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By H. Lachmund, R. Bruckhaus

At Dillinger Hüttenwerke/Germany steel production of grades for linepipe applications especially for sour service has a long tradition. The BOF process after replacement of the vessels is optimized by a newly developed lime addition model and variations in lance tip geometry. Equipped with three state-of-the-art VOD tank degassers metallurgical requirements of lowest contents of e. g. sulphur, nitrogen and hydrogen can be achieved. Three continuous casting machines of vertical bending type with solid core even improve already high levels of cleanliness. The vertical part corresponds to the metallurgical length of 12 to 15 m and therefore assures a maximum of cleanliness after solidification before bending. Slab thickness up to 400 mm can be produced with model controlled dynamic soft reduction. The accurate alignments of the casters assure minimized segregation and microporosity. Surface and internal cracks can be avoided by special cooling, bending and straightening strategies.

Jan 1, 2005

By S. R. McCutcheon, D. R. Lentz, W. S. Downey

"Abstract - The Little Falls member of the Nepisiguit Falls Formation is situated in the northern part of the Brunswick Belt of the Bathurst Mining Camp and has been interpreted as the distal equivalent of proximal tuffaceous rocks that host the stratiform Brunswick No. 12 and No. 6 Pb-Zn massive sulfide deposits. It comprises fine-grained, greenish-gray tuffaceous sandstone in the lower part, and coarse-grained, crystal-rich tuffaceous sandstone in the upper part. Petrographic evidence suggests that these rocks have a turbiditic origin. The Little Falls member is underlain by the Vallée Lourdes member, mainly composed of relatively shallow-water calcareous rocks, and is conformably overlain by Mn-rich sedimentary rocks, mainly red argillites that host the Tetagouche Falls Mn-(Fe) deposit. All these rocks are considered to belong to the Nepisiguit Falls Formation, part of the Ordovician Tetagouche Group. Whole-rock geochemical data from the fine-grained tuffaceous sandstone and coarse-grained tuffaceous sandstone indicate that the two units of the Little Falls member are distinct. Zr and TiO2 contents, and total rare earth element (REE) values are higher in the coarse-grained unit (average Zr/TiO2 = 0.040, average SREE = 247 ppm, n = 6) than in the fine-grained unit (average Zr/TiO2 = 0.048, average SREE = 158 ppm, n = 17), which can be attributed to the variation in crystal content between the two units. Both units are HREE-enriched and have elevated La/Yb relative to the typical Nepisiguit Falls Formation. Overall, the geochemical data combined with evidence from the bounding units suggest that the Little Falls member was deposited in relatively shallow water, possibly in a near-arc environment. The relationship of volcanic facies within the Nepisiguit Falls Formation and the geochemistry of these facies indicate strongly that fine grained, reworked tuffaceous rocks, regardless of whether they are the distal equivalents of proximal tuffaceous rocks, are not associated with the major ore-bearing horizons of the Bathurst Mining Camp. Sommaire - Le Membre de Little Falls de la Formation de Nepisiguit Falls se retrouve dans la partie nord de la Ceinture Brunswick du Camp Minier de Bathurst ou elle a été interprétée comme l’équivalent distal des roches tuffacées proximales hôtes des gisements de sulfures massifs de Pb-Zn stratiformes Brunswick No.12 et No.6. Il consiste en grès tuffacé à grains fins gris verdâtre dans sa partie inférieure et en grès tuffacé à grains grossiers riche en cristaux dans sa partie supérieure. Les données pétrographiques suggèrent que ces roches ont été déposées par des courants de turbidité. Le Membre de Little Falls repose sur le Membre de Vallée Lourdes, lequel consiste principalement en roches calcareuses déposées en eau relativement peu profonde; il est de plus recouvert en concordance par des roches sédimentaires manganifères, lesquelles consistent principalement en argilites rouges hôtes du gisement de Mn-(Fe) de Tetagouche Falls. Toutes ces roches appartiennent à la Formation de Nepisiguit Falls, laquelle fait partie du Groupe de Tetagouche, d’âge Ordovicien. Les données lithogéochimiques des grès tuffacés à grains fins et à grains grossiers indiquent que ces deux unités du Membre de Little Falls sont distinctes. Les teneurs en Zr et en TiO2, ainsi que la teneur totale en Éléments des Terres Rares (ÉTR) sont plus élevées dans l’unité à grains grossiers (Zr/TiO2 moyen = 0.040, SREE moyen = 247 ppm, n = 6) que dans l’unité à grains fins (Zr/TiO2 moyen = 0.048, SREE moyen = 158 ppm, n = 17), ce qui pourrait s’expliquer par la variation de la quantité de cristaux dans chacune de ces deux unités. Chacune de ces deux unités présente un enrichissement en ÉTRL ainsi qu’un rapport La/Yb relativement plus grand que ce qui est typiquement observé dans la Formation de Nepisiguit Falls. Les données géochimiques considérées conjointement à l’information provenant des unités adjacentes suggèrent que le Me"

Jan 1, 2006

By V. V. Severov, Z. Lafhaj

The flotation separation of salt type calcium minerals is problematic, due to the similarities in their formation properties and the same active Ca2+ related site for interaction with anionic collectors and similar physicochemical characteristics such as solubility, point of zero charge, surface speciation, Ca-site density. The work was performed to achieve effective and selective separation of the calcium-minerals using pure minerals samples: four calcite, two fluorite, and two apatite samples. The effect of pure and mixing anionic collectors such as oleic and linoleic acid to different ratio (2:1; 1:1; 1:2) as well as the role of nonionic collectors on the selective separation of Ca minerals were studied. All flotation tests were performed in self-aspirated flotation cell. The results obtained with the blend of anionic collectors with the molar ratio of 2:1 show a separation between apatite and calcite at pH 5 and a ratio 1:2 at pH 9. The enhancing of separation contrast using the sodium silicate as a depressant for calcite and apatite is also examined as a function of oleate/linoleate ratio. Additionally, this paper discusses the enhancing of the selective separation of Ca minerals when anionic collectors were blended with nonionic reagents. The surface reactions in aqueous mineral suspensions and the adsorption of anionic collectors blended with nonionic reagents were studied by FTIR spectroscopy. An unexpected synergistic effect was observed for some ratios between anionic and nonionic reagents. The mixture of fatty acids and nonionic reagent showed very high flotation efficiency in comparison with fatty acid alone for the flotation of an igneous low-grade phosphate ore.

Jan 1, 2016

By A. Aaltonen, S. Paloranta, H. Myllykangas

A property based dynamic model of flotation was built and validated for training purposes. The model is based on the work of the AMIRA P9 project. The recovery of each particle with composition and size is calculated in a given simulation step. The model takes into account machine and operational parameters such as air flowrate and froth height. The model was created using fullscale test data on Pyhlisalmi Cu-Zn-pyrite ore with flotation kinetics of multiphase particles determined. Simulation and validation shows that model can predict the dynamic behavior of the process accurately enough for training purposes.

Jan 1, 2009

By K. C. Grogan

"GeneralGIANT ORE is complex, with the gold values for the most part occurring in extremely close association with arsenopyrite, stibnite, jamesonite, and a wide group of antimonial minerals locally termed 'the grey minerals'. Pyrite is the most abundant of the sulphide minerals• and minor quantities of chalcopyrite, galena, and sphalerite also occur. Pyrrhotite has been found in some sections of the mine, but to date none of it has been nickeliferous. Native gold occurs in varying amounts throughout the ore bodies.In 1944, ore dressing investigations were commenced on diamond-drill core rejects and samples of surface outcrop ore. Results soon indicated that treatment to produce satisfactory recovery of the gold values would involve fine grinding to 80-85 per cent minus 200 mesh, recovery of free gold by jigs, followed by flotation, roasting of the flotation concentrate, and subsequent cyanidation of the calcine. Proceeding from this information, the flow-sheet was prepared, plant design worked out, equipment purchased, and construction of the treatment plant commenced in May, 1947.The crushing, grinding, and flotation units of the plant were rushed to completion and commenced operation on May 12th, l.948, at 225 tons of ore per day. This rate was maintained until January 27th, 1949, when the Allis-Chalmers roaster and cyanide plants were completed and commenced operation. During the period May 12th, 1948, to January 27th, 1949, gold recovered by amalgamation was the sole source of revenue. Flotation concentrate was stockpiled pending the completion of the Allis~Chalmers roaster and cyanide plants."

Jan 1, 1953

By W. W. Rudolph, L. N. Trevani, P. R. Tremaine

UV-visible spectroscopy, Raman spectroscopy, and vibrating tube densimetry have been used in our laboratory to determine equilibrium constants of aqueous species at temperatures as high as 325 °C. The UV-visible and Raman spectra of solutions containing metal complexes and ionized acids or bases can be used to yield formation constants by applying curve fitting methods to resolve the contribution of each species. Colorimetric pH indicators identified by Johnston and coworkers at the University of Texas (Austin) provide an alternative means of determining ionization constants and the pH of complex mixtures. High precision density measurements over the same range yield standard partial molar volumes, which are key parameters for "equations of state" for aqueous species. Examples are given for the copper-ammonia system, simple carboxylic acids, and the iron-sulphate system.

Jan 1, 2004

By V. G. Papangelakis, G. A. Moldoveanu

"One of the major commercially viable secondary sources of rare earths elements (REE) are the ion-adsorption ores, containing 0.05-0.3 wt% rare earth oxides physically adsorbed on the surface of clay minerals formed during weathering of lanthanide-rich rocks. Although ion-adsorption deposits are substantially lower grade than other types of rare earth sources, this is offset by the easier mining and processing costs and the low content of radioactive elements. The conventional extraction route involves ion exchange leaching with monovalent cation solutions (usually ammonium sulphate) under ambient conditions; during the process, the lanthanides are desorbed and transferred into solution, being replaced by the exchange cation. While ammonium ions are known to perform best, there is increased environmental motivation to investigate alternative lixiviants in order to minimize ammonium sulphate impact via reducing its use without considerable loss in rare earth recovery.The objective of the present research was to screen various cations salts (alkaline and alkalineearth metals present as sulphates, chlorides and acetates, respectively) in order to comparatively evaluate lanthanide desorption levels and provide a theoretical base of the observed behaviour. The overall aim is to gain a better understanding of how both cation and anion may affect the overall REE recovery from ores in order to provide alternative processing routes. The distinct exchange capabilities of cations were explained in terms of differences in cation hydration enthalpy within the same group, i.e. Cs+ > NH4 + > K+ > Na+ > Li+ and Ba2+ > Ca2+ > Mg2+. For the same cation, it was determined that REE extraction efficiency follows the order sulphate > acetate > chloride, based on dissimilarities in constants of formation values. Various process implications scenarios will be described based on using mixed cations and anion matrices."

Jan 1, 2016

By V. G. Papangelakis, S. Peters

Pressure oxidation of refractory gold ores can be conducted on ores with high carbonate content using just water or water with alkaline reagents to promote fast kinetics, and suppress the formation of elemental sulphur and CO2. In this work, a fundamental study was conducted to explore the silica-pyrite interaction in the presence of calcium and sodium carbonate. It was found that an alkaline environment increases the pyrite decomposition kinetics on one hand, but on the other dissolves silica, which encapsulates the dissolving pyrite thus hindering ultimately its complete decomposition.

Jan 1, 2011

By R. K. Collings

"This paper summarizes research that was done at the Mines Branch, Ottawa, to evaluate samples of phosphogypsum for gypsum products manufacture. The samples were from phosphate fertilizer facilities at: Port Maitland, Ontario ; Valleyfield, Quebec; and Fort Saskatchewan and Redwater, Alberta. All samples were wet-screened, washed, filtered and calcined in a laboratory kettle at atmospheric pressure. Tests were also made at higher pressures in a small autoclave. The gypsum and resulting hemi-hydrate, being acidic, were treated before, during and after calcining with various bases. The hemi-hydrate products were checked for time of set, compressive strength and bond to gypsum wallboard paper. The results of this study indicate that phosphogypsum from each of the sources investigated has potential as a substitute for mined gypsum in gypsum products manufacture. Pilot-scale testing is recommended to confirm that the product would be satisfactory for the manufacture of plaster products on a commercial basis."

Jan 1, 1972

?NWCC has the highest number of Aboriginal students of any post secondary institution in BC and the region served includes 25 bands ? Chair of the Board of Governors is Irene Seguin (Hagwiloo K?am Saxwhl Giis) from Gitwinksihlkw ? FN council ? 39 First Nations Members * focus is to develop policy recommendations to increase student success rates

May 1, 2009

By A. Warczok

Chalcocite concentrate obtained by magnetic separation and flotation of Bessemer matte is processed in the Inca top blowing bottom stirring MK reactor into semi-blister copper. The semi-blister is then converted into blister copper in the multi-purpose vessels (MPV) by oxidation of iron, nickel and sulphur. High melting point NiO and Fe30 4 are formed inside the MPV s, which together with Cu20 and smaller amount of fayalite are the major constituents of the solid mush. The accumulation of solid mush and buildup requires periodic MPV cleaning by adding reductant and copper-nickel matte, a unique process called "washout". Various reductants and their combinations, such as pig-iron, 15%Si Ferro-silicon and 50%Si Ferro-silicon, have been used for the reduction of solid mush and buildup. The possibilities of using calcium carbide as a reductant and slagging flux were examined experimentally at the crucible scale. The rate of reduction of MPV buildup was determined by continuous measurement of CO and C02 contents in the offgas and the flowrate of argon carrier gas. The rate of the buildup reduction with calcium carbide was approximately five times faster than the rate of reduction with coke. Additionally, the formation of CaO results in the melting of reduced buildup and formation of a slag at 1300°C and higher temperatures. It was found that simultaneous silica addition enhanced the melting and slag formation. The results showed the strong dependence of the reduction rate on temperature. Activation energy is approximately 225 kJ/mol. Expected benefits of using calcium carbide are related to cost saving on reductant, significant acceleration of solid mush reduction, and reduced amount iron input from reductant.

Jan 1, 2007

By L. C. S. Dharmasiri, S. M. Shin, A. Senaputra, J. S. Sohn, K. H. Park, J. Avraamides

Reducing agents can be applied to leach metal values from natural and secondary resources such as laterite ores and deep sea manganese nodules and recycled materials such as spent batteries / catalysts which contain high-valent metal oxides of manganese, cobalt and iron. Selective leaching of some metals can be achieved by selecting conditions to control the saturated solubility and dissolution rates of metals from oxides or mixed metal/oxide matrices. The leaching results are rationalized on the basis of chemical species, Eh-pH diagrams and heterogeneous kinetic models. The role of reducing agents such as hydrogen peroxide, sulfur dioxide and iron(II) sulphate, in acid, alkali and in the presence of complexing ligands such as ammonia for the improvement of the leaching of metal oxides and metals is discussed. Previous studies on acid leaching of metals from nickel laterites, manganese nodules and spent catalysts/batteries in the absence or presence of reducing agents show that the rate controlling step involves the diffusion of protons through a thickening product layer on the particle being leached. It is shown that the leaching of nickel and cobalt from manganese nodules and zinc-carbon batteries in ammoniacal sulphur dioxide solutions also obey shrinking core kinetics.

Jan 1, 2014

By G. W. Smith

"The adsorption of dehydroabietylamine acetate on quartz, hematite, rutile and baddeleyite has been deter-mined for concentrations ranging from 0.3 to 5,600 µ. moles/I and for pH values ranging from 2.5 to 10.5.The surface tension, UV and IR spectra, equivalent conductance and ion concentrations for dehydroabiety lamine acetate solutions have been determined.Contact-angle and flotability studies have established that good collection may be obtained with this amine but that selectivity depends on the suitable use of depressants for some of the minerals."

Jan 1, 1971

By A Walker

The presence of high noise levels in many industries, together with the fact that countries are becoming increasingly concerned with the health of its citizens, has contributed to the importance of the problem of hearing loss. This problem has become the focus of scientific research, law and medicine, and the object of this thesis is to present the means whereby noise may be detected, with its resulting effects and possible means of control, in mining operations. 0BJECTIONABLE noise is a particularly prevalent by-product of the mining industry, and, al-though a dangerous noise level has been recognized, it is believed that at no time now, or in the future, will it be possible to enumerate a single over-all decibel figure at which hearing impairment will oc-cur. Individual susceptibility must be recognized in any study of occupational loss of hearing aimed at the setting of standards and criteria for industrial noise control.

Jan 1, 1963

By R. M. de Carvalho

Empirical and phenomenological models of SAG and AG mills have dominated the scene for the last few decades, being used nearly every time a mill is scale-up or an attempt is made to improve its performance. However, in spite of their success, these models fail to describe the details of both the grinding environment and the breakage mechanisms. The result is a generally good track record, with a few ? but very important ? instances when these models fall short in their predictions, which can be very costly. Further, nearly all of these models require detailed calibration to industrial and pilot plant data, being costly in their application, although still with limited predictive capabilities. Recognizing these challenges, a new model framework has been proposed which overcomes the limitations of currently used models by coupling the microscale population balance model, the discrete element model and functions that describe internal classification at the mill grate. This model framework has already been applied to describe breakage in ball mills, with showing very promising results. However, in the case of SAG and AG mills a much greater level of complexity is involved in the model, given the interaction between the mechanical environment that is formed totally or, in part, by the ore itself, and the breakage response in the mill. The paper describes the model framework, demonstrating how it can address appropriately effects such as mill speed, mill filling and size distribution, on the response from the mill. Some of the advantages of the model are related to its intrinsic multi-component and dynamic nature, which allows simulating appropriately mixtures of ores of different competences in a transient manner.

Jan 1, 2012

By The Staff

Introduction It is the purpose of this paper to discuss a number of the metallurgical improvements in the technology of copper-nickel ore treatment which have been introduced during recent years in the plants of ?the International Nickel Company of Canada, Limited. In common with other ore treatment processes, the procedure for extracting nickel and copper is changing almost continuous! y. These changes are necessitated by reason of changes in ore grades and characteristics, rising material and labour charges, and the constant drive to maximize metal recovery and to minimize production costs. It is not possible to present a comprehensive list of all the changes made, and only a selected number of the improvements in the milling, smelting, and refining operations are covered. It should be clearly understood that some phases of the procedures described have been pioneered by others in kindred fields and due acknowledgment is given to their foresight and efforts. Articles have been published over the years describing the operations of the International Nickel Company plants and the reader is referred to the Engineering and Mining Journal, Vol. 130, No. 9, November 10th, 1930, and to the Canadian Mining Journal, Vol. 58, No. 11, November, 1937, and Vol. 67, No. 5, May, 1946. Other references are the Transactions of this Institute, 1932, 1938, and 1946; Metals Technology, American Institute of Mining and Metallurgical Engineers, February, 1938, and Canadian Chemistry and Process Industries, April, 1940.

Jan 1, 1948

By M. Piboule et J. M . Charbonneau, C. Picard

In the western part of the Chapais syncline (Abitibi-east, Quebec), the lava flows belonging to the Haliy Formation separate in two distinct sequences. The basal sequence contains prophyri tic metabasalts of calc-alkaline af f inity overlain by porphyritic metatrachyandesites and metatrachytes of alkaline to shoshonitic affinity. The upper sequence contains porphyritic metabasalts similar to those of the basal sequence along with highly potassic metaandesites trending to a subalkaline affinity. A geochemical study of trace and REE elements established that the composition of these lava flows results from a mixing or contamination process. The primitive tholeiitic liquids which are enriched in LREE were modified by the addition of a crustal contaminant enriched in Y, Zr, Th and K20. The magmatic liquids resulted from successive steps in the admixing process, evolved by fractionated crystallization. The mechanism of gradual admixing seems to be the major cause of the observed ea le-alkaline characteris ties and may also be the cause of the alkaline to shoshoni tic affinity in those lavas. The tendency to differentiation by fractional crystallization reveals the tholeiitic character of the primitive liquids.

Jan 1, 1984

Adsorption of guar gum was investigated on model minerals typically found in water-insoluble slimes of potash ores. The ionic strength of the adsorption mixtures was varied from distilled water to saturated NaC1 and KC1. The tests were also performed using a saturated brine. The adsorption density of guar gum on illite, dolomite, and kaolinite was found to be not only a function of total ionic strength but also of the type of electrolyte present in solution. Generally, the adsorption of the polymer on the clay minerals was higher in KC1 solutions than in NaCI, but the differences gradually disappeared when the electrolyte concentration approached saturation. The results were analyzed in terms of chaotropic (K ) or kosmotropic (Na') properties of background counter-ions and their different behaviors at the hydrated mineral-water interface. Guar gum adsorption on dolomite was related to the presence of calcium and magnesium sites on the mineral surface, and to the cis-configuration of OH groups of mannose units. Based on viscosity measurements, it was suggested that guar gum macromolecules form entanglements in NaCI solutions (and distilled water), but individual molecules exist in KC1 solutions thus creating different modes of adsorption of guar gum from concentrated NaCl and KCl solutions.

Jan 1, 2006

By N. Saracoglu, J. P. Golightly, R. H. Wallis, J. J. Brummer

"The McClean uranium deposits are located 11 km west northwest of the Rabbit Lake Mine. Their average grade is 1.8 % U3O8 , and they contain 6. 350 tonnes of uranium oxide in seven pods of variable grade and mineral assemblage. They are hosted by both basal Athabasca Group and the regolith developed on the underlying crystalline basement. The major mineral facies are: sulphide, arsenide, 'bleached', and hematite, with the important uranium minerals being coffinite, uraninite and pitchblende. Abundances of carbon and sulphur isotopes are consistent with their derivation from pyritic graphite in basement gneisses. Isotopes of oxygen and hydrogen suggest equilibration at temperatures of about 200°C. Ar39/ Ar40 age determination of illite associated with ore suggest mineralization began about 1300 m.y. ago and that significant alteration had ceased by about 1170 m.y. ago though Pb/ U data suggest the deposits continued to evolve into the Mesozoic.IntroductionThe McClean deposits lie on the eastern side of the Athabasca Basin of northern Saskatchewan where they are part of a cluster of uranium deposits lying west of Wollaston Lake (Fig. 1). The general stratigraphy is schematically portrayed in Figure 2 which emphasizes that mineralization is hosted by both the Athabasca Group and the underlying regolith and also that the deposits are preserved at depth and have not suffered from preand post-Pleistocene weathering and erosion. This circumstance, combined with their simple shape and the presence of seven separate zones of mineralization (pods) allows a description, based on over 450 fully cored drill holes, to be made of the wide variation in chemistry, grade, alteration patterns and position relative to the sub-Athabasca Group unconformity. Ar39 / Ar40 age determinations have been made of illites associated with regolith, Athabasca Group and mineralization and studies are in progress on C, S, 0 and H isotopes of mineralized material and host rocks. Only some of these data have been published; Brummer et al., (1981); Golightly et al., (1982); Bray et al., (1982); and Saracoglu et al., (1983). The only other published data on McClean geology are by Tremblay (1982, 1983)."

Jan 1, 1986

By Arnaud Faucher, Amar Sabih, Sudarshan Martins, Tristan Martin, Sami Makni, Peter Radziszewski, Poorya Hosseini, Francois-Raymond Boyer

The measurement of acoustic signals produced by a tumbling mill has been previously used to determine the operating state of the mill and correlate the variations of the sound intensity with the operating conditions of the mill. Separately, the discrete element model (DEM), a software simulation of the mill, was developed to provide insight into the operation of the mill. Presently, there has not been much work reconciling the DEM simulation of the mill with the acoustic signal. Working from basic principles of linear, time-invariant systems, agreement between an acoustic DEM simulation and the measured signal is sought. First, the impulse response function of the mill is measured. The DEM provides the forces applied to the mill shell as a function of time. A convolution of these simulated shell forces and the transfer function gives the simulated acoustic signal. This signal is compared to the measured acoustic signal, both in the time domain and the frequency domain. Finally, a discussion of the results is given.

Jan 1, 2012