demonstrated the voussoir beam mechanism and developed methods to estimate the crushing and buckling strength of voussoir beams. However, research on voussoir beams with multiple mid joints has not been suffICient and problems such as the voussoir beam support and applications of the voussoir beam mechanism to the mining environment have not been addressed. In this paper, mechanism of voussoir beams containing multiple mid joints and truss support are studied and applications of the voussoir beam mechanism to underground mine openings are discussed based on the numerical and experimental results.

Jan 1, 1995

By John T. Whetton

"FROM 1850 when the annual production was around 50 million tons, coal output in Great Britain expanded rapidly to 225 million tons in 1900 and 287 million tons in 1913. However, during the First World War, countries which had previously bought large quantities of coal from Britain sought other sources of sup-ply or developed their own coal re-sources. Thus from the record figure of 73 million tons exported in 1913, Britain's coal exports declined until in 1938 they stood at 39 mil-lion tons. An important reason for this was the development of oil engines for marine propulsion. Today, nearly all the navies and mercantile shipping in the world have turned to oil engines. Sometime in the future, however, it is reasonable to expect nuclear power to replace oil.During the Second World War, coal output in Great Britain and manpower at the mines were reduced considerably and in 1.945, 175 mil-lion tons were produced by 709,000 miners. Exports were meagre, only 8.""7 million tons went to foreign consumption. During the severe winter of 1947, inland demand for coal exceeded production and exports were prohibited. Even importation of coal was required to meet inland demand. These were years when the coal industry of Great Britain made immense efforts to secure maximum output irrespective of economy. The energy needs of Great Britain appeared insatiable; but had it been possible to export, the nationalised mining industry could have made huge profits as there was a world shortage of coal. However, home needs were considered to be the priority and many overseas markets were lost. Other producers moved in and secured long-term contracts. Not only was the British export market lost, but also the nationalised industry had to sell the imported coal at the same prices as home-produced coal and suffered losses up to of:3 per ton. Bence, at a time when the National Coal Board might have ac-cumulated a reserve fund to cope with less prosperons times, it was having to spend large sums of money securing sufficient coal for inland consumption. This was a time when intensive efforts in the mining industry, comparable with those of many industries and establishments inclusive of the armed services during the war, would have produced a greater amount of coal and have been of immense value to the country as a whole."

Jan 1, 1960

By P. Woo, N. Brodusch, R. Gauvin, H. Demers

The scanning electron microscope (SEM) was primary developed for imaging applications. With the introduction of the Si(Li) energy dispersive spectrometer (EDS), simultaneous imaging and x-ray microanalysis became possible. However, long working distance and high current were needed because the position and small solid angle of the EDS detector. The high spatial resolution is generally obtained at short working distance with a SEM. Unfortunately x-ray microanalysis is never performed in the best imaging conditions. The annular silicon drift detector system is inserted below the objective lens which gives a higher solid angle (up to 1.3 sr). In consequence, a lower working distance and probe current can be used. An improved spatial resolution becomes possible during x-ray microanalysis. With this x-ray detector installed on a cold-field emission scanning electron microscope, quantitative x-ray microanalysis with high spatial resolution at low beam energy and low current becomes possible with the possibility of using the various different type of imaging at the same time. Also, since the count rate can be as high as 1,500 kcps, which lowers significantly the detection limit of elements as well as the minimum feature sizes of different phases that can be distinguished.

Jan 1, 2014

By J. D. R. Neilsen

The objective of the research conducted and presented herein was to determine the effect of pre-established free gas saturation on the sweep efficiency of an isolated inverted five-spot well pattern. The investigation concluded that the ultimate recovery of an isolated inverted five-spot may be slightly increased by establishing a free gas saturation prior to water flooding; however, of more significance is the extreme deviation of the pattern's performance after water break-through from that commonly obtained from developed well patterns. The rapid "water-out" characteristic common to both linear floods and floods conducted in developed well patterns was not evidenced in the isolated inverted five-spot. Instead, the wells continued to produce oil long after breakthrough until ultimate areal sweep efficiencies of four, five, and six hundred percent were obtained prior to the water-oil ratio becoming excessive.

Jan 1, 1962

By Georgia J. Lysay

Kemess South Mine ended operations in March 2011. Final reclamation works began during operations in 2008 in anticipation of closure. The focus of reclamation during mine operations was on the inactive areas of the tailings dam, waste rock dumps, and expended borrow areas. The general reclamation strategy for the Kemess Mine site marries long-term erosion control with successional reclamation principles. For disturbed areas, this requires application of growth media, proper preparation of surfaces, and introduction of native pioneer plant species to initiate successional processes of recovery. Tailings are retained behind an earthfill dam of approximately 140 m in height, with a crest length in excess of 1 km. Reclamation activities at the dam have included placement of growth media, specialized surface preparation and construction of diversion ditches. The final closure spillway is currently being constructed, with completion scheduled for summer 2011. The two main waste rock dumps contain segregated non-acid generating (NAG) waste rock and potentially acid generating (PAG) waste rock. Resloping of the NAG dump for long-term stability commenced in 2009, followed by placement of growth media and ground preparation. The PAG waste rock will be fully relocated into the expended open pit for final, permanent subaqueous disposal.

May 1, 2011

By Martin Wacker

Cameco Corporation, on behalf of a joint venture, is preparing surface and underground facilities at their northern Saskatchewan property in preparation for the future operation of a high-grade uranium mine. The Cigar Lake orebody is situated about 430 metres below surface at the unconformity between metamorphic basement rocks and flat lying sandstone. Major technical factors influencing the mining method selection include ground stability, control of ground water, radiation exposure and ore handling and storage. A decade-long test mine program resulted in the selection and validation of ?jet boring? a non-entry mining method. Cigar Lake?s jet boring mining method involves several major steps; artificial ground freezing of the orebody and surrounding rock, TBM (tunnel boring) type development of access crosscuts below the orebody, installation of cased pilot holes upwards through the ore, and ore extraction using a rotating high pressure water jet within the pilot holes. The resulting cavities are surveyed and backfilled with concrete. The ore slurry will be processed underground and pumped to surface. This paper discusses the jet boring mining method in general terms and includes highlights of the Cigar Lake test mine program completed in 2000.

Apr 1, 2005

By So-Yeong Lee, Moosang Lee, Seung Hwan Ahn, Ho-Sang Sohn, Jongshin Chang

It is necessary to understand the characteristics, phase changes and chemical reactions of flue dusts introduced from a furnace to an off-gas line in order to achieve the stable operation and the improvement. This study is to develop the dust reaction model for chemical reactions of dusts in an uptake shaft of smelting furnace and a waste heat boiler. Phase equilibria and reaction paths in this system were determined by thermodynamic calculation with experimental and industrial data. The oxidation reaction rate of dusts was determined by the gas film mass transfer controlling. And the sulfation reaction rate was evaluated by the unreacted shrinking core model. Kinetic parameters were estimated by reference data including industrial ones. The present study with the developed model shows various effects of temperatures, dust particle sizes, and O2 gas partial pressures on dust reactions. INTRODUCTION The flue dusts from a copper smelting furnace move along a furnace off-gas stream into an uptake shaft and a waste heat boiler (WHB) and electrostatic precipitator(s). It is necessary to control the dust quality in order to stabilize the operation because the sticking behaviors differ depending on the phase of dusts. Phase changes of dusts are caused by chemical reactions at given conditions such as temperature and partial pressure of gases. Therefore, it is required to understand the phase changes and chemical reactions of dusts in order to perform the improvement and stable operation. The present study carried out the investigation to understand their fundamental knowledge. Especially, this study was focused on the kinetics of chemical reactions of flue dusts, developed the model. In particular, the scope of development and utilization of the model was defined as the uptake shaft of the Mitsubishi S furnace and the S-WHB radiation section in the Onsan smelter. Information needed for the modeling work referred to data from these processes.

Jan 1, 2019

By A. Scheltema Beduin, M. Kalisch, E. Floch, R. J. Dijkhuis, H. J. Oterdoom

In metallurgical copper production, the traditional aim is to increase recovery of copper to the maximum. SMS Siemag (SMS) has supplied numerous furnaces for this application. New targets are to make sure end of line products are as safe as possible with respect to health and environment, and to maximize raw material utilization. This means a for example a minimization of leachable metals in slag, so it can be safely used as a construction material, and either a targeted concentration or fixation of volatile compounds, such as arsenic. Currently, 2 process routes are generally applied for slag cleaning. The first is grinding followed by flotation, and the second is slag cleaning in an (electrical) furnace. Popularity of both options has fluctuated over the years, and currently the milling-flotation seems to be the more popular option. In this article some of the advantages and disadvantages of both methods are described, and especially how long term environmental policies could have an impact on the decision which process route to choose. Finally, this article will describe some of the developments SMS is working on in pyrometallurgical slag cleaning that could influence the direction for the design of the copper plant of the future.

Jan 1, 2014

By K. M. Wild, C. D. Martin, F. Amann

Peak laboratory strength data obtained from low permeability clay shales/rocks often display a bilinear or non-linear failure envelope. In many of these tests pore pressures are not measured because of issues associated with back-saturation prior to confined compressive loading. In such tests the effective state of stress at failure remains unknown and provides room for speculation. The non-linear shape of the failure envelope may have several reasons including the influence of capillary forces or the tendency of a saturated clay shale to dilate as the confining stress is changed. The former stems from sample preservation, preparation or core unloading effects and represents a partly saturated state (i.e., not representative for the in-situ state); the latter represents the response of a saturated material. This contribution discusses these issues based on a data set obtained from Opalinus Clay specimens, and concludes that without a careful back-saturation processes knowledge of the underpinning reasons for the non-linear failure envelope cannot be obtained.

Jan 1, 2015

By Tom Brady

A major focus of ground control research presently being conducted by the Spokane Research Laboratory of the National Institute for Occupational Safety and Health (NIOSH) is to incorporate data on weak rock masses into existing design relationships, with an emphasis on updating the span design curve for manned entries and the overbreak curve for longhole entries. Both curves were originally developed at the University of British Columbia, Vancouver, BC. The original database has been augmented by information from mines throughout the United States, Canada, Australia, and Europe. The common factor in all these mines is the presence of a weak back and/or walls. In most cases, the ore zone is the weakest rock unit and must be stabilized so that the mineral-bearing rock can be extracted safety. The current NIOSH research attempts to provide rock mechanics tools to assist a mine operator in making economic decisions that will also ensure a safe working environment. This paper documents the North American database.

May 1, 2006

By R. O. Loutfy, J. C. Withers

"Titanium powder is produced from a small fraction of sieved sponge, HDH of sponge or gas blown from a melt produced billet. Ore from foreign sources is chlorinated in a very high temperature fluid bed to make TiCl4, then vacuum distilled purified and then reduced to sponge by Kroll processing. Domestic ores of ilmenite or perovskite can be carbothermically reduced to Ti2OC which can be chlorinated at low temperatures of 250–400°C to produce TiCl4 which can be electrolyzed in a fused salt to Ti powder, or the Ti2OC used as an anode in electrolysis to produce Ti powder. The electrolysis process can be operated continuously to produce Ti powder at a lower cost than Kroll processed sponge including produce control size powder. Electrolysis processing was scaled up and operated at the commercial demonstration stage on a continued basis that verifies the potential of a low cost process to produce Ti powder.INTRODUCTIONTitanium and alloys of titanium powder have been elevated to strategic status resulting from a focus of producing meltless titanium components as well as a feed for additive manufacturing processing. However, the high cost of titanium powder has limited wide scale implementation of using titanium powder as a feed to any process to produce titanium components. Titanium powder free of alloying is available as sponge fines from the Kroll process as illustrated in Figure 1. Titanium alloy powder is much more expensive, also illustrated in Figure 1 produced from an alloy ingot or mil product as the feed and then transformed into powder by one of several melt form processes which accounts for the high cost of titanium alloy powder at approximately $60–150/lb. Ton lots of titanium alloy powder (i.e. Ti-6Al-4V) from one source is quoted at $120/lb. in the U.S. It appears that alloy powder production cost by current processing is not sensitive to volume."

Jan 1, 2016

By B. K. Choi, G. E. Kim, S. Noh, T. K. Kim

Oxide dispersion strengthened (ODS) steel has been developed as the most prospective core structural material for next-generation nuclear systems because of its excellent high strength and irradiation resistance. In ODS steel, finely dispersed nano-oxide particles with a high number density in the homogeneous grains can be very attractive to achieve superior mechanical properties at high temperatures, and these favorable microstructures can be significantly changed using process parameters during the mechanical alloying procedures. In this study, the effects of mechanical alloying times on the microstructure of 10Cr-1Mo ODS martensitic steel were investigated. Pre-alloyed powders with Y2O3 powder were mechanically alloyed for various milling times using a high energy horizontal ball-mill apparatus (model: symoloyer CM20). Powder properties such as the mean particle size, size distribution, and crystallite size were evaluated. Uniaxial hot pressing was employed to consolidate the milled powders. The results of a microstructural observation after the MA and UHP processes indicated that the homogeneity of the martensitic structures was considerably increased with the longer milling time. It is thus concluded that the mechanical properties of the ODS martensitic steel are greatly dependent on the mechanical alloying times.

Jan 1, 2015

By D. Racicot, T. Hanel, E. H. Chown

Over thirty plutons in the Chibougamau-Desmaraisville belt were examined briefly in the field and sampled, in addition to the few masses that have been studied in detail. The survey indicates that the intrusions may be conveniently grouped in four main categories, based on their time of intrusion. These are; remobilized basement domes, pre-kinematic intrusions, syn-kinematic intrusions and postkinematic intrusions. Basement domes, as exemplified by the Lappa rent Massif, are composed of migmatized tonalite-diorite gneiss that has undergone at least two periods of mafic dyke intrusion and at least three major deformational periods. The rise of the basement domes was accompanied by extensive mylonitization and the intrusion of syn-tectonic plutons. Pre-kinematic plutons, such the Chibougamau pluton, are diori te-tonalite in composition, and were intruded into the supracrustal pile and partly eroded before the main deformation of the belt. Syn-kinematic plutons occur principally as marginal intrusions bordering the belt (Barlow), or as discrete intrusions along structural highs (La Dauversiere), and are either hornblende monzodiorite or tonalite in composition. Post-kinematic plutons, such as Muscocho, are principally granodiorite and often porphyritic intrusions locally deforming the enclosing rocks. The close relationship between mineralization and high-level intrusions such as the pre-kinematic and some of the post-kinematic plutons is discussed.

Jan 1, 1984

By George Meadows

Consultation and Accommodation Introductions Consultation -Best Practices The Role of Negotiations The HVC Experience Summary / Conclusions The Challenge Meeting legal and policy obligations to consult while adhering to project priorities, timelines and budgets Defining who needs to be consulted, by whom, and ?how much?? Accommodation ?who is responsible and what is the appropriate scope? Social License -establishing positive working relationships with First Nations involved in project review / approvals / implementation in a manner that advances the interests of all parties

May 1, 2010

By G. Riveros

A new, continuous fire refining process for copper has been developed and tested at the 5 tph pilot scale. During oxidation, the blister copper flows through a packed bed of crushed refractory bricks counter-current to a hot oxygen containing gas. The resulting desulphurized copper flows then directly into a packed bed of charcoal for deoxidation. By controlling the air to natural gas ratio, both temperature and reducing conditions can be controlled. Based on extensive laboratory scale measurements of the rate of copper oxidation and reduction, the process concept was developed aided by process modeling and simulation. The industrial-pilot scale installation built at the ENAMI Paipote smelter in Chile, consists of two cylindrical, compact reactors, operating in line, with a designed capacity of 5 t/h of blister copper. The results of the industrial-pilot tests confirmed the feasibility of the new process. The blister copper processing capacity was increased to 10 t/h with satisfactory sulphur removal. The degree of oxidation as well the copper temperature was controlled with relative ease. The specially designed siphon block allowed for smooth tapping of the oxidized copper and separation of refining slag. The reduction of oxidized copper in the packed bed of charcoal appeared to be very effective while control of the degree of reduction according to the height of the bed ensured control of the oxygen content in the refined copper at the required level.

Jan 1, 2007